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31. 发明授权

US07759524B2 Process for producing phenol and methyl ethyl ketone 有权
标题翻译：苯酚和甲基乙基酮的制备方法
公开(公告)号：US07759524B2
公开(公告)日：2010-07-20
申请号：US12317044
申请日：2008-12-18
申请人： John Scott Buchanan , Jihad Mohammed Dakka , Stephen Zushma , Francisco Manuel Benitez , Steven E. Silverberg
发明人： John Scott Buchanan , Jihad Mohammed Dakka , Stephen Zushma , Francisco Manuel Benitez , Steven E. Silverberg
IPC分类号： C07C45/53 , C07C37/08
CPC分类号： C07C37/08 , C07C1/24 , C07C2/66 , C07C5/03 , C07C15/073 , C07C15/46 , C07C29/145 , C07C45/53 , C07C407/00 , C07C409/08 , C07C15/02 , C07C49/10 , C07C39/04 , C07C33/20
摘要： In a process for producing phenol and methyl ethyl ketone, benzene and a C4 olefin are contacted under alkylation conditions and in the presence of an alkylation catalyst to produce sec-butylbenzene. The sec-butylbenzene is then oxidized to produce an oxidation effluent comprising sec-butylbenzene hydroperoxide and acetophenone. At least part of the sec-butylbenzene hydroperoxide in the oxidation effluent is cleaved to produce phenol and methyl ethyl ketone, while at least part of the acetophenone is hydrogenated to produce at least one of methyl benzyl alcohol, styrene and ethylbenzene.
摘要翻译：在苯酚和甲基乙基酮的制备方法中，在烷基化条件下和烷基化催化剂的存在下，使苯和C 4烯烃接触，得到仲丁基苯。然后将仲丁基苯氧化以产生包含仲丁基苯氢过氧化物和苯乙酮的氧化流出物。将氧化流出物中的至少一部分仲丁基苯氢过氧化物切割以产生苯酚和甲基乙基酮，同时至少部分苯乙酮被氢化以产生甲基苄醇，苯乙烯和乙苯中的至少一种。

32. 发明申请

US20080306215A1 Functionalization of olefin/diene copolymers 审中-公开
标题翻译：烯烃/二烯共聚物的官能化
公开(公告)号：US20080306215A1
公开(公告)日：2008-12-11
申请号：US11810499
申请日：2007-06-06
申请人： Abhimanyu Onkar Patil , Stephen Zushma , Steven P. Rucker , Christian Peter Mehnert , Raymond A. Cook , Lisa Saunders Baugh , Enock Berluche
发明人： Abhimanyu Onkar Patil , Stephen Zushma , Steven P. Rucker , Christian Peter Mehnert , Raymond A. Cook , Lisa Saunders Baugh , Enock Berluche
IPC分类号： C08C19/34
CPC分类号： C08F8/00 , C08F2800/20 , C08F210/18 , C08F210/02 , C08F210/16 , C08F8/46 , C08F8/06 , C08F8/04 , C08F8/08
摘要： A process is described for functionalizing a copolymer comprising units derived from at least one α-olefin and units derived from at least one diene, which copolymer contains at least one double bond. The process comprises reacting the copolymer with at least one functionalizing agent to introduce polar pendant oxygen-containing functional groups onto the copolymer.
摘要翻译：描述了一种用于使包含至少一种α-烯烃的单元和源自至少一种二烯的单元的共聚物官能化的方法，该共聚物含有至少一个双键。该方法包括使共聚物与至少一种官能化试剂反应以将极性侧链含氧官能团引入到共聚物上。

33. 发明申请

US20080015314A1 Ethylene/dicyclopentadiene copolymers and functionalized derivatives thereof 有权
标题翻译：乙烯/二环戊二烯共聚物及其官能化衍生物
公开(公告)号：US20080015314A1
公开(公告)日：2008-01-17
申请号：US11801633
申请日：2007-05-10
申请人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Christian Peter Mehnert , Kevin R. Squire , Kenneth A. Cook , Caiguo Gong , Enock Berluche , Karla Schall Colle , Alan J. Oshinski , Stephen Zushma , Beverly J. Poole
发明人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Christian Peter Mehnert , Kevin R. Squire , Kenneth A. Cook , Caiguo Gong , Enock Berluche , Karla Schall Colle , Alan J. Oshinski , Stephen Zushma , Beverly J. Poole
IPC分类号： C08L45/00
CPC分类号： C08F210/02 , C08F8/04 , C08F8/08 , C08F232/00
摘要： Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)≧[(mole % DCPD×3.142)−4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicylopentadiene copolymers. Such copolymers can be readily derivatized by hydrogention and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics.Also disclosed are processes for preparing and optionally further derivatizing ethylene/dicyclopentadiene copolymers having the characteristics hereinbefore described. Such processes comprise: a) contacting ethylene with a polymerization mixture comprising greater than about 4.0 molar dicyclopentadiene, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst bearing a substituent, preferably a methyl substituent, at the 3-position of the cyclopentadienyl ring, under specific polymerization conditions including relatively high ethylene pressures to thereby form the desired ethylene-dicyclopentadiene copolymers within the polymerization mixture. Such copolymers are then recovered and/or further hydrogenated or functionalized.
摘要翻译：公开了一种选择类型的共聚物组合物，其包含具有衍生自乙烯和二环戊二烯（DCPD）共聚单体的单元的共聚物。这种共聚物组合物：a）具有约25摩尔％至约45摩尔％的DCPD衍生的共聚单体单元含量; b）具有大于约170,000的重均分子量，M < c）包含非晶材料，并且具有约8℃至约129℃的玻璃化转变温度，其也适合方程式T（g）（℃）] = [（摩尔％DCPDx 3.142）-4.67]; 和d）在乙烯 - 二茂二烯共聚物内不含有显着量的结晶聚乙烯均聚物或可结晶的聚乙烯链段。这样的共聚物可以通过水合和/或环氧化来容易地衍生，以提供适合用作工程热塑性塑料的聚合材料。还公开了制备和任选地进一步衍生具有上述特征的乙烯/二环戊二烯共聚物的方法。这样的方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂存在下，在含有大于约4.0摩尔二环戊二烯的聚合混合物的存在下，使乙烯与环戊二烯基环的3位具有取代基，优选甲基取代基接触在包括相对较高的乙烯压力的特定聚合条件下，从而在聚合混合物内形成所需的乙烯 - 二环戊二烯共聚物。然后回收和/或进一步氢化或官能化此类共聚物。

34. 发明授权

US06501000B1 Late transition metal catalyst complexes and oligomers therefrom 失效
标题翻译：后过渡金属催化剂络合物及其低聚物
公开(公告)号：US06501000B1
公开(公告)日：2002-12-31
申请号：US09542892
申请日：2000-04-04
申请人： Robert Timothy Stibrany , Michael Gerard Matturro , Stephen Zushma , Abhimanyu Onkar Patil
发明人： Robert Timothy Stibrany , Michael Gerard Matturro , Stephen Zushma , Abhimanyu Onkar Patil
IPC分类号： C07C226
CPC分类号： C07D233/20 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J31/183 , B01J2231/20 , B01J2531/824 , B01J2531/828 , B01J2531/847 , C07C2/32 , C07C2531/22
摘要： The invention is directed towards a composition comprising the formula LMX(X′)n wherein n equals 0 or 1; X and X′ are independently selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert; M is selected from the group consisting of nickel, palladium, and platinum and L is a nitrogen-containing bidentate ligand with more than two nitrogen atoms. The composition possesses a tetrahedral or pseudo-tetrahedral structure. The invention also provides a method for using the composition in conjunction with an activating cocatalyst to form short chain &agr;-olefins.
摘要翻译：本发明涉及包含式LMX（X'）n的组合物，其中n等于0或1; X和X'独立地选自卤化物，氢化物，三氟甲磺酸酯，乙酸酯，硼酸酯，C 1至C 12烷基，C 1至C 12烷氧基，C 3至C 12环烷基，C 3至C 12环烷氧基，芳基，硫醇酯，一氧化碳，氰酸酯，烯烃和单体可以插入的任何其它部分; M选自镍，钯和铂，L是具有两个以上氮原子的含氮二齿配位体。该组合物具有四面体或假四面体结构。本发明还提供了一种使用该组合物与活化助催化剂结合形成短链α-烯烃的方法。

35. 发明授权

US5691422A Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof 失效
标题翻译：具有末端醛或羟基取代基的饱和聚烯烃及其衍生物
公开(公告)号：US5691422A
公开(公告)日：1997-11-25
申请号：US662835
申请日：1996-06-12
申请人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
发明人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
IPC分类号： C08F8/00 , C08F8/32 , C08F210/16 , C08F210/18 , C10L1/198 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10M133/54 , C10M133/58
CPC分类号： C10M133/58 , C08F210/18 , C08F8/00 , C08F8/32 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/18 , C10M133/54 , C08F210/16 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06
摘要： A saturated polymer having a terminal aldehyde or hydroxy substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the saturated polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical, and wherein the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.
摘要翻译：具有末端醛或羟基取代基的饱和聚合物，其可以直接或以衍生形式用作燃料和润滑油组合物的分散剂，其中饱和聚合物的Mn为约300至10,000，并且衍生自聚烯烃其衍生自式H2C = CHR4的单体，其中R4是氢或直链或支链烷基，并且其中聚烯烃具有至少约30％的末端亚乙烯基不饱和键。特别理想的胺衍生物可以通过单步氨基甲基化方法或两步加氢甲酰化和还原胺化方法形成。

36. 发明授权

US5585516A Two tail-two head and two tail-one head surfactants 失效
标题翻译：两尾二头和两尾头表面活性剂
公开(公告)号：US5585516A
公开(公告)日：1996-12-17
申请号：US402071
申请日：1995-03-10
申请人： Ramesh Varadaraj , Stephen Zushma
发明人： Ramesh Varadaraj , Stephen Zushma
IPC分类号： C07C305/10 , C07C309/31 , C07C309/07 , C07C43/11
CPC分类号： C07C309/31 , C07C305/10
摘要： The present invention relates to novel two tail-two head and two tail-one head surfactants. In one embodiment, the present invention comprises a novel composition of matter having the general formula: ##STR1## wherein R1 and R2 may be the same or different and are selected from liner or branched hydrocarbon chains with carbon numbers 8 and 22;R3 is H, SO.sup.-.sub.y M.sup.+, or --O (CH2CH2O).sub.n X;R4 is SO.sup.-.sub.y M.sup.+, or --O (CH2CH2O).sub.n X;M is H, Li, Na, K, Rb or Cs;n is an integer from 2 to 50;y is 3 or 4; and,X is H or SO.sup.-.sub.y M.sup.-.Preferably, in the above composition when R3 is other than H, R3.dbd.R4.
摘要翻译：本发明涉及新型的二尾二头和两个尾一头表面活性剂。在一个实施方案中，本发明包括具有以下通式的物质的新组合物：不同且选自碳数为8和22的线型或支链烃链; R3是H，SO-yM +或-O（CH2CH2O）nX; R4是SO-yM +，或-O（CH2CH2O）nX; M是H，Li，Na，K，Rb或Cs; n为2-50的整数; y为3或4; X为H或SO-yM-。优选地，当上述组合物当R 3不是H时，R 3 = R 4。

37. 发明授权

US08658839B2 Oxidation of hydrocarbons 有权
标题翻译：碳氢化合物的氧化
公开(公告)号：US08658839B2
公开(公告)日：2014-02-25
申请号：US12675342
申请日：2008-10-08
申请人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
发明人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
IPC分类号： C07C35/08 , C07D209/48
CPC分类号： C07C409/04 , B01D15/00 , B01J31/0235 , C07C29/50 , C07C37/08 , C07C37/20 , C07C45/33 , C07C45/53 , C07C407/00 , C07C407/003 , C07C409/08 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C35/08 , C07C39/04 , C07C39/16 , C07C409/06 , C07C409/10
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; l is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of said formula (I) and the effluent is treated with a solid sorbent to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触：其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; l为0,1或2; m为1至3，R3可为R1列出的任何实体。接触产生包含氧化烃产物和所述式（I）的未反应酰亚胺催化剂的流出物，并且用固体吸附剂处理流出物以除去至少部分未反应的酰亚胺催化剂并产生包含所述氧化烃产物的经处理的流出物。然后可以回收有机相。

38. 发明授权

US08445730B2 Process for producing phenol 失效
标题翻译：苯酚生产工艺
公开(公告)号：US08445730B2
公开(公告)日：2013-05-21
申请号：US13061601
申请日：2009-07-14
申请人： Jihad M. Dakka , Kun Wang , Edmund J. Mozeleski , Stephen Zushma
发明人： Jihad M. Dakka , Kun Wang , Edmund J. Mozeleski , Stephen Zushma
IPC分类号： C07C409/00
CPC分类号： B01J23/002 , B01J21/066 , B01J23/28 , B01J23/30 , B01J23/888 , B01J31/0247 , B01J31/38 , B01J37/031 , B01J37/10 , B01J2523/00 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/08 , C07C409/14 , C07C2601/08 , C07C2601/14 , C07C2601/18 , Y02P20/52 , C07C39/04 , C07C49/10 , C07C49/403 , B01J2523/17 , B01J2523/48 , B01J2523/69 , B01J2523/842 , B01J2523/68
摘要： In a process for producing phenol or a substituted phenol, an alkylaromatic hydroperoxide having a general formula (I): in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with a catalyst comprising an oxide of at least one metal from Groups 3 to 5 and Groups 7 to 14 of the Periodic Table of the Elements and an oxide of at least one metal from Group 6 of the Periodic Table of the Elements.
摘要翻译：在制备苯酚或取代苯酚的方法中，具有通式（I）的烷基芳基氢过氧化物：其中R 1和R 2各自独立地表示具有1至4个碳原子的烷基，条件是R 1和R 2可以连接到形成具有4至10个碳原子的环状基团，所述环状基团任选被取代，并且R 3表示氢，具有1至4个碳原子的一个或多个烷基或环己基与包含以下化合物的催化剂接触：元素周期表第3至5族和第7至14族中的至少一种金属和至少一种元素周期表第6族金属的氧化物。

39. 发明申请

US20120215025A1 Oxidation Of Hydrocarbons 有权
标题翻译：碳氢化合物的氧化
公开(公告)号：US20120215025A1
公开(公告)日：2012-08-23
申请号：US13498998
申请日：2010-09-30
申请人： Jihad M. Dakka , Stephen Zushma , Nicolas P. Coute , Francisco M. Benitez , Edmund J. Mozeleski
发明人： Jihad M. Dakka , Stephen Zushma , Nicolas P. Coute , Francisco M. Benitez , Edmund J. Mozeleski
IPC分类号： C07C51/275
CPC分类号： C07C29/50 , C07C407/00 , C07C2601/14 , C07C35/08 , C07C409/14 , C07C409/04
摘要： In a process for oxidizing a hydrocarbon, the hydrocarbon is contacted with oxygen in the presence of an N-substituted cyclic imide and under conditions to oxidize the hydrocarbon to produce an oxidized hydrocarbon product and at least one decomposition product of the N-substituted cyclic imide. At least a portion of the at least one decomposition product is contacted with hydroxylamine or a salt thereof under conditions to convert the at least one decomposition product back to said imide.
摘要翻译：在氧化烃的方法中，在N-取代的环状酰亚胺的存在下，在氧化烃的条件下，使烃与氧接触以产生氧化的烃产物和至少一种N-取代的环状酰亚胺的分解产物。将至少一种分解产物的至少一部分与羟胺或其盐在将至少一种分解产物转化回所述酰亚胺的条件下接触。

40. 发明申请

US20120149941A1 Oxidation of Hydrocarbons 有权
标题翻译：碳氢化合物的氧化
公开(公告)号：US20120149941A1
公开(公告)日：2012-06-14
申请号：US13386250
申请日：2010-07-13
申请人： Kun Wang , Jihad M. Dakka , Stephen Zushma
发明人： Kun Wang , Jihad M. Dakka , Stephen Zushma
IPC分类号： C07C407/00
CPC分类号： C07C409/08 , C07C407/00 , C07C409/14 , C07C2601/14 , C07C409/10
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; l is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of said formula (I) and the effluent is treated with at least one solid sorbent chosen from alkali metal carbonates, alkali metal bicarbonates, alkali metal hydroxides, alkali metal hydroxide-carbonate complexes, alkaline earth metal carbonates, alkaline earth metal bicarbonates, alkaline earth metal hydroxides and alkaline earth metal hydroxide-carbonate complexes to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触：其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; l为0,1或2; m为1至3，R3可为R1列出的任何实体。接触产生包含氧化烃产物和所述式（I）的未反应酰亚胺催化剂的流出物，流出物用至少一种选自碱金属碳酸盐，碱金属碳酸氢盐，碱金属氢氧化物，碱金属氢氧化物 - 碳酸盐的固体吸附剂处理络合物，碱土金属碳酸盐，碱土金属碳酸氢盐，碱土金属氢氧化物和碱土金属氢氧化物 - 碳酸盐络合物，以去除至少部分未反应的酰亚胺催化剂并产生包含所述氧化的烃产物的经处理的流出物。然后可以回收有机相。

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