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    • 37. 发明授权
    • Semiconductor devices, and semiconductor processing methods
    • 半导体器件和半导体处理方法
    • US06828683B2
    • 2004-12-07
    • US09219041
    • 1998-12-23
    • Weimin LiZhiping Yin
    • Weimin LiZhiping Yin
    • H01L2348
    • H01L21/76834H01L21/3185H01L21/76801H01L23/53238H01L2924/0002H01L2924/00
    • In one aspect, the invention encompasses a semiconductor processing method wherein a conductive copper-containing material is formed over a semiconductive substrate and a second material is formed proximate the conductive material. A barrier layer is formed between the conductive material and the second material. The barrier layer comprises a compound having silicon chemically bonded to both nitrogen and an organic material. In another aspect, the invention encompasses a composition of matter comprising silicon chemically bonded to both nitrogen and an organic material. The nitrogen is not bonded to carbon. In yet another aspect, the invention encompasses a semiconductor processing method. A semiconductive substrate is provided and a layer is formed over the semiconductive substrate. The layer comprises a compound having silicon chemically bonded to both nitrogen and an organic material.
    • 一方面,本发明包括一种半导体处理方法,其中在半导体衬底上形成导电含铜材料,并且在导电材料附近形成第二材料。 在导电材料和第二材料之间形成阻挡层。 阻挡层包括具有与氮和有机材料化学键合的硅的化合物。 在另一方面,本发明包括包含与氮和有机材料化学键合的硅的物质组合物。 氮不与碳结合。 另一方面,本发明包括半导体处理方法。 提供半导体衬底并且在半导体衬底上形成层。 该层包括具有与氮和有机材料化学键合的硅的化合物。
    • 38. 发明授权
    • Anti-reflective coatings and methods for forming and using same
    • 抗反射涂层及其形成和使用方法
    • US06784094B2
    • 2004-08-31
    • US10744261
    • 2003-12-22
    • Zhiping YinGurtej Sandhn
    • Zhiping YinGurtej Sandhn
    • H01L214763
    • H01L21/76897H01L21/0276H01L21/318H01L21/76802H01L21/76814
    • An anti-reflective coating material layer is provided that has a relatively high etch rate such that it can be removed simultaneously with the cleaning of a defined opening in a relatively short period of time without affecting the critical dimensions of the opening. A method of forming such a layer includes providing a substrate assembly surface and using a gas mixture of at least a silicon containing precursor, a nitrogen containing precursor, and an oxygen containing precursor. The layer is formed at a temperature in the range of about 50° C. to about 600° C. Generally, the anti-reflective coating material layer deposited is SixOyNz:H, where x is in the range of about 0.39 to about 0.65, y is in the range of about 0.02 to about 0.56, z is in the range of about 0.05 to about 0.33, and where the atomic percentage of hydrogen in the inorganic anti-reflective coating material layer is in the range of about 10 atomic percent to about 40 atomic percent. The total SiH4 flow is generally in the range of about 80 sccm to about 400 sccm. The gas mixture may include SiH4 and N2O, where the ratio of SiH4:N2O is in the range of about 0.25 to 0.60. The inorganic anti-reflective coating material layer may be used for defining contact openings, openings for forming capacitor structures, or any other openings in oxide layers.
    • 提供了具有相对高的蚀刻速率的抗反射涂层材料层,使得其可以在相对较短的时间段内清洁所定义的开口同时移除,而不影响开口的临界尺寸。 形成这种层的方法包括提供衬底组合表面并使用至少含硅前体,含氮前体和含氧前体的气体混合物。 该层在约50℃至约600℃的温度范围内形成。通常,沉积的抗反射涂层材料为SixOyNz:H,其中x在约0.39至约0.65的范围内, y在约0.02至约0.56的范围内,z在约0.05至约0.33的范围内,并且其中无机抗反射涂层材料层中的氢的原子百分比在约10原子%至 约40原子%。 总SiH 4流通常在约80sccm至约400sccm的范围内。 气体混合物可以包括SiH 4和N 2 O,其中SiH 4 :N 2 O的比例在约0.25至0.60的范围内。 无机抗反射涂层材料层可用于限定接触开口,用于形成电容器结构的开口或氧化物层中的任何其它开口。
    • 39. 发明授权
    • Method of decontaminating process chambers, methods of reducing defects in anti-reflective coatings, and resulting semiconductor structures
    • 净化处理室的方法,减少抗反射涂层缺陷的方法,以及所得的半导体结构
    • US06670284B2
    • 2003-12-30
    • US10121645
    • 2002-04-12
    • Zhiping Yin
    • Zhiping Yin
    • H01L2131
    • H01L23/5329H01L21/0276H01L21/3145H01L2924/0002Y10S438/905H01L2924/00
    • A method for fabricating a substantially smooth-surfaced anti-reflective coating on a semiconductor device structure including generating a plasma from an inert gas in a process chamber in which the anti-reflective coating is to be deposited. The anti-reflective coating may include silicon, oxygen and nitrogen, and is preferably of the general formula SixOyNz, where x equals 0.40 to 0.65, y equals 0.02 to 0.56 and z equals 0.05 to 0.33. Preferably, x+y+z equals one. The method may also include fabricating a silicon nitride layer over the anti-reflective coating. A semiconductor device which includes a silicon nitride layer over the anti-reflective coating has a density of less than about 40,000 particles or surface roughness features in the silicon nitride of about 120-150 nanometers dimension per eight inch wafer. Accordingly, a mask that is subsequently formed over the silicon nitride layer has a substantially uniform thickness and is substantially distortion-free.
    • 一种用于在半导体器件结构上制造基本光滑表面的抗反射涂层的方法,包括在其中要沉积抗反射涂层的处理室中产生来自惰性气体的等离子体。 抗反射涂层可以包括硅,氧和氮,并且优选为通式SixOyNz,其中x等于0.40至0.65,y等于0.02至0.56,z等于0.05至0.33。 优选地,x + y + z等于1。 该方法还可以包括在抗反射涂层上制造氮化硅层。 在抗反射涂层上包括氮化硅层的半导体器件具有小于约40,000个颗粒的密度或氮化硅中的表面粗糙度特征,每八英寸晶片约120-150纳米尺寸。 因此,随后在氮化硅层上形成的掩模具有基本均匀的厚度并且基本上无变形。