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31. 发明授权

US4725656A Process for producing olefin polymers 失效
标题翻译：生产烯烃聚合物的方法
公开(公告)号：US4725656A
公开(公告)日：1988-02-16
申请号：US783816
申请日：1985-10-07
申请人： Norio Kashiwa , Akinori Toyota , Mamoru Kioka
发明人： Norio Kashiwa , Akinori Toyota , Mamoru Kioka
IPC分类号： C08F4/00 , C08F4/46 , C08F4/60 , C08F4/64 , C08F4/658 , C08F10/00 , C08F4/52 , C08F10/02 , C08F10/06
CPC分类号： C08F10/00
摘要： A process for producing a polymer or copolymer of an olefin which comprises polymerizing or copolymerizing at least one olefin with or without a diolefin in the presence of a catalyst composed of (A) a magnesium-containing solid titanium catalyst component containing magnesium, titanium, a halogen and an electron donor as essential ingredients and (B) an organoaluminum compound catalyst component; characterized in that(1) said catalyst further comprises (C) an organic silicon compound catalyst component having an Si-O-C or Si-N-C bond, and(2) said electron donor in the catalyst component (A) is selected from the group consisting of a cyclic mono- or poly-ester such as, diethyl cyclohexene-1,2-dicarboxylate, diethyl furane-3,4-dicarboxylate, di-isobutyl pyrrole-2,3-dicarboxylate, diethyl cyclohexene-1,6-dicarboxylate, di-n-propyl 1,2-benzenediacetate, and n-butyl tetrahydrothiophene-2,3-dicarboxylate.
摘要翻译：一种制备烯烃的聚合物或共聚物的方法，其包括在由（A）含镁的固体钛催化剂组分（含有镁，钛，金属和/或氧化物）的催化剂存在下聚合或共聚至少一种烯烃或不与二烯烃共聚卤素和电子给体作为必要成分，（B）有机铝化合物催化剂组分; 其特征在于，（1）所述催化剂还包含（C）具有Si-OC或Si-NC键的有机硅化合物催化剂组分，和（2）催化剂组分（A）中的所述电子给体选自环己基-1,2-二羧酸二乙基酯，呋喃-3,4-二羧酸二乙酯，二异丁基吡咯-2,3-二羧酸二乙酯，环己烯-1,6-二羧酸二乙酯， 1,2-苯二乙酸二正丙酯和四氢噻吩-2,3-二甲酸正丁酯。

32. 发明授权

US4490513A Process for producing polymers or copolymers of olefins containing at least three carbon atoms and catalysts therefor 失效
标题翻译：制备含有至少三个碳原子的烯烃的聚合物或共聚物的方法及其催化剂
公开(公告)号：US4490513A
公开(公告)日：1984-12-25
申请号：US836056
申请日：1977-09-23
申请人： Syuji Minami , Akinori Toyota , Norio Kashiwa
发明人： Syuji Minami , Akinori Toyota , Norio Kashiwa
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/04 , C08F4/02
CPC分类号： C08F10/00 , Y10S526/906
摘要： A process for producing a polymer or copolymer of an olefin containing at least 3 carbon atoms which comprises polymerizing or copolymerizing at least one olefin containing at least 3 carbon atoms, or copolymerizing the olefin with to 10 mole % of ethylene and/or a diolefin in the presence of a catalyst composed of (A) a magnesium-containing solid titanium catalyst component and (B) an organometallic compound of a metal of Groups I to III of the periodic table; wherein the solid titanium catalyst component (A) is a composition formed by contacting(i) a reaction product of an organic magnesium compound containing magnesium directly bonded to at least one carbon atom with an organic silicon-containing compound selected from the group consisting of organic silanols containing at least one hydroxyl group directly bonded to silicon and organopolysiloxanes,(ii) an organic acid ester, and(iii) a titanium compound.
摘要翻译：一种制备包含至少3个碳原子的烯烃的聚合物或共聚物的方法，其包括聚合或共聚至少一种含有至少3个碳原子的烯烃，或将烯烃与10摩尔％的乙烯和/或二烯烃共聚存在由（A）含镁固体钛催化剂组分和（B）元素周期表第I至III族金属的有机金属化合物组成的催化剂; 其中所述固体钛催化剂组分（A）是通过使（i）含有与至少一个碳原子直接键合的镁的有机镁化合物的反应产物与选自有机基团的有机含硅化合物含有至少一个与硅和有机聚硅氧烷直接结合的羟基的硅烷醇，（ii）有机酸酯，和（iii）钛化合物。

33. 发明授权

US4395519A Physically blended propylene polymer composition 失效
标题翻译：物理混合丙烯聚合物组成
公开(公告)号：US4395519A
公开(公告)日：1983-07-26
申请号：US196550
申请日：1980-10-14
申请人： Syuji Minami , Norio Kashiwa , Akifumi Kato , Junichi Watanabe
发明人： Syuji Minami , Norio Kashiwa , Akifumi Kato , Junichi Watanabe
IPC分类号： C08L23/10 , C08L23/16 , C08L23/06 , C08L23/12
CPC分类号： C08L23/10 , C08L23/16 , Y10S2/918
摘要： A physically blended propylene polymer composition composed of(A) 100 parts by weight of crystalline polypropylene containing 0 to 10 mole % of ethylene and/or another .alpha.-olefin,(B) 1 to 30 parts by weight of a propylene/ethylene random copolymer composed of 30 to 85 mole % of propylene, said copolymer containing 0 to 10 mole % of a diene component and having (i) a micro-isotacticity of at least 0.8 and (ii) a boiling n-cyclohexane insolubles content of 0 to 10% by weight, and(C) 0 to 30 parts by weight of polyethylene containing 0 to 15 mole % of an .alpha.-olefin,said components (A) and (B) having been physically mixed with each other.
摘要翻译：由（A）100重量份含有0-10摩尔％乙烯和/或另一个α-烯烃的结晶聚丙烯组成的物理混合丙烯聚合物组合物，（B）1至30重量份丙烯/乙烯无规共聚物由30至85摩尔％的丙烯组成，所述共聚物含有0至10摩尔％的二烯组分，并且具有（i）至少0.8的微全同立构规整度和（ii）沸点的n-环己烷不溶物含量为0至10 （C）0〜30重量份含有0〜15摩尔％α-烯烃的聚乙烯，所述成分（A）和（B）彼此物理混合。

34. 发明授权

US4370455A Process for polymerizing or copolymerizing olefins 失效
标题翻译：烯烃聚合或共聚方法
公开(公告)号：US4370455A
公开(公告)日：1983-01-25
申请号：US101470
申请日：1979-12-10
申请人： Takashi Ueda , Syuji Minami , Mamoru Kioka , Norio Kashiwa
发明人： Takashi Ueda , Syuji Minami , Mamoru Kioka , Norio Kashiwa
IPC分类号： C08F4/00 , C08F4/60 , C08F10/00 , C08F4/02
CPC分类号： C08F10/00
摘要： In a process for producing a polymer or copolymer of an alpha-olefin which comprises continuously polymerizing or copolymerizing the alpha-olefin or the alpha-olefin with up to 5 mole % of a diolefin in the presence of a catalyst comprising a transition metal catalyst component and an organoaluminum catalyst component, the improvement wherein:(I) said polymerization or copolymerization is carried out in the presence of a catalyst composed of (A) a solid magnesium compound obtained by reacting (i) an adduct between a magnesium halide and an electron donor, with (ii) an organometallic compound of a metal of Groups I to III of the Mendelejeff's periodic table, (B) a liquid transition metal compound, and (C) an organoaluminum compound, and(II) said continuous polymerization or copolymerization is carried out while feeding the compound (B) separately from the other compounds (A) and (C) into a polymerization or copolymerization zone.
摘要翻译：在制备α-烯烃的聚合物或共聚物的方法中，其包括在包含过渡金属催化剂组分的催化剂存在下，使α-烯烃或α-烯烃与至多5摩尔％的二烯烃连续聚合或共聚和有机铝催化剂组分的改进，其中：（I）所述聚合或共聚在催化剂存在下进行，所述催化剂由（A）通过（i）卤化镁和电子之间的加合物反应获得的固体镁化合物（ii）Mendelejeff周期表第I至III族金属的有机金属化合物，（B）液体过渡金属化合物和（C）有机铝化合物，和（II）所述连续聚合或共聚是在将化合物（B）与其它化合物（A）和（C）分开地进料到聚合或共聚区中的同时进行。

35. 发明授权

US4330649A Process for producing olefin polymers or copolymers 失效
标题翻译：生产烯烃聚合物或共聚物的方法
公开(公告)号：US4330649A
公开(公告)日：1982-05-18
申请号：US159440
申请日：1980-06-13
申请人： Mamoru Kioka , Hiroaki Kitani , Norio Kashiwa
发明人： Mamoru Kioka , Hiroaki Kitani , Norio Kashiwa
IPC分类号： C08F4/00 , C08F4/02 , C08F4/44 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/04
CPC分类号： C08F10/00 , C08F4/022
摘要： Improved process for producing olefin polymer or copolymer characterized by using (I) a solid catalyst component (A) which is he product of reaction of (a) a magnesium compound in the liquid state having no reducing ability with (b) a titanium compound in the liquid state in the presence of an electron donor having no active hydrogen, said magnesium compound (a) being a liquid magnesium compound or a solution of a magnesium compound or being obtained by contacting the magnesium compound with at least one electron donor selected from the group consisting of alcohols, organic carboxylic acids, aldehydes, amines and mixtures thereof, or the product of reaction of the magnesium compound (a) with the titanium compound (b) in the absence of the electron donor having no active hydrogen atom followed by treatment with the electron donor having no active hydrogen atom, and (II) the mole ratio of the compound (a) to the compound (b), calculated as metal atoms, is at least about 2.
摘要翻译：改进的制备烯烃聚合物或共聚物的方法，其特征在于使用（I）作为（a）不具有还原能力的液态的镁化合物与（b）钛化合物的反应的固体催化剂组分（A）在没有活性氢的电子给体的存在下的液态，所述镁化合物（a）是液体镁化合物或镁化合物的溶液，或通过使镁化合物与至少一种电子给体接触而获得，所述电子给体选自或由镁化合物（a）与钛化合物（b）在不存在不具有活性氢原子的电子给体存在下进行反应的反应产物，然后进行处理的产物如醇，有机羧酸，醛，胺及其混合物电子给体不具有活性氢原子，和（II）以金属原子计算的化合物（a）与化合物（b）的摩尔比为至少约2。

36. 发明授权

US4076924A Process for polymerization or copolymerizing olefins containing at least 3 carbon atoms 失效
标题翻译：聚合或共聚含有至少3个碳原子的烯烃的方法
公开(公告)号：US4076924A
公开(公告)日：1978-02-28
申请号：US608278
申请日：1975-08-27
申请人： Akinori Toyota , Kiyoshi Odawara , Norio Kashiwa
发明人： Akinori Toyota , Kiyoshi Odawara , Norio Kashiwa
IPC分类号： C08F4/02 , C08F10/00 , C08F10/06
CPC分类号： C08F10/00 , C08F4/022
摘要： A process for preparing a highly stereoregular olefin polymer or copolymer in high yield and with good reproducibility of quality and yield, which comprises polymerizing or copolymerizing an olefin containing at least 3 carbon atoms in the presence of a catalyst comprising(a) a solid titanium catalyst component obtained by reacting a solid magnesium component with a titanium compound in the absence of a free organometallic compound of a metal of Groups I to III of the periodic table and separating the solid component of the resulting reaction product, said magnesium component being obtained by separating a solid from a suspension of a reaction product derived from (i) a magnesium dihalide, (ii) an active hydrogen-containing organic compound, (iii) an organic acid ester and (iv) an organometallic compound of a metal of Groups I to III of the periodic table, and(b) an organometallic compound of a metal of Groups I to III of the periodic table.
摘要翻译：一种以高产率制备高度立构规整的烯烃聚合物或共聚物的方法，具有良好的质量和产率的再现性，其包括在催化剂存在下聚合或共聚含有至少3个碳原子的烯烃，所述催化剂包含（A）A固体钛酸盐催化剂通过在元素周期表I至III族的金属的自由有机化合物的残留物中反应固体镁组分而获得的组分，并分离所得反应产物的固体组分，所述镁组分通过分离衍生自（i）二卤化镁的反应产物的悬浮液的固体，（ii）含活性氢的有机化合物，（iii）有机酸酯和（iv）第I族金属的有机金属化合物 III，和（B）周期表第I至III组的金属的有机化合物。

37. 发明授权

US07714087B2 Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof 有权
标题翻译：含极性基团的烯烃共聚物，其制备方法，含有共聚物的热塑性树脂组合物及其用途
公开(公告)号：US07714087B2
公开(公告)日：2010-05-11
申请号：US12153003
申请日：2008-05-12
申请人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
发明人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
IPC分类号： C08F232/08
CPC分类号： C08F297/02 , C08F4/65912 , C08F4/6592 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/08 , C08F210/14 , C08F210/16 , C08J5/18 , C08J2351/06 , C08J2371/02 , C08J2387/00 , C08L53/00 , C08L2666/02 , C09J153/00 , C08F4/65927 , C08F222/06 , C08F2500/03 , C08F2500/12 , C08F2500/09 , C08F216/00
摘要： A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
摘要翻译：含有金属或极性树脂的粘合性优异的极性基团的烯烃共聚物，与其相容性优异的共聚物的制备方法，含有共聚物的热塑性树脂组合物及其用途。含有极性基团的烯烃共聚物包含衍生自2〜20个碳原子的α-烯烃的结构单元，以及衍生自具有极性基团的直链，支链或环状极性基团单体的结构单元例如羟基或环氧基和/或衍生自大分子单体的结构单元，其末端具有通过阴离子聚合，开环聚合或缩聚获得的聚合物链段。含极性基团的烯烃共聚物可以通过在茂金属催化剂的存在下与含极性基团的单体和/或大分子单体进行聚合来制备。含有极性基团的烯烃共聚物和含有共聚物的热塑性树脂组合物用于薄膜，片材，改性剂，建筑/土木工程材料，汽车外饰件，电气/电子部件，涂料基料，相容剂等。

38. 发明申请

US20090137757A1 Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof 有权
标题翻译：含极性基团的烯烃共聚物，其制备方法，含有共聚物的热塑性树脂组合物及其用途
公开(公告)号：US20090137757A1
公开(公告)日：2009-05-28
申请号：US12153003
申请日：2008-05-12
申请人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
发明人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
IPC分类号： C08F4/44
CPC分类号： C08F297/02 , C08F4/65912 , C08F4/6592 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/08 , C08F210/14 , C08F210/16 , C08J5/18 , C08J2351/06 , C08J2371/02 , C08J2387/00 , C08L53/00 , C08L2666/02 , C09J153/00 , C08F4/65927 , C08F222/06 , C08F2500/03 , C08F2500/12 , C08F2500/09 , C08F216/00
摘要： A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
摘要翻译：含有金属或极性树脂的粘合性优异的极性基团的烯烃共聚物，与其相容性优异的共聚物的制备方法，含有共聚物的热塑性树脂组合物及其用途。含有极性基团的烯烃共聚物包含衍生自2〜20个碳原子的α-烯烃的结构单元，以及衍生自具有极性基团的直链，支链或环状极性基团单体的结构单元例如羟基或环氧基和/或衍生自大分子单体的结构单元，其末端具有通过阴离子聚合，开环聚合或缩聚获得的聚合物链段。含极性基团的烯烃共聚物可以通过在金属茂催化剂的存在下将α-烯烃与含极性基团的单体和/或大分子单体进行聚合来制备。含有极性基团的烯烃共聚物和含有共聚物的热塑性树脂组合物用于薄膜，片材，改性剂，建筑/土木工程材料，汽车外饰件，电气/电子部件，涂料基料，相容剂等。

39. 发明申请

US20090124760A1 POLYOLEFIN HYBRID POLYMER AND METHOD FOR MANUFACTURING THE SAME 审中-公开
标题翻译：聚烯烃混合聚合物及其制造方法
公开(公告)号：US20090124760A1
公开(公告)日：2009-05-14
申请号：US11995165
申请日：2006-07-11
申请人： Hideyuki Kaneko , Shinichi Kojoh , Nobuo Kawahara , Shingo Matsuo , Tomoaki Matsugi , Norio Kashiwa
发明人： Hideyuki Kaneko , Shinichi Kojoh , Nobuo Kawahara , Shingo Matsuo , Tomoaki Matsugi , Norio Kashiwa
IPC分类号： C08L39/04
CPC分类号： C08L23/02 , C08F255/00 , C08F255/02 , C08F293/00 , C08F293/005 , C08L51/006 , C08L51/06 , C08L53/00 , C08L2666/02 , C09J151/006 , C09J151/06 , C09J153/00 , C08L2666/24
摘要： It is an object to provide a new polyolefin hybrid polymer composed of a polyolefin segment and a polar polymer segment (Z) and a method for manufacturing the hybrid polymer by an industrially advantageous procedure.A polyolefin hybrid polymer composed of a polyolefin segment and a polar polymer segment (Z), wherein the polyolefin hybrid polymer is a modified compound of maleic polyolefin (A), is characterized by comprising a constitutional unit represented by the general formula (I): wherein Z represents a polar polymer segment obtained by polymerizing monomers of at least one kind selected from organic compounds having at least one carbon-carbon unsaturated bond, and F represents a group including an unsaturated bond.
摘要翻译：本发明的目的是提供一种由聚烯烃链段和极性聚合物链段（Z）组成的新的聚烯烃混合聚合物，以及通过工业上有利的方法制备杂化聚合物的方法。由聚烯烃链段和极性聚合物链段（Z）组成的聚烯烃杂化聚合物，其中所述聚烯烃杂化聚合物是马来聚烯烃（A）的改性化合物，其特征在于包含由通式（I）表示的结构单元： Z表示通过聚合选自具有至少一个碳 - 碳不饱和键的有机化合物中的至少一种的单体获得的极性聚合物链段，F表示包含不饱和键的基团。

40. 发明授权

US07488789B2 Propylene copolymer, polypropylene composition, and uses thereof, transition metal compounds and catalyst for olefin polymerization 有权
标题翻译：丙烯共聚物，聚丙烯组合物及其用途，过渡金属化合物和用于烯烃聚合的催化剂
公开(公告)号：US07488789B2
公开(公告)日：2009-02-10
申请号：US10550017
申请日：2003-12-26
申请人： Shigenobu Ikenaga , Keiji Okada , Hiroshi Hoya , Norihide Inoue , Naritoshi Hirota , Hiromu Kaneyoshi , Munehito Funaya , Koji Kawai , Nobuo Kawahara , Shinichi Kojoh , Norio Kashiwa , Ryoji Mori
发明人： Shigenobu Ikenaga , Keiji Okada , Hiroshi Hoya , Norihide Inoue , Naritoshi Hirota , Hiromu Kaneyoshi , Munehito Funaya , Koji Kawai , Nobuo Kawahara , Shinichi Kojoh , Norio Kashiwa , Ryoji Mori
IPC分类号： C08F210/06 , C08F210/08 , C08F4/6592
CPC分类号： C08F210/06 , C08F4/65927 , C08L23/142 , Y10S428/91 , Y10S526/943 , Y10T428/1328 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938 , C08L2666/06 , C08F210/08 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/26
摘要： A propylene/1-butene random copolymer containing 60 to 90 mol % of propylene units and 10 to 40 mol % of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5%, a molecular weight distribution of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point of from 40 to 75° C. and a crystallization rate at 45° C. of 10 minutes or less, and satisfying the following relation, 146 exp (−0.022M)≧Tm≧125 exp (−0.032M), and an olefin catalyst for preparation thereof.
摘要翻译：含有60〜90摩尔％的丙烯单元和10〜40摩尔％的1-丁烯单元的丙烯/ 1-丁烯无规共聚物，其三元组全同立构规整度为85％以上且97.5％以下，分子量分布为1〜3，特性粘度为0.1〜12dl / g，熔点为40〜75℃，结晶率为45℃为10分钟以下，满足以下关系： 146 exp（-0.022M）> = Tm> = 125exp（-0.032M），以及用于其制备的烯烃催化剂。

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