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31. 发明授权

US07851320B2 Mesostructured aluminosilicate material 有权
标题翻译：中等结构铝硅酸盐材料
公开(公告)号：US07851320B2
公开(公告)日：2010-12-14
申请号：US12408437
申请日：2009-03-20
申请人： Alexandra Chaumonnot , Aurélie Coupe , Clément Sanchez , Patrick Euzen , Cédric Boissiere , David Grosso
发明人： Alexandra Chaumonnot , Aurélie Coupe , Clément Sanchez , Patrick Euzen , Cédric Boissiere , David Grosso
IPC分类号： C01B33/00 , C01B33/26
CPC分类号： B01J35/0013 , B01J29/041 , B01J35/023 , B01J35/10 , B01J35/1023 , B01J37/0045 , C01B39/02
摘要： A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminum oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.
摘要翻译：描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料，每个所述球形颗粒由基于氧化硅和氧化铝的基体构成，孔径在1.5至30nm的范围内，Si / Al 摩尔比至少为1，具有厚度在1至20nm范围内的非晶壁，所述球形基本粒子的最大直径为10μm。还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。

32. 发明授权

US07658836B2 Process for producing middle distillates by hydroisomerizing and hydrocracking feeds from the Fischer-Tropsch process using a multifunctional guard bed 有权
标题翻译：通过使用多功能保护床从费 - 托方法加氢异构化和加氢裂化原料生产中间馏分的方法
公开(公告)号：US07658836B2
公开(公告)日：2010-02-09
申请号：US11487591
申请日：2006-07-17
申请人： Patrick Euzen , Vincenzo Calemma
发明人： Patrick Euzen , Vincenzo Calemma
IPC分类号： C10G65/00 , C10G69/00 , C10G47/00
CPC分类号： B01J23/883 , B01J8/0207 , B01J21/12 , B01J23/40 , B01J27/19 , B01J35/0006 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J2208/025 , B01J2219/00038 , C10G2/32 , C10G45/38 , C10G47/14 , C10G65/12 , Y10S208/95
摘要： The process of producing middle distillates from effluents obtained by a Fischer-Tropsch synthesis, comprises a step for hydro-treatment and purification and/or decontamination by passage over a multi-functional guard bed prior to a step of hydrocracking/hydroisomerization. The guard bed reduces the amount of unsaturated compounds, oxygen-containing compounds, particulate mineral solids, and organometallic compounds.
摘要翻译：通过费 - 托合成获得的流出物生产中间馏分的方法包括在加氢裂化/加氢异构化步骤之前通过多功能保护床进行加氢处理和净化和/或去污的步骤。防护床减少了不饱和化合物，含氧化合物，微粒矿物固体和有机金属化合物的量。

33. 发明授权

US07572946B2 Process for oligomerizing olefins using a silica-alumina based catalyst 有权
标题翻译：使用二氧化硅 - 氧化铝基催化剂使烯烃低聚的方法
公开(公告)号：US07572946B2
公开(公告)日：2009-08-11
申请号：US11182021
申请日：2005-07-15
申请人： Sylvie Lacombe , Renaud Revel , Patrick Briot , Eric Llido , Patrick Euzen , Carole Bobin
发明人： Sylvie Lacombe , Renaud Revel , Patrick Briot , Eric Llido , Patrick Euzen , Carole Bobin
IPC分类号： C07C2/08
CPC分类号： C10G69/126 , C07C2/10 , C07C2521/12 , C10G50/00 , C10G2300/1092 , C10G2300/301 , C10G2300/4018 , C10G2300/802 , C10G2400/02 , C07C11/02
摘要： An olefin oligomerization process employs a particular silica-alumina catalyst which comprises a non zeolitic support based on silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2) and has the following characteristics: a mean pore diameter, measured by mercury porosimetry, in the range 20 to 140 Å; a total pore volume, measured by mercury porosimetry, in the range 0.1 ml/g to 0.6 ml/g; a total pore volume, measured by nitrogen porosimetry, in the range 0.1 ml/g to 0.6 ml/g; a BET specific surface area in the range 100 to 550 m2/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 140 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 160 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 200 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 500 Å, of less than 0.1 ml/g; and an X ray diffraction diagram containing at least the principal characteristic peaks of at least one of the transition aluminas included in the group composed of alpha, rho, khi, eta, gamma, kappa, theta and delta aluminas.
摘要翻译：烯烃低聚方法使用特定的二氧化硅 - 氧化铝催化剂，其包含基于二氧化硅 - 氧化铝的非沸石载体，其含有大于5重量％且95重量％以下的二氧化硅（SiO 2），并具有以下特征：通过水银孔率法测量的平均孔径在20至140埃的范围内; 通过水银孔率法测量的总孔体积在0.1ml / g至0.6ml / g的范围内; 通过氮气孔率法测量的总孔体积在0.1ml / g至0.6ml / g的范围内; 100-550m2 / g范围内的BET比表面积; 通过水银孔率法测定的孔体积，其直径大于140埃，小于0.1ml / g; 通过水银孔率法测量的孔体积，其直径大于160埃的孔隙小于0.1ml / g; 包含在直径大于200埃的孔中，通过水银孔率法测量的孔体积小于0.1ml / g; 通过水银孔率法测量的孔体积包含在直径大于500埃的小于0.1ml / g的孔中; 以及X射线衍射图，其至少包含由α，rho，khi，eta，γ，κ，θ和δ氧化铝组成的组中的至少一种过渡氧化铝的主要特征峰。

34. 发明申请

US20060079704A1 Process for co-producing olefins and esters by ethenolysis of unsaturated fats in non-aqueous ionic liquids 失效
标题翻译：通过非水性离子液体中不饱和脂肪的乙烯分解共同生产烯烃和酯的方法
公开(公告)号：US20060079704A1
公开(公告)日：2006-04-13
申请号：US11286351
申请日：2005-11-25
申请人： Sylvie Lacombe , Renaud Revel , Patrick Briot , Eric Llido , Patrick Euzen , Carole Bobin
发明人： Sylvie Lacombe , Renaud Revel , Patrick Briot , Eric Llido , Patrick Euzen , Carole Bobin
IPC分类号： C07C67/00 , C07C5/00
CPC分类号： C07C6/04 , C07C2/10 , C07C67/333 , C07C2521/12 , C10G50/00 , C10G69/126 , C10G2300/1014 , C10G2400/22 , C11C3/00 , C07C11/02 , C07C69/533
摘要： A process is described in which an unsaturated fat is reacted with ethylene in a metathesis reaction in the presence of at least one non-aqueous ionic liquid to produce both an olefinic fraction and a composition of monoalcohol or polyol esters. Particular application to an oleic sunflower seed oil, an oleic rapeseed oil or to a mixture of monoalcohol esters of said oils, the process producing both an olefinic fraction and a monoalcohol or glycerol esters composition generally having more than half of its chains constituted by unsaturated C10 chains.
摘要翻译：描述了一种方法，其中不饱和脂肪在复分解反应中在至少一种非水离子液体存在下与乙烯反应，以产生烯属馏分和一元醇或多元醇酯的组合物。特别应用于油酸向日葵籽油，油菜菜籽油或所述油的一元醇酯的混合物，该方法生产烯烃级分和一元醇或甘油酯组合物，其通常具有由不饱和C构成的链的一半以上 10个链。

35. 发明申请

US20050177017A1 Process for the production of phenylalkanes that use a catalyst based on silicated alumina 有权
标题翻译：制备使用基于硅酸铝的催化剂的苯基烷烃的方法
公开(公告)号：US20050177017A1
公开(公告)日：2005-08-11
申请号：US10981740
申请日：2004-11-05
申请人： Patrick Euzen , Emmanuelle Guillon
发明人： Patrick Euzen , Emmanuelle Guillon
IPC分类号： B01J21/12 , B01J23/42 , B01J35/00 , B01J35/10 , B01J37/00 , C07C2/66 , C07C5/00 , C07C2/68
CPC分类号： B01J21/12 , B01J23/42 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0009 , C07C2/66 , C07C15/107
摘要： The invention relates to a process for the production of at least one compound that is selected from among the 2-, 3-, 4-, 5-, and 6-phenylalkanes by alkylation of an aromatic compound by means of at least one olefin that comprises at least 9 carbon atoms per molecule, in the presence of a catalyst that comprises at least one non-zeolitic substrate with a silicated alumina base that contains an amount of more than 6% by weight and less than or equal to 50% by weight of silica (SiO2) and that exhibits particular characteristics, whereby said process is carried out at a temperature of between 30 and 400° C., a pressure of between 0.1 and 10 MPa, an hourly volumetric flow rate of 0.50 to 200 h−1, and an aromatic compound/olefin molar ratio of between 1:1 and 50:1.
摘要翻译：本发明涉及一种通过至少一种烯烃将芳族化合物烷基化制备至少一种选自2-，3-，4-，5-和6-苯基烷烃的化合物的方法，在每个分子中包含至少9个碳原子的催化剂存在下，所述催化剂包含至少一种非沸石基质，其中硅烷氧化铝基质含量超过6重量％且小于或等于50重量％的二氧化硅（SiO 2），并且其表现出特定的特性，由此所述方法在30至400℃的温度下进行，压力为0.1至10MPa，小时体积流速为0.50至200h -1 ，芳香族化合物/烯烃的摩尔比为1：1〜50：1。

36. 发明授权

US06218334B1 Catalysts which can be used in conversion reactions of hydrocarbons and containing silicon 失效
标题翻译：可用于烃和含硅转化反应的催化剂
公开(公告)号：US06218334B1
公开(公告)日：2001-04-17
申请号：US08973407
申请日：1997-12-15
申请人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
发明人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
IPC分类号： B01J2713
CPC分类号： C10G35/09 , B01J23/56 , B01J23/58 , B01J23/63 , B01J23/8933 , B01J27/13
摘要： The invention relates to a catalyst comprising: a matrix consisting of 0 and 100% by weight of &lgr; transition alumina, the complement up to 100% by weight of the matrix being in &ggr; transition alumina, and relative to the total weight of the catalyst, from 0.001 to 2% by weight of silicon, from 0.1 to 15% by weight of at least one halogen chosen from the group formed by fluorine, chlorine, bromine and iodine, from 0.01 to 2% by weight of at least one noble metal from the platinum group, from 0.005 to 10% by weight of at least one promoter metal chosen from the group formed by tin, germanium, indium, gallium, thallium, antimony, lead, rhenium, manganese, chromium, molybdenum and tungsten, and if required from 0.001 to 10% by weight of a doping metal.
摘要翻译：本发明涉及一种催化剂，其包括：由0和100重量％的羔羊酸过渡氧化铝组成的基体，所述基体的重量比率高达100重量％，并且相对于催化剂的总重量， 0.001至2重量％的硅，0.1至15重量％的至少一种选自氟，氯，溴和碘的卤素，0.01至2重量％的至少一种贵金属，选自0.005至10重量％的至少一种选自由锡，锗，铟，镓，铊，锑，铅，铼，锰，铬，钼和钨形成的助催化剂金属， 0.001〜10重量％的掺杂金属。

37. 发明授权

US6045689A Process for catalytic conversion of hydrocarbons into aromatic compounds with a catalyst containing silicon 失效
标题翻译：用含有催化剂的烃催化转化成芳族化合物的方法
公开(公告)号：US6045689A
公开(公告)日：2000-04-04
申请号：US973402
申请日：1997-12-15
申请人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
发明人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
IPC分类号： B01J23/56 , B01J23/63 , B01J23/64 , B01J27/13 , B01J27/135 , C10G35/09 , C10G35/06 , C10G35/085
CPC分类号： C10G35/09 , B01J23/56 , B01J23/63 , B01J27/13
摘要： A process for converting hydrocarbons into aromatic compounds, which entails contacting a composition containing hydrocarbons with a catalyst under temperature and pressure conditions to produce the aromatic compounds, the catalyst containing a matrix of .eta. transition alumina and/or .gamma. transition alumina. The catalyst contains 0.001 to 2 wt % of silicon, 0.1 to 15 wt % of at least one platinum group metal, and 0.005 to 10 wt % of at least one promoter metal. The promoter metals may be tin, germanium, indium, gallium, thallium, antimony, lead, rhenium, manganese, chromium, molybdenium or tungsten. The catalyst may also contain a doping metal.
摘要翻译： PCT No.PCT / FR96 / 00919 Sec。 371 1997年12月15日第 102（e）日期1997年12月15日PCT Filted 1996年6月14日PCT公布。出版物WO97 / 00306 日期1997年1月3日一种将烃转化为芳族化合物的方法，其需要在温度和压力条件下使含烃的组合物与催化剂接触以产生芳族化合物，所述催化剂含有等离子体氧化铝和/或γ过渡氧化铝。催化剂含有0.001〜2重量％的硅，0.1〜15重量％的至少一种铂族金属和0.005〜10重量％的至少一种助催化剂金属。助催化剂金属可以是锡，锗，铟，镓，铊，锑，铅，铼，锰，铬，钼或钨。催化剂也可以含有掺杂金属。

38. 发明授权

US5830822A High temperature resistant oxidation catalyst, a process for its preparation and a combustion process using this catalyst 失效
标题翻译：耐高温氧化催化剂，其制备方法和使用该催化剂的燃烧过程
公开(公告)号：US5830822A
公开(公告)日：1998-11-03
申请号：US496957
申请日：1995-06-30
申请人： Patrick Euzen
发明人： Patrick Euzen
IPC分类号： B01J23/00 , B01J23/34 , B01J23/78 , B01J23/80 , B01J37/03 , B01J21/04 , B01J101/32
CPC分类号： B01J37/03 , B01J23/002 , B01J23/34 , B01J23/78 , B01J23/80 , B01J2523/00
摘要： A non-selective high temperature resistant oxidation catalyst and a process for the preparation of this catalyst is described. The catalyst mainly has the formula A.sub.1-x B.sub.y C.sub.z Al.sub.12-y-z O.sub.19-.delta., where A represents at least one element selected from the group formed by barium, strontium and the rare earths; B represents at least one element with valency Y selected from the group formed by Mn, Co and Fe; C represents at least one element selected from the group formed by Mg and Zn; x has a value of 0 to 0.25, y has a value of 0.5 to 3 and z has a value of 0.01 to 3; the sum y+z has a maximum value of 4 and .delta. has a value which is determined as a function of the respective valencies X and Y of elements A and B and the value of x, y and z and is equal to 1-1/2{(1-x)X+yY-3y-z}. The catalysts of the invention are particularly for use in processes for the catalytic combustion of hydrocarbons, carbon monoxide, hydrogen or mixtures thereof.
摘要翻译：描述了非选择性耐高温氧化催化剂和制备该催化剂的方法。催化剂主要具有式A1-xByCzAl12-y-zO19-δ，其中A代表选自钡，锶和稀土形成的组中的至少一种元素; B表示选自由Mn，Co和Fe形成的基团中的至少一种价态Y的元素; C表示选自由Mg和Zn形成的基团中的至少一种元素; x的值为0〜0.25，y为0.5〜3，z为0.01〜3的值。总和y + z的最大值为4，delta具有被确定为元素A和B的各个价值X和Y的函数的值，并且x，y和z的值等于1- + E，fra 1/2 + EE {（1-x）X + yY-3y-z}。本发明的催化剂特别用于烃，一氧化碳，氢气或其混合物的催化燃烧方法。

39. 发明授权

US09862653B2 Use of a catalyst comprising a phosphorous modified zeolite in an alcohol dehydration process 有权
公开(公告)号：US09862653B2
公开(公告)日：2018-01-09
申请号：US14236726
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath , Joseph Lopez , Patrick Euzen
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath , Joseph Lopez , Patrick Euzen
IPC分类号： C07C1/24 , B01J37/10 , B01J37/28 , B01J29/40 , B01J29/85
CPC分类号： C07C1/24 , B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C2527/14 , C07C2529/06 , C07C2529/40 , Y02P20/52 , Y02P30/42 , C07C11/04
摘要： A catalyst can be used to convert an alcohol in a dehydration process into an olefin having the same number of carbon atoms as the alcohol. The catalyst can include a phosphorus modified zeolite made by providing a zeolite with at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with binders and shaping additives, and shaping the zeolite. An ion-exchange step can be performed, and the shaped catalyst can be steamed. Phosphorus can be introduced on the catalyst at an amount of at least 0.1 wt %, such as by dry impregnation or chemical vapor deposition. A metal can be introduced. The catalyst can be washed and/or calcinated, and steamed in an equilibration step. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C.

40. 发明授权

US07879224B2 Doped alumino-silicate catalyst and improved process for treatment of hydrocarbon feeds 有权
标题翻译：掺杂铝硅酸盐催化剂和改进的烃类进料处理方法
公开(公告)号：US07879224B2
公开(公告)日：2011-02-01
申请号：US11663497
申请日：2005-09-20
申请人： Patrick Euzen , Alexandra Chaumonnot , Magalie Roy-Auberger , Patrick Bourges , Tivadar Cseri , Maryline Delage , Nathalie Lett
发明人： Patrick Euzen , Alexandra Chaumonnot , Magalie Roy-Auberger , Patrick Bourges , Tivadar Cseri , Maryline Delage , Nathalie Lett
IPC分类号： C10G11/02 , B01J27/185
CPC分类号： B01J21/12 , B01J21/02 , B01J23/883 , B01J23/888 , B01J27/1853 , B01J27/188 , B01J35/0006 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/108 , B01J37/0201 , B01J37/20 , B01J37/28 , C10G49/02 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： The present invention concerns doped catalysts on an alumino-silicate support with an adapted macropore content and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table, a controlled quantity of phosphorus (optionally in combination with boron and/or silicon) as a doping element, and a non-zeolitic support based on alumina-silica containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
摘要翻译：本发明涉及具有适用的大孔含量和加氢裂化/加氢转化和使用它们的加氢处理方法的铝硅酸盐载体上的掺杂催化剂。该催化剂包含至少一种选自元素周期表第VIB族和第VIII族的元素形成的氢化脱氢元素，受控量的磷（任选与硼和/或硅组合）作为掺杂元素， - 基于含有大于5重量％和95重量％或更少的二氧化硅（SiO 2）的量的氧化铝 - 二氧化硅的硅铝石载体。

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