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    • 21. 发明授权
    • Condensation compound between fluorinated cyclopentane ring and aromatic ring, and process for producing the same
    • 氟化环戊烷环和芳环之间的缩合化合物及其制备方法
    • US08129400B2
    • 2012-03-06
    • US13106620
    • 2011-05-12
    • Yutaka IeYoshio Aso
    • Yutaka IeYoshio Aso
    • A61K31/435C07D221/02
    • C07D495/20C07D333/78H01L51/0036
    • A condensation compound of a fluorinated cyclopentane ring and an aromatic ring, which is useful, for example, for electronic materials, and a process for producing the same are provided. For instance, according to Scheme 1 below, a compound (68) containing a condensed structure formed of a hexafluorocyclopentane ring and an aromatic ring is synthesized. The aromatic ring is not limited to a thiophene ring but can be any ring and any substituent can be used. Thus a compound containing a condensed ring structure formed of a hexafluorocyclopentane ring and an aromatic ring, particularly, for instance, a thiophene ring, which was impossible to produce conventionally, can be produced easily with high yield. The compound of the present invention is particularly suitable to be applied to, for example, electronic materials or semiconductors. When it is polymerized and thereby the π-electronic conjugation is extended, it also is expected to be applied to, for example, n-type organic semiconductors and molecular wires that are indispensable for developing molecular electronics elements.
    • 提供氟化环戊烷环和芳环的缩合化合物,其可用于例如电子材料,以及其制备方法。 例如,根据下述方案1,合成含有由六氟环戊烷环和芳香环形成的稠合结构的化合物(68)。 芳环不限于噻吩环,而是可以是任何环,并且可以使用任何取代基。 因此,可以容易地以高产率制备含有由六氟环戊烷环和芳环形成的稠环结构的化合物,特别是例如噻吩环,这是不可能制备的。 本发明的化合物特别适用于例如电子材料或半导体。 当其被聚合并由此延长了电子共轭时,也可以应用于例如用于开发分子电子元件不可或缺的n型有机半导体和分子线。
    • 22. 发明授权
    • Condensation compound between fluorinated cyclopentane ring and aromatic ring, and process for producing the same
    • 氟化环戊烷环和芳环之间的缩合化合物及其制备方法
    • US08008336B2
    • 2011-08-30
    • US11885913
    • 2006-03-02
    • Yutaka IeYoshio Aso
    • Yutaka IeYoshio Aso
    • A61K31/409C07D495/22
    • C07D495/20C07D333/78H01L51/0036
    • A condensation compound of a fluorinated cyclopentane ring and an aromatic ring, which is useful, for example, for electronic materials, and a process for producing the same are provided. For instance, according to Scheme 1 below, a compound (68) containing a condensed structure formed of a hexafluorocyclopentane ring and an aromatic ring is synthesized. The aromatic ring is not limited to a thiophene ring but can be any ring and any substituent can be used. Thus a compound containing a condensed ring structure formed of a hexafluorocyclopentane ring and an aromatic ring, particularly, for instance, a thiophene ring, which was impossible to produce conventionally, can be produced easily with high yield. The compound of the present invention is particularly suitable to be applied to, for example, electronic materials or semiconductors. When it is polymerized and thereby the π-electronic conjugation is extended, it also is expected to be applied to, for example, n-type organic semiconductors and molecular wires that are indispensable for developing molecular electronics elements.
    • 提供氟化环戊烷环和芳环的缩合化合物,其可用于例如电子材料,以及其制备方法。 例如,根据下述方案1,合成含有由六氟环戊烷环和芳香环形成的稠合结构的化合物(68)。 芳环不限于噻吩环,而是可以是任何环,并且可以使用任何取代基。 因此,可以容易地以高产率制备含有由六氟环戊烷环和芳环形成的稠环结构的化合物,特别是例如噻吩环,这是不可能制备的。 本发明的化合物特别适用于例如电子材料或半导体。 当其被聚合并由此延长了电子共轭时,也可以应用于例如用于开发分子电子元件不可或缺的n型有机半导体和分子线。
    • 23. 发明申请
    • Condensation Compound Between Fluorinated Cyclopentane Ring and Aromatic Ring, and Process for Producing the Same
    • 氟化环戊烷环与芳香环之间的缩合化合物及其制备方法
    • US20080207922A1
    • 2008-08-28
    • US11885913
    • 2006-03-02
    • Yutaka IeYoshio Aso
    • Yutaka IeYoshio Aso
    • C07D333/64
    • C07D495/20C07D333/78H01L51/0036
    • A condensation compound of a fluorinated cyclopentane ring and an aromatic ring, which is useful, for example, for electronic materials, and a process for producing the same are provided. For instance, according to Scheme 1 below, a compound (68) containing a condensed structure formed of a hexafluorocyclopentane ring and an aromatic ring is synthesized. The aromatic ring is not limited to a thiophene ring but can be any ring and any substituent can be used. Thus a compound containing a condensed ring structure formed of a hexafluorocyclopentane ring and an aromatic ring, particularly, for instance, a thiophene ring, which was impossible to produce conventionally, can be produced easily with high yield. The compound of the present invention is particularly suitable to be applied to, for example, electronic materials or semiconductors. When it is polymerized and thereby the π-electronic conjugation is extended, it also is expected to be applied to, for example, n-type organic semiconductors and molecular wires that are indispensable for developing molecular electronics elements.
    • 提供氟化环戊烷环和芳环的缩合化合物,其可用于例如电子材料,以及其制备方法。 例如,根据下述方案1,合成含有由六氟环戊烷环和芳香环形成的稠合结构的化合物(68)。 芳环不限于噻吩环,而是可以是任何环,并且可以使用任何取代基。 因此,可以容易地以高产率制备含有由六氟环戊烷环和芳环形成的稠环结构的化合物,特别是例如噻吩环,这是不可能制备的。 本发明的化合物特别适用于例如电子材料或半导体。 当其聚合并且由此π-电子共轭延长时,其也被期望应用于例如用于开发分子电子元件不可缺少的n型有机半导体和分子线。
    • 26. 发明授权
    • Method of making agglomerate of whiskers or short fibers
    • 制作晶须或短纤维附聚物的方法
    • US5269993A
    • 1993-12-14
    • US968427
    • 1992-10-29
    • Tadao ShimizuYoshio AsoHidefumi Konnai
    • Tadao ShimizuYoshio AsoHidefumi Konnai
    • C04B18/02C08K7/02B29B9/08
    • C08K7/02C04B18/02
    • Whiskers having a diameter of 0.1-10 .mu.m and a length of 5-200 .mu.m are pelletized and granulated into agglomerates which have a size of 0.1-10 mm and a bulk density of 0.2-1.0 kg/liter.To pelletize, powders of whiskers are moistened with water while mixing to form primary aggregates. Then, the powders and the primary aggregates are subjected to a rolling movement to cause the primary aggregates to grow into secondary aggregates having desired size distribution. Finally, the secondary aggregates are dried to obtain pelletized or granulated agglomerates of whiskers.Handling of whiskers is facilitated because the agglomerates are less bulky and less likely to fly up in the air. When blended into molding materials for fiber reinforcement, however, the agglomerates are readily disintegrated back into separated individual fibers to provide homogeneous dispersion.
    • 将直径为0.1-10μm,长度为5-200μm的晶须造粒并造粒成具有0.1-10mm尺寸和堆积密度为0.2-1.0kg /升的团块。 为了造粒,将晶须的粉末用水润湿,同时混合形成初级聚集体。 然后,对粉末和初级聚集体进行滚动运动,使一次聚集体生长成具有所需尺寸分布的二次聚集体。 最后,将二次聚集体干燥以获得颗粒状或颗粒状的晶须附聚物。 因为聚集体体积较小并且不太可能在空气中飞升,因此易于处理晶须。 然而,当共混成纤维增强的成型材料时,附聚物容易地分解回分离的单独纤维中以提供均匀的分散体。
    • 28. 发明授权
    • Electromagnetic valve
    • 电磁阀
    • US06854706B2
    • 2005-02-15
    • US10223373
    • 2002-08-20
    • Hideharu SatoYoshio AsoShinichi YoshimuraTakumi Matsumoto
    • Hideharu SatoYoshio AsoShinichi YoshimuraTakumi Matsumoto
    • F16K31/06F16K31/00
    • F16K31/0655Y10S251/904
    • To provide an electromagnetic valve where an end cover can easily be fitted into a valve hole, and a valve body can be small-sized. In an electromagnetic valve, an end cover 30 for closing a hole end 21e of a valve hole 21a formed in a valve body 21 is constituted by a lid plate 31, a plurality of arm pieces 31a provided so as to extend from a peripheral edge of the lid plate 31, engagement resilient pieces 32 provided on a side of an inner face of the lid plate 31 from the arm pieces 31a in a standing manner, respectively, and which are formed at their distal end portions with engagement claws 33 expanding in a taper shape, and a fitting cylindrical portion 34 which is provided in a projecting manner on an inner face of the lid plate 31 such that its height from the inner face is lower than those of the engagement resilient pieces 32 and which is disposed on its outer periphery with a seal member 25, the fitting cylindrical portion 34 is tightly fitted into the hole end 21e opened in the valve body 21, and the engagement claws 33 are engaged with stepped portions 21c in engagement grooves 21b provided in a recessed manner in the vicinity of the hole end 21e of the valve body 21.
    • 提供一种电磁阀,其中端盖可以容易地装配到阀孔中,并且阀体可以小型化。 在电磁阀中,用于封闭形成在阀体21中的阀孔21a的孔端21e的端盖30由盖板31,多个臂件31a构成,多个臂件31a从 盖板31,分别设置在盖板31的内表面一侧的卡合弹性片32,并且在它们的远端部分处形成有以一定的方式扩展的接合爪33 锥形形状,以及嵌合圆筒部34,其以突出的方式设置在盖板31的内表面上,使得其从内表面的高度低于接合弹性片32的高度,并且设置在其外部 具有密封构件25的周边,嵌合圆筒部34紧密地配合到在阀体21中开口的孔端21e中,并且卡合爪33与设置在凹部中的卡合槽21b中的台阶部21c卡合 在阀体21的孔端部21e附近。
    • 29. 发明授权
    • Electromagnetic valve
    • 电磁阀
    • US06748976B2
    • 2004-06-15
    • US10197558
    • 2002-07-18
    • Hideharu SatoYoshio AsoShinichi YoshimuraTakumi Matsumoto
    • Hideharu SatoYoshio AsoShinichi YoshimuraTakumi Matsumoto
    • F15B13044
    • F16K24/04Y10T137/86622
    • To provide an electromagnetic valve where constitution and assembling of a current conduction system to a solenoid portion is simplified to improve assembling easiness and an insulation performance of the current conduction system can easily be secured. In an electromagnetic valve provided with a valve portion 1 having a valve body switching flow paths according to approach to/separation from a valve seat in a housing 10 and a solenoid portion 2 driving the valve body, the housing 10 is formed from electrically insulating synthetic resin, a current conduction terminals 40 constituting a current conduction system of the solenoid portion is inserted into a terminal insertion hole 45 opened on a joining face 10a of the housing 10 with the solenoid portion 2 so that the solenoid portion and the valve portion are fixed to each other, and an opening 48 through which contact terminals 53 extend front the outside to the current conduction terminals 40 in the terminal insertion hole 45 to be electrically connected thereto is provided in the housing.
    • 为了提供一种电磁阀,其电流传导系统与螺线管部分的结构和组装被简化以提高组装的容易性,并且可以容易地确保电流传导系统的绝缘性能。 在具有阀体1的电磁阀中,阀体1具有根据壳体10中的阀座的接近/分离的阀体切换流路和驱动阀体的螺线管部2,壳体10由电绝缘合成 构成电磁线圈部分的电流传导系统的导通端子40被插入在电磁铁部分2的壳体10的接合面10a上开口的端子插入孔45中,使得螺线管部分和阀部分固定 并且在壳体内设置开口48,开口部48通过该开口48将接触端子53向外延伸到端子插入孔45内的电流导通端子40。
    • 30. 发明授权
    • Electromagnetic valve
    • 电磁阀
    • US06745790B2
    • 2004-06-08
    • US10224609
    • 2002-08-21
    • Hedeharu SatoYoshio AsoShinichi YoshimuraTakumi Matsumoto
    • Hedeharu SatoYoshio AsoShinichi YoshimuraTakumi Matsumoto
    • F15B13044
    • F16K31/0627F16K31/0655Y10T137/5987Y10T137/86622
    • An electromagnetic valve having a high coupling strength between a valve portion and a solenoid portion is secured at a low cost without large-sizing the solenoid portion. Recessed portions positioned on one end side of a valve body and having inner wall faces formed by inclining faces that incline from the one end side of the valve body to the other end side towards its depth are provided on a valve body side face positioned on one end side of the valve body to be opposed to each other. Cuttings for forming caulking pieces are positioned corresponding to the recessed portions on the side wall on an opening side of a magnetic case. The valve and solenoid portions are coupled such that they are biased in directions they are fitted to each other by abutting the caulking pieces on the inclining faces to caulk them in the recessed portions
    • 在阀部分和螺线管部分之间具有高耦合强度的电磁阀以较低的成本被确保,而不会使螺线管部分大型化。 位于阀体的一端侧的凹部具有从位于阀体的一端侧朝向其深度的另一端侧的倾斜面形成的内壁面,设置在位于一侧的阀体侧面 阀体的端面彼此相对。 用于形成铆接件的切屑对应于磁性壳体的开口侧上的侧壁上的凹部。 阀和螺线管部分被联接,使得它们通过将铆接片抵靠在倾斜面上而彼此嵌合的方向被偏压,以将其铆接在凹部中