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    • 33. 发明授权
    • Polyolefinic compositions
    • 聚烯烃组合物
    • US08575272B2
    • 2013-11-05
    • US13386381
    • 2010-07-20
    • Marco CiarafoniPaola MassariGisella BiondiniRoberto Pantaleoni
    • Marco CiarafoniPaola MassariGisella BiondiniRoberto Pantaleoni
    • C08L23/12C08F297/08C08J5/18
    • C08J5/18C08F297/083C08J2323/12C08L23/06C08L23/12C08L23/16C08L2205/03C08L2666/02
    • A polymer composition comprising (percent by weight):a) 57%-74%, of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar % and a polydispersity index ranging from 5 to 10;b) 8 to 15%, of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 50%, and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; and c) 18-28%, of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g; said composition having a value of melt flow rate ranging from 35 to 60 g/10 min, and the amount of hexane extractables lower than 4.0 wt %.
    • 包含(重量%)的聚合物组合物:a)57%-74%的具有全同立构五单元组的结晶丙烯聚合物(mmmm),通过13C-MNR测量在25℃下不溶于二甲苯的级分, 高于97.5摩尔%,多分散指数为5〜10; b)8至15%的乙烯和丙烯的弹性体共聚物,所述共聚物具有一定量的衍生自乙烯的重复单元,范围为30至50%,并且在环境温度下部分溶于二甲苯; 在环境温度下可溶于二甲苯的聚合物级分的特性粘度值为2.5至3.5dl / g; 和c)18-28%的特性粘度值为1.5-4dl / g的乙烯均聚物; 所述组合物的熔体流动速率范围为35至60g / 10min,并且己烷可提取物的量低于4.0wt%。
    • 35. 发明申请
    • POLYOLEFINIC COMPOSITIONS
    • 聚合物组合物
    • US20120172533A1
    • 2012-07-05
    • US13386381
    • 2010-07-20
    • Marco CiarafoniPaola MassariGisella BiondiniRoberto Pantaleoni
    • Marco CiarafoniPaola MassariGisella BiondiniRoberto Pantaleoni
    • C08L23/16
    • C08J5/18C08F297/083C08J2323/12C08L23/06C08L23/12C08L23/16C08L2205/03C08L2666/02
    • A polymer composition comprising (per cent by weight):a) 57%-74%, of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar % and a polydispersity index ranging from 5 to 10;b) 8 to 15%, of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 50%, and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; andc) 18-28%, of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g;said composition having a value of melt flow rate ranging from 35 to 60 g/10 min, and the amount of hexane extractables lower than 4.0 wt %.
    • 包含(重量%)的聚合物组合物:a)57%-74%的具有全同立构五单元组的结晶丙烯聚合物(mmmm),通过13C-MNR测量在25℃下不溶于二甲苯的级分。 ,高于97.5摩尔%,多分散指数为5〜10; b)8至15%的乙烯和丙烯的弹性体共聚物,所述共聚物具有一定量的衍生自乙烯的重复单元,范围为30至50%,并且在环境温度下部分溶于二甲苯; 在环境温度下可溶于二甲苯的聚合物级分的特性粘度值为2.5至3.5dl / g; 和c)18-28%的特性粘度值为1.5-4dl / g的乙烯均聚物; 所述组合物的熔体流动速率范围为35至60g / 10min,并且己烷可提取物的量低于4.0wt%。
    • 36. 发明申请
    • POLYOLEFINIC COMPOSITIONS
    • 聚合物组合物
    • US20120165472A1
    • 2012-06-28
    • US13386389
    • 2010-07-20
    • Paola MassariMarco CiarafoniGisella BiondiniRoberto Pantaleoni
    • Paola MassariMarco CiarafoniGisella BiondiniRoberto Pantaleoni
    • C08L23/16
    • C08L23/12C08F297/083C08L23/06C08L23/16C08L2205/03C08L2666/02
    • A polymer composition comprising (per cent by weight): a) 70-84% of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar %; b) 8-15% of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 25 to 50 wt % and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; and c) 8-15% of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g; said composition having a value of melt flow rate ranging from 55 to 90 g/10 min, and the amount of hexane extractables lower than 3.5 wt %.
    • 包含(重量%)的聚合物组合物:a)通过13C-MNR在25℃下不溶于二甲苯的级分测量的具有全同立构五单元组(Mwmm)的结晶丙烯聚合物的70-84%,更高 大于97.5摩尔% b)8-15%的乙烯和丙烯的弹性体共聚物,该共聚物具有一定量的衍生自乙烯的重复单元,范围为25至50重量%,并且在环境温度下部分可溶于二甲苯; 在环境温度下可溶于二甲苯的聚合物级分的特性粘度值为2.5至3.5dl / g; 和c)8-15%的特性粘度值为1.5-4dl / g的乙烯均聚物; 所述组合物的熔体流动速率范围为55至90g / 10min,并且己烷可提取物的量低于3.5wt%。
    • 40. 发明申请
    • Polyolefinic Compositions Having Good Whitening Resistance
    • 具有良好美白抗性的聚烯烃组合物
    • US20080167428A1
    • 2008-07-10
    • US11793843
    • 2005-11-28
    • Paola MassariMarco CiarafoniJean News
    • Paola MassariMarco CiarafoniJean News
    • C08L23/14C08L23/10
    • C08L23/10C08L23/04C08L23/06C08L23/08C08L23/12C08L23/142C08L23/16C08L2205/03C08L2666/02C08F210/06C08F2/001C08F4/6492C08F4/651
    • A polypropylene composition comprising (percent by weight) (a) 50-77 % of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar % and a polydispersity index ranging from 4 to 10; (b) 13-28 % of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 70 % and being partially soluble in xylene at ambient temperature, the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2 to 4 dl/g; and (c) 10-22 % of polyethylene having an intrinsic viscosity value ranging from 1 to 3 dl/g, in said composition component (b) plus component (c) being in amounts of at least 25 wt %. The polymer composition exhibits good impact resistant, whitening resistance and relatively low stiffness.
    • 包含(重量百分比)(a)50-77%的具有全同立构五单元组的结晶丙烯聚合物(mmmm),通过不溶于二甲苯的级分测得的13 C-MNR 在25℃,高于97.5摩尔%,多分散指数为4至10; (b)13-28%的乙烯和丙烯的弹性体共聚物,该共聚物具有一定量的衍生自乙烯的重复单元,范围为30至70%,并且在环境温度下部分溶于二甲苯,聚合物馏分可溶于二甲苯 环境温度的特性粘度值范围为2至4dl / g; 和(c)所述组合物组分(b)加组分(c)的特性粘度值为1至3dl / g的聚乙烯的10-22%的量为至少25重量%。 聚合物组合物表现出良好的抗冲击性,耐白化性和相对低的刚度。