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    • 33. 发明授权
    • Mask blank, transfer mask, and method of manufacturing a transfer mask
    • 掩模空白,转印掩模和制造转印掩模的方法
    • US09017902B2
    • 2015-04-28
    • US13378739
    • 2010-06-17
    • Osamu NozawaHiroyuki IwashitaMasahiro HashimotoAtsushi Kominato
    • Osamu NozawaHiroyuki IwashitaMasahiro HashimotoAtsushi Kominato
    • G03F1/50G03F1/58G03F1/80
    • G03F1/50G03F1/58G03F1/80
    • Provided is a mask blank which enables EB defect correction to be suitably applied and which further enables a reduction in the thickness of a light-shielding film. A mask blank 10 is used for producing a transfer mask adapted to be applied with ArF exposure light and has a light-shielding film 2 on a transparent substrate 1. The light-shielding film 2 has an at least two-layer structure comprising a lower layer composed mainly of a material containing a transition metal, silicon, and at least one or more elements selected from oxygen and nitrogen and an upper layer composed mainly of a material containing a transition metal, silicon, and at least one or more elements selected from oxygen and nitrogen. The ratio of the etching rate of the lower layer to that of the upper layer is 1.0 or more and 20.0 or less in etching which is carried out by supplying a fluorine-containing substance to a target portion and irradiating charged particles to the target portion.
    • 提供了能够适当地应用EB缺陷校正的掩模坯料,并且还能够减少遮光膜的厚度。 掩模坯料10用于制造适于施加ArF曝光光的转印掩模,并且在透明基板1上具有遮光膜2.遮光膜2具有至少两层结构,包括下层 主要由含有过渡金属,硅和至少一种或多种选自氧和氮的元素的材料构成的层,以及主要由含有过渡金属,硅以及至少一种或多种元素的材料组成的上层 氧气和氮气。 在通过向目标部分供给含氟物质并将带电粒子照射到目标部分进行的蚀刻中,下层的蚀刻速率与上层的蚀刻速率的比例为1.0以上且20.0以下。
    • 37. 发明授权
    • Phase shift mask blank, phase shift mask, and method for manufacturing phase shift mask blank
    • 相移掩模空白,相移掩模和用于制造相移掩模空白的方法
    • US08614035B2
    • 2013-12-24
    • US13491957
    • 2012-06-08
    • Osamu NozawaMasahiro Hashimoto
    • Osamu NozawaMasahiro Hashimoto
    • G03F1/32
    • G03F1/32G03F1/54
    • A phase shift mask blank having, on a transparent substrate, a phase shift film including, as main components, a metal, silicon (Si) and nitrogen (N), having optical characteristics of a transmittance of equal to or greater than 9% and equal to or less than 30% with respect to a wavelength of the ArF excimer laser beam and a phase difference of equal to or greater than 150° and less than 180°, and a light-shielding film formed on the phase shift film. A thickness of the phase shift film is equal to or less than 80 nrn, a refractive index (n) with respect to the wavelength of the ArF excimer laser beam is equal to or greater than 2.3, and an extinction coefficient (k) is equal to or greater than 0.28.
    • 一种相移掩模坯料,其在透明基板上具有包括具有等于或大于9%的透光率的光学特性的金属,硅(Si)和氮(N)作为主要成分的相移膜,以及 相对于ArF准分子激光束的波长和相位差等于或大于150度且小于180度的等于或小于30%,以及形成在相移膜上的遮光膜。 相移膜的厚度等于或小于80nrn,相对于ArF准分子激光束的波长的折射率(n)等于或大于2.3,消光系数(k)相等 大于或等于0.28。