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31. 发明申请

US20140005324A1 SEALING PROPYLENE COPOLYMER 有权
标题翻译：密封丙烯共聚物
公开(公告)号：US20140005324A1
公开(公告)日：2014-01-02
申请号：US13984245
申请日：2012-02-07
申请人： Kristin Reichelt , Luigi Resconi , Juha Paavilainen
发明人： Kristin Reichelt , Luigi Resconi , Juha Paavilainen
IPC分类号： C08L23/14 , C09D123/14
CPC分类号： C08L23/14 , C08F2/001 , C08F4/65912 , C08J5/18 , C08L23/142 , C08L2203/162 , C08L2205/025 , C08L2308/00 , C08L2314/02 , C09D123/14 , C09D123/142 , C08L2666/06 , C08F210/16
摘要： Propylene copolymer composition comprising a propylene copolymer (A) having a comonomer content in the range of equal or more than 0.5 to equal or below 2.0 wt.-%, the comonomers are C5 to C12 α-olefins, and a propylene copolymer (B) having a comonomer content in the range of equal or more than 4.0 to equal or below 10.0 wt.-%, the comonomers are C5 to C12 α-olefins, wherein further the propylene copolymer composition has a comonomer content in the range of equal or more than 3.5 to equal or below 7.0 wt.-%, the comonomers are C5 to C12 α-olefins, and the weight ratio of the propylene copolymer (A) to the propylene copolymer (B) is in the range of 20/80 to below 55/45.
摘要翻译：包含丙烯共聚物（A）的丙烯共聚物组合物，其共聚单体含量在等于或大于0.5至等于或低于2.0重量％的范围内，共聚单体是C 5 -C 12α-烯烃，丙烯共聚物（B）共聚单体含量在等于或大于4.0至等于或低于10.0重量％的范围内，共聚单体是C 5至C 12α-烯烃，其中丙烯共聚物组合物的共聚单体含量在等于或更大的范围内 3.5以上7.0重量％以下，共聚单体为C 5〜C 12α-烯烃，丙烯共聚物（A）与丙烯共聚物（B）的重量比为20/80〜 55/45。

32. 发明申请

US20130289229A1 CATALYSTS 有权
标题翻译：催化剂
公开(公告)号：US20130289229A1
公开(公告)日：2013-10-31
申请号：US13806421
申请日：2011-06-29
申请人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
发明人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
IPC分类号： C08F110/06
CPC分类号： C08F4/65912 , C07F17/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F2500/03 , C08F2500/12
摘要： A complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5.
摘要翻译：式（I）的络合物：其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β-原子处与环戊二烯基环分支的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β-原子处分支到环戊二烯基的C 3 -C 20烃基 β原子是Si原子的环; n为0-3; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R5基团取代，每个R 5相同或不同，并且是任选地含有一个或多个属于基团14的杂原子的C 1 -C 20烃基 -16; 并且任选地两个相邻的R5基团可以形成另外的单环或多环稠合至可任选被一个或两个基团R 5取代的W。

33. 发明申请

US20130131291A1 SOLID PARTICULATE CATALYSTS COMPRISING BRIDGED METALLOCENES 有权
标题翻译：包含桥接金属的固体颗粒催化剂
公开(公告)号：US20130131291A1
公开(公告)日：2013-05-23
申请号：US13643865
申请日：2011-04-27
申请人： Luigi Resconi , Pascal Castro , Lauri Huhtanen , Norbert Hafner
发明人： Luigi Resconi , Pascal Castro , Lauri Huhtanen , Norbert Hafner
IPC分类号： C08F4/76
CPC分类号： C08F4/76 , C08F4/6428 , C08F4/6592 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65927 , C08F2500/12 , C08F2500/17 , C08F2500/03 , C08F2500/15
摘要： A polypropylene homopolymer with a melting point of less than 147° C., a percentage of 2.1 errors of at least 1% and a xylene soluble fraction of less than 0.5 wt %.
摘要翻译：熔点小于147℃的聚丙烯均聚物，至少1％的2.1误差百分比和小于0.5重量％的二甲苯可溶部分。

34. 发明授权

US08101695B2 Propylene based terpolymers 有权
标题翻译：丙烯基三元共聚物
公开(公告)号：US08101695B2
公开(公告)日：2012-01-24
申请号：US11791253
申请日：2005-11-21
申请人： Luigi Resconi , Simona Guidotti
发明人： Luigi Resconi , Simona Guidotti
IPC分类号： C08F210/06 , C08F210/08 , C08F210/14 , C08F4/6392 , C08F4/6592 , B01J31/22
CPC分类号： C08F210/06 , C08F4/65912 , C08F10/00 , Y10S526/943 , C08F4/65927 , C08F210/08 , C08F210/14 , C08F2500/17 , C08F2500/20 , C08F2500/03
摘要： A propylene-based terpolymer comprising: a) from 10.0% by mol to 79.0% by mol of propylene derived units; b) from 89.5% by mol to 20.5% by mol of 1-butene derived units; and c) from 0.5% by mol to 15% by mol of derived units of alpha olefin of formula CH2═CHZ wherein Z is a C4-C20 alkyl radical.
摘要翻译：一种丙烯基三元共聚物，其包含：a）10.0摩尔％至79.0摩尔％的丙烯衍生单元; b）89.5摩尔％至20.5摩尔％的1-丁烯衍生单元; 和c）0.5摩尔％至15摩尔％的衍生单元的式CH 2 = CHZ的α-烯烃，其中Z是C 4 -C 20烷基。

35. 发明授权

US07985799B2 Polymerization process for preparing polyolefin blends 失效
标题翻译：制备聚烯烃共混物的聚合方法
公开(公告)号：US07985799B2
公开(公告)日：2011-07-26
申请号：US11919852
申请日：2006-05-08
申请人： Luigi Resconi , Daniele Bigiavi
发明人： Luigi Resconi , Daniele Bigiavi
IPC分类号： C08F297/08 , C08F10/00 , C08L23/00
CPC分类号： C08L23/12 , C08L23/10 , C08L23/14 , C08L23/18 , C08L23/20 , C08L2308/00 , C08L2666/06
摘要： A process for preparing polyolefin blends comprising:a) polymerizing in a solution phase propylene or 1-butene to prepare a polymeric solution containing a semicrystalline polymer component;b) polymerizing in a solution phase 1-hexene or 1-octene to prepare a polymeric solution containing an amorphous polymer component;c) mixing the polymeric solutions obtained from steps a) and b);d) subjecting the mixture of step c) to a devolatilization step to separate a polyolefin blend comprising a semicrystalline component and an amorphous component;the polymerization steps a) and b) being carried out in two polymerization reactors connected in parallel.
摘要翻译：一种制备聚烯烃共混物的方法，包括：a）在溶液相中聚合丙烯或1-丁烯，以制备含有半结晶聚合物组分的聚合物溶液; b）在溶液相1-己烯或1-辛烯中聚合以制备含有无定形聚合物组分的聚合物溶液; c）将从步骤a）和b）获得的聚合物溶液混合; d）将步骤c）的混合物进行脱挥发分步骤以分离包含半结晶组分和非晶组分的聚烯烃共混物; 聚合步骤a）和b）在并联连接的两个聚合反应器中进行。

36. 发明申请

US20100249346A1 METALLOCENE COMPOUNDS BASED ON ETHANEDIYL-BRIDGED INDENE AND CYCLOPENTADITHIOPHENE LIGANDS 审中-公开
标题翻译：基于乙二胺四乙酸和环戊二酸二乙酯的金属化合物
公开(公告)号：US20100249346A1
公开(公告)日：2010-09-30
申请号：US12734171
申请日：2008-10-01
申请人： Michael Schiendorfer , Luigi Resconi , Eleonora Ciaccia
发明人： Michael Schiendorfer , Luigi Resconi , Eleonora Ciaccia
IPC分类号： C08F4/52 , C07D495/04 , B01J31/14
CPC分类号： C07F17/00 , C07D495/04 , C08F4/65912 , C08F10/00 , C08F210/16 , C08F4/65927 , C08F210/08
摘要： A metallocene compound of formula (I) Wherein M is an atom of a transition metal; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group optionally containing heteroatoms R1 and R2, equal to or different from each other, are C1-C40 hydrocarbon radical optionally containing heteroatoms; R3 is a C1-C40 hydrocarbon radical optionally containing heteroatoms; R4, R5, R6 and R7, equal to or different from each other, are hydrogen atoms or C1-C40 hydrocarbon radical optionally containing heteroatoms or groups among R4, R5, R6 and R7 can also be joined to form a from 4 to 7 membered ring.
摘要翻译：式（I）的茂金属化合物，其中M是过渡金属的原子; X，是氢原子，卤原子或任选含有杂原子R 1和R 2的烃基，彼此相同或不同，是任选含有杂原子的C 1 -C 40烃基; R3是任选含有杂原子的C 1 -C 40烃基; R 4，R 5，R 6和R 7彼此相同或不同，是氢原子或任选地含有在R4，R5，R6和R7之间的杂原子或基团的C1-C40烃基也可以连接形成4至7元环。

37. 发明授权

US07619051B2 Butene-1/ethylene copolymer 有权
标题翻译：丁烯-1 /乙烯共聚物
公开(公告)号：US07619051B2
公开(公告)日：2009-11-17
申请号：US11376409
申请日：2006-03-15
申请人： Luigi Resconi
发明人： Luigi Resconi
IPC分类号： C08F210/08 , C08F210/02 , C08F4/642 , C08F4/6592
CPC分类号： C08F10/08 , C08F4/65912 , C08F110/08 , C08F210/08 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/12 , C08F2500/15 , C08F2500/03 , C08F2500/20 , C08F210/16
摘要： A 1-butene/ethylene copolymer having a content of ethylene derived units from 0.1% to 5% by weight in which an ethylene content in the polymer (C2) and a melting point of the polymer (Tm) meet the following relation: Tm
摘要翻译：聚合物（C2）中的乙烯含量和聚合物的熔点（Tm）的乙烯衍生单元含量为0.1〜5重量％的1-丁烯/乙烯共聚物满足以下关系：Tm < -0.3283C23 + 4.7184C22-22.454C2 + 114。

38. 发明申请

US20090043045A1 Polymerization Process for Preparing Polyolefin Blends 失效
标题翻译：制备聚烯烃共混物的聚合方法
公开(公告)号：US20090043045A1
公开(公告)日：2009-02-12
申请号：US11919852
申请日：2006-05-08
申请人： Luigi Resconi , Daniele Bigiavi
发明人： Luigi Resconi , Daniele Bigiavi
IPC分类号： C08F2/01 , C08L23/12
CPC分类号： C08L23/12 , C08L23/10 , C08L23/14 , C08L23/18 , C08L23/20 , C08L2308/00 , C08L2666/06
摘要： A process for preparing polyolefin blends comprising: a) polymerizing in a solution phase propylene or 1-butene to prepare a polymeric solution containing a semicrystalline polymer component; b) polymerizing in a solution phase 1-hexene or 1-octene to prepare a polymeric solution containing an amorphous polymer component; c) mixing the polymeric solutions obtained from steps a) and b); d) subjecting the mixture of step c) to a devolatilization step to separate a polyolefin blend comprising a semicrystalline component and an amorphous component; the polymerization steps a) and b) being carried out in two polymerization reactors connected in parallel.
摘要翻译：一种制备聚烯烃共混物的方法，包括：a）在溶液相中聚合丙烯或1-丁烯，以制备含有半结晶聚合物组分的聚合物溶液; b）在溶液相1-己烯或1-辛烯中聚合以制备含有无定形聚合物组分的聚合物溶液; c）将从步骤a）和b）获得的聚合物溶液混合; d）将步骤c）的混合物进行脱挥发分步骤以分离包含半结晶组分和非晶组分的聚烯烃共混物; 聚合步骤a）和b）在并联连接的两个聚合反应器中进行。

39. 发明申请

US20090005523A1 Process for the Preparation of Atactic 1-Butene Polymers 有权
标题翻译：制备无规1-丁烯聚合物的方法
公开(公告)号：US20090005523A1
公开(公告)日：2009-01-01
申请号：US11579525
申请日：2005-04-25
申请人： Luigi Resconi , Simona Guidotti
发明人： Luigi Resconi , Simona Guidotti
IPC分类号： C08F210/08 , C08F4/606
CPC分类号： C08F10/08 , C08F4/65912 , C08F110/08 , C08F210/02 , C08F210/08 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/03 , C08F2500/20 , C08F2500/15 , C08F210/06 , C08F210/16
摘要： A process for obtaining atactic 1-butene polymer optionally containing at least one comonomer selected from ethylene, propylene or an alpha-olefin of formula CH2═CHRo, wherein Ro is a linear or branched C3-C20 alkyl group, comprising the step of polymerizing 1-butene and optionally ethylene, propylene or said alpha-olefin, in the presence of a catalyst system obtainable by contacting:a) at least one metallocene compound of formula (I) in its meso or meso-like form wherein M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent C1-C40 hydrocarbon radical optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; R1 and R2, are C1-C40 hydrocarbon radicals; T, equal to or different from each other, is a moiety of formula (IIa) or (IIb): wherein R3 is a C1-C40 hydrocarbon radical; R4 and R6, are hydrogen atoms or C1-C40 hydrocarbon radicals; R5 is a C1-C40 hydrocarbon radical; R7 and R8, equal to or different from each other, are hydrogen atoms or C1-C40 hydrocarbon radicals; and b) an alumoxane or a compound capable of forming an alkyl metallocene cation;
摘要翻译：一种获得任选含有至少一种选自乙烯，丙烯或式CH2-CHRo的α-烯烃的共聚单体的无规1-丁烯聚合物的方法，其中Ro是直链或支链C 3 -C 20烷基，其包括聚合1 丁烯和任选的乙烯，丙烯或所述α-烯烃，在催化剂体系存在下，可通过以下步骤：a）至少一种其中间或内消旋形式的式（I）金属茂化合物，其中M是过渡金属; p是0至3的整数; X相同或不同，是氢原子，卤素原子或烃基; L是任选含有属于元素周期表第13-17族的杂原子的二价C 1 -C 40烃基; R1和R2是C1-C40烃基; T为等于或不同的式（IIa）或（IIb）的部分：其中R 3为C 1 -C 40烃基; R4和R6是氢原子或C1-C40烃基; R5是C1-C40烃基; R 7和R 8彼此相同或不同，为氢原子或C 1 -C 40烃基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物;

40. 发明申请

US20080269439A1 Process for the Polymerization of Alpha Olefins 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US20080269439A1
公开(公告)日：2008-10-30
申请号：US11919843
申请日：2006-04-12
申请人： Luigi Resconi , Simona Guidotti , Iolanda Santoriello
发明人： Luigi Resconi , Simona Guidotti , Iolanda Santoriello
IPC分类号： C08F4/42 , C07F17/00 , C07F7/08 , C08F4/602
CPC分类号： C08F10/08 , C07F7/081 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F110/08 , C08F210/08 , Y10S526/943 , C08F4/65927 , C08F2/02 , C08F2500/17 , C08F210/16
摘要： A process for preparing 1-butene polymers, comprising polymerizing 1-butene or copolymerizing 1-butene with ethylene, propylene or an alpha-olefin of formula CHT2=CHT wherein T is a C3-C10 alkyl group, in the presence of a catalyst system obtainable by contacting: A) a metallocene compound belonging to formula (I): wherein M is zirconium titanium or hafnium; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a hydrocarbon radical optionally containing heteroatoms; R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 are hydrogen atoms, or C1-C4O hydrocarbon radicals optionally containing heteroatoms; R1, R2 and R3, are linear or branched, C1-C2o-alkyl radicals, optionally containing heteroatoms: B) a Jumoxane or a compound capable of forming an alkyl metallocene cation; and optionally C) organo aluminum compound.
摘要翻译：一种制备1-丁烯聚合物的方法，包括将1-丁烯或1-丁烯与乙烯，丙烯或式CHT 2 CH = CHT的α-烯烃聚合，其中T是C 3 在可以通过下述方法获得的催化剂体系存在下进行：A）属于式（I）的金属茂化合物：其中M是锆钛或铪; X彼此相同或不同，为氢原子，卤素原子，任选含有杂原子的烃基; R 4，R 5，R 6，R 7，R 8， R 9，R 10，R 11，R 12和R 13是氢原子或任选含有杂原子的C 1 -C 40烃基; R 1，R 2和R 3是直链或支链的C 1 -C 2 O 任选地含有杂原子的烷基：B）Jumoxane或能够形成烷基金属茂阳离子的化合物; 和任选的C）有机铝化合物。

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