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31. 发明授权

US6133482A Method for producing carbonyl compounds 失效
标题翻译：生产羰基化合物的方法
公开(公告)号：US6133482A
公开(公告)日：2000-10-17
申请号：US331063
申请日：1999-06-16
申请人： Thomas Fetzer , Dirk Demuth , Heinz Rutter , Helmuth Menig , Peter Resch , Wilhelm Ruppel , Harro Wache
发明人： Thomas Fetzer , Dirk Demuth , Heinz Rutter , Helmuth Menig , Peter Resch , Wilhelm Ruppel , Harro Wache
IPC分类号： B01J23/72 , C07C45/38 , C07C45/39 , C07C47/127 , C07C45/29
CPC分类号： C07C45/39 , C07C45/38
摘要： In a process for preparing carbonyl compounds of the formula ##STR1## where R.sup.1 is a hydrogen atom or an alkyl radical having from 1 to 3 carbon atoms, R.sup.2 is a hydrogen atom or a radical of the formula ##STR2## where R.sup.3 is a hydrogen atom or together with R.sup.4 is an oxygen atom, R.sup.4 is the radical OR.sup.6 or together with R.sup.3 is an oxygen atom, R.sup.5 is a hydrogen atom, an alkyl radical having from 1 to 8 carbon atoms or a cyclohexyl or cyclopentyl radical and R.sup.6 is an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula --CH.sub.2 --CHO or --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CHO, by gas-phase oxidation of methanol or alcohols of the formula ##STR3## where R.sup.1 and R.sup.5 are as defined above and R.sup.7 is a hydrogen atom or a radical OR.sup.8 and R.sup.8 is a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical for the formula --CH.sub.2 --CH.sub.2 --OH or --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --OH, using an oxygen-containing gas in the presence of copper- and/or silver-containing catalysts and an amount of a phosphorus compound which is volatile under the reaction conditions which is such that the amount of phosphorus (calculated as P) is up to 20 ppm, based on the weight of alcohol used, the phosphorus is introduced within the catalyst bed.
摘要翻译： PCT No.PCT / EP97 / 06856 Sec。 371日期1999年6月16日第 102（e）日期1999年6月16日PCT 1997年12月23日PCT公布。公开号WO98 / 28251 日期1998年7月2日在制备下式的羰基化合物的方法中，其中R 1是氢原子或具有1至3个碳原子的烷基，R 2是氢原子或下式的基团，其中R 3是氢原子或与R4一起为氧原子，R4为基团OR6或与R3为氧原子一起，R5为氢原子，具有1至8个碳原子的烷基或环己基或环戊基，R6为烷基具有1至4个碳原子的基团，环己基或环戊基或式-CH2-CHO或-CH2-CH2-O-CH2-CHO的基团，通过下式的甲醇或醇的气相氧化其中R1 R 5为氢原子或OR 8，R 8为氢原子，碳原子数为1〜4的烷基，环己基或环戊基或式-CH 2 -CH 2 - 的基团， OH或-CH 2 -CH 2 -O-CH 2 -CH 2 -OH，使用含铜气体在铜和/或银-co 在催化剂和一定量的磷化合物中，在反应条件下挥发的量为磷（根据P计算）高达20ppm，基于所使用的醇的重量，磷被引入催化剂床。

32. 发明授权

US6090977A Continuous heterogeneously catalyzed gas-phase partial oxidation of an organic compound 失效
标题翻译：连续不均匀催化的有机化合物的气相部分氧化
公开(公告)号：US6090977A
公开(公告)日：2000-07-18
申请号：US610888
申请日：1996-03-05
申请人： Werner Hefner , Otto Machhammer , Hans-Peter Neumann , Andreas Tenten , Wilhelm Ruppel , Herbert Vogel
发明人： Werner Hefner , Otto Machhammer , Hans-Peter Neumann , Andreas Tenten , Wilhelm Ruppel , Herbert Vogel
IPC分类号： C07B35/04 , C07B41/06 , C07B41/08 , C07C27/00 , C07C45/35 , C07C47/22 , C07C51/235 , C07C51/25 , C07C51/265 , C07C57/05 , C07D301/08 , C07C27/14
CPC分类号： C07D301/08 , C07C45/35 , C07C51/235 , C07C51/25 , C07C51/252 , C07C51/265
摘要： In a process for the continuous heterogeneously catalyzed gas-phase partial oxidation of an organic compound in an oxidation reactor, whose feed gas mixture comprises, apart from the organic compound to be partially oxidized and molecular oxygen as oxidant, at least one diluent gas which is essentially inert under the conditions of the heterogeneously catalyzed gas-phase partial oxidation, where the essentially inert diluent gas consists partly of combustible gases, after passage through the oxidation reactor, the combustible constituents of the inert diluent gas present in the product gas stream leaving the oxidation reactor are not recirculated to the heterogeneously catalyzed gas-phase partial oxidation, but are put to further use for the purposes of another chemical reaction.
摘要翻译：在氧化反应器中的有机化合物的连续非均相催化气相部分氧化的方法中，其进料气体混合物除了要被部分氧化的有机化合物和分子氧作为氧化剂外，还包含至少一种稀释气体在非均相催化的气相部分氧化的条件下基本上是惰性的，其中基本上惰性的稀释气体部分地由可燃气体组成，在通过氧化反应器之后，存在于产物气流中的惰性稀释气体的可燃组分离开氧化反应器不再循环到非均相催化的气相部分氧化，而是进一步用于另一种化学反应。

33. 发明授权

US6072087A Method for producing carbonyl compounds 失效
标题翻译：生产羰基化合物的方法
公开(公告)号：US6072087A
公开(公告)日：2000-06-06
申请号：US331068
申请日：1999-06-16
申请人： Thomas Fetzer , Dirk Demuth , Heinz Rutter , Helmuth Menig , Peter Resch , Wilhelm Ruppel , Harro Wache
发明人： Thomas Fetzer , Dirk Demuth , Heinz Rutter , Helmuth Menig , Peter Resch , Wilhelm Ruppel , Harro Wache
IPC分类号： C07B61/00 , C07C45/38 , C07C45/39 , C07C47/127 , C07C45/29
CPC分类号： C07C45/39 , C07C45/38
摘要： The present invention relates to a process for the preparation of carbonyl compounds of the formula ##STR1## in which R.sup.1 denotes a hydrogen atom or an alkyl radical containing from 1 to 3 carbon atoms, R.sup.2 denotes a hydrogen atom or a radical of the formula ##STR2## in which R.sup.3 denotes a hydrogen atom or, together with R.sup.4, an oxygen atom, R.sup.4 denotes the radical OR.sup.6 or, together with R.sup.3, an oxygen atom, R.sup.5 denotes a hydrogen atom or an alkyl radical containing from 1 to 8 carbon atoms or a cyclohexyl or cyclopentyl radical, and R.sup.6 denotes an alkyl radical containing from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula--CH.sub.2 --CHO or --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CHO,by gas-phase oxidation of methanol or alcohols of the formula ##STR3## in which R.sup.1 and R.sup.5 have the meanings specified above and R.sup.7 denotes a hydrogen atom or a radical OR.sup.8, and R.sup.8 denotes a hydrogen atom, an alkyl radical containing from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula --CH.sub.2 --CH.sub.2 --OH or --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --OH, using an oxygen-containing gas in the presence of a (copper and/or silver)-containing catalyst and a phosphorus compound which is volatile under the conditions of the reaction and is present in an amount such that the weight of phosphorus (calculated as P), based on the weight of alcohol used, is not more than 20 ppm, wherein the amount of phosphorus used is divided into at least two portions, of whicha) the first portion is added together with the mixture of gaseous starting materials before this reaches the catalyst bed andb) at least one further portion is added within the catalyst bed.
摘要翻译： PCT No.PCT / EP97 / 06855 Sec。 371日期1999年6月16日第 102（e）日期1999年6月16日PCT 1997年12月9日PCT公布。 WO98 / 28250 PCT出版物日期：1998年7月2日本发明涉及制备式中羰基化合物的方法，其中R 1表示氢原子或含有1至3个碳原子的烷基，R 2表示氢原子或式中R 3表示氢原子，或与R 4一起形成氧原子，R 4表示基团OR 6，或与R 3一起形成氧原子，R 5表示氢原子或含有1〜8个碳原子的烷基，或环己基或环戊基，R6表示含有1至4个碳原子的烷基，环己基或环戊基或式-CH2-CHO或-CH2-CH2-O-CH2-CHO的基团，其中R1和R5具有上述含义的甲醇或醇的相氧化，R7表示氢原子或OR8基，R8表示氢原子，含有1至4个碳原子的烷基，环己基或环戊基或基团使用含氧气体在含（铜和/或银）催化剂和挥发性的磷化合物的存在下，使用含氧气体，-CH2-CH2-OH或-CH2-CH2-O-CH2-CH2-OH 反应条件以使得基于所使用的醇的重量计算的磷重量（以P计）不超过20ppm的量存在，其中使用的磷的量被分成至少两个部分，其中a）第一部分在气体原料混合物到达催化剂床之前一起加入，以及b）在催化剂床内加入至少另外一部分。

34. 发明授权

US5821390A Catalytic gas-phase oxidation of propene to acrolein 失效
标题翻译：丙烯催化气相氧化成丙烯醛
公开(公告)号：US5821390A
公开(公告)日：1998-10-13
申请号：US525011
申请日：1995-09-08
申请人： Wilhelm Ruppel , Ulrike Wegerle , Andreas Tenten , Ulrich Hammon
发明人： Wilhelm Ruppel , Ulrike Wegerle , Andreas Tenten , Ulrich Hammon
IPC分类号： B01J23/88 , B01J8/06 , B01J21/02 , B01J23/16 , B01J23/887 , B01J27/132 , B01J27/192 , C07B61/00 , C07C45/35 , C07C47/22
CPC分类号： B01J27/192 , B01J23/8876 , B01J8/067 , C07C45/35 , B01J2208/00212 , B01J2208/00221 , B01J2219/00777
摘要： A gas-phase mixture of propene and oxygen is catalytically oxidized by passing a reactant gas mixture comprising propene and oxygen through a plurality of catalyst containing contact tubes in a fixed bed reactor and simultaneously passing only one heat-exchange medium at elevated temperature over the exterior surfaces of the contact tubes in a longitudinal flow pattern which is cocurrent with the direction of flow of the reactants through said tube; simultaneously superposing a transverse flow on said longitudinal flow of heat exchange medium by means of an arrangement of successive baffles along the contact tubes which leave passage cross-sections free, thereby resulting in a meandrous flow of the heat-exchange medium through the reactor and setting the flow rate of said heat-exchange medium so that its temperature between the point of entry of the medium into the reactor and its point of exit increases by 2.degree. to 10.degree. C.; and obtaining product acrolein at a selectivity .gtoreq.85 mol % from the reactor at a single pass propene conversion .gtoreq.90 mol %.
摘要翻译：丙烯和氧气的气相混合物通过在固定床反应器中通过包含丙烯和氧气的反应气体混合物通过多个含有接触管的催化剂催化氧化，同时仅使一个热交换介质在高温下通过外部接触管的表面以与通过所述管的反应物的流动方向并流的纵向流动图案; 同时通过沿着接触管的连续挡板的布置使横向流在所述纵向流动的热交换介质上，使得通道横截面自由，从而导致热交换介质通过反应器的蜿蜒流动和设定所述热交换介质的流速使得其进入反应器的入口点和其出口点之间的温度升高2℃至10℃; 并且在单次丙烯转化率为90摩尔％时，以反应器的选择性> 85％摩尔得到产物丙烯醛。

35. 发明授权

US5739391A Catalytic gas-phase oxidation of acrolein to acrylic acid 失效
标题翻译：丙烯醛催化气相氧化成丙烯酸
公开(公告)号：US5739391A
公开(公告)日：1998-04-14
申请号：US525118
申请日：1995-09-08
申请人： Wilhelm Ruppel , Ulrike Wegerle , Andreas Tenten , Ulrich Hammon
发明人： Wilhelm Ruppel , Ulrike Wegerle , Andreas Tenten , Ulrich Hammon
IPC分类号： B01J23/28 , B01J8/06 , B01J21/02 , B01J23/16 , C07B61/00 , C07C51/25 , C07C57/055 , C07C51/16
CPC分类号： B01J8/067 , C07C51/252 , B01J2208/00212
摘要： A process for the catalytic gas-phase oxidation of acrolein to acrylic acid in a multiple contact tube fixed-bed reactor through whose space surrounding the contact tubes only one heat-exchange medium circuit is passed, at elevated temperature on catalytically active multimetal oxides with an acrolein conversion for a single pass of .gtoreq.95 mol % and an acrylic acid formation selectivity of .gtoreq.90 mol %, which comprises firstly passing the heat-exchange medium through the multiple contact tube fixed-bed reactor longitudinally, considered over the reaction container as a whole, to the contact tubes in cocurrent to the reaction-gas mixture and secondly superposing a transverse flow within the reaction container by means of an arrangement of successive baffles along the contact tubes which leaves passage cross sections free, so as to give a meandrous flow of the heat-exchange medium, seen in longitudinal section through the contact tube bundle, and setting the flow rate of the circulated heat-exchange medium so that its temperature rises by from 2.degree. to 10.degree. C. between the point of entry into the reactor and the point of exit out of the reactor.
摘要翻译：一种在多接触管固定床反应器中将丙烯醛催化气相氧化成丙烯酸的方法，其中通过其接触管周围的空间仅使一个热交换介质回路在高温下通过催化活性多金属氧化物，其具有丙烯醛转化率为> / = 95mol％，丙烯酸形成选择性> 90wt％，其包括首先使热交换介质通过多接触管固定床反应器纵向通过反应容器作为整体，与反应气体混合物并流到接触管，并且其次通过沿接触管的连续挡板的布置叠加在反应容器内的横向流动，使得通道横截面自由，从而通过接触管束在纵剖面中看到热交换介质的蜿蜒流动，并设定循环hea的流量 t-交换介质，使其在进入反应器的点和从反应器出来的点之间的温度升高2℃至10℃。

36. 发明授权

US5705684A Preparation of acrolein, acrylic acid or a mixture thereof from propane 失效
标题翻译：由丙烷制备丙烯醛，丙烯酸或其混合物
公开(公告)号：US5705684A
公开(公告)日：1998-01-06
申请号：US618440
申请日：1996-03-08
申请人： Werner Hefner , Otto Machhammer , Hans-Peter Neumann , Andreas Tenten , Wilhelm Ruppel , Herbert Vogel
发明人： Werner Hefner , Otto Machhammer , Hans-Peter Neumann , Andreas Tenten , Wilhelm Ruppel , Herbert Vogel
IPC分类号： C07C47/22 , C07B61/00 , C07C45/33 , C07C45/35 , C07C51/25 , C07C57/04 , C07C57/05 , C07C57/055 , C07C51/16
CPC分类号： C07C45/35 , C07C45/33 , C07C51/252
摘要： In a process for preparing acrolein, acrylic acid or a mixture thereof from propane, propane is partially dehydrogenated to propylene in a first stage, the product gas mixture resulting therefrom is, after separating off hydrogen and water vapor, used as feed to an oxidation reactor, the propylene formed in the dehydrogenation is partially oxidized in the oxidation reactor using molecular oxygen in the presence of non-dehydrogenated propane as inert diluent gas to give acrolein, acrylic acid or a mixture thereof and the propane present in the product gas mixture of the partial oxidation is subsequently recirculated to the dehydrogenation stage A.
摘要翻译：在从丙烷制备丙烯醛，丙烯酸或其混合物的方法中，丙烷在第一阶段部分脱氢为丙烯，由此产生的产物气体混合物在分离出氢和水蒸汽后，用作进料到氧化反应器在脱氢反应中形成的丙烯在氧化反应器中，在非脱氢丙烷作为惰性稀释气体存在下，使用分子氧进行部分氧化，得到丙烯醛，丙烯酸或其混合物，并存在于丙烯醛随后将部分氧化再循环到脱氢阶段A.

37. 发明授权

US5684188A Continuous heterogeneously catalyzed gas-phase oxidation of propylene to acrolein, acrylic acid or a mixture thereof 失效
标题翻译：将丙烯连续异质催化气相氧化成丙烯醛，丙烯酸或其混合物
公开(公告)号：US5684188A
公开(公告)日：1997-11-04
申请号：US611790
申请日：1996-03-06
申请人： Werner Hefner , Otto Machhammer , Hans-Peter Neumann , Andreas Tenten , Wilhelm Ruppel , Herbert Vogel
发明人： Werner Hefner , Otto Machhammer , Hans-Peter Neumann , Andreas Tenten , Wilhelm Ruppel , Herbert Vogel
IPC分类号： C07C27/00 , C07C27/14 , C07C45/35 , C07C47/22 , C07C51/25 , C07C57/05 , C07C57/055 , C07C45/34 , C07C51/23
CPC分类号： C07C45/35 , C07C51/252
摘要： In a process for the continuous heterogeneously catalyzed gas-phase oxidation of propylene to acrolein, acrylic acid or a mixture thereof in an oxidation reactor whose feed gas mixture comprises, apart from propylene and molecular oxygen as oxidant, only at least one diluent gas which is essentially inert under the conditions of the heterogeneously catalyzed gas-phase oxidation and where, in continuous operation, at least a part of the essentially inert diluent gases present in the product gas mixture is separated off therefrom and is reused as a constituent of the feed gas mixture to the oxidation reactor, the essentially inert diluent gas mixture comprises more than 85% by volume of at least one saturated hydrocarbon having from 1 to 5 carbon atoms.
摘要翻译：在丙烯到丙烯醛，丙烯酸或其混合物在氧化反应器中的连续非均相催化气相氧化的方法中，其进料气体混合物除了丙烯和分子氧作为氧化剂之外，仅包含至少一种稀释气体在非均相催化的气相氧化的条件下基本上是惰性的，并且其中在连续操作中，产物气体混合物中存在的至少一部分基本上惰性的稀释气体从其中分离出来，并且作为进料气体的组分重复使用与氧化反应器的混合物，基本上惰性的稀释气体混合物包含大于85体积％的至少一种具有1至5个碳原子的饱和烃。

38. 发明授权

US5149884A Tube bundle reactor, use thereof in exothermic organic reactions, and preparation of ketones and aldehydes using same 失效
标题翻译：管组件反应器，在有机有机反应中使用，以及使用其制备酮和醛
公开(公告)号：US5149884A
公开(公告)日：1992-09-22
申请号：US680631
申请日：1991-04-01
申请人： Karl Brenner , Wilhelm Ruppel , Otto Woerz , Klaus Halbritter , Hans-Juergen Scheiper , Werner Aquila , Hartwig Fuchs
发明人： Karl Brenner , Wilhelm Ruppel , Otto Woerz , Klaus Halbritter , Hans-Juergen Scheiper , Werner Aquila , Hartwig Fuchs
IPC分类号： B01J8/06 , C07B61/00 , C07C45/00 , C07C45/38 , C07C45/39 , C07C47/21 , C07C67/00
CPC分类号： B01J8/067 , C07C45/38 , C07C45/39 , B01J2208/00212 , B01J2208/0053
摘要： In a tube bundle reactor for carrying out catalytic organic reactions in the gas phase, comprising reaction tubes (A) arranged between tubesheets (B), the reaction tubes have an inside diameter ranging from 0.5 to 3 cm, the ratio of reaction tube length to inside diameter ranges from 2 to 10, and the reaction tubes (A) are surrounded by a fluid heat transport medium flowing in the crosswise direction; said tube bundle reactor is useful in particular in exothermic organic reactions.
摘要翻译：在用于在气相中进行催化有机反应的管束反应器中，包括布置在管板（B）之间的反应管（A），反应管的内径范围为0.5至3cm，反应管长度与内径为2〜10，反应管（A）由沿横向流动的流体传热介质包围; 所述管束反应器尤其可用于放热有机反应中。

39. 发明授权

US5144091A Preparation of acrolein or methacrolein by actalytic gas-phase oxidation of propene or isobutene 失效
标题翻译：丙烯酸或甲基纤维素通过丙烯酸或丙烯酸的活性气相氧化法制备
公开(公告)号：US5144091A
公开(公告)日：1992-09-01
申请号：US732910
申请日：1991-07-19
申请人： Hans Martan , Ulrike Wegerle , Wilhelm Ruppel , Lothar Riekert , Dieter Becker , Michael Kotter
发明人： Hans Martan , Ulrike Wegerle , Wilhelm Ruppel , Lothar Riekert , Dieter Becker , Michael Kotter
IPC分类号： B01J23/88 , B01J23/887 , B01J27/19 , B01J27/192 , C07B61/00 , C07C45/35 , C07C47/22
CPC分类号： B01J27/192 , B01J23/002 , B01J23/8876 , C07C45/35 , B01J2523/00
摘要： A process for the catalytic gas-phase oxidation of propene or isobutene to acrolein or methacrolein in a tubular fixed bed reactor or catalytically active oxides with a .gtoreq.90% conversion of the initial olefin on a single passage, wherein the temperature of the gases containing the reactants in the direction of flow along the tubes from their entrance until the conversion of the initial olefin is from 30 to 70% is from 360.degree. to 420.degree. C. and is then adjusted to from 360.degree. to 300.degree. C. until the conversion of the initial olefin is from 80 to 90% and is thereafter maintained at from 330.degree. to 390.degree. C. until the gases emerge from the tubes, is described.
摘要翻译：在管式固定床反应器中催化气相氧化丙烯或异丁烯至丙烯醛或甲基丙烯醛的方法或在单一通道上具有初始烯烃转化率> 90％的催化活性氧化物的方法，其中气体的温度在反应物的入口方向沿着管的流动方向含有反应物，直到初始烯烃的转化率为30-70％为360℃至420℃，然后调节至360℃至300℃直至描述了初始烯烃的转化率为80-90％，然后保持在330℃至390℃，直到气体从管中出来。

40. 发明授权

US08889936B2 Method of regenerating ruthenium catalysts for the hydrogenation of benzene 有权
标题翻译：再生用于氢化苯的钌催化剂的方法
公开(公告)号：US08889936B2
公开(公告)日：2014-11-18
申请号：US12375759
申请日：2007-07-27
申请人： Jochem Henkelmann , Michael Becker , Michael Schönherr , Wilhelm Ruppel , Ulrike Wegerle , Bianca Stäck
发明人： Jochem Henkelmann , Michael Becker , Michael Schönherr , Wilhelm Ruppel , Ulrike Wegerle , Bianca Stäck
IPC分类号： C07C5/10 , B01J23/46 , B01J23/96 , B01J38/04 , B01J23/75 , B01J23/40 , B01J23/755
CPC分类号： B01J38/04 , B01J23/40 , B01J23/462 , B01J23/75 , B01J23/755 , B01J23/96 , C07C5/10 , C07C2523/46 , Y02P20/584 , Y10S585/906 , C07C13/18
摘要： The present patent application describes a method of regenerating a ruthenium catalyst for the hydrogenation of benzene, which comprises flushing the catalyst with inert gas in a regeneration step until the original activity or part of the original activity has been attained.
摘要翻译：本专利申请描述了一种再生用于苯氢化的钌催化剂的方法，其包括在再生步骤中用惰性气体冲洗催化剂直到达到原始活性或部分原始活性。

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