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    • 32. 发明授权
    • Oxoalkyl esters
    • 氧代烷基酯
    • US4398038A
    • 1983-08-09
    • US396290
    • 1982-07-08
    • Michael LicciardelloRichard M. BodenHugh WatkinsMarie R. Hanna
    • Michael LicciardelloRichard M. BodenHugh WatkinsMarie R. Hanna
    • C07D319/08C11B9/00C07C69/76
    • C07D319/08C11B9/0015C11B9/0061Y02P20/582
    • Described is a genus of compounds defined according to the structure: ##STR1## wherein Z represents carbinol having the structure: ##STR2## or carboxaldehyde having the structure: ##STR3## and wherein R represents 3-heptanyl or phenyl produced by (i) reacting a carboxylic acid with 2,2-dimethyl-1,3-propanediol to form the compound wherein Z represents carbinol; (ii) and then, if desired, subsequently reacting the resulting alcohol to form an aldehyde; and organoleptic uses of such compounds in the field of perfumery, colognes and perfumed articles (e.g. perfumed polymers, or solid or liquid anionic, cationic, nonionic or switterionic detergents, fabric softener compositions, drier-added fabric softener articles, hair preparations, hair sprays, bath preparations and the like).
    • 描述了根据以下结构定义的化合物属:其中Z表示具有以下结构的甲醇:具有以下结构的羧甲基,其中R表示3-庚基或苯基,其通过以下步骤制备:(i) 与2,2-二甲基-1,3-丙二醇的羧酸形成其中Z代表甲醇的化合物; (ii)然后,如果需要,随后使所得醇反应形成醛; 以及这些化合物在香料,古龙水和香料制品领域(例如加香聚合物,或固体或液体阴离子,阳离子,非离子或转换洗涤剂,织物柔软剂组合物,干燥剂加入的织物柔软剂制品,头发制剂,喷发剂)中的感官用途 ,浴液等)。
    • 33. 发明授权
    • Use in modifying smoking tobacco aroma and flavor or mono-oxomethyl
substituted polyhydrodimethanonaphthalene derivatives
    • 用于改变吸烟烟草香气和风味或单氧甲基取代的多羟基甲基萘衍生物
    • US4391284A
    • 1983-07-05
    • US354387
    • 1982-03-02
    • Mark A. SpreckerMarie R. HannaRichard J. TokarzewskiRobert P. BelkoHugh WatkinsManfred H. Vock
    • Mark A. SpreckerMarie R. HannaRichard J. TokarzewskiRobert P. BelkoHugh WatkinsManfred H. Vock
    • A24B15/34C07C47/347C07C47/445A24B3/12A24B15/30
    • A24B15/345C07C47/347C07C47/445
    • Described is the use in modifying, augmenting or enhancing the aroma or taste of smoking tobacco products of mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '", R.sub.1 "", R.sub.3, R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '", R.sub.5 "" and R.sub.6 represent hydrogen or methyl with the provisos:(i) at least four of R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '" and R.sub.1 "" are hydrogen; and (ii) at least four of R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '" and R.sub.5 "" represent hydrogen;and wherein Z represents one of the moieties:(i) carboxaldehyde having the structure: ##STR2## (ii) alkylene dioxy or dialkoxy methyl having the structure: ##STR3## (iii) hydroxy methyl having the structure: ##STR4## (iv) acetoxymethyl having the structure: ##STR5## and wherein R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl or R.sub.7 and R.sub.8 taken together represent C.sub.2 -C.sub.4 alkylene; wherein the line represented by:[++++]is either (i) a carbon-carbon single bond when R.sub.7 and R.sub.8 taken together are C.sub.2 -C.sub.4 alkylene or (ii) no bond at all when R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl.
    • 描述了用于改变,增强或增强具有以下通用结构的单氧代甲基取代的多羟基甲基萘衍生物的烟草产品的香气或味道:其中虚线表示碳 - 碳单键或碳 - 碳双 键; 其中R1,R1',R1“,R1”,R1“,R3,R5,R5',R5”,R5“,R5”和R6表示氢或甲基, 条件:(i)R1,R1',R1“,R1”和R1“”中的至少四个为氢; 和(ii)R5,R5',R5“,R5”和R5“中的至少四个表示氢; (ⅰ)具有以下结构的甲醛:(ⅱ)具有以下结构的亚烷基二氧基或二烷氧基甲基:(ⅲ)具有以下结构的羟基甲基:(ⅳ) 具有以下结构的乙酰氧基甲基:其中R7和R8分别代表C1-C4低级烷基或R7和R8一起代表C2-C4亚烷基; 其中由以下各项表示的线:[++++]是(i)当R 7和R 8一起为C 2 -C 4亚烷基时的碳 - 碳单键或(ii)当R7和R8分别表示C1 -C4低级烷基。
    • 34. 发明授权
    • Perfumed stable aqueous hypochlorite bleach compositions containing
2-methyl-2-octanol and thickened variation thereof
    • 含有2-甲基-2-辛醇的稀释稳定的含水次氯酸盐漂白剂组合物及其增稠变化
    • US4390448A
    • 1983-06-28
    • US313685
    • 1981-10-22
    • Richard M. BodenMichael LicciardelloJoseph J. Maisano, Jr.Marie R. Hanna
    • Richard M. BodenMichael LicciardelloJoseph J. Maisano, Jr.Marie R. Hanna
    • A01N59/00C11D1/24C11D1/75C11D3/395C11D3/50C11D7/54
    • C11D3/50A01N59/00C11D3/3956C11D1/24C11D1/75
    • Described is a process for producing a stable single phase aqueous alkali metal hypochlorite solution having good surface tension properties and optionally having a relatively high viscosity (5-25 centipoises at 20.degree.-40.degree. C.) and having a stable fragrance consisting, in sequential order, of the steps of (a) adjusting the pH of an aqueous alkali metal hypochlorite solution to the range of 11-14.0; (b) admixing a composition of matter selected from the group consisting of: (i) a chemical compound having the structure: ##STR1## wherein at least one of R.sub.1 and R.sub.2 is C.sub.10 -C.sub.12 straight chain or branched chain alkyl and M.sub..alpha. and M.sub..beta. are the same or different and each represents alkali metal selected from the group consisting of lithium, potassium and sodium; and (ii) a mixture of at least one compound having the structure: ##STR2## and a compound having the structure: ##STR3## wherein R.sub.3 "' is straight chain alkyl; wherein more than 55% of the R.sub.3 "' moieties consist of straight chain alkyl having from 11 up to 13 carbon atoms and wherein A and B are each separately methyl or taken together complete a morpholine ring, with a perfuming quantity of 2-methyl-2-octanol whereby a premix is formed; (c) optionally adding to said premix a gel-forming agent selected from the group consisting of sodium palmitate, lithium palmitate, potassium palmitate, sodium laurate, lithium laurate, potassium laurate, sodium stearate, potassium stearate and lithium stearate; and (d) adding said premix to the pH-adjusted hypochlorite solution.
    • 描述了一种制备稳定的单相碱金属碱金属次氯酸盐溶液的方法,该溶液具有良好的表面张力特性,并且任选具有较高的粘度(在20-40℃下为5-25厘泊),并具有稳定的香料, 以下步骤:(a)将碱金属次氯酸盐水溶液的pH调节至11-14.0的范围; (b)混合选自以下的物质组合物:(i)具有以下结构的化合物:其中R 1和R 2中的至少一个为C 10 -C 12直链或支链烷基和Mα, Mβ相同或不同,各自表示选自锂,钾和钠的碱金属; 和(ii)具有以下结构的至少一种化合物的混合物:< IMAGE>和具有以下结构的化合物:其中R 3“是直链烷基; 其中超过55%的R3“部分由具有11至13个碳原子的直链烷基组成,并且其中A和B各自独立地是甲基或一起形成吗啉环,其中加香量为2-甲基 -2-辛醇,由此形成预混物; (c)任选地向所述预混物中加入选自棕榈酸钠,棕榈酸棕榈酸酯,棕榈酸钾,月桂酸钠,月桂酸锂,月桂酸钾,硬脂酸钠,硬脂酸钾和硬脂酸锂的凝胶形成剂; 和(d)将所述预混合物加入经pH调节的次氯酸盐溶液中。
    • 36. 发明授权
    • Bicycle lactones, perfumery uses thereof, processes for preparing same and intermediates therefor
    • 自行车内酯,其香料用途,其制备方法及其中间体
    • US06835699B2
    • 2004-12-28
    • US10401824
    • 2003-03-28
    • Richard A. WeissMark A. SpreckerMarie R. HannaCharles E. J. BeckHarold W. Jackson
    • Richard A. WeissMark A. SpreckerMarie R. HannaCharles E. J. BeckHarold W. Jackson
    • C11D350
    • A61K8/498A61L9/01A61L9/012A61Q13/00C07D311/02C07D311/74C11B9/008C11D3/2096C11D3/50
    • Described are bicyclic lactones, both fused ring lactones defined according to the generic structure: and spiro lactones defined according to the generic structure: uses thereof in augmenting, enhancing or imparting aromas in or to perfume compositions, perfumed articles, colognes and perfumed polymers; processes for preparing such bicyclic lactones and intermediates therefor. In the structure: Z is one of the moieties: one of R1 or R3 is methyl and the other is hydrogen; and R4, R5, R6, R7, R8 and R9 are hydrogen or nonadjacent C1-C3 alkyl. In the structure: Y represents C2-C12 substituted or unsubstituted alkylidenyl, alkenylidenyl or alkadienylidenyl having the structure: and completes a C5-C15 cycloalkyl, cycloalkadienyl or cycloalkenyl ring moiety; and wherein R12, R13, R14, R16, R17, R28, R29, R30 and R31 represent hydrogen or R1 or R3 nonadjacent alkyl; wherein s is an integer of from 0 up to 10; t is an integer of from 0 up to 10; and v is an integer of 1 or 2; with the proviso that the sum of s and t is between 0 and 10 according to the inequalities: 0≦s+t≦10; 0≦s≦10; and 0≦t≦10.
    • 描述的是双环内酯,根据通用结构定义的稠环内酯和根据通用结构定义的螺内酯:用于增强,增强或赋予香料组合物,香料制品,古龙水和加香聚合物中的香气; 制备这种双环内酯的方法及其中间体。在结构中:Z是部分之一:R 1或R 3中的一个是甲基,另一个是氢; 且R 4,R 5,R 6,R 7,R 8和R 9为氢或不相邻的C 1 -C 3烷基。 在结构中:Y表示具有以下结构的C 2 -C 12取代或未取代的亚烷基,亚烯基或链二烯基;并且完成C 5 -C 15环烷基,环链二烯基或环烯基环部分; 并且其中R 12,R 13,R 14,R 16,R 17,R 28,R 29,R 30和R 31表示氢或R 1或R 3不相邻的烷基; 其中s为0至10的整数; t是0到10的整数; v为1或2的整数; 条件是根据不等式,s和t之和在0和10之间:0 <= s + t <= 10; 0 <= s <= 10; 0 <= T&LE; 10。
    • 37. 发明授权
    • Bicyclic lactones, perfumery uses thereof, processes for preparing same and intermediates therefor
    • 双环内酯,其香料用途,其制备方法及其中间体
    • US06462015B1
    • 2002-10-08
    • US09709109
    • 2000-11-10
    • Richard A. WeissMark A. SpreckerMarie R. HannaCharles E. J. BeckHarold W. Jackson
    • Richard A. WeissMark A. SpreckerMarie R. HannaCharles E. J. BeckHarold W. Jackson
    • A61K746
    • A61K8/498A61L9/01A61L9/012A61Q13/00C07D311/02C07D311/74C11B9/008C11D3/2096C11D3/50
    • Described are bicyclic lactones, both fused ring lactones defined according to the generic structure: and spiro lactones defined according to the generic structure: uses thereof in augmenting, enhancing or imparting aromas in or to perfume compositions, perfumed articles, colognes and perfumed polymers; processes for preparing such bicyclic lactones and intermediates therefor. In the structure: Z is one of the moieties: one of R1 or R3 is methyl and the other is hydrogen; and R4, R5, R6, R7, R8 and R9 are hydrogen or nonadjacent C1-C3 alkyl. In the structure: Y represents C2-C12 substituted or unsubstituted alkylidenyl, alkenylidenyl or alkadienylidenyl having the structure: and completes a C5-C15 cycloalkyl, cycloalkadienyl or cycloalkenyl ring moiety; and wherein R12, R13, R14, R16, R17, R28, R29, R30 and R31 represent hydrogen or nonadjacent alkyl; wherein s is an integer of from 0 up to 10; t is an integer of from 0 up to 10; and v is an integer of 1 or 2; with the proviso that the sum of s and t is between 0 and 10 according to the inequalities: 0≦s+t≦10;0≦s≦; 10; and 0 ≦t≦10.
    • 描述的是双环内酯,根据通用结构定义的稠环内酯和根据通用结构定义的螺内酯:用于增强,增强或赋予香料组合物,香料制品,古龙水和加香聚合物中的香气; 制备这种双环内酯的方法及其中间体。在结构中:Z是部分之一:R 1或R 3中的一个是甲基,另一个是氢; 且R 4,R 5,R 6,R 7,R 8和R 9为氢或不相邻的C 1 -C 3烷基。 在结构中:Y表示具有以下结构的C 2 -C 12取代或未取代的亚烷基,亚烯基或链二烯基;并且完成C 5 -C 15环烷基,环链二烯基或环烯基环部分; 并且其中R12,R13,R14,R16,R17,R28,R29,R30和R31表示氢或不相邻的烷基; 其中s为0至10的整数; t是0到10的整数; v为1或2的整数; 条件是根据不等式,s和t之和在0和10之间:0 <= s + t <= 10; 0 <= s <=; 10; 0 <= t <= 10。