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31. 发明授权

US4253866A Methyl .alpha.-[4-(6'-methyl-5'-carbothiamido-pyrid-2'-yl)-oxy-phenoxy]-proprio nate 失效
标题翻译： α-[4-（6'-甲基-5'-甲硫基 - 吡啶-2'-基） - 氧基 - 苯氧基] - 丙酸甲酯
公开(公告)号：US4253866A
公开(公告)日：1981-03-03
申请号：US962518
申请日：1978-11-20
申请人： Rolf Schurter , Hermann Rempfler
发明人： Rolf Schurter , Hermann Rempfler
IPC分类号： C07D405/12 , A01N39/02 , A01N43/40 , A01P13/00 , A01P13/02 , C07D213/64 , C07D213/643 , C07D213/69 , C07D213/74 , C07D213/79 , C07D213/83 , C07D213/84 , C07D213/85
CPC分类号： C07D213/643 , A01N43/40 , C07D213/69 , C07D213/74 , C07D213/83 , C07D213/84
摘要： The present invention concerns pyridyloxy-phenoxy-alkanecarboxylic acid derivatives of the formula ##STR1## wherein A is hydrogen, halogen, alkyl, alkoxy, cyano, nitro or carbothiamideB is hydrogen, halogen, alkyl, cyano, mono- or dialkylamino, alkoxy-carbonyl or carbothiamideC is hydrogen, halogen, cyano, nitro or carbothiamideD is hydrogen, halogen, alkyl, mono- or dialkylaminoR.sub.1 is hydrogen, alkyl, alkoxyalkyl or benzylR is the rest of the acid a salt or an ester,with the proviso that if the pyridine ring is substituted by halogen and/or alkyl and C is also halogen, then the radicals A, B and D must contain no less than two halogen atoms or alkyl radicals.These derivatives have herbicidal and plant-growth regulating activity.
摘要翻译：本发明涉及下式的吡啶氧基 - 苯氧基 - 烷酸羧酸衍生物，其中A是氢，卤素，烷基，烷氧基，氰基，硝基或碳硫酰胺B是氢，卤素，烷基，氰基，一或二烷基氨基，烷氧基 - 羰基或碳硫酰胺C是氢，卤素，氰基，硝基或碳硫代酰胺D是氢，卤素，烷基，单或二烷基氨基，R 1是氢，烷基，烷氧基烷基或苄基R是其余的酸盐或酯，条件是如果吡啶环被卤素和/或烷基取代，C也是卤素，则基团A，B和D必须含有不少于两个卤原子或烷基。这些衍生物具有除草和植物生长调节活性。

32. 发明授权

US4225336A Phenoxyalkyloxazolines, as selective herbicides in cereals 失效
标题翻译：苯氧基恶唑啉，作为谷物中的选择性除草剂
公开(公告)号：US4225336A
公开(公告)日：1980-09-30
申请号：US62191
申请日：1979-07-30
申请人： Werner Fory , Hermann Rempfler , Georg Pissiotas , Otto Rohr , Beat Bohner
发明人： Werner Fory , Hermann Rempfler , Georg Pissiotas , Otto Rohr , Beat Bohner
IPC分类号： A01N43/76 , C07D263/14 , A01N9/28
CPC分类号： C07D263/14 , A01N43/76
摘要： Phenoxyalkyloxyzolines corresponding to the formula ##STR1## wherein R is hydrogen or methylZ is a Phenyl-or Pyridyl-radical ##STR2## R.sub.1 is halogen, trifluoromethyl, cyano or nitro R.sub.2 is hydrogen, halogen or cyanoR.sub.3 is halogen trifluoromethyl or cyano andn is 1 or 2.are effective herbicides which are tolerant towards cereal.
摘要翻译：对应于式“IMAGE”的苯氧基烷氧基唑，其中R为氢或甲基Z为苯基或吡啶基，R1为卤素，三氟甲基，氰基或硝基，R2为氢，卤素或氰基R3为卤素三氟甲基或氰基，n为是1或2.是对谷物耐受的有效除草剂。

33. 发明授权

US4067725A 3-Pyridyl-oxy-alkanecarboxylic acid amides 失效
标题翻译： 3-吡啶基 - 氧 - 链烷羧酸酰胺
公开(公告)号：US4067725A
公开(公告)日：1978-01-10
申请号：US715351
申请日：1976-08-18
申请人： Rolf Schurter , Niels Clauson-Kaas , Hermann Rempfler
发明人： Rolf Schurter , Niels Clauson-Kaas , Hermann Rempfler
IPC分类号： A01N43/40 , A01N25/32 , A62D3/30 , A62D101/04 , C07D213/65 , C07D213/73 , C07D213/79 , C07D213/81 , C07D213/84 , C07D401/12 , C07D413/12 , C07D417/12 , A01N9/22 , C07D213/56
CPC分类号： C07D213/73 , C07D213/65 , C07D213/79 , C07D213/81
摘要： The present invention relates to 3-pyridyl-oxy-alkancarboxylic acid amides of formula ##STR1## wherein A and B are individually hydrogen, halogen, alkyl, cyano, nitro or amino,C is hydrogen, halogen or nitron is 1 or 2Q is an aliphatic bridge, that can also be branched, unsaturated or substituted,R.sub.1 and R.sub.2 independently are hydrogen, alkyl, alkoxy, alkenyl, alkynyl, phenyl or benzyl,R.sub.1 and R.sub.2 together with the nitrogen atom to which they are bound are a 5 to 6 membered heterocycle.The invention also relates to processes for the production of these amides, to their use as regulators of plant growth and as antidotes for herbicides, as well as to compositions containing these amides as active substance.
摘要翻译：本发明涉及式（I）的3-吡啶基 - 氧 - 烷羧酸酰胺，其中A和B各自为氢，卤素，烷基，氰基，硝基或氨基，C为氢，卤素或硝基。是一个脂肪族桥，其也可以是支链，不饱和或取代的，R 1和R 2分别独立地为氢，烷基，烷氧基，烯基，炔基，苯基或苄基，R 1和R 2与它们所键合的氮原子一起为5 至6元杂环。

34. 发明授权

US5154751A Herbicidal urea compounds and compositions 失效
标题翻译：除草剂尿素化合物和组合物
公开(公告)号：US5154751A
公开(公告)日：1992-10-13
申请号：US530711
申请日：1990-05-30
申请人： Hermann Rempfler
发明人： Hermann Rempfler
IPC分类号： A01H5/10 , A01N47/36 , C07D213/74 , C07D213/75 , C07D213/79 , C07D213/80 , C07D213/84 , C07D213/85 , C07D405/04 , C07D409/04
CPC分类号： C07D213/75 , A01N47/36 , C07D213/85 , C07D405/04
摘要： The invention relates to novel compositions having herbicidal and plant growth regulating properties and containing, as active ingredient, a compound of formula I ##STR1## wherein R.sub.1 to R.sub.6 are as defined in the description, to novel compounds of formula I and intermediates, and to the preparation thereof.
摘要翻译：本发明涉及具有除草和植物生长调节性质的新型组合物，并且含有作为活性成分的式I化合物其中R 1至R 6如说明书中所定义，式I化合物与式I化合物和中间体，以及其制备。

35. 发明授权

US4973690A Novel ureas 失效
标题翻译：小牛尿
公开(公告)号：US4973690A
公开(公告)日：1990-11-27
申请号：US332189
申请日：1989-04-03
申请人： Hermann Rempfler , Dieter Durr
发明人： Hermann Rempfler , Dieter Durr
IPC分类号： A01N47/36 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/70 , C07D239/84 , C07D239/95 , C07D405/04 , C07D471/04 , C07D491/04 , C07D491/048 , C07D491/052 , C07D495/04
CPC分类号： C07D405/04 , C07D239/42 , C07D239/46 , C07D239/70 , C07D239/84 , C07D471/04 , C07D491/04 , C07D495/04
摘要： The present invention relates to novel N-phenyl-N-pyrimidin-2-ylureas having a herbicidal and plant growth-regulating activity, to agrochemical compositions that contain those substances as active ingredients, to the use of the novel ureas for controlling weeds or for regulating plant growth, and to processes for the preparation of the novel compounds. The invention also relates to novel intermediates and to processes for the preparation thereof.The novel compounds correspond to formula I ##STR1## in which the radicals R.sup.1 to R.sup.6 have the meanings given in the text.
摘要翻译：本发明涉及具有除草和植物生长调节活性的新型N-苯基-N-嘧啶-2-基脲，其含有这些物质作为活性成分的农用化学组合物，用于控制杂草的新颖脲或用于调节植物生长，以及制备新化合物的方法。本发明还涉及新型中间体及其制备方法。新化合物对应于其中基团R 1至R 6具有本文给出的含义的式I（I）。

36. 发明授权

US4966622A N-phenyl-N-pyrimidin-2-ylureas 失效
标题翻译： N-苯基-N-嘧啶-2-基脲
公开(公告)号：US4966622A
公开(公告)日：1990-10-30
申请号：US332193
申请日：1989-04-03
申请人： Hermann Rempfler , Dieter Durr , Rudolf C. Thummel
发明人： Hermann Rempfler , Dieter Durr , Rudolf C. Thummel
IPC分类号： A01N47/36 , A01N57/24 , C07D239/42 , C07D239/46 , C07D239/47 , C07D405/04 , C07D409/04 , C07F9/6512
CPC分类号： C07D239/42 , A01N47/36 , A01N57/24 , C07D239/47 , C07D405/04 , C07D409/04 , C07F9/65127
摘要： The present invention relates to novel N-phenyl-N-pyrimidin-2-ylureas having a herbicidal and plant growth-regulating activity, to agrochemical compositions containing those substances as active ingredients, to the use of the novel ureas for controlling weeds or for regulating plant growth, and to processes for the preparation of the novel compounds. The invention also relates to novel intermediates and to processes for the preparation thereof.The novel compounds correspond to formula I ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 are each, independently of the others, hydrogen; halogen; C.sub.1 -C.sub.4 alkyl; C.sub.1 -C.sub.4 alkoxy; C.sub.1 -C.sub.4 haloalkyl; C.sub.1 -C.sub.4 haloalkoxy; C.sub.1 -C.sub.4 alkyl-S(O).sub.n -; nitro; cyano; C.sub.1 -C.sub.4 alkoxycarbonyl; C.sub.1 -C.sub.4 alkylcarbonyl; di-(C.sub.1 -C.sub.4 alkylamino)-carbonyl; mono-(C.sub.1 -C.sub.4 alkylamino)carbonyl; carbamoyl; C.sub.1 -C.sub.4 haloalkyl-S(O).sub.n -; or -PO[O-(C.sub.1 -C.sub.4)-alkyl].sub.2 ;R.sup.4 is C.sub.1 -C.sub.6 alkyl; C.sub.1 -C.sub.4 alkoxy; C.sub.1 -C.sub.4 alkyl-S(O).sub.n -; C.sub.1 -C.sub.4 haloalkyl; C.sub.1 -C.sub.4 haloalkoxy; phenyl that is unsubstituted or is substituted by up to three identical or different substituents from halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl and C.sub.1 -C.sub.4 alkoxy; 2-furanyl; 2-thienyl; 3-thienyl; C.sub.3 -C.sub.6 -cycloalkyl that is unsubstituted or is substituted by up to three identical or different C.sub.1 -C.sub.4 alkyl radicals; cyano; C.sub.2 -C.sub.4 haloalkenyl; C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkyl; C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkoxy; or halogen-C.sub.1 -C.sub.4 alkylthio;R.sup.5 is hydrogen; C.sub.1 -C.sub.3 alkyl; C.sub.1 -C.sub.3 haloalkyl; halogen; or C.sub.1 -C.sub.3 haloalkoxy; andn is 0, 1 or 2,with the proviso that when one of the radicals R.sup.1, R.sup.2 and R.sup.3 is nitro, that substituent may not be bonded in the 2- or 6-position of the phenyl ring.
摘要翻译：本发明涉及具有除草和植物生长调节活性的新型N-苯基-N-嘧啶-2-基脲，含有这些物质作为活性成分的农用化学组合物，用于控制杂草或用于调节植物生长，以及制备新化合物的方法。本发明还涉及新型中间体及其制备方法。该化合物对应于式Ⅰ（I）其中R1，R2和R3各自独立地为氢; 卤素; C 1 -C 4烷基; C1-C4烷氧基; C 1 -C 4卤代烷基; C1-C4卤代烷氧基; C 1 -C 4烷基-S（O）n - ; 硝基氰基; C1-C4烷氧基羰基; C1-C4烷基羰基; 二（C 1 -C 4烷基氨基） - 羰基; 单（C 1 -C 4烷基氨基）羰基; 氨基甲酰基; C 1 -C 4卤代烷基-S（O）n - 或-PO [O-（C 1 -C 4） - 烷基] 2; R4是C1-C6烷基; C1-C4烷氧基; C 1 -C 4烷基-S（O）n - ; C 1 -C 4卤代烷基; C1-C4卤代烷氧基; 未被取代或被卤素，C1-C4烷基，C1-C4卤代烷基和C1-C4烷氧基中最多三个相同或不同的取代基取代的苯基; 2-呋喃基; 2-噻吩基; 3-噻吩基; 未被取代或被至多三个相同或不同的C 1 -C 4烷基取代的C 3 -C 6环烷基; 氰基; C 2 -C 4卤代烯基; C 1 -C 4烷氧基-C 1 -C 4烷基; C1-C4烷氧基-C1-C4烷氧基; 或卤素-C 1 -C 4烷硫基; R5是氢; C1-C3烷基; C 1 -C 3卤代烷基; 卤素; 或C 1 -C 3卤代烷氧基; 并且n为0,1或2，条件是当基团R 1，R 2和R 3中的一个为硝基时，该取代基不能键合在苯环的2-或6-位。

37. 发明授权

US4831148A Process for the preparation of fluorinated pyridine derivatives 失效
标题翻译：制备氟化吡啶衍生物的方法
公开(公告)号：US4831148A
公开(公告)日：1989-05-16
申请号：US784017
申请日：1985-10-04
申请人： Rolf Schurter , Urs Siegrist , Hermann Rempfler , Peter Baumeister
发明人： Rolf Schurter , Urs Siegrist , Hermann Rempfler , Peter Baumeister
IPC分类号： A01N43/40 , C07D213/61 , C07D213/64 , C07D213/643 , C07D213/73
CPC分类号： C07D213/643 , C07D213/61 , C07D213/73
摘要： In accordance with a novel process, 2,3-difluoropyridines of formula I ##STR1## wherein X is halogen or trifluoromethyl, are prepared by diazotising a 3-amino-2-halopyridine of formula II ##STR2## wherein X is as defined for formula I and Y is bromine, chlorine or fluorine, in the presence of hydrogen fluroide, to give a 3-fluoro-2-halopyridine of formula III ##STR3## wherein X and Y are as defined for formula II, and treating resultant 3-fluoro-2-halopyridines of formula III, wherein Y is bromine or chlorine, with a fluorinating agent.The 2,3-difluoropyridines prepared by the novel process are valuable intermediates for the preparation of 2-[4-(3-fluoropyridin-2-yloxy)-phenoxy]propionic acid derivatives which are known as herbicides.
摘要翻译：根据新方法，通过重氮化式II的3-氨基-2-卤代吡啶（II）制备其中X为卤素或三氟甲基的式I（I）的2,3-二氟吡啶，其中式 X如式I所定义，Y是溴，氯或氟，在氢氟酸存在下，得到式III的3-氟-2-卤代吡啶（III），其中X和Y如对于并且用氟化剂处理其中Y是溴或氯的式III的3-氟-2-卤代吡啶。通过新方法制备的2,3-二氟吡啶类是制备称为除草剂的2- [4-（3-氟吡啶-2-基氧基） - 苯氧基]丙酸衍生物的有价值的中间体。

38. 发明授权

US4731090A Process for protecting keratinous material from attack by insects feed on keratin with pyridyloxytrifluoromethanesulfonanilides 失效
标题翻译：保护角质材料免受昆虫侵袭角蛋白与吡啶氧基三氟甲磺酰苯胺的过程
公开(公告)号：US4731090A
公开(公告)日：1988-03-15
申请号：US680685
申请日：1984-12-12
申请人： Manfred Boger , Bernardo de Sous , Dieter Reinehr , Werner Schmid , Hermann Rempfler , Hans Tobler
发明人： Manfred Boger , Bernardo de Sous , Dieter Reinehr , Werner Schmid , Hermann Rempfler , Hans Tobler
IPC分类号： C07D213/64 , A01N43/40 , A01N47/02 , C07D213/643 , D06M13/02 , D06M13/322 , D06M13/402 , D06M13/438 , D06M16/00 , D06M101/00 , D06M101/02 , D06M101/10 , D06M3/00
CPC分类号： C07D213/643 , A01N47/02 , D06M16/006
摘要： A process for protecting keratinous material with the aid of substantially novel pyridyloxytrifluoromethanesulfonanilides from pests that feed on keratin, said pyridyloxytrifluoromethanesulfonanilides having the formula ##STR1## wherein R.sub.1 and R.sub.2, each independently of the other, are halogen, haloalkyl, alkyl, nitro, cyano, alkoxy or haloalkoxy or alkoxycarbonyl, andn and m, each independently of the other, are 0 or a value from 1 to 3, with the proviso that if n or m>1, the substituents R.sub.1 and R.sub.2 may be identical or different, and that at least one substituent selected from the group consisting of halogen, haloalkyl and haloalkoxy is present in the molecule.The preparation of these compounds and the use thereof as active ingredients of compositions providing a mothproof and beetle-resistant finish are also described herein.
摘要翻译：具有式“IMAGE”的所述吡啶氧基三氟甲磺酰苯胺，其中R 1和R 2各自独立地为卤素，卤代烷基，烷基，硝基，氰基，氰基，烷氧基或卤代烷氧基或烷氧基羰基，n和m各自独立地为0或1至3的值，条件是如果n或m> 1，则取代基R 1和R 2可以相同或不同，并且在分子中存在至少一个选自卤素，卤代烷基和卤代烷氧基的取代基。本文还描述了这些化合物的制备及其作为提供防蛀和甲虫耐磨性的组合物的活性成分的用途。

39. 发明授权

US4640703A 2-phenoxypropionic acid cyanamides as herbicides 失效
标题翻译： 2-苯氧基丙酸氰胺作为除草剂
公开(公告)号：US4640703A
公开(公告)日：1987-02-03
申请号：US676962
申请日：1984-11-30
申请人： Beat Bohner , Hermann Rempfler , Rolf Schurter
发明人： Beat Bohner , Hermann Rempfler , Rolf Schurter
IPC分类号： A01N37/02 , A01N47/40 , C07D213/64 , C07D213/643 , C07D213/73 , C07D215/22 , C07D215/227 , C07D241/44 , C07D263/58 , C07D277/68 , A01N43/40 , A01N43/60 , A01N43/76
CPC分类号： C07D213/643 , A01N47/40 , C07D213/73 , C07D215/227 , C07D241/44 , C07D263/58 , C07D277/68
摘要： 2-Phenoxypropionic acid cyanamides of the formula ##STR1## have a useful selective herbicidal activity against weeds, preferably grass weeds, in crops of useful plants.In this formulaR is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.4 alkenyl, C.sub.3 -C.sub.4 alkynyl or C.sub.2 -C.sub.4 alkoxyalkyl, andT is a radical ##STR2## wherein A is oxygen or sulfur,X is fluorine, chlorine, bromine, iodine or trifluoromethyl,Y is hydrogen, fluorine, chlorine, bromine or trifluormethyl, andZ is nitrogen or the methine bridge.
摘要翻译：具有式“IMAGE”的2-苯氧基丙酸氰酰胺在有用植物的作物中具有对杂草，优选禾本科杂草的有用的选择性除草活性。在该式中，R是氢，C 1 -C 4烷基，C 3 -C 4烯基，C 3 -C 4炔基或C 2 -C 4烷氧基烷基，T是基团，其中A是氧或硫，X是氟，氯，溴，碘或三氟甲基，Y是氢，氟，氯，溴或三氟甲基，Z是氮或次甲基桥。

40. 发明授权

US4420328A Derivatives of 5-(pyridyl-2-oxy)-2-nitrobenzoic acid, and herbicidal compositions containing them 失效
标题翻译： 5-（吡啶基-2-氧基）-2-硝基苯甲酸的衍生物和含有它们的除草组合物
公开(公告)号：US4420328A
公开(公告)日：1983-12-13
申请号：US342879
申请日：1982-01-26
申请人： Hermann Rempfler
发明人： Hermann Rempfler
IPC分类号： A01N43/40 , C07D213/64 , C07D213/643
CPC分类号： C07D213/643 , A01N43/40
摘要： The invention relates to 5-(pyridyl-2'-oxy)-2-nitrobenzoic acid derivatives of the formula ##STR1## wherein A is the cyano group, the carboxyl group or a salt, an ester, a thioester or an amide thereof, X is halogen or a halomethyl group, Y is hydrogen, halogen or a halomethyl group. These compounds have herbicidal properties and are suitable for selectively controlling weeds in crops of useful plants, especially in soybeans, cereals and rice crops.
摘要翻译：本发明涉及下式的5-（吡啶基-2'-氧）-2-硝基苯甲酸衍生物，其中A是氰基，羧基或其盐，酯，硫酯或酰胺， X是卤素或卤代甲基，Y是氢，卤素或卤代甲基。这些化合物具有除草性质，适用于有选择地控制有用植物作物中的杂草，特别是在大豆，谷类和水稻作物中。

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