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    • 23. 发明授权
    • Hybrid material and process for producing the same
    • 混合材料及其制造方法
    • US5656709A
    • 1997-08-12
    • US449720
    • 1995-05-24
    • Yoshiaki FukushimaMasaaki Tani
    • Yoshiaki FukushimaMasaaki Tani
    • C08G79/00C08G78/00
    • C08G79/00
    • A hybrid material includes a layer containing an octahedral sheet comprising octahedra linked with each other to provide a sheet-like structure and a tetrahedral sheet comprising tetrahedra linked with each other to provide a sheet-like structure; and an organic portion bonded by covalent bond to an element located at the tetrahedral site of the tetrahedra constituting the layer; each of the octahedra having an element at the octahedral site thereof with a valence in the range of from 3.5 to 4.5 on average over the entire octahedral sheet, and each of the tetrahedra having an element at the tetrahedral site thereof with a valence in the range of from 4.5 to 5.5 on average over the entire tetrahedral sheet. A process for fabricating the hybrid material and a process for controlling the content of the organic and inorganic components of the hybrid material are also provided. Any type of organic component is allowed to be incorporated in the hybrid material.
    • 混合材料包括包含彼此连接的八面体的八面体片以提供片状结构的层和包含彼此连接的四面体的四面体片以提供片状结构; 以及通过共价键与位于构成该层的四面体的四面体位置的元素结合的有机部分; 每个八面体在其八面体位置具有在整个八面体片材上平均3.5至4.5的化合价的元素,并且每个四面体的四面体位置处的元素的价数在该范围内 在整个四面体片材上平均为4.5至5.5。 还提供了制造混合材料的方法和控制混合材料的有机和无机组分的含量的方法。 允许将任何类型的有机组分并入混合材料中。
    • 27. 发明授权
    • Solid composite material and production method thereof
    • 固体复合材料及其制备方法
    • US07858684B2
    • 2010-12-28
    • US11866173
    • 2007-10-02
    • Hiroaki WakayamaYoshiaki Fukushima
    • Hiroaki WakayamaYoshiaki Fukushima
    • C08K3/00C08K3/26C09D17/00C08G65/04C08F6/00C08J3/00
    • C08J3/215C08J2333/26C08J2371/02C08K3/26C08L71/02
    • An object of the invention is to provide a solid composite material easily molded into a desirable shape and superior both in hardness and toughness, and a method of producing the same. A solid composite material 1 having an organic matrix of fibrous organic polymers of nonionic polymer and fine particles of a crystalline metal carbonate having an average diameter of 30 nm or less dispersed therein and a production method thereof. The production method includes mixing, gelation, and reactive precipitation steps. In the mixing step, a liquid mixture is prepared by mixing a hydrophilic nonionic polymers with a metal ion source in water. In the gelation step, the nonionic polymer in the liquid mixture is allowed to gel, to give a gel solvent. In the reactive precipitation step, a metal carbonate is precipitated by adding a carbonic acid source to the gel solvent.
    • 本发明的目的是提供一种容易模塑成所希望的形状和优异的硬度和韧性的固体复合材料及其制造方法。 具有非离子聚合物的纤维状有机聚合物的有机基质和分散在其中的平均粒径为30nm以下的结晶性金属碳酸盐的微粒的固体复合材料1及其制造方法。 生产方法包括混合,凝胶化和反应沉淀步骤。 在混合步骤中,通过将亲水性非离子聚合物与金属离子源在水中混合来制备液体混合物。 在凝胶化步骤中,使液体混合物中的非离子聚合物凝胶化,得到凝胶溶剂。 在反应沉淀步骤中,通过向凝胶溶剂中加入碳酸源来沉淀金属碳酸盐。