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    • 33. 发明授权
    • Radiation sensitive resin composition
    • 辐射敏感树脂组合物
    • US06322949B2
    • 2001-11-27
    • US09739833
    • 2000-12-20
    • Mitsuhito SuwaHaruo IwasawaToru KajitaShin-ichiro Iwanaga
    • Mitsuhito SuwaHaruo IwasawaToru KajitaShin-ichiro Iwanaga
    • G03F7004
    • G03F7/0045G03F7/038G03F7/039Y10S430/115Y10S430/122Y10S430/128
    • A positive-tone or negative-tone radiation sensitive resin composition comprising (A) a photoacid generator represented by the following formula (1-1) or (1-2): wherein R1, R2, R5, and R6 are an alkyl group , R3 and R7 are a hydroxyl group or —OR4 (wherein R4 is an organic group), A1− and A2− indicate a monovalent anion, a and c denote an integer of 4-7, and b and d an integer of 0-7. The positive-tone resin composition further comprises (B1) an acid-cleavable group-containing resin or (B2) an alkali-soluble resin and an alkali solubility control agent, and the negative-tone radiation sensitive resin composition further comprises (C) an alkali-soluble resin and (D) a crosslinking agent. The resin compositions are highly sensitive and exhibit superior resolution and pattern forming performance.
    • 一种正色调或负色调辐射敏感性树脂组合物,其包含(A)由下式(1-1)或(1-2)表示的光酸产生剂:其中R1,R2,R5和R6是烷基, R3和R7是羟基或-OR4(其中R4是有机基团),A1-和A2-表示一价阴离子,a和c表示4-7的整数,b和d是0-7的整数 。 正色调树脂组合物还包含(B1)含有酸分解性基团的树脂或(B2)碱溶性树脂和碱溶性调节剂,负色调辐射敏感性树脂组合物还包含(C) 碱溶性树脂和(D)交联剂。 树脂组合物高度敏感,表现出优异的分辨率和图案形成性能。
    • 34. 发明授权
    • Radiation sensitive resin composition
    • 辐射敏感树脂组合物
    • US06180316B2
    • 2001-01-30
    • US09231762
    • 1999-01-15
    • Toru KajitaMitsuhito SuwaHaruo IwasawaMasafumi Yamamoto
    • Toru KajitaMitsuhito SuwaHaruo IwasawaMasafumi Yamamoto
    • G03F7004
    • G03F7/0395G03F7/0045G03F7/039Y10S430/106Y10S430/111
    • A radiation-sensitive resin composition which comprises, (A) a polymer containing, (a) a recurring unit (I) of the following formula (1):  or a recurring unit (I) of the formula (1) and a recurring unit (II) of the following formula (2),  and (b) a recurring unit (III) which is derived from a monomer having at least two polymerizable carbon—carbon double bonds by cleavage of the carbon—carbon double bonds, wherein the monomer has, in addition to said at least two polymerizable carbon—carbon double bonds, at least one acid-decomposable divalent group of the following formula (3) or (4),  said at least two polymerizable carbon—carbon double bonds being linked via the least one acid-decomposable divalent group of the formula (3) or (4), and (B) a photoacid generator.
    • 一种辐射敏感性树脂组合物,其包含(A)含有(a)下式(1)的重复单元(I)或式(1)的重复单元(I)的聚合物和重复单元 (II)和(b)通过裂解碳 - 碳双键衍生自具有至少两个可聚合碳 - 碳双键的单体的重复单元(III),其中单体 除了所述至少两个可聚合碳 - 碳双键之外,还具有至少一个下式(3)或(4)的可酸分解的二价基团,所述至少两个可聚合碳 - 碳双键经由 至少一个式(3)或(4)的酸可分解的二价基团,和(B)光酸产生剂。