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31. 发明申请

US20100124706A1 SECONDARY BATTERY AND ANODE 审中-公开
标题翻译：二次电池和阳极
公开(公告)号：US20100124706A1
公开(公告)日：2010-05-20
申请号：US12616633
申请日：2009-11-11
申请人： Takakazu Hirose , Kenichi Kawase , Kazunori Noguchi , Takayuki Fujii
发明人： Takakazu Hirose , Kenichi Kawase , Kazunori Noguchi , Takayuki Fujii
IPC分类号： H01M6/16 , H01M4/58 , H01M4/42 , H01M6/04
CPC分类号： H01M10/0525 , H01M4/134 , H01M4/58 , H01M10/0568 , H01M10/0569
摘要： A secondary battery capable of obtaining superior cycle characteristics and superior swollenness characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution is impregnated in a separator provided between the cathode and the anode. An anode active material layer contains a crystalline anode active material having silicon as an element. The anode active material layer has a coating section where the surface of an anode current collector is coated with the anode active material and a non-coating section where the surface of the anode current collector is not coated with the anode active material but is exposed. Thereby, the physical property of the anode active material is hardly deteriorated with age. Further, at the time of charge and discharge, the anode active material layer is hardly expanded and shrunk, and thus the anode current collector is hardly deformed.
摘要翻译：提供能够获得优异的循环特性和优异的膨胀特性的二次电池。二次电池包括阴极，阳极和电解液。将电解液浸渍在设置在阴极和阳极之间的隔膜中。阳极活性材料层含有具有硅作为元素的结晶阳极活性材料。负极活性物质层具有涂覆部分，其中阳极集电体的表面涂覆有负极活性材料和非涂覆部分，其中阳极集电器的表面没有被阳极活性材料涂覆但被暴露。由此，阳极活性物质的物性几乎不随着年龄而劣化。此外，在充放电时，阳极活性物质层几乎不膨胀收缩，因此阳极集电体几乎不变形。

32. 发明申请

US20100104951A1 ANODE CURRENT COLLECTOR, ANODE, AND SECONDARY BATTERY 有权
标题翻译：阳极收集器，阳极和二次电池
公开(公告)号：US20100104951A1
公开(公告)日：2010-04-29
申请号：US12604114
申请日：2009-10-22
申请人： Masayuki Iwama , Kenichi Kawase
发明人： Masayuki Iwama , Kenichi Kawase
IPC分类号： H01M10/05 , H01M4/02 , H01M4/58 , H01M10/02
CPC分类号： H01M4/133 , H01M4/1393
摘要： A secondary battery that has superior safety and is able to provide more favorable cycle characteristics is provided. A laminated body in which a cathode and an anode are layered with a separator impregnated with an electrolytic solution in between is contained in a package can and a package cup. In the anode, an anode active material layer containing an anode active material such as silicon is provided on an anode current collector in which projection sections are formed on a base material. The base material contains carbon and sulfur respectively having a content ratio of 100 ppm or less, and contains crystallites having an average diameter of from 0.01 μm to 5 μm both inclusive.
摘要翻译：提供了具有优异安全性并能够提供更有利的循环特性的二次电池。其中阴极和阳极层叠有浸渍有电解液的隔膜的层压体包含在包装罐和包装杯中。在阳极中，在负极集电体上设置含有阳极活性物质如硅的负极活性物质层，在阳极集电体上，在基材上形成有突起部。基材含有分别具有100ppm以下的含量的碳和硫，并且包含平均直径为0.01μm以上且5μm以下的微晶。

33. 发明申请

US20100092856A1 ANODE AND SECONDARY BATTERY 审中-公开
标题翻译：阳极和二次电池
公开(公告)号：US20100092856A1
公开(公告)日：2010-04-15
申请号：US12419684
申请日：2009-04-07
申请人： Takakazu Hirose , Kenichi Kawase , Kazunori Noguchi , Takayuki Fujii , Rikako Imoto
发明人： Takakazu Hirose , Kenichi Kawase , Kazunori Noguchi , Takayuki Fujii , Rikako Imoto
IPC分类号： H01M2/02 , H01M4/58 , H01M6/16
CPC分类号： H01M10/0525 , H01M4/134 , H01M4/1395 , H01M4/58 , H01M10/0566 , H01M2300/0025
摘要： A secondary battery capable of improving the cycle characteristics and the initial charge and discharge characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode has an anode active material layer on an anode current collector. The anode active material layer contains a crystalline anode active material having silicon as an element, and is linked to the anode current collector.
摘要翻译：提供能够改善循环特性和初始充放电特性的二次电池。二次电池包括阴极，阳极和电解液。阳极在阳极集电器上具有阳极活性材料层。负极活性物质层含有以硅为元素的结晶性负极活性物质，并与阳极集电体连接。

34. 发明申请

US20090269677A1 ANODE AND SECONDARY BATTERY 有权
标题翻译：阳极和二次电池
公开(公告)号：US20090269677A1
公开(公告)日：2009-10-29
申请号：US12428518
申请日：2009-04-23
申请人： Takakazu Hirose , Kenichi Kawase , Tomoo Takada , Kazunori Noguchi , Takayuki Fujii
发明人： Takakazu Hirose , Kenichi Kawase , Tomoo Takada , Kazunori Noguchi , Takayuki Fujii
IPC分类号： H01M10/26 , H01M4/36
CPC分类号： H01M4/624 , H01M4/134 , H01M4/621 , H01M4/626 , H01M10/0525 , H01M10/0569 , H01M10/0587 , H01M2300/0037
摘要： A secondary battery capable of improving the cycle characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution is impregnated in a separator provided between the cathode and the anode. The anode has an anode structure on an anode current collector. The anode structure has a structure in which a plurality of anode active material particles having silicon are held by a plurality of metal fibers forming a three-dimensional network structure. Due to the plurality of metal fibers, sufficient conductive paths are obtained among the plurality of anode active material particles. Thus, compared to a general anode in which an active material layer is provided on a current collector made of a metal foil or the like, the current collectivity is improved.
摘要翻译：提供能够改善循环特性的二次电池。二次电池包括阴极，阳极和电解液。将电解液浸渍在设置在阴极和阳极之间的隔膜中。阳极在阳极集电器上具有阳极结构。阳极结构具有多个由硅构成的多个金属纤维形成三维网状结构的多个具有硅的负极活性物质粒子的结构。由于多个金属纤维，在多个负极活性物质粒子之间获得足够的导电路径。因此，与在由金属箔等构成的集电体上设置活性物质层的一般的阳极相比，电流集中性提高。

35. 发明申请

US20090092892A1 ANODE AND METHOD OF MANUFACTURING THE SAME, AND BATTERY AND METHOD OF MANUFACTURING THE SAME 有权
标题翻译：阳极及其制造方法，电池及其制造方法
公开(公告)号：US20090092892A1
公开(公告)日：2009-04-09
申请号：US11995802
申请日：2007-05-22
申请人： Hiroyuki Yamaguchi , Hiroshi Horiuchi , Kenichi Kawase , Tadahiko Kubota , Hideki Nakai , Takakazu Hirose
发明人： Hiroyuki Yamaguchi , Hiroshi Horiuchi , Kenichi Kawase , Tadahiko Kubota , Hideki Nakai , Takakazu Hirose
IPC分类号： H01M4/52
CPC分类号： H01M4/366 , H01M4/13 , H01M4/131 , H01M4/134 , H01M4/139 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/483 , H01M4/485 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M10/058 , H01M10/0587 , H01M2004/027 , H01M2300/0028 , H01M2300/0034 , Y02E60/122 , Y02P70/54
摘要： An anode capable of improving charge-discharge efficiency, and a method of manufacturing the anode, and a battery using the anode are provided. An anode 22 has a configuration in which an anode active material layer 22B is arranged on an anode current collector 22A. The anode active material layer 22B includes anode active material particles made of an anode active material including at least one of silicon and tin as an element. An oxide-containing film including an oxide of at least one kind selected from the group consisting of silicon, germanium and tin is formed in a region in contact with an electrolytic solution of the surface of each anode active material particle by a liquid-phase method such as a liquid-phase deposition method. The region in contact with the electrolytic solution of the surface of each anode active material particle is covered with the oxide-containing film, thereby the chemical stability of the anode 22 is improved, and charge-discharge efficiency is improved. The thickness of the oxide-containing film is preferably within a range from 0.1 nm to 500 nm both inclusive.
摘要翻译：提供一种能够提高充放电效率的阳极及其制造方法以及使用阳极的电池。阳极22具有负极活性物质层22B配置在阳极集电体22A上的结构。负极活性物质层22B包括由包含硅和锡中的至少一种作为元素的负极活性物质制成的负极活性物质粒子。在与阳极活性物质粒子的表面的电解液接触的区域中，通过液相法形成含有选自硅，锗，锡中的至少一种的氧化物的含氧化物膜例如液相沉积法。与负极活性物质粒子的表面的电解液接触的区域被含氧化物膜覆盖，阳极22的化学稳定性提高，充放电效率提高。含氧化物膜的厚度优选为0.1nm〜500nm的范围。

36. 发明申请

US20090004568A1 ANODE AND BATTERY 审中-公开
标题翻译：阳极和电池
公开(公告)号：US20090004568A1
公开(公告)日：2009-01-01
申请号：US12127457
申请日：2008-05-27
申请人： Takakazu Hirose , Hideki Nakai , Momoe Adachi , Hiroyuki Yamaguchi , Kenichi Kawase , Tadahiko Kubota
发明人： Takakazu Hirose , Hideki Nakai , Momoe Adachi , Hiroyuki Yamaguchi , Kenichi Kawase , Tadahiko Kubota
IPC分类号： H01M4/00 , H01M4/58
CPC分类号： H01M10/0569 , H01M2/0217 , H01M2/022 , H01M2/0285 , H01M4/02 , H01M4/134 , H01M4/362 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/626 , H01M10/0525 , H01M10/0568 , H01M2004/027
摘要： A battery capable of improving the cycle characteristics is provided. The battery includes a cathode, an anode and an electrolytic solution. The anode has an anode current collector, an anode active material layer provided on the anode current collector, and a coat provided on the anode active material layer, in which the coat contains a fluorine resin having an ether bond.
摘要翻译：提供了能够改善循环特性的电池。电池包括阴极，阳极和电解液。阳极具有负极集电体，设置在负极集电体上的负极活性物质层和设置在负极活性物质层上的涂层，其中该涂层含有具有醚键的氟树脂。

37. 发明授权

US07416817B2 Battery 有权
标题翻译：电池
公开(公告)号：US07416817B2
公开(公告)日：2008-08-26
申请号：US10713969
申请日：2003-11-14
申请人： Kenichi Kawase , Tomoo Takada , Yukio Miyaki
发明人： Kenichi Kawase , Tomoo Takada , Yukio Miyaki
IPC分类号： H01M6/16
CPC分类号： H01M4/13 , H01M4/0421 , H01M4/0497 , H01M4/131 , H01M4/134 , H01M4/139 , H01M4/1395 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M10/052 , H01M10/0567 , H01M10/0587
摘要： The invention provides a battery which can improve cycle characteristics by forming a more stable and stronger film on the surface of an anode active material layer. A cathode and an anode are layered with a separator in between. The anode has an anode collector and the anode active material layer. The anode active material layer contains Si, Sn, or an alloy thereof, and formed by vapor-phase method, liquid phase method, or sinter method. It is preferable that the anode active material layer is alloyed with the anode collector on at least a part of interface between the anode active material layer and the anode collector. The separator is impregnated with an electrolyte solution. The electrolyte solution contains cyclic carbonic ester having saturated bonds such as vinylene carbonate and vinylethylene carbonate as a solvent. Consequently, a strong and stable film is formed on the surface of the anode active material layer, and decomposition of the electrolyte solution in the anode is inhibited.
摘要翻译：本发明提供了一种通过在阳极活性材料层的表面上形成更稳定和更强的膜来改善循环特性的电池。阴极和阳极之间用隔膜分层。阳极具有阳极集电体和负极活性物质层。阳极活性物质层含有Si，Sn或其合金，通过气相法，液相法或烧结法形成。优选的是，阳极活性物质层与阳极集电体在阳极活性物质层和阳极集电体的界面的至少一部分上合金化。隔膜用电解质溶液浸渍。电解液含有碳酸亚乙烯酯和碳酸乙烯亚乙酯作为溶剂的具有饱和键的环状碳酸酯。因此，在负极活性物质层的表面形成强而稳定的膜，并且抑制阳极中的电解液的分解。

38. 发明申请

US20080160406A1 BATTERY 有权
标题翻译：电池
公开(公告)号：US20080160406A1
公开(公告)日：2008-07-03
申请号：US11768485
申请日：2007-06-26
申请人： Yoshikazu Kato , Kenichi Kawase
发明人： Yoshikazu Kato , Kenichi Kawase
IPC分类号： H01M4/60
CPC分类号： H01M4/60 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/604 , H01M4/621 , H01M4/622 , H01M10/052 , H01M10/0525 , Y02E60/122
摘要： A battery capable of improving the safety when the battery is broken while securing the cycle characteristics is provided. The battery includes a cathode, an anode, and an electrolyte. The anode includes an anode active material layer that has a resin containing sulfur (S). Compared to a case not having the resin containing resin, a sufficient discharge capacity can be obtained even when charge and discharge is repeated, and smoking and ignition are not easily generated when the battery is broken. Thereby, the cycle characteristics are secured, and the safety when the battery is broken is improved.
摘要翻译：提供一种能够在确保循环特性的同时在电池破损时提高安全性的电池。电池包括阴极，阳极和电解质。阳极包括具有含硫（S）的树脂的负极活性物质层。与不含树脂的树脂相比，即使重复进行充放电也能够获得充分的放电容量，并且在电池破损时不容易产生吸烟和点火。由此，确保了循环特性，提高了电池破损时的安全性。

39. 发明申请

US20070207386A1 Battery and method of manufacturing the same 有权
标题翻译：电池及其制造方法
公开(公告)号：US20070207386A1
公开(公告)日：2007-09-06
申请号：US11282231
申请日：2005-11-18
申请人： Isamu Konishiike , Kenichi Kawase , Kensuke Yamamoto , Yukiko Iijima , Tomoo Takada , Takakazu Hirose
发明人： Isamu Konishiike , Kenichi Kawase , Kensuke Yamamoto , Yukiko Iijima , Tomoo Takada , Takakazu Hirose
IPC分类号： H01M4/62 , H01M4/58 , B05D5/12
CPC分类号： H01M4/382 , H01M4/0423 , H01M4/134 , H01M4/386 , H01M10/052 , H01M2004/027 , Y10T29/49115
摘要： A battery capable of improving cycle characteristics is provided. An anode active material layer is formed by a vapor phase method, and includes Si as an element. In the anode active material layer, a plurality of primary particles formed by growth in a thickness direction are included, and the plurality of primary particles are agglomerated to form a plurality of secondary particles. Each secondary particle is separated by a groove formed by charge and discharge, and some of primary particles are split particles split by the groove. The average number of the split particles per secondary particle in 5 or more adjacent secondary particles is 10 or more. Moreover, the primary particles and the secondary particles are inclined to the same side.
摘要翻译：提供了能够改善循环特性的电池。阳极活性物质层通过气相法形成，并且包括Si作为元素。在负极活性物质层中，包含通过在厚度方向生长而形成的多个一次粒子，并且多个一次粒子凝集形成多个二次粒子。每个二次粒子由通过充放电形成的沟槽分开，并且一些一次粒子是由凹槽分裂的分裂粒子。 5个以上相邻二次粒子中的二次粒子的平均粒子数为10个以上。此外，一次粒子和二次粒子向同一侧倾斜。

40. 发明授权

US07226700B2 Anode and battery using the same 有权
标题翻译：阳极和电池使用相同
公开(公告)号：US07226700B2
公开(公告)日：2007-06-05
申请号：US10745156
申请日：2003-12-23
申请人： Tomoo Takada , Kenichi Kawase , Yukio Miyaki
发明人： Tomoo Takada , Kenichi Kawase , Yukio Miyaki
IPC分类号： H01M4/38
CPC分类号： H01M4/13 , H01M2/0222 , H01M4/0421 , H01M4/0426 , H01M4/38 , H01M4/387 , H01M4/661 , H01M4/70 , H01M6/10 , H01M10/0525 , H01M2004/027
摘要： Provided is a battery capable of improving cycle characteristics without increasing the thickness of an anode current collector. An anode active material layer including at least one kind selected from the group consisting of Sn and compounds thereof is formed on an anode current collector having a projection on a substrate through a vapor deposition method, a liquid-phase deposition method or a sintering method, and the anode current collector and the anode active material layer are alloyed with each other in at least a portion of an interface therebetween. By a function of the projection, the anode current collector can be prevented from being cracked into small pieces due to expansion and shrinkage of the anode active material layer. Further, a stress on the anode active material layer due to the expansion and the shrinkage can be spread out so that cracks produced in the anode active material layer can be scattered in various directions to reduce the size of the cracks.
摘要翻译：提供一种能够在不增加阳极集电体的厚度的情况下改善循环特性的电池。通过气相沉积法，液相沉积法或烧结法在具有突起的阳极集电体上形成包括选自Sn及其化合物中的至少一种的负极活性物质层，并且阳极集电体和负极活性物质层在它们之间的界面的至少一部分中彼此合金化。通过投影的功能，可以防止阳极集电体由于负极活性物质层的膨胀和收缩而破裂成小块。此外，由于膨胀和收缩，负极活性物质层的应力可以展开，使得在阳极活性物质层中产生的裂纹可以在各个方向上散射以减小裂纹的尺寸。

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