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31. 发明授权

US08486494B2 Organic/inorganic composite coating film, structural color film using the same, and preparation methods thereof 有权
标题翻译：有机/无机复合涂膜，使用其的结构色膜及其制备方法
公开(公告)号：US08486494B2
公开(公告)日：2013-07-16
申请号：US12530903
申请日：2008-03-06
申请人： Norimasa Fukazawa , Ren-Hua Jin
发明人： Norimasa Fukazawa , Ren-Hua Jin
IPC分类号： B32B3/26 , B05D3/10
CPC分类号： C23C18/127 , C03C1/008 , C03C17/009 , C08K3/22 , C08L2205/20 , C09D1/00 , C09D7/67 , C09D7/68 , C09D7/69 , C09D7/70 , C23C18/1216 , C23C18/1254 , C23C18/1295 , Y10T428/24388 , Y10T428/24405 , Y10T428/249953
摘要： An organic/inorganic composite coating film comprising an inorganic material as a matrix and an organic material combined therewith. The coating film has a regular hollow structure therein, and the coating film surface has a rugged pattern with semispherical protrusions. Also provided is a large-area structural color film obtained by burning the composite coating film. The organic/inorganic composite coating film is obtained by applying an aqueous coating composition comprising a metal alkoxide, an aqueous dispersion of monodisperse polymer particles, and an acid catalyst to a substrate and curing the coating composition. Burning the organic/inorganic composite coating film gives the structural color film.
摘要翻译：一种有机/无机复合涂膜，其包含作为基质的无机材料和与其结合的有机材料。涂膜在其中具有规则的中空结构，并且涂膜表面具有具有半球形突起的凹凸图案。还提供了通过燃烧复合涂膜获得的大面积结构彩色膜。有机/无机复合涂膜通过将包含金属醇盐，单分散聚合物颗粒的水分散体和酸催化剂的水性涂料组合物涂覆到基材上并固化涂料组合物而获得。燃烧有机/无机复合涂膜得到结构色膜。

32. 发明申请

US20130040129A1 INFRARED ABSORBING THIN FILM CONTAINING RUTILE-TYPE TITANIUM OXIDE CRYSTAL AND METHOD FOR PRODUCING THE SAME 失效
标题翻译：含有类型氧化钛晶体的红外吸收薄膜及其制造方法
公开(公告)号：US20130040129A1
公开(公告)日：2013-02-14
申请号：US13642186
申请日：2011-03-31
申请人： Ren-Hua Jin , Pei-Xin Zhu
发明人： Ren-Hua Jin , Pei-Xin Zhu
IPC分类号： C09K3/00 , B05D5/00 , B32B5/02 , B82Y30/00
CPC分类号： C01G23/047 , B82Y30/00 , C01G45/02 , C01G51/02 , C01P2002/50 , C01P2002/52 , C01P2002/72 , C01P2002/82 , C01P2006/60 , C04B35/46 , C04B35/6325 , C04B2235/3234 , C04B2235/3265 , C04B2235/3275 , C04B2235/3279 , C04B2235/441 , C04B2235/443 , C04B2235/5454 , C04B2235/80 , F24S70/25 , H01G9/20 , H01M14/00
摘要： There are provided an infrared absorbing thin film that efficiently absorbs infrared rays and has good versatility by controlling the absorption intensity of titanium oxide in an infrared region and a method for producing the infrared absorbing thin film. The infrared absorbing thin film containing a rutile-type titanium oxide crystal can be produced through a step of dispersing or dissolving a complex of an amino group-containing basic polymer and a transition metal ion in an aqueous medium; a step of obtaining a composite having a polymer/titania layered structure in which the complex of the amino group-containing basic polymer and the transition metal ion is sandwiched between layers of titania, by mixing the aqueous dispersion with a water-soluble titanium compound in the aqueous medium; a step of calcining the composite in an air atmosphere at a temperature of 650° C. or higher and pulverizing the obtained crystal into a powder; and a step of mixing the obtained powder with a sol of a metal alkoxide to prepare a fluid liquid composition, coating a surface of a substrate with the obtained fluid liquid composition, and aging the coating film.
摘要翻译：提供一种通过控制红外线区域中的氧化钛的吸收强度和红外线吸收薄膜的制造方法，能够有效地吸收红外线并具有良好的通用性的红外线吸收薄膜。含有金红石型氧化钛晶体的红外吸收薄膜可以通过将含氨基的碱性聚合物和过渡金属离子的络合物分散或溶解在水性介质中的步骤来制造; 通过将水性分散体与水溶性钛化合物混合，得到具有聚氨酯层叠结构的复合体的步骤，其中含氨基的碱性聚合物和过渡金属离子的络合物夹在二氧化钛层之间水介质; 将复合体在650℃以上的温度下在空气气氛中煅烧的步骤，将得到的结晶粉碎成粉末; 以及将得到的粉末与金属醇盐的溶胶混合以制备流体液体组合物的步骤，用所得流体液体组合物涂布基材的表面，并使涂膜老化。

33. 发明授权

US08257662B2 Process for producing nanostructure composite-covered structure, nanostructure composite-covered structure, and reactor using nanostructure composite-covered structure 失效
标题翻译：使用纳米结构复合覆盖结构生产纳米结构复合覆盖结构，纳米结构复合覆盖结构和反应器的方法
公开(公告)号：US08257662B2
公开(公告)日：2012-09-04
申请号：US12675959
申请日：2008-09-01
申请人： Ren-Hua Jin , Jian-Jun Yuan
发明人： Ren-Hua Jin , Jian-Jun Yuan
IPC分类号： B01J8/02 , B01J35/02 , G11B5/64
CPC分类号： C23C28/00 , B01J23/38 , B01J35/0006 , B01J35/023 , B01J37/0215 , B01J37/0219 , B01J37/082 , C03C17/007 , C03C2217/445 , C03C2217/475 , C03C2217/485 , Y10T428/265
摘要： The present invention provides a structure in which the surface of a solid substrate of any shape is covered with metal oxide, in particular, a nanostructure composite in which polyethyleneimine, which is an organic substance, and metal oxide, which is an inorganic substance, are combined in nano-meter scale, spreads at the entire surface of a substrate, and the nanostructure composite forms a nano-boundary of complex shapes so as to thoroughly cover the entire surface of the substrate; a structure in which metal ions, metal nano-particles, organic pigment molecules are contained in the nanostructure composite; a process for producing these structures which can produce these structures with ease and efficiently; and an application method for the structures as an immobilized catalyst type reactor.
摘要翻译：本发明提供一种结构，其中任何形状的固体基材的表面被金属氧化物覆盖，特别是其中作为有机物质的聚乙烯亚胺和作为无机物质的金属氧化物的纳米结构复合物是以纳米尺度结合，在基底的整个表面上扩散，纳米结构复合物形成复杂形状的纳米边界，以彻底覆盖基底的整个表面; 在纳米结构复合体中含有金属离子，金属纳米粒子，有机颜料分子的结构; 制造能够容易且高效地生产这些结构的这些结构的方法; 以及作为固定化催化剂型反应器的结构的涂布方法。

34. 发明申请

US20110160374A1 STRUCTUAL OBJECT COATED WITH SUPERHYDROPHBIC NANOSTRUCTURE COMPOSITE AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：用超级纳米结构复合材料涂覆的结构物体及其制造方法
公开(公告)号：US20110160374A1
公开(公告)日：2011-06-30
申请号：US12737128
申请日：2009-05-25
申请人： Ren-Hua Jin , Jian-Jun Yuan
发明人： Ren-Hua Jin , Jian-Jun Yuan
IPC分类号： C09D139/00 , B05D3/10 , B05D3/02 , B05D7/22 , B82Y30/00
CPC分类号： C09C1/30 , B08B17/065 , B82Y30/00 , C01P2004/03 , C01P2004/64 , C03C17/22 , C03C2217/76 , C09C1/3081 , Y10T428/1314 , Y10T428/2935
摘要： The present invention relates to a structural object coated with a superhydrophobic nanostructure composite, the structural object being obtained by densely coating a surface of a solid substrate having a desired shape with a nanostructure obtained by combining a polymer having a polyethyleneimine skeleton with silica on the nanometer order, and bonding a hydrophobic group to the surface of the nanostructure, and a process for producing the structural object. The present invention also relates to a structural object coated with a superhydrophobic nanostructure composite, the structural object being obtained by removing the polymer having the polyethyleneimine skeleton from the nanostructure and bonding a hydrophobic group to the surface of the residual nanostructure containing silica as a main constituent component, and a process for producing the structural object. Furthermore, the present invention provides a method of using the structural object as a container for transferring an aqueous solution.
摘要翻译：本发明涉及涂覆有超疏水纳米结构复合材料的结构物体，该结构物体通过将具有聚乙烯亚胺骨架的聚合物与二氧化硅在纳米上组合而获得的具有所需形状的固体基底的表面密集地涂覆而获得将疏水性基团键合到纳米结构体的表面，以及制造该结构体的工序。本发明还涉及一种涂覆有超疏水性纳米结构复合材料的结构物体，该结构物体是通过从纳米结构中除去具有聚乙烯亚胺骨架的聚合物而获得的，并将疏水基团结合到含有二氧化硅作为主要成分的残余纳米结构物的表面上组件，以及用于生产结构对象的过程。此外，本发明提供一种使用结构物作为水溶液转移容器的方法。

35. 发明授权

US07674866B2 Method of producing polymer using iron complex as catalyst 失效
标题翻译：使用铁络合物作为催化剂生产聚合物的方法
公开(公告)号：US07674866B2
公开(公告)日：2010-03-09
申请号：US12066706
申请日：2006-09-12
申请人： Hideo Nagashima , Shota Niibayashi , Ren-Hua Jin , Hitoshi Hayakawa
发明人： Hideo Nagashima , Shota Niibayashi , Ren-Hua Jin , Hitoshi Hayakawa
IPC分类号： C07F4/06 , C08F4/80
CPC分类号： C08F4/40 , C08F6/02 , C08F20/18 , C08F293/005 , C08F2438/01
摘要： The object of the present invention is to provide a method of producing a polymer wherein radical-polymerizable monomers can be polymerized in a quantitative manner in a relatively short time, and a polymer or a block copolymer having at its termini a functional group that can be chemically converted while the polymer or the block copolymer has a high molecular weight can be produced. Furthermore, the object of the present invention is to provide a method of producing a polymer wherein the polymer is re-precipitated in a general solvent by an easy method, and the used iron complexes are recovered in the solvent, thereby recycling the iron complexes.
摘要翻译：本发明的目的是提供一种生产聚合物的方法，其中可自由基聚合的单体可以在相当短的时间内以定量方式聚合，并且聚合物或嵌段共聚物在其末端具有官能团，其可以是可以在聚合物或嵌段共聚物具有高分子量的情况下进行化学转化。此外，本发明的目的是提供一种聚合物的制造方法，其中通过简单的方法将聚合物在一般溶剂中再沉淀，并将所用的铁络合物回收到溶剂中，从而再循环铁络合物。

36. 发明申请

US20070197708A1 Composite nanofiber, composite nanofiber association, complex structure, and production method thereof 失效
标题翻译：复合纳米纤维，复合纳米纤维关联，复合结构及其制备方法
公开(公告)号：US20070197708A1
公开(公告)日：2007-08-23
申请号：US11569300
申请日：2005-05-27
申请人： Ren-Hua Jin , Jian-Jun Yuan
发明人： Ren-Hua Jin , Jian-Jun Yuan
IPC分类号： C08K3/08
CPC分类号： C08L79/02 , B82Y30/00 , D01F6/96 , D06M11/79 , D06M13/507 , D06M2101/30 , Y10T428/12035 , Y10T428/12174 , Y10T428/12438 , Y10T428/24603 , Y10T442/2885
摘要： A silica nanofiber is derived from a crystalline polymer filament of a polymer including straight chain polyethyleneimine backbones, which is capable of forming a water-insoluble crystal in the presence of water molecules at room temperature, and the crystalline polymer filament in the silica concentrates metal ions, thereby realizing a composite nanofiber including metals or metal ions in the silica. Furthermore, the composite nanofiber of the present invention can be easily produced by fixing a polymer structure in the silica as the scaffold for metal ions and concentrating metal ions at the scaffold or reducing the metal ions. Furthermore, a metal-containing silica nanofiber can be easily obtained by removing a polymer component from the composite nanofiber, the composite nanofiber association, and the complex nanofiber structure. These nanofibers can be assembled and integrated, and the assembled or integrated association or structure can realize various shapes.
摘要翻译：二氧化硅纳米纤维来源于包含直链聚乙烯亚胺骨架的聚合物的结晶聚合物长丝，其能够在室温下在水分子存在下形成水不溶性晶体，二氧化硅中的结晶聚合物长丝浓缩金属离子从而实现在二氧化硅中包含金属或金属离子的复合纳米纤维。此外，本发明的复合纳米纤维可以通过将二氧化硅中的聚合物结构固定在金属离子的支架上并将金属离子浓缩在支架上或还原金属离子而容易地制备。此外，通过从复合纳米纤维，复合纳米纤维结合体和复合纳米纤维结构中除去聚合物组分，可以容易地获得含金属的二氧化硅纳米纤维。这些纳米纤维可以组装和集成，并且组装或整合的关联或结构可以实现各种形状。

37. 发明申请

US20070142611A1 Comb-shaped epoxy resin and method for preparing comb-shaped epoxy resin 失效
标题翻译：梳状环氧树脂及梳状环氧树脂的制备方法
公开(公告)号：US20070142611A1
公开(公告)日：2007-06-21
申请号：US10593244
申请日：2005-03-23
申请人： Yuji Ohashi , Ren-Hua Jin , Seungtaeg Lee
发明人： Yuji Ohashi , Ren-Hua Jin , Seungtaeg Lee
IPC分类号： C08G59/14
CPC分类号： C08L51/08 , C08F283/06 , C08F283/10 , C08F290/144 , C08G59/184 , C08G73/0206 , C08G73/0233 , C08L53/00 , C08L63/00 , C08L2666/02 , C08L2666/20
摘要： The present invention provides a comb-shaped epoxy resin represented by the following formula (1): in the formula (1), X1 and X2 represent a divalent group having a residue selected from xanthene residue, biphenylene residue, hydrogenated bisphenol residue, alkylene residue and polyoxyalkylene residue, each may having a methyl group or a ethyl group as a substituent, and at least one of them is an aromatic residue, Y represents a polymer chain such as linear polymer chain, a number average polymerization degree being 5 to 2000, and n (number average polymerization degree) represents an integer within a range of 3 to 200, and to a method for preparing the comb-shaped epoxy resin.
摘要翻译：本发明提供由下式（1）表示的梳形环氧树脂：在式（1）中，X 1和X 2表示具有选自呫吨残基，联苯残基，氢化双酚残基，亚烷基残基和聚氧化烯残基的残基各自可以具有甲基或乙基作为取代基，并且其中至少一个是芳族残基，Y表示聚合物链例如线性聚合物链，数均聚合度为5〜2000，n（数均聚合度）为3〜200的整数，以及制备梳形环氧树脂的方法。

38. 发明授权

US07049369B2 Styrene resin composition and process for producing the same 有权
标题翻译：苯乙烯树脂组合物及其制造方法
公开(公告)号：US07049369B2
公开(公告)日：2006-05-23
申请号：US10501920
申请日：2003-01-30
申请人： Hiroyuki Yamazaki , Tsuyoshi Morita , Ren-Hua Jin
发明人： Hiroyuki Yamazaki , Tsuyoshi Morita , Ren-Hua Jin
IPC分类号： C08F212/04
CPC分类号： C08L25/06 , C08L2205/02 , C08L2666/04
摘要： A styrene resin composition is provided which has a high molecular weight enabling a molded product obtained therefrom to have satisfactory strength, has a high melt mass-flow rate, high melt tension, and hence excellent moldability, and is less apt to gel during production, and a process for producing such a styrene resin composition. The styrene resin composition comprises a linear polystyrene having a weight average molecular weight of 200,000 to 350,000 and a multibranched polystyrene having a weight average molecular weight of 1,000,000 to 10,000,000, has an average molecular weight of 250,000 to 700,000, and a melt mass-flow rate (MFR) and melt tension (MT) which satisfy the following formulas (1) and (2) respectively: MFR≧45×exp(−0.1×Mw×10−4) (1) MT≧0.07Mw×10−4+1.8. (2)
摘要翻译：提供一种具有高分子量的苯乙烯树脂组合物，使得由其获得的模塑产品具有令人满意的强度，具有高熔体质量流动速率，高熔体张力，因此优异的模塑性，并且在生产过程中不易凝胶化，和这种苯乙烯树脂组合物的制造方法。苯乙烯树脂组合物包含重均分子量为200,000至350,000的直链聚苯乙烯和重均分子量为1,000,000至10,000,000的多支链聚苯乙烯，其平均分子量为25万至700,000，熔体质量流动速率（MFR）和熔体张力（MT）分别满足下列公式（1）和（2）：<？in-line-formula description =“In-line formula”end =“lead”？> MFR> = 45xexp（（1）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In- 线公式“end =”lead“？> MT> = 0.07Mwx10 -4 +8.8。（2）<？in-line-formula description =“In-line Formulas”end =“tail”？>

39. 发明申请

US20060078736A1 Three-dimensional periodic structure, three-dimensional periodic porous structure, and method for producing these 审中-公开
标题翻译：三维周期性结构，三维周期性多孔结构及其制备方法
公开(公告)号：US20060078736A1
公开(公告)日：2006-04-13
申请号：US11206292
申请日：2005-08-18
申请人： Norimasa Fukazawa , Ren-Hua Jin
发明人： Norimasa Fukazawa , Ren-Hua Jin
IPC分类号： B32B15/02
CPC分类号： G02B6/1225 , B82Y20/00 , G02B5/20 , Y10T428/2998
摘要： The three-dimensional periodic structure of the present invention comprises a matrix made of an inorganic oxides in which core-shell particles are disposed so as to contact with each other, the core-shell particles each comprising a core portion made of a fine particle and a shell portion made of a crosslinked hydrophilic organic polymer backbones, wherein the hydrophilic organic polymer backbones and the inorganic oxides hybridize into an organic/inorganic a composite.
摘要翻译：本发明的三维周期性结构包括由核 - 壳粒子彼此接触地配置的无机氧化物构成的基体，所述核 - 壳粒子各自包含由微粒构成的芯部，由交联的亲水性有机聚合物主链制成的壳部分，其中所述亲水性有机聚合物主链和所述无机氧化物与有机/无机复合材料杂交。

40. 发明授权

US6031066A Process for producing .alpha., .beta.-unsaturated carboxylic acid ester polymer 失效
标题翻译：制备α，β-不饱和羧酸酯聚合物的方法
公开(公告)号：US6031066A
公开(公告)日：2000-02-29
申请号：US246158
申请日：1999-02-08
申请人： Ren-Hua Jin
发明人： Ren-Hua Jin
IPC分类号： C08F20/34 , C08G63/02
CPC分类号： C08F20/34
摘要： An object is: to provide a novel, generally applicable polymerization initiator which can be prepared easily and which is highly stable, for application to the production of polymers and block copolymers of .alpha.,.beta.-unsaturated carboxylic acid esters; to polymerize .alpha.,.beta.-unsaturated carboxylic acid esters using the polymerization initiator; and to provide a novel, generally applicable production process for polymers and block copolymers of .alpha.,.beta.-unsaturated carboxylic acid esters having high molecular weight and little discoloration, by which active hydrogen-containing monomers can be polymerized. This is achieved by a novel production process involving polymerization of various .alpha.,.beta.-ethylenically unsaturated carboxylic acid esters using as a polymerization initiator a polymer containing a tertiary amino group obtained by the polymerization of an .alpha.,.beta.-unsaturated carboxylic acid ester containing a tertiary amino group, in the presence of a trivalent phosphorus compound.
摘要翻译：目的是提供一种新颖的，普遍适用的聚合引发剂，其可以容易地制备并且高度稳定，用于生产α，β-不饱和羧酸酯的聚合物和嵌段共聚物; 使用聚合引发剂聚合α，β-不饱和羧酸酯; 并且提供一种新颖的，普遍适用的具有高分子量和少变色的α，β-不饱和羧酸酯的聚合物和嵌段共聚物的生产方法，通过该方法可以聚合活性含氢单体。这是通过一种新的制备方法来实现的，该方法包括使用各种α，β-烯键式不饱和羧酸酯作聚合引发剂聚合，所述聚合引发剂含有通过聚合含有叔碳原子的α，β-不饱和羧酸酯获得的叔氨基氨基，在三价磷化合物的存在下。

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