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    • 32. 发明申请
    • CU-BASED CERMET FOR HIGH-TEMPERATURE FUEL CELL
    • 基于CU的高温燃料电池
    • US20110053041A1
    • 2011-03-03
    • US12865956
    • 2008-02-13
    • Michael C. TuckerCraig P. Jacobson
    • Michael C. TuckerCraig P. Jacobson
    • H01M4/90B22F3/10B22F3/11B32B15/02
    • C22C30/02C22C29/12C22C32/0021H01M4/9066H01M8/1253H01M2008/1293Y02E60/525Y02P70/56
    • Copper-based cermets and methods of preparing them are provided. The Cu-based cermets have interpenetrating networks of copper alloy and stabilized zirconia that are in intimate contact and display high electronic connectivity through the copper alloy phase. In certain embodiments, methods of preparing the cermets involving sintering a mixture of ceramic and copper-based powders in a reducing atmosphere at a temperature above the melting point of the copper or copper alloy are provided. Also provided are electrochemical structures having the Cu-based cermet, e.g., as an anode structure or a barrier layer between an anode and a metal support. Applications of the cermet compositions and structures include use in high-operating-temperature electrochemical devices, including solid oxide fuel cells, hydrogen generators, electrochemical flow reactors, etc.
    • 提供铜基金属陶瓷及其制备方法。 铜基金属陶瓷具有铜合金和稳定化氧化锆的互穿网络,其通过铜合金相紧密接触并显示出高电子连接性。 在某些实施方案中,提供了制备金属陶瓷的方法,所述方法包括在铜或铜合金的熔点以上的温度下在还原气氛中烧结陶瓷和铜基粉末的混合物。 还提供了具有Cu基金属陶瓷的电化学结构,例如阳极结构或阳极和金属载体之间的阻挡层。 金属陶瓷组合物和结构的应用包括用于高工作温度电化学装置,包括固体氧化物燃料电池,氢发生器,电化学流动反应器等。