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31. 发明授权

US5630920A Electrochemical sensor for determining the oxygen concentration in gas mixtures 失效
标题翻译：用于测定气体混合物中氧浓度的电化学传感器
公开(公告)号：US5630920A
公开(公告)日：1997-05-20
申请号：US545865
申请日：1996-01-19
申请人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Frank Stanglmeier
发明人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Frank Stanglmeier
IPC分类号： G01N27/409 , G01N27/407 , G01N27/26
CPC分类号： G01N27/4071 , G01N27/4075
摘要： An electrochemical sensor for determining the oxygen concentration in gas mixtures is proposed. The sensor has a solid electrolyte (10) with oxygen ionic conductivity, which has a measuring electrode (11) that does not catalyze establishment of equilibrium of the gas mixture and is exposed to the gas mixture. The measuring electrode (11) contains platinum and bismuth. The effect of these materials is that the free oxygen contained in the gas mixture is preferentially adsorbed, without reacting with the other gas components such as CO and HC.
摘要翻译： PCT No.PCT / DE95 / 00253 Sec。 371日期1996年1月19日 102（e）日期1996年1月19日PCT提交1995年2月28日PCT公布。出版物WO95 / 25276 日期1995年9月21日提出了一种用于测定气体混合物中氧浓度的电化学传感器。传感器具有氧离子导电性的固体电解质（10），其具有不催化气体混合物平衡并暴露于气体混合物的测量电极（11）。测量电极（11）含有铂和铋。这些材料的作用是优先吸附气体混合物中所含的游离氧，而不与其他气体组分如CO和HC反应。

32. 发明授权

US5486279A Electrochemical measuring probe 失效
标题翻译：电化学测量探头
公开(公告)号：US5486279A
公开(公告)日：1996-01-23
申请号：US227568
申请日：1994-04-14
申请人： Karl-Hermann Friese , Helmut Weyl , Hans-Martin Wiedenmann
发明人： Karl-Hermann Friese , Helmut Weyl , Hans-Martin Wiedenmann
IPC分类号： G01N27/407
CPC分类号： G01N27/4075 , G01N27/4077
摘要： An electrochemical measuring probe for determining the oxygen content of gases, in particular of exhaust gases of internal combustion engines, whose measuring probe body consists essentially of a solid electrolyte, for example stabilised ZrO.sub.2 and whose electrode exposed to the gas to be measured is a cermet electrode which is coated with a finely porous ion-conducting covering layer composed of an ion-conducting supporting matrix material having no sintering activity of the type standard for cermet electrodes the covering layer is covered by a porous protective layer. The ion-conducting porous covering layer appreciably increases the activity of the cermet electrode.
摘要翻译：用于确定气体，特别是内燃机废气的氧含量的电化学测量探针，其测量探针主体基本上由固体电解质组成，例如稳定的ZrO 2，并且其暴露于待测气体的电极是金属陶瓷涂覆有不含金属陶瓷电极类型标准物的烧结活性的离子传导性支撑基体材料的细孔离子传导性覆盖层的电极覆盖层被多孔保护层覆盖。离子导电多孔覆盖层显着提高了金属陶瓷电极的活性。

33. 发明授权

US5423973A Exhaust gas sensor and method of producing the same 失效
标题翻译：废气传感器及其制造方法
公开(公告)号：US5423973A
公开(公告)日：1995-06-13
申请号：US211083
申请日：1994-06-20
申请人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Helmut Weyl
发明人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Helmut Weyl
IPC分类号： G01N27/12 , G01N27/407 , G01N27/409 , G01N27/41 , G01N27/26
CPC分类号： G01N27/4075
摘要： An exhaust gas sensor which is exposed to exhaust gas, includes a measuring electrode; and a porous ceramic coating provided on the measuring electrode and comprised of at least two layers, a first porous ceramic layer which is provided on the measuring electrode and at least a second porous ceramic layer which is provided on the first porous ceramic layer and which is directly exposed to the exhaust gas, wherein the first porous ceramic layer contains getter substances for removal of substances that are harmful to the measuring electrode, and wherein the second porous ceramic layer is provided with one of a diffusion resistance or a catalytic effect relative to exhaust gas constituents such that, at the boundary of the first and second porous ceramic layers, a gas composition is present in use which is comprised of one of oxidizable or reducible gas constituents and which sets a control position for the exhaust gas sensor.
摘要翻译： PCT No.PCT / DE92 / 00714 Sec。 371日期：1994年6月20日 102（e）日期1994年6月20日PCT提交1992年8月27日PCT公布。公开号WO93 / 06472 日本1997年4月1日。一种暴露于废气的排气传感器，包括测量电极; 以及设置在所述测量电极上并且包括至少两层的多孔陶瓷涂层，设置在所述测量电极上的第一多孔陶瓷层和设置在所述第一多孔陶瓷层上的至少第二多孔陶瓷层，直接暴露于废气中，其中第一多孔陶瓷层含有用于除去对测量电极有害的物质的吸气剂物质，并且其中第二多孔陶瓷层具有相对于排气的扩散阻力或催化作用之一气体成分，使得在第一和第二多孔陶瓷层的边界处，存在使用中的气体组合物，其由可氧化或可还原的气体成分之一组成，并且设置用于排气传感器的控制位置。

34. 发明授权

US5314604A Sensor element for limit current sensors to determine the .lambda.-value of gas mixtures 失效
标题翻译：用于限制电流传感器的传感器元件，以确定气体混合物的λ值
公开(公告)号：US5314604A
公开(公告)日：1994-05-24
申请号：US39135
申请日：1993-04-12
申请人： Karl-Hermann Friese , Werner Gruenwald , Hans-Martin Wiedenmann
发明人： Karl-Hermann Friese , Werner Gruenwald , Hans-Martin Wiedenmann
IPC分类号： G01N27/419 , B01D53/86 , F02D41/14 , G01N27/26 , G01N27/406 , G01N27/41 , G01N27/417
CPC分类号： G01N27/417
摘要： A sensor element for broad band sensors to determine the .lambda.-value of gas mixtures is suggested. This sensor element can be manufactured in ceramic-sheet and screen-printing technology and is provided in the diffusion gap (7) downstream from a pair of pump electrodes (8,8"), arranged on both sides of the diffusion gasp (7), with a Nernst electrode (9) which functions as an exhaust gas electrode. Due to this arrangement of the Nernst electrode (9), it is possible in a simple manner to effectively protect the pump cell formed by the interior pump electrodes (8,8') from overload and to prevent falsification of the sensor signal.
摘要翻译： PCT No.PCT / DE91 / 00752 Sec。 371日期：1993年4月12日 102（e）日期1993年4月12日PCT 1991年9月21日PCT PCT。公开号WO92 / 07252 日期：1992年4月30日。建议用于确定气体混合物的λ值的宽带传感器的传感器元件。该传感器元件可以以陶瓷片和丝网印刷技术制造，并且设置在布置在扩散气体（7）的两侧的一对泵电极（8,8“）下游的扩散间隙（7）中），其具有用作排气电极的能斯特电极（9）。由于能斯特电极（9）的这种布置，可以以简单的方式有效地保护由内部泵电极（8,8'）形成的泵电池免于过载并且防止传感器信号的伪造。

35. 发明授权

US4400260A Shielded, heated electrochemical gas sensor 失效
标题翻译：屏蔽，加热电化学气体传感器
公开(公告)号：US4400260A
公开(公告)日：1983-08-23
申请号：US367276
申请日：1982-04-12
申请人： Roland Stahl , Hans-Martin Wiedenmann
发明人： Roland Stahl , Hans-Martin Wiedenmann
IPC分类号： G01N27/41 , G01N27/406 , G01N27/407 , G01N27/409 , G01N27/416 , H05B3/14 , G01N27/46
CPC分类号： G01N27/4071 , G01N27/4067
摘要： To extend temperature range of solid electrolyte ion conductive-type gas sensors, particularly for the exhaust gases from internal combustion engines, and to prevent leakage currents between a heater element and the solid electrolyte body at temperatures just above the response temperature of the sensor, but below its normal operating temperatures, that is, even in the range of between 250.degree. C. to 400.degree. C., a layer-like shielding electrode (18,29) is provided, positioned between the solid electrolyte body (11,25) and the insulating layer (17,31). The shielding electrode is galvanically connected to the return line (21,33) of the heating element. In accordance with one embodiment, the shielding electrode and one of the operating electrodes, for example, the sensing electrode (29), can be the same metallic film or element applied to the sensor, with an additional electrical insulation layer (32) interposed in the region between the film electrode (29) and the solid electrolyte body (25), the heater element (16,30) being positioned with the interposition of the electrical insulating layer over the film electrode in that region. Preferably, the width of the respective insulating layers decreases in a direction away from solid electrolyte body.The system is applicable both to potentiometric, as well as polarographic-type sensors, of, selectively, closed tubular or plate-like construction, with electrodes exposed either to a reference gas or having, respectively, different catalytic activity.
摘要翻译：为了扩展固体电解质离子传导型气体传感器的温度范围，特别是用于来自内燃机的废气，并且在刚好高于传感器的响应温度的温度下防止加热器元件和固体电解质体之间的漏电流，但是低于其正常工作温度，即即使在250℃至400℃的范围内，也提供了位于固体电解质体（11,25）之间的层状屏蔽电极（18,29）和绝缘层（17,31）。屏蔽电极电连接到加热元件的返回线（21,33）。根据一个实施例，屏蔽电极和操作电极中的一个，例如感测电极（29）可以是与传感器相同的金属膜或元件，其中插入有另外的电绝缘层（32）在薄膜电极（29）和固体电解质体（25）之间的区域中，加热器元件（16,30）定位成在该区域中在电极上插入电绝缘层。优选地，各绝缘层的宽度在远离固体电解质体的方向上减小。该系统适用于电位计和极谱法传感器，选择性地，封闭的管状或板状结构，电极暴露于参考气体或分别具有不同的催化活性。

36. 发明授权

US4268468A Method of making a medical prosthesis 失效
标题翻译：制作医疗假体的方法
公开(公告)号：US4268468A
公开(公告)日：1981-05-19
申请号：US923934
申请日：1978-07-13
申请人： Friedrich J. Esper , Hans-Martin Wiedenmann
发明人： Friedrich J. Esper , Hans-Martin Wiedenmann
IPC分类号： A61B17/58 , A61F2/00 , A61F2/28 , A61F2/30 , A61F2/38 , A61L27/00 , A61L27/34 , A61L27/44 , B29C27/00 , B29C27/22 , B29D9/00 , B29G7/00
CPC分类号： A61F2/30965 , A61F2/30767 , A61L27/34 , A61L27/443 , A61F2310/00574
摘要： A bone replacement, for example a portion of a hip joint, a bone junction plate, or the like, includes a core element of a fiber-reinforced thermosetting material with a surface element made of a biologically compatible material, typically polyethylene, completely surrounding the core element. The outside surface element is internally interlocked with the core element, by being molded in one heat treatment operation which simultaneously cures the thermosetting material while molding the outside biologically compatible surface element thereto and interlocking and integrating the two elements into one unitary structure. Preferably, the fiber reinforcement is formed as fibers, woven mats, felted mats, or the like, and the surface element may, likewise, include a reinforcement beneath the surface actually in contact with the human body.
摘要翻译：骨替代物，例如髋关节的一部分，骨接合板等，包括纤维增强热固性材料的芯元件，其具有由生物相容性材料（通常为聚乙烯）制成的表面元件，其完全包围核心元素。外表面元件通过在一个热处理操作中被模制而与芯元件内部互锁，同时固化热固性材料，同时将外部生物相容的表面元件模制到其上并将两个元件互锁并整合成一体的一体结构。优选地，纤维增强件形成为纤维，编织垫，毡毡等，并且表面元件同样可以包括实际上与人体接触的表面下方的增强件。

37. 发明授权

US07361620B2 Catalytically active layer 失效
标题翻译：催化活性层
公开(公告)号：US07361620B2
公开(公告)日：2008-04-22
申请号：US10284887
申请日：2002-10-31
申请人： Hans-Martin Wiedenmann , Frank Stanglmeier , Karl-Hermann Friese
发明人： Hans-Martin Wiedenmann , Frank Stanglmeier , Karl-Hermann Friese
IPC分类号： G01N27/407
CPC分类号： B01J25/00 , B01J23/40 , G01N27/4075 , Y10T29/49002
摘要： A catalytically active layer that is used, for example, as an electrode for a solid electrolyte-based sensor element of a gas sensor for determining a gas component in a gas mixture. The catalytically active layer includes a metallic component, that includes a noble metal in the form of platinum, rhodium, and/or palladium, and additionally a base metal. At least a portion of the originally present base metal is replaced by cavities in the metallic component.
摘要翻译：一种催化活性层，其用作例如用于确定气体混合物中的气体成分的气体传感器的基于固体电解质的传感器元件的电极。催化活性层包括金属组分，其包括铂，铑和/或钯形式的贵金属，以及另外的贱金属。原来存在的贱金属的至少一部分由金属部件中的空腔代替。

38. 发明授权

US06613206B1 Gas sensor 失效
标题翻译：气体传感器
公开(公告)号：US06613206B1
公开(公告)日：2003-09-02
申请号：US09308078
申请日：1999-07-14
申请人： Helmut Weyl , Hans-Martin Wiedenmann , Theodor Graser , Karl-Heinz Effenberger , Clemens Simon , Anton Hans
发明人： Helmut Weyl , Hans-Martin Wiedenmann , Theodor Graser , Karl-Heinz Effenberger , Clemens Simon , Anton Hans
IPC分类号： G01N27407
CPC分类号： G01N27/407
摘要： A gas sensor, in particular a lambda probe, for ascertaining the pollutant and/or oxygen content in emission gases of internal combustion engines, having a housing accommodating at least one sensor element, the sensor element having a section on the terminal side and a section on the measuring-gas side, and having a connecting element that connects the sensor element, which has a plurality of electrically conductive contact areas, at its terminal-side section to a plurality of electrically conductive supply leads. The gas sensor has the feature of a connecting element which is formed from a spring element produced in one piece from ceramic material.
摘要翻译：一种气体传感器，特别是λ探测器，用于确定内燃机的排放气体中的污染物和/或氧含量，其具有容纳至少一个传感器元件的壳体，该传感器元件在终端侧具有一部分，在测量气体侧，并且具有将其端子侧部分具有多个导电接触区域的传感器元件连接到多个导电供应引线的连接元件。气体传感器具有由陶瓷材料一体制成的弹簧元件形成的连接元件的特征。

39. 发明授权

US06347543B1 Measuring sensor and method for its fabrication 失效
标题翻译：测量传感器及其制造方法
公开(公告)号：US06347543B1
公开(公告)日：2002-02-19
申请号：US09434667
申请日：1999-11-05
申请人： Heinz Geier , Helmut Weyl , Hans-Martin Wiedenmann , Karl-Hermann Friese
发明人： Heinz Geier , Helmut Weyl , Hans-Martin Wiedenmann , Karl-Hermann Friese
IPC分类号： G01N2704
CPC分类号： G01N27/4078 , G01N27/407 , Y10T29/49211
摘要： A measuring sensor, in particular, for determining the oxygen content in exhaust gases of internal combustion engines, includes a ceramic molding arranged in a metal housing for the accommodation of a sensor element, in particular, planar, the sensor element being sealed by a seal element made of warm-deformable temperature-resistant material. The molded housing is designed in one piece and has a cylindrically shaped longitudinal hole on the connector side, around the sensor element, and the seal element is compressed between a first compressing element on the measuring-gas side and a second compressing element on the connector side, such that it tightly encloses the sensor element and hermetically seals the sensor element with respect to the molded housing.
摘要翻译：特别地，用于确定内燃机排气中的氧含量的测量传感器包括布置在金属壳体中用于容纳传感器元件，特别是平面的陶瓷模制件，传感器元件由密封件元件由耐温变形的耐温材料制成。模制壳体被设计成一体并且在连接器侧上具有围绕传感器元件的圆柱形纵向孔，并且密封元件在测量气体侧的第一压缩元件和连接器上的第二压缩元件之间被压缩使得其紧密地包围传感器元件并相对于模制壳体气密地密封传感器元件。

40. 发明授权

US6096181A Sealing element for a sensor 失效
标题翻译：用于传感器的密封元件
公开(公告)号：US6096181A
公开(公告)日：2000-08-01
申请号：US91198
申请日：1998-06-10
申请人： Karl-Hermann Friese , Helmut Weyl , Hans-Martin Wiedenmann , Anton Hans
发明人： Karl-Hermann Friese , Helmut Weyl , Hans-Martin Wiedenmann , Anton Hans
IPC分类号： G01N27/409 , G01N27/407
CPC分类号： G01N27/4078 , G01N27/4077 , Y10S277/936 , Y10S277/939 , Y10S277/94 , Y10S277/941
摘要： An electrochemical sensor for determining the oxygen content of gases of internal combustion engines includes a ceramic element that is inserted with a sealing ring into a housing. The sealing ring is built up from different metal layers. The arrangement of the metal layers proceeds from a metal support which is composed of a steel alloy. The sealing ring is covered on both sides with a roll-clad copper layer. A nickel layer can additionally be arranged beneath the copper layer.
摘要翻译： PCT No.PCT / DE97 / 02197 Sec。 371日期1999年1月6日 102（e）1999年1月6日PCT PCT 1997年9月26日PCT公布。公开号WO98 / 15820PC 日期1998年04月16日用于确定内燃机气体的氧含量的电化学传感器包括一个陶瓷元件，其中密封环插入壳体中。密封环由不同的金属层构成。金属层的布置从由钢合金构成的金属支撑体进行。密封圈两侧均覆盖有卷绕铜层。镍层可另外设置在铜层的下方。

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