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1. 发明授权

US08388870B2 Metal-nanoparticle-containing composite, dispersion liquid thereof, and methods for producing the metal-nanoparticle-containing composite and the dispersion liquid 有权
标题翻译：含有金属纳米颗粒的复合物，其分散液，以及制备含金属纳米颗粒的复合物和分散液的方法
公开(公告)号：US08388870B2
公开(公告)日：2013-03-05
申请号：US13502564
申请日：2010-09-06
申请人： Yoshiyuki Sano , Nobuhiro Sekine , Ren-Hua Jin , Hiroshi Yonehara , Masafumi Uota
发明人： Yoshiyuki Sano , Nobuhiro Sekine , Ren-Hua Jin , Hiroshi Yonehara , Masafumi Uota
IPC分类号： H01B1/22 , B22F9/24 , B22F1/02
CPC分类号： C22C9/00 , B22F1/0022 , B22F9/24 , B82Y30/00 , C22C5/02 , C22C5/04 , C22C5/06
摘要： Provided are a composite of nanoparticles of a metal such as gold, silver, a platinum metal, or copper, and a polymer, the composite allowing formation of a metal film having a sufficiently low resistivity in terms of practicality simply by drying at room temperature without requiring any special heating-baking step or any step of removing a protective agent with a solvent; a dispersion liquid of the composite; methods for producing the foregoing; and a plastic substrate formed from the dispersion liquid. The composite comprises a (meth)acrylic-based copolymer having, as side chains, a polyethylene glycol chain and a phosphate residue represented by —OP(O)(OH)2 and having, at at least one end of the molecular chain, —SR (where R represents an alkyl group or the like).
摘要翻译：提供了金属，金，铂金属或铜等金属的纳米颗粒与聚合物的复合物，该复合物简单地通过在室温下干燥而形成具有足够低的电阻率的金属膜，而没有需要任何特殊的加热烘烤步骤或用溶剂去除保护剂的任何步骤; 复合材料的分散液; 生产上述方法; 以及由分散液形成的塑料基板。该复合材料包含（甲基）丙烯酸类共聚物，其具有作为侧链的聚乙二醇链和由-OP（O）（OH）2表示的磷酸酯残基，并且在分子链的至少一端具有 - SR（其中R表示烷基等）。

2. 发明申请

US20120161090A1 RUTILE-TYPE TITANIUM OXIDE CRYSTAL AND MID-INFRARED FILTER USING THE SAME 审中-公开
标题翻译：使用相同类型的氧化锆氧化锆晶体和中红外滤光片
公开(公告)号：US20120161090A1
公开(公告)日：2012-06-28
申请号：US13322346
申请日：2010-05-24
申请人： Pei-Xin Zhu , Ren-Hua Jin
发明人： Pei-Xin Zhu , Ren-Hua Jin
IPC分类号： G02B5/20
CPC分类号： C01G23/047 , C01G23/053 , C01P2002/54 , C01P2002/72 , C01P2002/82 , C09C1/3653 , G02B1/02 , G02B5/208
摘要： A highly versatile material for mid-infrared filters is provided by precisely controlling the absorption intensity of titanium oxide in an infrared region. A rutile-type titanium oxide crystal is produced by a method including a step (I) of dispersing or dissolving a complex of an amino group-containing basic polymer and a transition metal ion in an aqueous medium, a step (II) of obtaining a composite having a polymer/titania layered structure in which the complex of the amino group-containing basic polymer and the transition metal ion is sandwiched between layers of titania, by causing a hydrolysis reaction between the aqueous dispersion or aqueous solution prepared in the step (I) and a water-soluble titanium compound in the aqueous medium, and a step (III) of calcining the composite having the layered structure in an air atmosphere at a temperature of 650° C. or higher to dope a surface of a titanium oxide crystal with the transition metal ion and simultaneously to cause growth into a rutile-type crystal phase. The thus-obtained crystal can be used for mid-infrared filters.
摘要翻译：通过精确控制红外线区域中氧化钛的吸收强度，可以提供中红外线滤光片的多用途材料。通过包含将含氨基的碱性聚合物和过渡金属离子的配合物分散或溶解在水性介质中的工序（I）的方法制造金红石型氧化钛晶体，得到具有聚合物/二氧化钛层状结构的复合体，其中含氨基的碱性聚合物和过渡金属离子的络合物夹在二氧化钛层之间，通过在步骤（I）中制备的水性分散体或水溶液之间进行水解反应）和水性介质中的水溶性钛化合物，以及在650℃以上的温度下在空气气氛中煅烧具有层状结构的复合体的步骤（III），以将氧化钛晶体的表面与过渡金属离子同时引起生长成金红石型晶相。由此获得的晶体可以用于中红外滤光器。

3. 发明申请

US20100104810A1 ORGANIC/INORGANIC COMPOSITE COATING FILM, STRUCTURAL COLOR FILM USING THE SAME, AND PREPARATION METHODS THEREOF 有权
标题翻译：有机/无机复合涂膜，使用其的结构色彩膜及其制备方法
公开(公告)号：US20100104810A1
公开(公告)日：2010-04-29
申请号：US12530903
申请日：2008-03-06
申请人： Norimasa Fukazawa , Ren-Hua Jin
发明人： Norimasa Fukazawa , Ren-Hua Jin
IPC分类号： B32B3/26 , B05D3/10
CPC分类号： C23C18/127 , C03C1/008 , C03C17/009 , C08K3/22 , C08L2205/20 , C09D1/00 , C09D7/67 , C09D7/68 , C09D7/69 , C09D7/70 , C23C18/1216 , C23C18/1254 , C23C18/1295 , Y10T428/24388 , Y10T428/24405 , Y10T428/249953
摘要： An organic/inorganic composite coating film comprising an inorganic material as a matrix and an organic material combined therewith. The coating film has a regular hollow structure therein, and the coating film surface has a rugged pattern with semispherical protrusions. Also provided is a large-area structural color film obtained by burning the composite coating film. The organic/inorganic composite coating film is obtained by applying an aqueous coating composition comprising a metal alkoxide, an aqueous dispersion of monodisperse polymer particles, and an acid catalyst to a substrate and curing the coating composition. Burning the organic/inorganic composite coating film gives the structural color film.
摘要翻译：一种有机/无机复合涂膜，其包含作为基质的无机材料和与其结合的有机材料。涂膜在其中具有规则的中空结构，并且涂膜表面具有具有半球形突起的凹凸图案。还提供了通过燃烧复合涂膜获得的大面积结构彩色膜。有机/无机复合涂膜通过将包含金属醇盐，单分散聚合物颗粒的水分散体和酸催化剂的水性涂料组合物涂覆到基材上并固化涂料组合物而获得。燃烧有机/无机复合涂膜得到结构色膜。

4. 发明申请

US20090198009A1 METAL NANOPARTICLE DISPERSION AND PRODUCTION PROCESS OF THE SAME 审中-公开
标题翻译：金属纳米颗粒分散体及其生产工艺
公开(公告)号：US20090198009A1
公开(公告)日：2009-08-06
申请号：US12309966
申请日：2006-08-09
申请人： Koichiro Matsuki , Seung Taeg Lee , Ren-Hua Jin
发明人： Koichiro Matsuki , Seung Taeg Lee , Ren-Hua Jin
IPC分类号： C08L79/00 , C08G73/04 , C08K3/08
CPC分类号： C08L79/02 , B82Y30/00 , C08G73/024 , C08K3/08 , C08K2201/011
摘要： A metal nanoparticle dispersion comprising: a dispersion of a polymer compound (X), which comprises a polyalkyleneimine chain (a), a hydrophilic segment (b) and a hydrophobic segment (c), and metal nanoparticles (Y).
摘要翻译：一种金属纳米粒子分散体，包括：包含聚亚烷基亚胺链（a），亲水链段（b）和疏水链段（c）的高分子化合物（X）和金属纳米粒子（Y）的分散体。

5. 发明申请

US20070166472A1 Organic-inorganic hybrid nanofiber, organic-inorganic hybrid structure, and method for producing the same 审中-公开
标题翻译：有机 - 无机杂化纳米纤维，有机 - 无机杂化结构及其制备方法
公开(公告)号：US20070166472A1
公开(公告)日：2007-07-19
申请号：US10589439
申请日：2005-02-14
申请人： Ren-Hua Jin , Jian-Jun Yuan
发明人： Ren-Hua Jin , Jian-Jun Yuan
IPC分类号： B05D7/00
CPC分类号： C08G83/001 , B82Y30/00
摘要： The present invention relates to an organic-inorganic hybrid nanofiber formed from a crystalline polymer filament made of a polymer having a straight-chain polyethyleneimine skeleton, and a silica covering the aforementioned crystalline polymer filament, a structure formed from the aforementioned organic-inorganic hybrid nanofiber, and a method for producing the same.
摘要翻译：本发明涉及由具有直链聚乙烯亚胺骨架的聚合物制成的结晶聚合物长丝和覆盖上述结晶聚合物长丝的二氧化硅形成的有机 - 无机杂化纳米纤维，由上述有机 - 无机杂化纳米纤维，及其制造方法。

6. 发明申请

US20120235094A1 SILICA NANOFIBER/METAL OXIDE NANOCRYSTAL COMPOSITE AND METHOD FOR PRODUCING THE SAME 审中-公开
标题翻译：二氧化硅纳米纤维/金属氧化物纳米复合材料及其制造方法
公开(公告)号：US20120235094A1
公开(公告)日：2012-09-20
申请号：US13512854
申请日：2010-11-29
申请人： Pei-Xin Zhu , Ren-Hua Jin
发明人： Pei-Xin Zhu , Ren-Hua Jin
IPC分类号： B05D3/02 , C09K11/59
CPC分类号： C01B33/12 , B82Y30/00 , C01B13/32 , C01P2002/72 , C01P2002/84 , C01P2002/85 , C01P2004/03 , C01P2004/04 , C01P2004/16 , C01P2004/64 , C04B35/6224 , C04B35/62847 , C04B35/62852 , C04B35/62855 , C04B35/62886 , C04B35/62892 , C04B35/63444 , C04B2235/441 , C04B2235/443 , C04B2235/444 , C04B2235/449 , C04B2235/483 , C04B2235/5264 , C08L79/02 , D01F9/08 , Y10T428/298
摘要： A silica nanofiber/metal oxide nanocrystal composite is produced by a method including associating a polymer having a linear polyethyleneimine skeleton in a water-based medium in the presence of ice, adding alkoxysilane to the water-based medium obtained in the above step to form a composite nanofiber including the associate and silica that covers the associate, while the fiber spontaneously forms a disc-shaped network structure, a step of depositing a metal oxide on a surface of the fiber by mixing the disc-shaped structure obtained in the above step with a hydrolyzable metal compound, and a step of calcining the disc-shaped. structure obtained in the step above to form a silica nanofiber through removal of the polymer in the fiber, to convert the metal oxide into a nanocrystal, and to bond the nanocrystal to the fiber. When zinc oxide is used as the metal oxide, the composite functions as a luminous body.
摘要翻译：二氧化硅纳米纤维/金属氧化物纳米晶体复合体通过包括在冰存在下将具有线性聚乙烯亚胺骨架的聚合物在水性介质中缔合而制备的方法，在上述步骤中得到的水性介质中加入烷氧基硅烷，形成复合纳米纤维包括助剂和覆盖助剂的二氧化硅，而纤维自发地形成盘形网状结构，通过将上述步骤获得的盘状结构与水解性金属化合物，以及煅烧所述盘状的步骤。在上述步骤中获得的结构，通过除去纤维中的聚合物形成二氧化硅纳米纤维，将金属氧化物转化为纳米晶体，并将纳米晶体结合到纤维上。当使用氧化锌作为金属氧化物时，复合物起到发光体的作用。

7. 发明授权

US08017234B2 Structural object coated with superhydrophobic nanostructure composite and process for producing the same 有权
标题翻译：涂覆有超疏水纳米结构复合材料的结构物及其制造方法
公开(公告)号：US08017234B2
公开(公告)日：2011-09-13
申请号：US12737128
申请日：2009-05-25
申请人： Ren-Hua Jin , Jian-Jun Yuan
发明人： Ren-Hua Jin , Jian-Jun Yuan
IPC分类号： D02G3/00
CPC分类号： C09C1/30 , B08B17/065 , B82Y30/00 , C01P2004/03 , C01P2004/64 , C03C17/22 , C03C2217/76 , C09C1/3081 , Y10T428/1314 , Y10T428/2935
摘要： The present invention relates to a structural object coated with a superhydrophobic nanostructure composite, the structural object being obtained by densely coating a surface of a solid substrate having a desired shape with a nanostructure obtained by combining a polymer having a polyethyleneimine skeleton with silica on the nanometer order, and bonding a hydrophobic group to the surface of the nanostructure, and a process for producing the structural object. The present invention also relates to a structural object coated with a superhydrophobic nanostructure composite, the structural object being obtained by removing the polymer having the polyethyleneimine skeleton from the nanostructure and bonding a hydrophobic group to the surface of the residual nanostructure containing silica as a main constituent component, and a process for producing the structural object. Furthermore, the present invention provides a method of using the structural object as a container for transferring an aqueous solution.
摘要翻译：本发明涉及涂覆有超疏水纳米结构复合材料的结构物体，该结构物体通过将具有聚乙烯亚胺骨架的聚合物与二氧化硅在纳米上组合而获得的具有所需形状的固体基底的表面密集地涂覆而获得将疏水性基团键合到纳米结构体的表面，以及制造该结构体的工序。本发明还涉及一种涂覆有超疏水性纳米结构复合材料的结构物体，该结构物体是通过从纳米结构中除去具有聚乙烯亚胺骨架的聚合物而获得的，并将疏水基团结合到含有二氧化硅作为主要成分的残余纳米结构物的表面上组件，以及用于生产结构对象的过程。此外，本发明提供一种使用结构物作为水溶液转移容器的方法。

8. 发明申请

US20100087618A1 Linear (meth)acryloyl-containing compound, star (meth) acryloyl- containing compound, and method of manufacture 审中-公开
标题翻译：含有（甲基）丙烯酰基线的化合物，含星形（甲基）丙烯酰基的化合物及其制造方法
公开(公告)号：US20100087618A1
公开(公告)日：2010-04-08
申请号：US12311013
申请日：2006-09-20
申请人： Seung Taeg Lee , Ren-Hua Jin , Jing Yu , Hongwei He , Dou Luo
发明人： Seung Taeg Lee , Ren-Hua Jin , Jing Yu , Hongwei He , Dou Luo
IPC分类号： C08G59/68
CPC分类号： C08F283/10 , C08G59/1438
摘要： A linear (meth)acryloyl-containing compound is offered, including a chemical compound having a structure in which structural units expressed by the following general formula (1) (In Formula (1), A is a bivalent hydrocarbon radical which may contain heteroatoms.) are connected by the following general formula (2) or (3) (In Formula (3), R is a hydrogen atom or a methyl group.) (provided that the same substance or different substances may be connected as A of the aforementioned general formula (1)), and the molecular ends are epoxy groups or are expressed by the following general formula (4) (In Formula (4), R is a hydrogen atom or methyl group, and B is a monovalent hydrocarbon radical.), wherein the totality of the structural units expressed by the aforementioned general formula (3) or the aforementioned general formula (4) includes an average of 3 or more in a single molecule, and the number average molecular weight is 500-10,000.
摘要翻译：提供了含（甲基）丙烯酰基的线型化合物，包括其结构由以下通式（1）表示的化合物（在式（1）中，A为可含有杂原子的二价烃基）。）通过以下通式（2）或（3）连接（在式（3）中，R是氢原子或甲基）（前提是相同的物质或不同的物质可以连接为上述通式（1）），分子末端为环氧基，或由以下通式（4）表示（式（4）中，R为氢原子或甲基，B为单价烃基。其中由上述通式（3）或上述通式（4）表示的结构单元的总数在单个分子中平均为3以上，数均分子量为500〜10000。

9. 发明申请

US20100062928A1 METHOD FOR PRODUCTION OF DOPED TITANIUM OXIDE, DOPED TITANIUM OXIDE, AND VISIBLE LIGHT-RESPONSIVE PHOTOCATALYST COMPRISING THE DOPED TITANIUM OXIDE 有权
标题翻译：用于生产氧化铅，氧化铅的方法和包含氧化铅的可见光反应光催化剂
公开(公告)号：US20100062928A1
公开(公告)日：2010-03-11
申请号：US12518957
申请日：2007-12-10
申请人： Ren-Hua Jin , Pei-Xin Zhu , Norimasa Fukazawa
发明人： Ren-Hua Jin , Pei-Xin Zhu , Norimasa Fukazawa
IPC分类号： B01J31/06 , C08K3/22
CPC分类号： C01G23/047 , B01J21/063 , B01J23/06 , B01J23/26 , B01J23/34 , B01J23/72 , B01J23/745 , B01J23/75 , B01J23/755 , B01J35/002 , B01J35/004 , B01J35/006 , B01J37/0018 , B01J37/031 , B01J37/08 , B01J37/084 , B82Y30/00 , C01G23/04 , C01P2002/01 , C01P2002/22 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/82 , C01P2002/84 , C01P2002/86 , C01P2002/88 , C01P2004/04 , C01P2004/64 , C09C1/3676
摘要： The present invention provides a doped titanium oxide having visible light-responsiveness whose structure is specified, and a simple production method thereof. By burning with heat a layered structure composite laminated alternately with polymer and the titania, which is obtained using basic polymer having amino group(s) and water-soluble titanium compound, carbon atoms and nitrogen atoms in the polymer are, doped to the crystalline surface of titanium oxide. As making the polymer complex with metal ions beforehand, the metal ions can be also doped to the titanium oxide.
摘要翻译：本发明提供具有可见光响应性的掺杂氧化钛，其结构被指定，并且其简单的制备方法。通过加热将与使用具有氨基和水溶性钛化合物的碱性聚合物获得的聚合物和二氧化钛交替层叠的层状结构复合物，聚合物中的碳原子和氮原子掺杂到晶体表面的氧化钛。当预先将金属离子与金属离子配合时，金属离子也可以掺杂到氧化钛中。

10. 发明授权

US07670509B2 Composite nanofiber, composite nanofiber association, complex structure, and production method thereof 失效
标题翻译：复合纳米纤维，复合纳米纤维关联，复合结构及其制备方法
公开(公告)号：US07670509B2
公开(公告)日：2010-03-02
申请号：US11569300
申请日：2005-05-27
申请人： Ren-Hua Jin , Jian-Jun Yuan
发明人： Ren-Hua Jin , Jian-Jun Yuan
IPC分类号： H01B1/00
CPC分类号： C08L79/02 , B82Y30/00 , D01F6/96 , D06M11/79 , D06M13/507 , D06M2101/30 , Y10T428/12035 , Y10T428/12174 , Y10T428/12438 , Y10T428/24603 , Y10T442/2885
摘要： A silica nanofiber is derived from a crystalline polymer filament of a polymer including straight chain polyethyleneimine backbones, which is capable of forming a water-insoluble crystal in the presence of water molecules at room temperature, and the crystalline polymer filament in the silica concentrates metal ions, thereby realizing a composite nanofiber including metals or metal ions in the silica. Furthermore, the composite nanofiber of the present invention can be easily produced by fixing a polymer structure in the silica as the scaffold for metal ions and concentrating metal ions at the scaffold or reducing the metal ions. Furthermore, a metal-containing silica nanofiber can be easily obtained by removing a polymer component from the composite nanofiber, the composite nanofiber association, and the complex nanofiber structure. These nanofibers can be assembled and integrated, and the assembled or integrated association or structure can realize various shapes.
摘要翻译：二氧化硅纳米纤维来源于包含直链聚乙烯亚胺骨架的聚合物的结晶聚合物长丝，其能够在室温下在水分子存在下形成水不溶性晶体，并且二氧化硅中的结晶聚合物长丝浓缩金属离子从而实现在二氧化硅中包含金属或金属离子的复合纳米纤维。此外，本发明的复合纳米纤维可以通过将二氧化硅中的聚合物结构固定在金属离子的支架上并将金属离子浓缩在支架上或还原金属离子而容易地制备。此外，通过从复合纳米纤维，复合纳米纤维结合体和复合纳米纤维结构中除去聚合物组分，可以容易地获得含金属的二氧化硅纳米纤维。这些纳米纤维可以组装和集成，并且组装或整合的关联或结构可以实现各种形状。

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