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31. 发明授权

US07442810B2 Method for the production of defined mixtures of THF, BDO and GBL by gas phase hydrogenation 失效
标题翻译：通过气相氢化制备THF，BDO和GBL的限定混合物的方法
公开(公告)号：US07442810B2
公开(公告)日：2008-10-28
申请号：US10581074
申请日：2004-12-04
申请人： Markus Roesch , Rolf Pinkos , Michael Hesse , Stephan Schlitter , Henrik Junicke , Olga Schubert , Alexander Weck , Gunther Windecker
发明人： Markus Roesch , Rolf Pinkos , Michael Hesse , Stephan Schlitter , Henrik Junicke , Olga Schubert , Alexander Weck , Gunther Windecker
IPC分类号： C07D307/00 , C07D307/02
CPC分类号： C07D307/33 , C07D307/08
摘要： A process for variably preparing mixtures of optionally alkyl-substituted BDO, GBL and THF by two-stage hydrogenation in the gas phase of C4 dicarboxylic acids and/or derivatives thereof, which comprises a) hydrogenating in a gas phase a gas stream of C4 dicarboxylic acids and/or derivatives thereof over a particular catalyst at a particular pressure and temperature to give a stream mainly containing of optionally alkyl-substituted GBL and THF, b) removing any succinct anhydride, c) converting the products remaining predominantly in the gas phase in the partial condensation, THF, water and GBL to give a stream comprising a mixture of BDO, GBL and THF, d) removing the hydrogen from the products and recycling it into the hydrogenation, e) distillatively separating the products, THF, BDO, GBL and water, if appropriate recycling a GBL-rich stream or if appropriate discharging it, and working up BDO, THF and GBL distillatively, and setting the ratio of the products, THF, GBL and BDO, relative to one another within the range from 10 to 100% by weight of THF, from 0 to 90% by weight of GBL and from 0 to 90% by weight of BDO only by varying the temperatures in the two hydrogenation zones and also if appropriate the GBL recycle stream.
摘要翻译：一种在可能地制备任选烷基取代的BDO，GBL和THF的混合物的方法，其通过在C 4 C 4羧酸和/或其衍生物的气相中进行两步氢化，其包括a）在在特定的压力和温度下，将特定催化剂上的C 4 O 2羧酸和/或其衍生物的气流气相，得到主要含有烷基取代的GBL和THF的物流，b）除去任何简单的酸酐，c）将部分冷凝，THF，水和GBL中主要保留在气相中的产物进行转化，得到包含BDO，GBL和THF的混合物的流，d）从产物中除去氢并将其再循环进入氢化，e）蒸馏分离产物，THF，BDO，GBL和水，如果适当回收富含GBL的物流或适当排放，并蒸馏处理BDO，THF和GBL，并设定产物的比例，TH F，GBL和BDO相对于10重量％至100重量％的THF，0至90重量％的GBL和0至90重量％的BDO，仅通过改变两者中的温度加氢区，如果合适的话也可以使用GBL再循环流。

32. 发明申请

US20080221371A1 Method for the Separation of Polymeric By-Products from 1,4-Butynediol 失效
标题翻译：从1,4-丁炔二醇分离聚合副产物的方法
公开(公告)号：US20080221371A1
公开(公告)日：2008-09-11
申请号：US12065311
申请日：2006-08-23
申请人： Rudolf Erich Lorenz , Rolf Pinkos , Michael Steiniger , Gerd Schafer , Thomas Danner
发明人： Rudolf Erich Lorenz , Rolf Pinkos , Michael Steiniger , Gerd Schafer , Thomas Danner
IPC分类号： C07C29/17 , C07C31/20 , C07C29/68
CPC分类号： C07C29/76 , C07C29/17 , C07C29/172 , C07C33/046 , C07C33/035 , C07C31/207
摘要： The present invention relates to a process for purifying 1,4-butynediol, which comprises compressing 1,4-butynediol to from 50 to 1500 bar, depressurizing it, waiting for phase separation to occur after depressurization and separating off the bottom phase, and a process for the hydrogenation of 1,4-butynediol to 1,4-butenediol and 1,4-butanediol using the purified 1,4-butynediol.
摘要翻译：本发明涉及一种纯化1,4-丁炔二醇的方法，其包括将1,4-丁炔二醇压缩至50至1500巴，对其进行减压，等待在减压和分离底相后发生相分离，以及使用纯化的1,4-丁炔二醇将1,4-丁炔二醇氢化成1,4-丁烯二醇和1,4-丁二醇的方法。

33. 发明授权

US07408083B2 Method for the production of diaminodiarylmethanes 失效
标题翻译：二氨基二芳基甲烷的制备方法
公开(公告)号：US07408083B2
公开(公告)日：2008-08-05
申请号：US10564059
申请日：2004-06-25
申请人： Ulrich Steinbrenner , Eckhard Stroefer , Martin Sohn , Veronika Quaschning , Helmut Moehwald , Kai Thiele , Filip Deberdt , Jan D. Jacobs , Rolf Pinkos
发明人： Ulrich Steinbrenner , Eckhard Stroefer , Martin Sohn , Veronika Quaschning , Helmut Moehwald , Kai Thiele , Filip Deberdt , Jan D. Jacobs , Rolf Pinkos
IPC分类号： C07C209/78
CPC分类号： C07C209/86 , C07C209/78 , C07C211/50
摘要： A process is described for preparing diaminodiarylmethanes comprising the steps a) reacting an aromatic amine with a methylene-donating agent in the presence of homogeneous acid catalysts, b) removing the homogeneous acid catalyst from the reaction product, c) working up and purifying the reaction product, which comprises removing the homogeneous acid catalyst from the reaction mixture by adsorption to a solid adsorbent.
摘要翻译：描述了制备二氨基二芳基甲烷的方法，包括以下步骤：a）在均相酸催化剂存在下使芳族胺与亚甲基供体试剂反应，b）从反应产物中除去均相酸催化剂，c）加工并纯化反应产物，其包括通过吸附到固体吸附剂从反应混合物中除去均相酸催化剂。

34. 发明申请

US20080058539A1 Method for the Distillative Processing of Tetrahydrofuran 有权
标题翻译：四氢呋喃蒸馏处理方法
公开(公告)号：US20080058539A1
公开(公告)日：2008-03-06
申请号：US11575668
申请日：2005-09-21
申请人： Gunther Windecker , Alexander Weck , Markus Rosch , Michael Steiniger , Rolf Pinkos , Dany Hautte
发明人： Gunther Windecker , Alexander Weck , Markus Rosch , Michael Steiniger , Rolf Pinkos , Dany Hautte
IPC分类号： C07D307/02
CPC分类号： C07D307/08
摘要： The present invention provides a process for distillatively purifying tetrahydrofuran in the presence of a polar solvent.
摘要翻译：本发明提供一种在极性溶剂存在下蒸馏精制四氢呋喃的方法。

35. 发明申请

US20060052551A1 Method for producing monoesters and diesters of polytetrahydrofuran and of tetrahydrofuran copolymers 有权
标题翻译：聚四氢呋喃和四氢呋喃共聚物的单酯和二酯的制备方法
公开(公告)号：US20060052551A1
公开(公告)日：2006-03-09
申请号：US10527583
申请日：2003-09-04
申请人： Rolf Pinkos , Achim Gerstlauer , Martin Haubner , Stephan Sehlitter , Stefan Kashammer , Klaus Pfaff
发明人： Rolf Pinkos , Achim Gerstlauer , Martin Haubner , Stephan Sehlitter , Stefan Kashammer , Klaus Pfaff
IPC分类号： C08G59/14
CPC分类号： C08G65/20
摘要： The present invention provides a process for preparing mono- or diesters of polytetrahydrofuran or of tetrahydrofuran copolymers by polymerizing tetrahydrofuran in the presence of at least one telogen and/or of a comonomer over an acidic catalyst, wherein the polymerization reactor is started up using a mixture of polytetrahydrofuran, the mono- or diesters of polytetrahydrofuran and/or of the THF copolymers, tetrahydrofuran, any comonomer and at least one carboxylic acid and/or one carboxylic anhydride.
摘要翻译：本发明提供了一种通过在酸性催化剂上在至少一种环糊精和/或共聚单体存在下使四氢呋喃聚合来制备聚四氢呋喃或四氢呋喃共聚物的单酯或二酯的方法，其中聚合反应器使用混合物的聚四氢呋喃，聚四氢呋喃和/或THF共聚物，四氢呋喃，任何共聚单体和至少一种羧酸和/或一种羧酸酐的单酯或二酯。

36. 发明授权

US06888021B2 Hydrogenation of benzenepolycarboxylic acids or derivatives thereof using a catalyst containing macropores 有权
标题翻译：使用含有大孔的催化剂氢化苯多元羧酸或其衍生物
公开(公告)号：US06888021B2
公开(公告)日：2005-05-03
申请号：US09879456
申请日：2001-06-13
申请人： Melanie Brunner , Arnd Böttcher , Boris Breitscheidel , Klaus Halbritter , Jochem Henkelmann , Lucien Thil , Rolf Pinkos
发明人： Melanie Brunner , Arnd Böttcher , Boris Breitscheidel , Klaus Halbritter , Jochem Henkelmann , Lucien Thil , Rolf Pinkos
IPC分类号： B01J23/46 , C07B61/00 , C07C51/36 , C07C61/08 , C07C61/09 , C07C67/303 , C07C69/75 , C08K5/12 , C07C69/74 , C07C69/66 , C08K5/09
CPC分类号： C08K5/12 , C07C51/36 , C07C67/303 , C07C69/75 , C07C2601/14 , C07C61/09
摘要： A process for producing plasticizers in which a phthalic acid having the CAS Nos. 111381-89-6, 111381-90-9, 111381-91-0, 68515-44-6, 68515-45-7 and 3648-20-7, the formed plasticizers and a method of increasing the plasticity of a plastic product.
摘要翻译：一种生产增塑剂的方法，其中具有CAS号111381-89-6,111381-90-9,111381-91-0,68515-44-6,68515-45-7和3648-20-7的邻苯二甲酸，形成的增塑剂和增加塑料制品的可塑性的方法。

37. 发明授权

US06596862B2 Purification of N-vinyl-&egr;-caprolactam 有权
标题翻译： N-乙烯基-ε-己内酰胺的纯化
公开(公告)号：US06596862B2
公开(公告)日：2003-07-22
申请号：US10152637
申请日：2002-05-23
申请人： Arnd Böttcher , Rolf Pinkos , Rudolf Erich Lorenz , Heike Becker
发明人： Arnd Böttcher , Rolf Pinkos , Rudolf Erich Lorenz , Heike Becker
IPC分类号： C07D22310
CPC分类号： C07D223/10 , C07D201/16
摘要： A process for purifying N-vinyl-&egr;-caprolactam comprises converting the N-vinyl-&egr;-caprolactam which is to be purified and has a purity of at least 95% by weight into a melt, partially crystallizing the melt and separating the crystals from the mother liquor.
摘要翻译：一种纯化N-乙烯基-ε-己内酰胺的方法包括将要纯化的纯度为至少95重量％的N-乙烯基-ε-己内酰胺转化成熔体，使熔体部分结晶并将晶体从母酒。

38. 发明授权

US06407294B1 Method for producing 1,6-hexanediol 有权
标题翻译： 1,6-己二醇的制备方法
公开(公告)号：US06407294B1
公开(公告)日：2002-06-18
申请号：US09529789
申请日：2000-04-20
申请人： Boris Breitscheidel , Rolf Pinkos , Frank Stein , Shelue Liang , Rolf Hartmuth Fischer
发明人： Boris Breitscheidel , Rolf Pinkos , Frank Stein , Shelue Liang , Rolf Hartmuth Fischer
IPC分类号： C07C2700
CPC分类号： C07C29/149 , C07C2601/08 , C07C35/06 , C07C31/135 , C07C31/20
摘要： A process for producing 1,6-hexanediol by hydrogenation of adipic esters and/or 6-hydroxycaproic esters in the gas phase at elevated temperature and elevated pressure in the presence of chromium-free catalysts comprises hydrogenating a) over a catalyst comprising copper, manganese and aluminum as essential constituents or over Raney copper, b) at a temperature of from 150 to 230° C. and a pressure of from 10 to 70 bar, c) at a molar ratio of hydrogen to ester to be hydrogenated within the range from 150:1 to 300:1, and d) at a catalyst space velocity of from 0.01 to 0.3 kg of C6 ester per liter of catalyst per hour.
摘要翻译：在无铬催化剂存在下，在升高的温度和升高的压力下，气相中己二酸酯和/或6-羟基己酸酯的氢化制备1,6-己二醇的方法包括在包含铜，锰和铝作为必需组分或在阮内铜上，b）在150-230℃的温度和10至70巴的压力下，c）以氢化至酯的摩尔比在150℃的范围内：1至300:1，和d），催化剂空速为每升催化剂每小时0.01至0.3kg的C6酯。

39. 发明授权

US06313358B1 Method for producing hexanediol 失效
标题翻译：己二醇的制备方法
公开(公告)号：US06313358B1
公开(公告)日：2001-11-06
申请号：US09673125
申请日：2000-10-11
申请人： Boris Breitscheidel , Rolf Pinkos , Frank Stein
发明人： Boris Breitscheidel , Rolf Pinkos , Frank Stein
IPC分类号： C07C2700
CPC分类号： B01J23/72 , C07C29/149 , C07C67/60 , C07C2601/14 , C07C69/44 , C07C31/20 , C07C35/14
摘要： Hexanediol is prepared by hydrogenating dialkyl adipates or mixtures which contain a dialkyl adipate as the essential component and organic halogen compounds as impurities, by a process in which, before the hydrogenation, the dialkyl adipates or the mixtures containing dialkyl adipates are passed at from 50 to 250° C. and from 1 to 100 bar over copper catalysts which have a copper content, calculated as CuO, of from 0.5 to 80% by weight, a surface area of from 5 to 1500 m2/g, a porosity of from 0.05 to 1.5 cm3/g and a copper surface area of from 0.1 to 20 m2/g, in order to remove the organic halogen compounds.
摘要翻译：通过以下方法将含己二酸二烷基酯的二烷基己二酸酯或其混合物加氢制备，其中氢化前，己二酸二烷基酯或含有己二酸二烷基酯的混合物在50至 250℃和1至100巴，铜铜催化剂的铜含量（按CuO计）为0.5至80重量％，表面积为5至1500平方米/克，孔隙率为0.05至 1.5cm 3 / g，铜表面积为0.1〜20m 2 / g，以除去有机卤素化合物。

40. 发明授权

US5965751A Process for hydrogenation of dihydrofurans to give tetrahydrofurans 失效
标题翻译：二氢呋喃氢化制得四氢呋喃的方法
公开(公告)号：US5965751A
公开(公告)日：1999-10-12
申请号：US68978
申请日：1998-05-22
申请人： Franz Josef Brocker , Rolf Fischer , Gerd Kaibel , Rolf Pinkos
发明人： Franz Josef Brocker , Rolf Fischer , Gerd Kaibel , Rolf Pinkos
IPC分类号： B01J37/02 , C07D307/08 , C23C14/16 , B01J23/44
CPC分类号： C07D307/08 , B01J37/0225 , B01J37/0238 , C23C14/16
摘要： In a process for the catalytic hydrogenation of 2,5- and 2,3-dihydrofuran with hydrogen to give tetrahydrofuran, use is made of a catalyst in which a metal or a plurality of metals have been deposited by vapor deposition or sputtering on a metal wire mesh or a metal foil as support.
摘要翻译： PCT No.PCT / EP96 / 05071 Sec。 371日期：1998年5月22日 102（e）日期1998年5月22日PCT 1996年11月18日PCT公布。第WO97 / 19939号公报日期：1997年6月5日在用氢气将2,5-和2,3-二氢呋喃催化氢化得到四氢呋喃的方法中，使用其中通过气相沉积沉积金属或多种金属的催化剂或溅射在金属丝网或金属箔上作为载体。

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