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    • 37. 发明专利
    • CONTROLLING METHOD FOR PLATING THICKNESS IN ELECTROLESS PLATING
    • JPS57185968A
    • 1982-11-16
    • JP6991581
    • 1981-05-09
    • HITACHI CABLE
    • YAMAGISHI RIYOUZOUYOSHIOKA OSAMUISHIKAWA TETSUO
    • C23C18/16C23C18/31C23C18/40
    • PURPOSE:To determine and control the plating thickness of a substrate to be plated in accordance with the electric resistance value of a fine wire for monitoring an insulator in the stage of electroless plating by immersing said fine wire together with the substrate into a plating soln. and measuring the electric resistance of the wire with time. CONSTITUTION:A monitor fixing jig 3 which is fixed with a monitoring wire 1 for measuring resistance value is immersed in a plating cell 8 contg. an electroless plating soln. 4 and is connected to a resistance measuring device 9 by means of lead wires 2a, 2b. The wire 1 is made of an acid resistant and alkali resistant electric insulating material of ethylene fluoride, PE or the like. At the same time, a substrate is immersed in the soln. 4 and is subjected to electroless plating. The change in the electric resistance value occuring in the formation of a plating layer on the surface of the wire 1 is measured with the device 9 and the thickness of the plating layer is determined from the measured value, whereby the thickness of the plating layer of the substrate surface is controlled. When the desired thickness is attained, the substrate is taken up from the plating soln.
    • 38. 发明专利
    • Heat resistant silver coated conductor
    • 耐热镀银导体
    • JPS5757886A
    • 1982-04-07
    • JP13272780
    • 1980-09-24
    • Hitachi Cable Ltd
    • YAMAGISHI RIYOUZOUYOSHIOKA OSAMU
    • C25D5/10
    • PURPOSE: To obtain an inexpensive Ag coated conductor enhancing the adhesion of the Ag coated layer after head deterioration in an oxidizing atmosphere and enabling the reduction of the layer in thickness by forming a Co layer having a prescribed thickness as an under coat metallic layer on a Cu or Cu alloy substrate and coating the Co layer with Ag.
      CONSTITUTION: On a Cu or Cu alloy substrate an under coat metallic layer of Co having 0.2W4, especially about 1μm thickness is formed, and the layer is coated with an Ag layer to obtain the desired heat resistant Ag coated conductor. The Ag coated layer may be converted into an Ag alloy layer by adding ≥1 kind of metallic element having an effect of controlling the oxygen permeability of ag, e.g., Sb, Se, Sn, Zn, Ni or Cu. The Ag coated conductor is suitable for use as a lead frame matetrial for electronic parts, especially a semiconductor circuit element.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:为了获得廉价的Ag涂层导体,增强氧化气氛中的头部退化后的Ag涂层的粘附性,并且能够通过在具有规定厚度的Co层作为下涂层金属层上形成厚度来降低厚度层 Cu或Cu合金基体,并用Ag涂覆Co层。 构成:在Cu或Cu合金基材上,形成具有0.2-4,特别是约1μm厚度的Co的底涂层金属层,并且该层涂覆有Ag层以获得所需的耐热Ag涂层导体。 通过添加具有控制Ag的氧气渗透性的作用的SbCl,Se,Sn,Zn,Ni或Cu,可以添加> = 1种具有氧气渗透性的金属元素,从而将Ag涂层转变为Ag合金层。 Ag涂层导体适用于电子部件,特别是半导体电路元件的引线框架材料。
    • 40. 发明专利
    • INSIDE SURFACE PLATING METHOD OF ZIRCALLOY PIPE
    • JPS5538918A
    • 1980-03-18
    • JP10937178
    • 1978-09-06
    • HITACHI CABLE
    • YOSHIOKA OSAMUISHIKAWA TETSUOYAMAGISHI RIYOUZOU
    • C25D5/38C25D5/34C25D7/04
    • PURPOSE:To eveny activate the inside surface of the pipe and enable plating to be evenly performed by using NH4HF2, N2SiF6 and NH4F as pickling solution and connecting the pipes of the same quality as the abovementioned pipe to both ends of the pipe then performing pickling activation treatment in pretreating of the inside surface plating of the zicalloy pipe. CONSTITUTION:In pretreatment of the inside surface plating of a zircalloy pipe 1 for atomic fuel covering the metal pipes 2, 2 composed of the zircalloy pipes of the same kind as that of the pipe 1 are connected respectively to both ends of the pipe 1 and the outside surfaces thereof are covered with plastic pipes 6, 3. Next, the pickling solution is circulated in the pipes 2 and 1 through the plastic pipe 3 by a circulating pump 4 from a vessel 5 which contains one or more kinds of NH4HF2, H2SiF6, NH4F, HF or HBF4 as the pickling solution, whereby the inside surface of the zicalloy pipe 1 is activated. This method enables the entire inside surface of the plated zircalloy pipe to be subjected to pickling activation treatment owing to the presence of the metal pipes 2, 2.