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    • 24. 发明授权
    • Treating solution for metal surface treatment and a method for surface treatment
    • 金属表面处理处理方法及表面处理方法
    • US07531051B2
    • 2009-05-12
    • US10480841
    • 2002-06-12
    • Takaomi NakayamaHiroyuki SatoTetsuo OotsukiTadashi MatsushitaEisaku OkadaFumiya YoshidaKatsuhiro Shiota
    • Takaomi NakayamaHiroyuki SatoTetsuo OotsukiTadashi MatsushitaEisaku OkadaFumiya YoshidaKatsuhiro Shiota
    • C23C22/06C23C22/50C23C22/53
    • C25D3/02C23C22/34C23C22/44C25D3/54C25D5/34
    • The present invention is the method for surface treatment of a metal material containing iron and/or zinc, containing component (A) and component (B); where (A) is a compound containing at least one metal element selected from the group consisting of Ti, Zr, Hf and Si, (B) is a compound containing fluorine as a supplying source of HF, wherein the ratio K=A/B between the total mole weight A of metal elements of Ti, Zr, Hf and Si in the compound of component (A) and the mole weight B which when the total fluorine atoms in the fluorine-containing compound of component (B) is converted to HF is within the range of 0.06≦K≦0.18, and the concentration of component (A) indicated by the total mole concentration of metal elements of Ti, Zr, Hf and Si is within the region of 0.05 to 100 m mol/L. To the treating solution for surface treatment, at least one compound containing at least one metal element selected from the group consisting of Ag, Al, Cu, Fe, Mn, Mg, Ni, Co and Zn can be blended. It is possible to form a surface-treated film which is superior in corrosion resistance after being coated on the surface of a metal containing iron or zinc from a solution which does not contain a harmful component to the environment.
    • 本发明是含有组分(A)和组分(B)的含铁和/或锌的金属材料的表面处理方法。 其中(A)是含有选自Ti,Zr,Hf和Si中的至少一种金属元素的化合物,(B)是含氟作为HF的供给源的化合物,其中K = A / B 在组分(A)的化合物中Ti,Zr,Hf和Si的金属元素的总摩尔量A与摩尔重量B之间,当组分(B)的含氟化合物中的总氟原子转化为 HF在0.06 <= K <= 0.18的范围内,Ti,Zr,Hf和Si的金属元素的总摩尔浓度所表示的成分(A)的浓度为0.05〜100μmol/ L. 对于用于表面处理的处理溶液,可以混合至少一种含有选自Ag,Al,Cu,Fe,Mn,Mg,Ni,Co和Zn中的至少一种金属元素的化合物。 可以在不含有有害成分的溶液与环境中涂布含铁或锌的金属的表面后,形成耐腐蚀性优异的表面处理膜。
    • 27. 发明授权
    • Process and apparatus for composite electroplating a metallic material
    • 复合电镀金属材料的方法和装置
    • US5496463A
    • 1996-03-05
    • US350449
    • 1994-12-07
    • Seiki MoriYasutoshi OhtohMasaaki Beppu
    • Seiki MoriYasutoshi OhtohMasaaki Beppu
    • F02F1/00C25D5/08C25D7/04C25D15/00C25D15/02C25D17/00C25D17/12
    • C25D15/02
    • In an electroplating container in which at least one portion of an inside surface of the container is formed from a metal material serving as cathode or anode and an anode or cathode is placed in the container, a composite electroplating liquid containing metal ions and fine solid particles is introduced into a bottom portion of the container in such a manner that the introduced composite electroplating liquid spouts downward against an inside bottom surface of the container and is allowed to flow upward through a flow path formed between the anode and the cathode, and an electric current is applied between the anode and cathode so as to form a composite electroplating layer including the fine solid particles evenly distributed in a metal matrix on a surface of the cathode or anode facing the flow path.
    • 在其中容器的内表面的至少一部分由用作阴极或阳极的金属材料和阳极或阴极形成的电镀容器中放置在容器中,包含金属离子和细固体颗粒的复合电镀液 引入到容器的底部,使得引入的复合电镀液体向下突出抵靠容器的内底面,并且允许其通过形成在阳极和阴极之间的流路向上流动,并且电 在阳极和阴极之间施加电流,以便形成复合电镀层,该复合电镀层包括均匀分布在面向流路的阴极或阳极表面上的金属基质中的细固体颗粒。
    • 30. 发明授权
    • Process for surface treatment titanium-containing metallic material
    • 表面处理含钛金属材料的工艺
    • US5116430A
    • 1992-05-26
    • US653087
    • 1991-02-08
    • Eiji HiraiKazuyoshi KurosawaYoshio Matsumura
    • Eiji HiraiKazuyoshi KurosawaYoshio Matsumura
    • C25D15/02
    • C25D15/02Y10T428/12812
    • A titanium-containing metallic material having a high heat-resistant and abrasion resistant surface is produced by (A) cleaning a titanium-containing metallic material, (B) first plating the cleaned surface of the metallic material with Cu or Ni by a strike or flash plating method, (C) second plating the first plated surface of the Ti-containing material with Ni, Ni-P alloy or a composite material comprising a Ni-P alloy matrix and fine ceramic particles dispersed in the matrix by an electroplating method, (D) non-oxidatively heat treating the second plated Ti-containing material at 450.degree. C. or more for one hour or more, (E) surface activating the second plated surface of the Ti-containing material, (F) coating the activated surface of the Ti-containing material with a heat and abrasion resistant coating layer comprising a matrix consisting of a Ni-P alloy or cobalt and fine ceramic particles dispersed in the matrix, and optionally, (G) surface-roughening the heat and abrasion-resistant coating layer surface of the Ti-containing material to a R.sub.Z of 1.0 to 10.0 .mu.m, and (H) coating the roughened surface of the Ti-containing material with a solid lubricant coating layer comprising at least one member selected from MoS.sub.2, graphite, boron nitride and F-containing polymer resin.