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    • 31. 发明授权
    • Semiconductor device
    • 半导体器件
    • US07586143B2
    • 2009-09-08
    • US11339701
    • 2006-01-26
    • Kenichi Watanabe
    • Kenichi Watanabe
    • H01L27/108
    • H01L21/486H01L23/5223H01L23/5226H01L28/40H01L28/60H01L2924/0002H01L2924/00
    • A substrate is provided with a first wiring layer 111, an interlayer insulating film 132 on the first wiring layer 111, a hole 112A formed in the interlayer insulating film, a first metal layer 112 covering the hole 112A, a second metal layer 113 formed in the hole 112A, a dielectric insulating film 135 on the first metal layer 112, and second wiring layers 114-116 on the dielectric insulating film 135, wherein the first metal layer 112 constitutes at least part of the lower electrode, an area, facing the lower electrode, of the second wiring layers 114-116 constitutes the upper electrode, and a capacitor 160 is constructed of the lower electrode, the dielectric insulating film 135 and the upper electrode P1.
    • 基板在第一布线层111上设置有第一布线层111,层间绝缘膜132,形成在层间绝缘膜中的孔112A,覆盖孔112A的第一金属层112,形成在第一布线层111上的第二金属层113 孔112A,第一金属层112上的介电绝缘膜135和介电绝缘膜135上的第二布线层114-116,其中第一金属层112构成下电极的至少一部分,面向 第二布线层114-116的下电极构成上电极,电容器160由下电极,电介质绝缘膜135和上电极P1构成。
    • 39. 发明申请
    • Silsesquioxane derivative having functional group
    • 具有官能团的倍半硅氧烷衍生物
    • US20060089504A1
    • 2006-04-27
    • US11294364
    • 2005-12-06
    • Kenya ItoMikio YamahiroKenichi Watanabe
    • Kenya ItoMikio YamahiroKenichi Watanabe
    • C07F7/10
    • C08G77/06C08G77/045C08G77/38
    • A conventional silsesquioxane derivative has the problems that the functional groups are restricted and the chemical structure is not readily controlled and that it is expensive. The present inventors have developed a process for producing a silsesquioxane derivative at a high yield by a simple process in order to solve such problems. The novel silsesquioxane derivative according to the present invention is controlled in a structure thereof and has a functional group, which is excellent in reactivity with a target compound, to be modified. The present invention relates to a production process for a silsesquioxane derivative represented by Formula (2), characterized by using a silicon compound represented by Formula (1). In Formula (1) and Formula (2), R is a group selected from hydrogen, alkyl, aryl and arylalkyl; M is a monovalent alkaline metal atom; at least one of Y is a group represented by Formula (3), and the remainder of Y is hydrogen; R1 and R2 in Formula (3) represent the same group as defined for R; and Z is a functional group or a group having a functional group.
    • 常规的倍半硅氧烷衍生物存在官能团受限并且化学结构不容易控制并且昂贵的问题。 为了解决这些问题,本发明人通过简单的工艺开发了高产率的倍半硅氧烷衍生物的制备方法。 根据本发明的新型倍半硅氧烷衍生物在其结构中被控制,并且具有与待改性的目标化合物的反应性优异的官能团。 本发明涉及由式(2)表示的倍半硅氧烷衍生物的制备方法,其特征在于使用由式(1)表示的硅化合物。 在式(1)和式(2)中,R是选自氢,烷基,芳基和芳基烷基的基团; M是一价碱性金属原子; Y中的至少一个为由式(3)表示的基团,Y的其余部分为氢; 式(3)中的R 1和R 2代表与R所定义的相同的基团; Z为官能团或具有官能团的基团。