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    • 37. 发明专利
    • PRODUCTION OF HIGH-PURITY STAINLESS STEEL
    • JPS62139807A
    • 1987-06-23
    • JP28104585
    • 1985-12-16
    • NIPPON STEEL CORP
    • IKEHARA YASUMASAARIYOSHI HARUKIMORISHIGE HIROAKI
    • C21C7/00C21C5/00C21C7/04C21C7/068
    • PURPOSE:To produce a high-purity stainless steel contg. P and S at low ratios by refining a molten metal in a reaction vessel which can make oxygen blowing and stirring by using a low-phosphorus molten iron and Cr ore as a raw material and low-phosphorus lime as a fluxing agent and using a reducing agent essentially consisting of Al. CONSTITUTION:The low-phosphorus molten iron carburized by about 4% with graphite carbon is charged into a refining furnace such as AOD. O2 and Ar are blown from the bottom tuyeres into the furnace to oxidize and remove the C contained therein and to increase the temp. of the molten metal. The Cr ore and the low-phosphorus line which is a slag forming agent are added from the furnace top to the molten metal when the prescribed temp. is attained. The Cr ore and Al scrap contg. Ti scrap and Si scrap are charged as a reducing agent to the molten metal, by which Cr2O3 and FeO in the Cr ore are reduced and the CaO/Al2O3 in the molten slag is made 1-1.7. The molten slag is discharged and again the Cr ore and quick lime are added to the molten metal. the molten metal is then desiliconized by stirring the same by the gaseous Ar blown thereto. The high-purity ferritic stainless steel contg. P and S at low ratios and having an excellent weld crack resistant characteristic and stress corrosion resistant characteristic is produced. An austenitic stainless steel is obtd. if Ni is added to the raw material.
    • 38. 发明专利
    • NON-TILTING FURNACE OPERATING METHOD IN REFINING OF CHROMIUN STEEL
    • JPS61174306A
    • 1986-08-06
    • JP1501185
    • 1985-01-29
    • NIPPON STEEL CORP
    • ARIYOSHI HARUKIHIDAKA RYOICHIMORISHIGE HIROAKI
    • C21C5/28C21C7/00C21C7/068
    • PURPOSE:To detect quickly the [C] in the steel during refining of a Cr steel by changing over a mixed gas ratio in accordance with the predicted [C] while the [C] in the steel is in a prescribed range and determining the timing for changing over the next mixed gas ratio in accordance with the simultaneous analysis value of the C and S during blowing. CONSTITUTION:The mixed gas ratio is changed over in accordance with the predicted [C] while the [C] in the steel is between 0.7-0.05% in the decarburization refining stage of the molten Cr steel by an AOD furnace. The timing for the next change over of the mixed gas ratio is determined in accordance with the component analysis values obtd. by using a pin sampler during blowing and a simultaneous analyzer for [C] and [S]. More specifically, the temp. is measured and the sample is drawn by the pin sampler with the non-tilted furnace without interruption the supply of the gaseous O2 from the inside pipe of double tuyeres and the diluting gas at the predicted [C] value in the steel=0.25%. The ratio is immediately changed over to the O2 in the inside pipe/the diluting gas (Ar) ratio=1/2 and the refining is continued. The intendended change over to O2/Ar ratio=1/3 is made possible at the [C] value=0.12% in about 2min after the analysis values are known even if the actual [C] value is as low as 0.19% with respect to, for example, the predicted [C] value=0.25%.