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    • 36. 发明授权
    • Polysiloxane graft copolymer latex for strengthening textile structures
    • 用于加强纺织结构的聚硅氧烷接枝共聚物胶乳
    • US5278228A
    • 1994-01-11
    • US539762
    • 1990-06-18
    • Martin MatnerRaoul ReszHeinrich AlbertsVolker Damrath
    • Martin MatnerRaoul ReszHeinrich AlbertsVolker Damrath
    • C08F283/12C09J151/00C09J151/08D06M13/02D06M13/07D06M13/224D06M13/322D06M13/345D06M13/348D06M15/643D06M15/647C08L51/08
    • C08F283/122D06M15/643
    • A binder for textile structures which are graft copolymer latices in which the following are incroporated in the graft copolymer:(1) as graft substrate, from 40 to 70% by weight, of a polyorganosiloxane end blocked with hydroxyl groups as indicated in the following general formula ##STR1## wherein R.sup.1 denotes alkyl groups having 1 to 24 carbon atoms or aryl groups having 6 to 10 carbon atoms,R.sup.2 denotes divalent alkylene groups having 1 to 8 carbon atoms,R.sup.3 denotes alkyl groups having 1 to 24 carbon atoms, aryl groups, alkoxy groups having 1 to 6 carbon atoms or a hydroxyl group,R.sup.2 and R.sup.3 together with the silicon atom may form a 5 membered or 6 membered ring containing a trivalent unbranched or branched alkyl group having to 8 carbon atoms, anda stands for 80 to 99 mol %,b stands for 1 to 20 mol %, anda+b=100 mol %and the viscosity of the polymer determined at 25.degree. C. is from 100 to 100,000 mPa.s,(2) as grafted vinyl polymer, from 30 to 60% by weight, of styrene and/or .alpha.-methyl styrene, (meth)acrylic acid ester, (meth)-acrylonitrile or mixtures of these monomers and optionally one or more vinyl monomers of the general formula ##STR2## wherein R' denotes a hydrogen atom or a methyl group,R" denotes a alkyl group having 1 to 18 carbon atoms,Y denotes a hydrogen atom or the group OH or OR andZ denotes OH or ##STR3##
    • 用于织物结构的粘合剂是接枝共聚物胶乳,其中以下在接枝共聚物中被覆盖:(1)作为接枝基材,40至70重量%的用羟基封端的聚有机硅氧烷末端,如以下通式所示 式(*化学结构*)其中R1表示具有1至24个碳原子的烷基或具有6至10个碳原子的芳基,R 2表示具有1至8个碳原子的二价亚烷基,R 3表示具有1至24个碳原子的烷基 芳基,碳原子数为1〜6的烷氧基或羟基,R2和R3与硅原子一起形成含有8个碳原子的三价未支链或支链烷基的5元或6元环, 表示80〜99摩尔%,b表示1〜20摩尔%,a + b = 100摩尔%,在25℃下测定的聚合物的粘度为100〜100,000mPa.s,(2)为 接枝乙烯基聚合物,重量比为30至60% 芘和/或(α) - 甲基苯乙烯,(甲基)丙烯酸酯,(甲基)丙烯腈或这些单体的混合物和任选的一种或多种通式(* CHEMICAL STRUCTURE *)的乙烯基单体,其中R'表示 氢原子或甲基,R“表示碳原子数1〜18的烷基,Y表示氢原子或基团OH或OR,Z表示OH或(*化学结构*)
    • 39. 发明授权
    • Process for the production of high molecular weight polychloroprene and
its use as a starting material for adhesives
    • 用于生产高分子量聚氯丁二烯的方法及其用作粘合剂的起始材料
    • US4405742A
    • 1983-09-20
    • US280018
    • 1981-06-30
    • Rudiger MuschRudiger SchubartWilhelm GobelHeinrich AlbertsGerhard Hohmann
    • Rudiger MuschRudiger SchubartWilhelm GobelHeinrich AlbertsGerhard Hohmann
    • C08F36/18C09J3/12C08F2/24C08F2/38
    • C08F36/18
    • By adding substances corresponding to the following general formula I ##STR1## in which X=O, S or N--R.sub.5 ; R.sub.1 =hydrogen, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.19 -alkenyl, phenyl, C.sub.1 -C.sub.4 -alkylene phenyl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.5 -C.sub.12 -cycloalkenyl; R.sub.2 =hydrogen, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.12 -alkenyl, phenyl or C.sub.1 -C.sub.4 -alkylene phenyl; R.sub.3 =hydrogen, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.19 -alkenyl, phenyl, C.sub.1 -C.sub.4 -alkylene phenyl, acryl formyl or acetyl; R.sub.4 and R.sub.5 =same or different, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.19 -alkenyl, phenyl, C.sub.1 -C.sub.4 -alkylene phenyl, acryl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.5 -C.sub.12 -cycloalkenyl; R.sub.4 and R.sub.5 may also form a C.sub.4 -C.sub.7 -ring which may optionally contain an oxygen atom in ether form and the radicals R.sub.1 and R.sub.2 may form a C.sub.5 -C.sub.12 -alkylene bridge or a C.sub.5 -C.sub.12 -alkenylene bridge, the radicals R.sub.1 and R.sub.4 may form a C.sub.2 -C.sub.9 -alkylene bridge and the radicals R.sub.1 and R.sub.3 may form a C.sub.3 -C.sub.10 -alkylene bridge; where R.sub.1 and R.sub.2 are attached, the ring formed may be bridged by a C.sub.1 -C.sub.4 -alkylene bridge and the ring systems formed may be substituted by the radical R.sub.6 which represents hydrogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl, in quantities of from 0.05 to 3% by weight, based on 100 parts by weight of monomer, to the aqueous emulsion polymerization of chloroprene at the beginning of the reaction, during or after polymerization, but at the latest before the residual monomers are removed, high-viscosity polychloroprenes characterized by excellent processing behaviour and product properties are obtained.
    • 通过添加对应于下列通式I(I)的物质,其中X = O,S或N-R 5; R1 =氢,C1-C19 - 烷基,C2-C19 - 烯基,苯基,C1-C4-亚烷基苯基,C5-C12-环烷基或C5-C12-环烯基; R2 =氢,C1-C19 - 烷基,C2-C12-烯基,苯基或C1-C4-亚烷基苯基; R3 =氢,C1-C19 - 烷基,C2-C19 - 烯基,苯基,C1-C4-亚烷基苯基,丙烯酰甲酰基或乙酰基; R 4和R 5相同或不同,C 1 -C 19 - 烷基,C 2 -C 19 - 烯基,苯基,C 1 -C 4亚烷基苯基,丙烯酰基,C 5 -C 12 - 环烷基或C 5 -C 12 - 环烯基; R4和R5还可以形成可以任选地含有醚形式的氧原子的C 4 -C 7环,并且基团R 1和R 2可以形成C 5 -C 12亚烷基桥或C 5 -C 12 - 亚烯基桥,基团R 1和 R4可以形成C 2 -C 9 - 亚烷基桥,基团R 1和R 3可以形成C 3 -C 10亚烷基桥; 其中R 1和R 2连接,所形成的环可以被C 1 -C 4 - 亚烷基桥桥连,所形成的环体系可以被代表氢,C 1 -C 5 - 烷基或C 2 -C 5 - 烯基的基团R 6代替, 在反应开始时,在聚合过程中或之后的氯丁二烯的水乳液聚合中,基于100重量份的单体,以0.05重量%的量计,残留单体除去之前的量高 获得以优异的加工性能和产品性能为特征的粘性聚氯乙烯。