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31. 发明授权

US3988388A Polymerizable organic dispersion of unsaturated polyester vinyl monomer and EVA copolymers 失效
标题翻译：不饱和聚酯乙烯基单体和EVA共聚物的可聚合有机分散体
公开(公告)号：US3988388A
公开(公告)日：1976-10-26
申请号：US552860
申请日：1975-02-25
申请人： Heinrich Alberts , Hansjochen Schulz-Walz , Herbert Bartl , Leonhard Goerden , Klaus Schuster
发明人： Heinrich Alberts , Hansjochen Schulz-Walz , Herbert Bartl , Leonhard Goerden , Klaus Schuster
IPC分类号： C08L67/00 , C08J3/09 , C08J5/24 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/06 , C08L77/00 , C08L101/00
CPC分类号： C08J5/24 , C08J3/09 , C08L67/06 , C08J2367/06
摘要： Pourable and pumpable, storage-stable organic dispersions which can be cured with little shrinkage comprising unsaturated polyesters, copolymerizable vinyl monomers, ethylene vinyl ester copolymers and optionally dispersing agents.
摘要翻译：可浇注和可泵送的储存稳定的有机分散体，其可以几乎不收缩而固化，包括不饱和聚酯，可共聚乙烯基单体，乙烯乙烯基酯共聚物和任选的分散剂。

32. 发明授权

US3962371A Weather-resistant thermoplasts 失效
标题翻译：耐候热塑性塑料
公开(公告)号：US3962371A
公开(公告)日：1976-06-08
申请号：US530171
申请日：1974-12-06
申请人： Heinrich Alberts , Herbert Bartl , Richard Prinz , Salah Elabd Elghani , Winfried Fischer
发明人： Heinrich Alberts , Herbert Bartl , Richard Prinz , Salah Elabd Elghani , Winfried Fischer
IPC分类号： C08L33/00 , C08L23/00 , C08L25/00 , C08L25/12 , C08L33/02 , C08L33/18 , C08L51/00 , C08L51/02 , C08L51/06 , C08L101/00 , C08L51/04 , C08L23/08 , C08L23/14
CPC分类号： C08L25/12 , C08L33/18 , C08L51/003 , C08L51/06
摘要： Weather-resistant thermoplastic moulding compounds of mixtures ofA. copolymers of (meth)acrylonitrile, of at least one aromatic vinyl compound and of optionally at least one monoolefin, andB. a graft copolymer of an ethylene/vinyl ester copolymer as graft substrate and grafted polymerized units of (meth)acrylonitrile of at least one aromatic monovinyl compound and of optionally at least one aliphatic monoolefin.
摘要翻译：（甲基）丙烯腈，至少一种芳族乙烯基化合物和任选的至少一种单烯烃的A.共聚物的混合物的耐候性热塑性成型化合物和B.作为接枝基材的乙烯/乙烯基酯共聚物的接枝共聚物和至少一种芳族单乙烯基化合物和任选的至少一种脂肪族单烯烃的（甲基）丙烯腈的接枝聚合单元。

33. 发明授权

US3941756A New water-insoluble preparations of peptide materials, their production and their use 失效
标题翻译：肽材料的新型水不溶性制剂，其生产及其用途
公开(公告)号：US3941756A
公开(公告)日：1976-03-02
申请号：US481225
申请日：1974-06-20
申请人： Fritz Huper , Erich Rauenbusch , Gunter Schmidt-Kastner , Bruno Bomer , Herbert Bartl
发明人： Fritz Huper , Erich Rauenbusch , Gunter Schmidt-Kastner , Bruno Bomer , Herbert Bartl
IPC分类号： C08F8/00 , C08F20/20 , C12N11/08 , C08F220/20 , C08F222/04
CPC分类号： C12N11/08 , C08F20/20 , C08F8/00
摘要： There are disclosed water-insoluble proteinic preparations in which a protein or polypeptide is bound to a copolymer, which preparations are useful for binding enzymes in order to carry out enzyme-catalyzable reactions. These preparations comprise a peptide material bound to a crosslinked copolymer comprising the following copolymerized units:A. about 0.1 to 30 wt. % of at least one .alpha.,.beta.-monoolefinically unsaturated dicarboxylic acid anhydride having about 4 to 9 carbon atoms;B. about 35 to 90 wt. % of at least one di- and/or poly(meth)acrylate of a diol and/or polyol as hereinafter defined; andC. about 5 to 60 wt. % of at least one hydrophilic monomer,The copolymer having a bulk volume of 1.4 to 30 ml/g and a specific surface area of about 1 to 500 m.sup.2 /g, and containing, after saponification of the anhydride groups, about 0.01 to 14 milliequivalents of acid per gram.
摘要翻译：公开了其中蛋白质或多肽与共聚物结合的水不溶性蛋白质制剂，该制剂可用于结合酶以进行酶促催化反应。这些制剂包含与包含以下共聚单元的交联共聚物结合的肽材料：

34. 发明授权

US5616529A Process for the preparation of branched low-pressure polyethylene, new low-pressure polyethylenes, and preformed bifunctional catalysts 失效
标题翻译：制备支链低压聚乙烯，新型低压聚乙烯和预制双功能催化剂的方法
公开(公告)号：US5616529A
公开(公告)日：1997-04-01
申请号：US607651
申请日：1996-02-27
申请人： Karl-Heinz A. Ostoja-Starzewski , Josef Witte , Herbert Bartl , Karl-Heinz Reichert , Georgios Vasiliou
发明人： Karl-Heinz A. Ostoja-Starzewski , Josef Witte , Herbert Bartl , Karl-Heinz Reichert , Georgios Vasiliou
IPC分类号： C08F4/78 , C08F4/00 , C08F4/02 , C08F4/22 , C08F4/24 , C08F4/60 , C08F4/72 , C08F4/80 , C08F8/00 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/26 , C08F210/02
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F210/16
摘要： Branched low-pressure polyethylenes are prepared by oligomerization of ethylene on a nickel-containing catalyst and polymerization of the oligomers obtained, if appropriate in the presence of ethylene, on a chromium-containing catalyst.
摘要翻译：分支的低压聚乙烯是通过在含镍催化剂上乙烯低聚而制备的，如果合适的话，在含铬催化剂上聚合获得的低聚物。

35. 发明授权

US4620021A Organic nickel compounds, production and use thereof as catalysts in the polymerization of olefins 失效
标题翻译：有机镍化合物，其在烯烃聚合中的生产和用途作为催化剂
公开(公告)号：US4620021A
公开(公告)日：1986-10-28
申请号：US654227
申请日：1984-09-25
申请人： Karl-Heinz A. O. Starzewski , Josef Witte , Herbert Bartl
发明人： Karl-Heinz A. O. Starzewski , Josef Witte , Herbert Bartl
IPC分类号： C08L67/00 , C07F15/04 , C08F4/26 , C08F4/60 , C08F4/80 , C08F10/00 , C08J3/24 , C08L69/00
CPC分类号： C07F15/04 , C08F10/00
摘要： Olefins such as ethylene can be polymerized with a catalyst which comprises nickel compounds obtained by reacting a nickel-(O) compound or a nickel compound which may be converted in situ into a nickel-(O) compound with an adduct or a mixture of a quinoid compound and a tertiary phosphine and with a compound corresponding to the following general formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkenyl, C.sub.6 -C.sub.12 aryl or C.sub.3 -C.sub.8 cycloalkyl optionally substituted by halogen, hydroxy, C.sub.1 -C.sub.20 alkoxy, nitro or C.sub.6 -C.sub.12 aryloxy; also C.sub.6 -C.sub.12 aryl-C.sub.1 -C.sub.20 alkyl, C.sub.6 -C.sub.12 aryl-C.sub.2 -C.sub.20 alkenyl, C.sub.1 -C.sub.20 alkyl-C.sub.6 -C.sub.12 aryl, C.sub.1 -C.sub.20 alkyl-C.sub.3 -C.sub.8 cycloalkyl and C.sub.6 -C.sub.12 aryl-C.sub.3 -C.sub.8 cycloalkyl, di-C.sub.1 -C.sub.4 alkylamino, optionally substituted phenoxy or alkoxy; R.sup.4, R.sup.5 and R.sup.6 represent hydrogen, silyl, halogen, cyano or R.sup.1 andX represents O, NR.sub.4 or ##STR2##
摘要翻译：烯烃如乙烯可以与催化剂聚合，所述催化剂包括通过使镍 - （O）化合物或镍化合物原位转化成镍 - （O）化合物而获得的镍化合物与加合物或其混合物喹啉化合物和叔膦，并具有对应于下列通式的化合物：其中R 1，R 2和R 3独立地表示C 1 -C 20烷基，C 2 -C 20烯基，C 6 -C 12芳基或C 3 -C 8环烷基任选被卤素，羟基，C 1 -C 20烷氧基，硝基或C 6 -C 12芳氧基取代; 还有C 6 -C 12芳基-C 1 -C 20烷基，C 6 -C 12芳基-C 2 -C 20烯基，C 1 -C 20烷基-C 6 -C 12芳基，C 1 -C 20烷基-C 3 -C 8环烷基和C 6 -C 12芳基-C 3 -C 8环烷基，二-C 1 -C 4烷基氨基，任选取代的苯氧基或烷氧基; R4，R5和R6表示氢，甲硅烷基，卤素，氰基或R1，X表示O，NR4或

36. 发明授权

US4360635A Thermoplastic moulding compositions of cellulose ester graft copolymers or mixtures thereof with cellulose esters 失效
标题翻译：纤维素酯接枝共聚物或其与纤维素酯的混合物的热塑性模塑组合物
公开(公告)号：US4360635A
公开(公告)日：1982-11-23
申请号：US215939
申请日：1980-12-12
申请人： Heinrich Alberts , Winfried Fischer , Christian Leuschke , Herbert Bartl
发明人： Heinrich Alberts , Winfried Fischer , Christian Leuschke , Herbert Bartl
IPC分类号： C08F255/02 , C08F263/02 , C08L31/04 , C08L51/02 , C08L51/00 , C08F291/06
CPC分类号： C08F255/026 , C08F263/02 , C08L31/04 , C08L51/02
摘要： Transparent thermoplastic moulding compositions having improved mechanical properties consist of graft copolymers or mixtures thereof with a cellulose ester of aliphatic C.sub.1 -C.sub.5 carboxylic acids, wherein the graft copolymers consist of an ethylene vinyl ester copolymer and a cellulose ester of aliphatic C.sub.1 -C.sub.5 -carboxylic acids as the graft substrate, at least part of which being bridged with polymerized grafted units of vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid, and, optionally, C.sub.2 -C.sub.4 -olefins.
摘要翻译：具有改进的机械性能的透明热塑性模塑组合物由接枝共聚物或其与脂族C 1 -C 5羧酸纤维素酯的混合物组成，其中接枝共聚物由乙烯乙烯基酯共聚物和脂族C 1 -C 5羧酸的纤维素酯组成作为接枝基材，其至少一部分与丙烯酸和/或甲基丙烯酸的乙烯基酯和/或烷基酯的聚合接枝单元和任选的C 2 -C 4 - 烯烃桥接。

37. 发明授权

US4347341A Process for the production of ethylene graft copolymers containing anhydride or carboxyl groups 失效
标题翻译：制备含有酸酐或羧基的乙烯接枝共聚物的方法
公开(公告)号：US4347341A
公开(公告)日：1982-08-31
申请号：US295642
申请日：1981-08-24
申请人： Herbert Bartl , Klaus Schuster
发明人： Herbert Bartl , Klaus Schuster
IPC分类号： C08F255/00 , C08F255/02 , C08F263/00 , C08F263/02 , C08F263/04
CPC分类号： C08F263/02 , C08F255/02
摘要： A process for the production of ethylene graft copolymers containing anhydride or carboxyl groups in homogeneous or heterogeneous phase in tert.-butanol or methylene chloride wherein (A) from 5 to 70% by weight of a monomer mixture of: (a) from 10 to 80% by weight of a vinyl ester of an aliphatic C.sub.1 -C.sub.18 -monocarboxylic acid; and (b) from 90 to 30% by weight of maleic acid anhydride and/or its C.sub.1 -C.sub.20 -alkyl semiesters; are radically polymerized in the presence of (B) from 95 to 30% by weight of an ethylene homopolymer or an ethylene/vinyl ester copolymer as the graft substrate.
摘要翻译：一种在叔丁醇或二氯甲烷中制备均相或非均相含有酸酐或羧基的乙烯接枝共聚物的方法，其中（A）5-70重量％的单体混合物：（a）10〜 80重量％的脂族C1-C18-一元羧酸的乙烯基酯; 和（b）90至30重量％的马来酸酐和/或其C 1 -C 20烷基半酯; 在（B）95〜30重量％的乙烯均聚物或乙烯/乙烯基酯共聚物作为接枝基材的存在下自由基聚合。

38. 发明授权

US4329267A Process for the preparation of ethylene-vinyl ester graft polymer dispersions 失效
标题翻译：乙烯 - 乙烯基酯接枝聚合物分散体的制备方法
公开(公告)号：US4329267A
公开(公告)日：1982-05-11
申请号：US238996
申请日：1981-02-27
申请人： Klaus Riebel , Heinrich Alberts , Herbert Bartl , Fritz Mietzsch , Ulrich Steffen
发明人： Klaus Riebel , Heinrich Alberts , Herbert Bartl , Fritz Mietzsch , Ulrich Steffen
IPC分类号： C08F255/00 , C08F255/02 , C08F263/00 , C08F263/02 , C08F263/04 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/06 , C08L101/00
CPC分类号： C08F255/026 , C08F263/02
摘要： A process for the preparation of dispersions of optionally cross-linked ethylene-vinyl ester graft polymers wherein an ethylene-vinyl ester copolymer is used as graft substrate and a vinyl ester of a C.sub.1 -C.sub.18 carboxylic acid and/or a C.sub.1 -C.sub.10 -alkyl ester of acrylic and/or methacrylic acid are used as a graft monomer which is polymerized, optionally together with a cross-linking agent having two or more C--C double bonds, in organic solution until at least 25% by weight of the graft monomer has been reacted, the reaction product is converted into a stable finely divided dispersion by the addition of a precipitating agent under the action of shearing forces and polymerisation is completed before, during or after the formation of the dispersion.
摘要翻译：用于制备任选交联的乙烯 - 乙烯基酯接枝聚合物的分散体的方法，其中使用乙烯 - 乙烯基酯共聚物作为接枝基材和C1-C18羧酸和/或C1-C10-烷基的乙烯基酯使用丙烯酸和/或甲基丙烯酸的酯作为接枝单体，其在有机溶液中任选地与具有两个或更多个CC双键的交联剂一起聚合，直到至少25重量％的接枝单体已经被反应后，通过在剪切力的作用下加入沉淀剂将反应产物转化成稳定的细碎分散体，并且在形成分散体之前，期间或之后完成聚合。

39. 发明授权

US4272428A Plasticized vinyl chloride polymer 失效
标题翻译：增塑氯乙烯聚合物
公开(公告)号：US4272428A
公开(公告)日：1981-06-09
申请号：US41546
申请日：1979-05-23
申请人： Christian Lindner , Carlhans Suling , Herbert Bartl , Dietrich Hardt , Karola Brudermanns
发明人： Christian Lindner , Carlhans Suling , Herbert Bartl , Dietrich Hardt , Karola Brudermanns
IPC分类号： C08L27/00 , C08K5/10 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/28 , C08L27/06 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L69/00 , C08L101/00 , C08K5/04
CPC分类号： C08L27/06 , C08L69/005 , C08L69/00
摘要： A thermoplastic molding composition contains a mixture of 10 to 95% by weight of a vinyl chloride polymer and 90 to 5% by weight of an adipate/carbonate mixed ester which is the transesterification reaction product of an adipate-diol polyester having terminal hydroxyls and a bifunctional carbonic acid aryl ester. The composition has a favorable combination of physical properties which include good cold fracture behavior coupled with easy processability and good ageing characteristics.
摘要翻译：热塑性模塑组合物包含10至95重量％的氯乙烯聚合物和90至5重量％的己二酸酯/碳酸酯混合酯的混合物，其为具有末端羟基的己二酸酯 - 二醇聚酯和具有末端羟基的酯交换反应产物双功能碳酸芳酯。该组合物具有良好的物理性质的组合，其包括良好的冷断裂行为以及易加工性和良好的老化特性。

40. 发明授权

US4256636A Azo-di-isobutyric acid-(N,N-hydroxyalkyl)-amidines 失效
标题翻译：偶氮二异丁酸 - （N，N-羟烷基） - 脒
公开(公告)号：US4256636A
公开(公告)日：1981-03-17
申请号：US76235
申请日：1979-09-17
申请人： Ernst Roos , Herbert Bartl , Klaus Schuster , Adolf Schmidt
发明人： Ernst Roos , Herbert Bartl , Klaus Schuster , Adolf Schmidt
IPC分类号： C07C257/14 , C08F4/04 , C07C123/00
CPC分类号： C07C257/14 , C08F4/04
摘要： An azo di-isobutyric acid-(N,N'-hydroxyalkyl)-amidine corresponding to the formula (I): ##STR1## in which R and R', which may be the same or different, represent linear or branched alkylene radicals containing from 2 to 4 carbon atoms, andX represents R'-OH or H.They may be produced by reacting an azo-di-isobutyric acid iminoalkyl ether containing from 1 to 4 carbon atoms in the alkyl group with at least one mono-alkanolamine containing from 2 to 4 carbon atoms or with a mixture of at least one monoalkanolamine and at least one dialkanolamine each containing from 2 to 4 carbon atoms in an alkanol radical, the molar ratio of monoalkanolamines to dialkanolamines in the mixture amounting to substantially 1:1, in substantially equivalent quantitative ratios at a temperature in the range of from 0.degree. to 50.degree. C. The amidines may be used as polymerization initiators, as cross-linking agents and as blowing agents in the production of foams.
摘要翻译：对应于式（I）的偶氮二异丁酸 - （N，N'-羟基烷基） - 脒：其中R和R'可以相同或不同，表示直链或支链含有2至4个碳原子的亚烷基，X代表R'-OH或H.

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