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    • 36. 发明授权
    • De-fluorination of wafer surface and related structure
    • 晶圆表面脱氟及相关结构
    • US07049209B1
    • 2006-05-23
    • US10907463
    • 2005-04-01
    • Timothy J. DaltonNicholas C. M. FullerKaushik A. KumarCatherine Labelle
    • Timothy J. DaltonNicholas C. M. FullerKaushik A. KumarCatherine Labelle
    • H01L21/322
    • H01L21/31138H01L21/02063H01L21/3105H01L21/76814
    • Methods of de-fluorinating a wafer surface after damascene processing and prior to photoresist removal are disclosed, as is a related structure. In one embodiment, the method places the wafer surface in a chamber and exposes the wafer surface to a plasma from a source gas including at least one of nitrogen (N2) and/or hydrogen (H2) at a low power density or ion density. The exposing step removes the chemisorbed and physisorbed fluorine residue present on the wafer surface (and chamber), and improves ultra low dielectric (ULK) interconnect structure robustness and integrity. The exposing step is operative due to the efficacy of hydrogen and nitrogen radicals at removing fluorine-based species and also due to the presence of a minimal amount of ion energy in the plasma. The low power density nitrogen and/or hydrogen-containing plasma process enables negligible ash/adhesion promoter interaction and reduces integration complexity during dual damascene processing of low-k OSG-based materials.
    • 公开了在镶嵌处理之后和光致抗蚀剂去除之前脱晶晶片表面的方法,如相关结构。 在一个实施例中,该方法将晶片表面放置在室中并将晶片表面暴露于来自包括氮(N 2 H 2)和/或氢(H 2 )。 曝光步骤去除晶片表面(和室)上存在的化学吸附和物理吸附的氟残基,并改善超低介电(ULK)互连结构的鲁棒性和完整性。 曝光步骤由于氢和氮自由基在除去氟基物质的作用以及由于在等离子体中存在最少量的离子能量而有效。 低功率密度氮和/或含氢等离子体方法使得可以忽略灰分/粘附促进剂相互作用,并降低在低k OSG基材料的双镶嵌加工过程中的集成复杂性。