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31. 发明专利

JP2008181831A Nonaqueous electrolyte and secondary battery using same 有权
标题翻译：非电解电解质和二次电池使用相同
公开(公告)号：JP2008181831A
公开(公告)日：2008-08-07
申请号：JP2007015944
申请日：2007-01-26
申请人： Adeka Corp , Denso Corp , 株式会社Adeka , 株式会社デンソー
发明人： HIRATA KAZUKI , SUZUKI SATORU , USAMI KYOHEI , TAKI NORIYUKI , TOMITA ATSURO , ASANO HIROTO
IPC分类号： H01M10/05 , H01M10/0567
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte keeping low internal resistance and high electric capacity in long use or in high-temperature storage, and to provide a nonaqueous electrolyte secondary battery using this nonaqueous electrolyte. SOLUTION: The nonaqueous electrolyte prepared by dissolving an electrolyte salt in an organic solvent includes a silicon compound containing an unsaturated bond having a carbon-carbon triple bond and a carbon-carbon double bond within a molecule, represented by general formula (1). In the formula, R 1 and R 2 independently represent a 1-8C alkyl group, a 2-8C alkenyl group, a 2-8C alkynyl group or a 6-18C aryl group, each may be replaced with a halogen atom; R 3 , R 4 , R 5 and R 6 independently represent a hydrogen atom, a 1-8C alkyl group, a 2-8C alkenyl group, a 2-8C alkynyl group, a 6-18C aryl group, each may be replaced with a halogen atom, or a silyl group. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种在长期使用或高温储存中保持低内阻和高电容的非水电解质，并提供使用该非水电解质的非水电解质二次电池。解决方案：通过将电解质盐溶解在有机溶剂中制备的非水电解质包括在通式（1）表示的分子内含有具有碳 - 碳三键和碳 - 碳双键的不饱和键的硅化合物）。在该式中，R SB 1和R SB 2独立地表示1-8C烷基，2-8C烯基，2-8C炔基或6-18C 芳基可以被卤素原子取代; R SB 3，R SB 3，R SB 5和SB SB 6独立地代表氢原子，1-8C烷基基团，2-8C烯基，2-8C炔基，6-18C芳基各自可以被卤素原子或甲硅烷基取代。版权所有（C）2008，JPO＆INPIT

32. 发明专利

JP2003282063A Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：JP2003282063A
公开(公告)日：2003-10-03
申请号：JP2002311459
申请日：2002-10-25
申请人： Denso Corp , 株式会社デンソー
发明人： AWANO NAOMI , USAMI KYOHEI , FUKAYA ATSUSHI
IPC分类号： H01M4/13 , H01M4/62 , H01M10/05 , H01M10/052 , H01M10/0566 , H01M10/0567 , H01M4/02 , H01M10/40
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a non-aqueous electrolyte secondary battery with high safety. SOLUTION: The battery contains at least one sort of a reaction suppressor among a redox agent and a radical capture agent in the interior, and minute powder and/or a film component, from which the reaction suppressor is discharged when the inside of the above non-aqueous electrolyte secondary battery becomes beyond a predetermined temperature. When the interior of the battery becomes beyond the predetermined temperature, by discharging the reaction suppressor, which suppresses the battery reaction, in the inside of the battery, and by preventing the battery reaction from advancing further, the temperature rise in the inside of the non-aqueous electrolyte secondary battery is prevented. That is, the generated active oxygen is stabilized by the radical capture agent, then, the radical reaction hereafter is suppressed. Moreover, the battery reaction can be suppressed, generation of reaction heat can be reduced, and a thermal run away can be stopped, by making an oxidation-reduction reaction suppressor react prior to the battery reaction. Moreover, since the reaction suppressor is isolated at the time of the usual operation, the battery reaction can not be influenced badly. COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供高安全性的非水电解质二次电池。解决方案：电池在内部的氧化还原剂和自由基捕获剂中含有至少一种反应抑制剂，以及微粉末和/或膜成分，当反应抑制剂的内部上述非水电解质二次电池变得超过预定温度。当电池内部变得超过预定温度时，通过在电池内部放电抑制电池反应的反应抑制器，并且通过防止电池反应进一步前进，内部的非温度升高防止了水电解质二次电池。也就是说，所产生的活性氧被自由基捕获剂稳定，然后抑制自由基反应。此外，通过在电池反应之前使氧化还原反应抑制剂反应，可以抑制电池反应，可以减少反应热的产生，并且可以停止热离开。此外，由于反应抑制剂在通常的操作时被隔离，电池反应不会受到严重的影响。版权所有（C）2004，JPO

33. 发明专利

JP2013145702A Nonaqueous electrolyte secondary battery, and nonaqueous electrolyte for secondary battery 审中-公开
标题翻译：非电解电解质二次电池和非电解电解质二次电池
公开(公告)号：JP2013145702A
公开(公告)日：2013-07-25
申请号：JP2012005920
申请日：2012-01-16
申请人： Adeka Corp , 株式会社Adeka , Denso Corp , 株式会社デンソー
发明人： TAKI NORIYUKI , WATANABE YOSHIKAZU , SHIBUYA ATSUTERU , TAZAKI AKIKO , KATSUNO EIJI , TACHIBANA YUKI , YOSHIDA SHUHEI , USAMI KYOHEI , YAMADA MANABU
IPC分类号： H01M10/0567 , H01M4/58 , H01M10/052
CPC分类号： Y02E60/122 , Y02T10/7011
摘要： PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte secondary battery with a cathode containing a transition metal and lithium which is capable of keeping a small internal resistance and a high electric capacity even after being stored under a high-temperature condition or being charged and discharged at a high temperature, by suppressing deterioration owing to metal elution from the cathode or the like.SOLUTION: The nonaqueous electrolyte comprises a silyl ester compound represented by the general formula (1). In the formula (1), R, Rand Reach represent an alkyl group having 1-6 carbon atoms or an alkenyl group having 2-6 carbon atoms.
摘要翻译：要解决的问题：提供一种具有含有过渡金属和锂的阴极的非水电解质二次电池，其即使在高温条件下储存或被充放电之后也能够保持小的内电阻和高电容在高温下，通过抑制由于阴极等的金属洗脱而导致的劣化。溶液：非水电解质包含由通式（1）表示的甲硅烷基酯化合物。在式（1）中，R，Rand Reach表示具有1-6个碳原子的烷基或具有2-6个碳原子的链烯基。

34. 发明专利

JP2011103208A Secondary battery 有权
标题翻译：二次电池
公开(公告)号：JP2011103208A
公开(公告)日：2011-05-26
申请号：JP2009257326
申请日：2009-11-10
申请人： Denso Corp , 株式会社デンソー
发明人： NAGATA YUTAKA , KOBAYAKAWA RYUTA , USAMI KYOHEI , YAMADA MANABU
IPC分类号： H01M4/60
CPC分类号： Y02E60/12
摘要： PROBLEM TO BE SOLVED: To provide a secondary battery with high energy density and capable of having cycle characteristics improved. SOLUTION: In the secondary battery, at least either a positive electrode or a negative electrode is provided with a copolymer obtained through a process that an organic redox compound having a carbonyl group or an amine group and a linker compound having an amine group or a carbonyl group form an amide or an imide bond by condensation polymerization. The secondary battery can restrain the copolymer from eluting into electrolyte solution enabling improvement of cycle characteristics. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供具有高能量密度并且能够改善循环特性的二次电池。解决方案：在二次电池中，正极或负极中的至少一个具有通过具有羰基或胺基的有机氧化还原化合物和具有胺基的连接化合物的方法得到的共聚物或羰基通过缩聚形成酰胺或酰亚胺键。二次电池可以抑制共聚物洗脱到电解质溶液中，从而可以改善循环特性。版权所有（C）2011，JPO＆INPIT

35. 发明专利

JP2011077029A Nonaqueous electrolytic solution, and nonaqueous electrolytic solution secondary battery using the nonaqueous electrolytic solution 有权
标题翻译：非电解电解质和非电解电解质二次电池使用非电解电解质
公开(公告)号：JP2011077029A
公开(公告)日：2011-04-14
申请号：JP2010186003
申请日：2010-08-23
申请人： Adeka Corp , Denso Corp , 株式会社Adeka , 株式会社デンソー
发明人： TAKI NORIYUKI , ONUMA YUYU , WATANABE HIROTOMO , SHIBUYA ATSUTERU , UMEMOTO HISASHI , USAMI KYOHEI , YAMADA MANABU
IPC分类号： H01M10/0567 , H01M10/052 , H01M10/0569
CPC分类号： Y02E60/122 , Y02T10/7011
摘要： PROBLEM TO BE SOLVED: To provide a nonaqueous electrolytic solution for a secondary battery and a nonaqueous electrolytic solution secondary battery using the nonaqueous electrolytic solution in which even in the secondary battery having a crystalline carbon material high in crystallinity such as graphite as an active material, and using a negative electrode manufactured by using a polymer carboxylic acid compound as a binder, less inner resistance and high electric capacity can be maintained in use for a long period. SOLUTION: The nonaqueous electrolytic solution used for the secondary battery having the negative electrode containing the polymer carboxylic acid compound contains an unsaturated phosphate ester compound represented by general formula (1). In the formula, R 1 and R 2 are each independently a hydrogen atom or an alkyl group of carbon number of 1 to 8, and R 3 is the alkyl group of carbon number of 1 to 8, an alkenyl group of carbon number of 2 to 8, an alkynyl group of carbon number of 2 to 8 or a halogenated alkyl group of carbon number of 1 to 8. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种二次电池用非水电解液和非水电解液二次电池，其使用非水电解液，其中即使在具有高结晶度的结晶碳材料的二次电池中，例如石墨为活性物质，使用通过使用聚合物羧酸化合物作为粘合剂制造的负极，能够长时间保持使用较少的内阻和高电容。解决方案：具有含有聚合物羧酸化合物的负极的二次电池用非水电解液含有通式（1）表示的不饱和磷酸酯化合物。在该式中，R 1和R 2各自独立地为氢原子或碳原子数为1至8的烷基，R 3为SP 碳原子数为1〜8的烷基，碳原子数为2〜8的烯基，碳数为2〜8的炔基或碳数为1〜8的卤代烷基。版权所有（C）2011，JPO＆INPIT

36. 发明专利

JP2007012595A Nonaqueous electrolyte and nonaqueous electrolyte secondary battery using the same 有权
标题翻译：使用非电解电解质和非电解电解质二次电池
公开(公告)号：JP2007012595A
公开(公告)日：2007-01-18
申请号：JP2006122217
申请日：2006-04-26
申请人： Adeka Corp , Denso Corp , 株式会社Adeka , 株式会社デンソー
发明人： YAMAMOTO KOHEI , FUKAYA ATSUSHI , USAMI KYOHEI , YAMADA MANABU , TAKI NORIYUKI
IPC分类号： H01M10/05 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569
CPC分类号： H01M10/0567 , H01M4/131 , H01M4/133 , H01M10/052 , H01M10/0568 , H01M10/4235
摘要： PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte that can provide a battery capable of maintaining a high electrical capacity and excellent in cycle characteristics, low temperature characteristics and long-term stability, and to provide a nonaqueous electrolyte secondary battery using the nonaqueous electrolyte. SOLUTION: This invention provides a nonaqueous electrolyte and a nonaqueous electrolyte secondary battery including the nonaqueous electrolyte. The nonaqueous electrolyte is obtained by dissolving an electrolyte salt in an organic solvent, and contains at least one silicon compound represented by a general formula (1) or a general formula (2). In the general formula (1), R 1 and R 2 represent groups such as an alkyl group having 1 to 10 carbon atoms; R 3 represents an alkenyl group having 13 to 20 carbon atoms; and X represents a halogen atom. In the general formula (2), R 4 to R 7 represent groups such as an alkyl group having 1 to 10 carbon atoms; R 8 and R 9 represent halogen atoms, trifluoromethyl groups or the like; n represents 1 or 2; and Y represents a direct bond, an oxygen atom, an alkylene group or the like. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决问题的方法：提供能够提供能够保持高电容性，循环特性优异，低温特性和长期稳定性的电池的非水电解质，并且提供一种非水电解质二次电池，其使用非水电解质。解决方案：本发明提供一种非水电解质和包含非水电解质的非水电解质二次电池。非水电解质是通过将电解质盐溶解在有机溶剂中而得到的，含有至少一种由通式（1）或通式（2）表示的硅化合物。在通式（1）中，R SB 1和R SB 2代表诸如具有1-10个碳原子的烷基; R SB 3表示碳原子数为13〜20的烯基， X表示卤素原子。在通式（2）中，R 4 至R SB 7表示例如具有1-10个碳原子的烷基; R SB 8和R SB 9表示卤素原子，三氟甲基等; n表示1或2; Y表示直接键，氧原子，亚烷基等。版权所有（C）2007，JPO＆INPIT

37. 发明专利

JP2003031208A Nonaqueous electrolyte secondary battery 有权
标题翻译：非电解电解质二次电池
公开(公告)号：JP2003031208A
公开(公告)日：2003-01-31
申请号：JP2001209662
申请日：2001-07-10
申请人： Denso Corp , 株式会社デンソー
发明人： AWANO NAOMI , USAMI KYOHEI
IPC分类号： H01M2/16 , H01M2/34 , H01M4/13 , H01M4/62 , H01M10/05 , H01M10/052 , H01M10/0566 , H01M10/058 , H01M4/02 , H01M10/40
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte secondary battery with high safety.
SOLUTION: This nonaqueous electrolyte secondary battery contains a shut off means isolating between active materials and/or between the active material and a current collector when the inside of the nonaqueous electrolyte secondary battery becomes a prescribed temperature or higher in an active material layer. When the nonaqueous electrolyte secondary battery causes thermal runaway due to unexpected situation, reaction proceeds in succession on the inside of the nonaqueous electrolyte secondary battery to generate heat, and the reaction is further accelerated. When the inside of the nonaqueous electrolyte secondary battery becomes a specified temperature or higher, the connection between the active materials or between the active material and the current collector is isolated and is electrically shut off, and further proceeding of the reaction is prevented to suppress the increase of the temperature inside the nonaqueous electrolyte secondary battery. As the shut off means, thermal expansion powder expanding its volume at a specified temperature or higher is listed.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：提供高安全性的非水电解质二次电池。解决方案：当非水电解质二次电池的内部在活性物质层中达到规定温度以上时，该非水电解质二次电池含有隔离活性物质和/或活性物质与集电体之间的截止装置。当非水电解质二次电池由于意想不到的情况导致热失控时，反应继续进行到非水电解质二次电池的内部以产生热量，并进一步加速反应。当非水电解质二次电池的内部达到规定温度以上时，活性物质或活性物质与集电体之间的连接被隔离并被电断开，并且防止反应的进一步的抑制提高非水电解质二次电池内的温度。作为切断装置，列出了在特定温度以上扩大其体积的热膨胀粉末。

38. 发明公开

EP2683011A4 NONAQUEOUS ELECTROLYTE SOLUTION FOR BATTERIES, AND NONAQUEOUS ELECTROLYTE SECONDARY BATTERY USING SAME 有权
标题翻译：自由水电解质溶液对于电池及二次电池与水无电解质与溶液
公开(公告)号：EP2683011A4
公开(公告)日：2014-08-13
申请号：EP11860524
申请日：2011-03-04
申请人： DENSO CORP , ADEKA CORP
发明人： YAMAMOTO KOUHEI , UMEMOTO HISASHI , USAMI KYOHEI , YAMADA MANABU , TAKI TAKAYUKI , OHNUMA YUYU , WATANABE HIROAKI , SHIBUYA ATSUKI
IPC分类号： H01M4/62 , H01M4/587 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569
CPC分类号： H01M10/0567 , H01M4/36 , H01M4/587 , H01M4/622 , H01M10/0525 , H01M10/0568 , H01M10/0569 , Y02T10/7011
摘要： The present invention relates to provide a nonaqueous electrolyte solution for secondary batteries, which can maintain a small internal resistance and a high electrical capacitance in long-term use in a nonaqueous electrolyte secondary battery using, as an active material, a crystalline carbon material having a high crystallinity, such as graphite and using a negative electrode produced using a polymeric carboxylic compound as a binding agent, and a nonaqueous electrolyte secondary battery using the nonaqueous electrolyte solution for secondary batteries. The present invention further provides a nonaqueous electrolyte solution for batteries, which contains, as an (A) component, at least one compound selected from a group consisting of an unsaturated phosphate ester compound represented by a general formula (1) and an unsaturated phosphate ester compound represented by a general formula (2), as a (B) component, at least one compound selected from a group consisting of a sulfite ester compound, a sulfonate ester compound, an alkali metal imide salt compound, a fluorosilane compound, and an organic disilane compound or an organic disiloxane compound, an organic solvent as a (C) component, and electrolyte salt as a (D) component, and a nonaqueous electrolyte secondary battery using the nonaqueous electrolyte solution for batteries.
摘要翻译：本发明涉及提供一种用于二次电池的非水电解质溶液，其可以保持内阻小，并且在非水电解质二次电池的长期使用使用高电容，作为活性材料的，具有结晶性的碳材料高结晶度，颜色：如石墨和使用利用聚羧酸化合物，其为结合剂制成的负电极，以及使用的二次电池用非水电解质溶液的非水电解质二次电池。本发明还提供了电池的非水电解质溶液，其含有作为（A）成分，从以下一组由通式表示的不饱和磷酸酯化合物中的至少一种化合物（1）和非饱和磷酸酯由通式（2）表示的化合物，作为（B）成分，从一组以超过碱金属亚胺盐化合物，氟硅烷化合物亚硫酸盐酯化合物，磺酸酯化合物，由......组成中的至少一种化合物，以及有机化合物或有机二硅氧烷化合物，以有机溶剂作为组分（C），和电解质盐，其为（D）成分的二硅烷和使用用于电池的非水电解质溶液的非水电解质二次电池。

39. 发明专利

FR2772390A1 Non-flammable non-aqueous electrolyte solution for rechargeable batteries 未知
公开(公告)号：FR2772390A1
公开(公告)日：1999-06-18
申请号：FR9815228
申请日：1998-12-02
申请人： DENSO CORP
发明人： USAMI KYOHEI , ITO MIHO , KUBOTA NAOHIRO , MASHIMO SHINYA
IPC分类号： C09K21/12 , H01M2/16 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/42 , H01M2/00
摘要： A nonflammable electrolytic solution comprising an electrolyte salt in an organic solvent containing at least one phosphorus compound of formula (I) is new: (R )n-P(O)-(OR )m (I) R = 1-8C alkyl, haloalkyl, aryl, alkaryl, aralkyl or CH2COOR ; R = Me, Et or 1-8C haloalkyl; R = 1-8C alkyl or haloalkyl; m and n = 1 or 2; m+n = 3. The solution contains a compound (I) were R = alkyl and/or where at least one of R -R is haloalkyl and/or where m = 2 and n = 1. The organic solvent comprises one or more carbonates, lactones, ethers, sulpholanes and/or dioxolanes. The electrolyte salt is a lithium salt in which the anion is PF6, BF4, ClO4, AsF6, SO3CF3, N(SO2CF2)2 or C(SO2CF2)3. (I) is present in the organic solvent in an amount of 5-100 wt.%.

40. 发明专利

DE60321755D1 未知
公开(公告)号：DE60321755D1
公开(公告)日：2008-08-07
申请号：DE60321755
申请日：2003-07-03
申请人： ADEKA CORP , DENSO CORP
发明人： AWANO NAOMI , USAMI KYOHEI , KUBOTA NAOHIRO
IPC分类号： H01M6/16 , H01M2/16 , H01M10/05 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569
摘要： A nonaqueous electrolytic solution comprising an electrolyte salt dissolved in an organic solvent is disclosed. The nonaqueous electrolytic solution contains a silicon compound represented by formula (I): wherein R 1 represents an alkenyl group having 2 to 10 carbon atoms; R 2 and R 3 each represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or a halogen atom; and X represents a halogen atom.

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