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    • 32. 发明授权
    • Use of Ta-capped metal line to improve formation of memory element films
    • 使用钽盖金属线改善记忆元素膜的形成
    • US07288782B1
    • 2007-10-30
    • US11251291
    • 2005-10-14
    • Steven C. AvanzinoAmit P. Marathe
    • Steven C. AvanzinoAmit P. Marathe
    • H01L47/00
    • H01L21/76843H01L21/76852H01L27/2463H01L45/085H01L45/1233H01L45/14H01L45/146H01L45/16
    • Disclosed are methods for deposition of improved memory element films for semiconductor devices. The methods involve providing a hard mask over an upper surface of a metal line of a semiconductor substrate where vias are to be placed, recess etching the mask substantially in all upper surfaces except where vias are to be placed, depositing a Ta-containing capping layer over substantially all the metal line surfaces except the surface where vias are to be placed, polishing the Ta-containing capping layer to produce a damascened Ta-containing cap while exposing the metal line at the via forming surface, depositing a dielectric layer, patterning the dielectric layer to form a via, and depositing memory element films. The improved Ta—Cu interface of the subject invention mitigates and/or eliminates lateral growth of memory element films and copper voiding under the dielectric layer at the top surface of the metal line, and thereby enhances reliability and performance of semiconductor devices.
    • 公开了用于沉积用于半导体器件的改进的存储元件膜的方法。 所述方法包括在要放置通孔的半导体衬底的金属线的上表面上提供硬掩模,基本上在除了要放置通孔之外的所有上表面中蚀刻掩模,沉积含Ta的覆盖层 在除了要放置通孔的表面之外的基本上所有的金属线表面上,抛光含Ta的封盖层,以在露出金属线在通孔形成表面的同时产生一个镶嵌的含Ta盖,沉积介电层, 电介质层以形成通孔,以及沉积存储元件膜。 本发明的改进的Ta-Cu界面缓和了和/或消除了金属线顶表面下的介质层下存储元件膜的横向生长和铜空隙化,从而提高了半导体器件的可靠性和性能。
    • 36. 发明授权
    • Use of an alloying element to form a stable oxide layer on the surface of metal features
    • 使用合金元素在金属表面上形成稳定的氧化物层
    • US06717266B1
    • 2004-04-06
    • US10175393
    • 2002-06-18
    • Amit P. MaratheDarrell M. Erb
    • Amit P. MaratheDarrell M. Erb
    • H01L2348
    • H01L23/53238H01L21/76886H01L21/76888H01L2924/0002H01L2924/00
    • The electromigration resistance of planarized metallization patterns, for example copper, inlaid in the surface of a layer of dielectric material, is enhanced by a process comprising blanket-depositing on the planarized, upper surfaces of the metallization features and the dielectric layer at least one alloying layer comprising at least one alloying element for the metal of the features, and diffusing the at least one alloying element within the metallization features to effect alloying therewith. The at least one alloying element diffused within the metallization features, under conditions wherein an oxide layer forms on the surface of the metallization features, forms a stable oxide layer on the surface of the metallization features. The stable oxide layer reduces electromigration from the metallization features along the oxide layer.
    • 通过包括在金属化特征和电介质层的平坦化的上表面上覆盖沉积至少一种合金化的方法来增强镶嵌在介电材料层的表面中的平坦化金属化图案(例如铜)的电迁移阻力 该层包括用于特征金属的至少一个合金元素,并且将金属化特征内的至少一个合金元素扩散以实现与其的合金化。 在其中在金属化特征的表面上形成氧化物层的条件下,在金属化特征内扩散的至少一种合金元素在金属化特征的表面上形成稳定的氧化物层。 稳定的氧化物层减少沿着氧化物层的金属化特征的电迁移。