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21. 发明专利

CA1210197A METHOD FOR PRODUCING A POLYBUTADIENE MATERIAL 未知
公开(公告)号：CA1210197A
公开(公告)日：1986-08-19
申请号：CA438453
申请日：1983-10-05
申请人： UBE INDUSTRIES
发明人： UENO HARUO , ASHITAKA HIDETOMO , NAKAJIMA KOICHI
IPC分类号： C08F4/00 , C08F4/60 , C08F36/00 , C08F136/06 , C08F236/00 , C08F236/10 , C08F4/70 , C08F2/06
摘要： METHOD FOR PRODUCING A POLYBUTADIENE MATERIAL A 1,2-polymerization of 1,3-butadiene is carried out in a polymerization solvent in the presence of a 1,2-polymerization catalyst consisting essentially of a cobalt compound soluble in the polymerization solvent, an organic aluminum halide, an organic magnesium compound, and carbon disulfide and/or phenyl isothiocyanate and in the presence or absence of a cis-1,4- -polymerization product of 1,3-butadiene.

22. 发明专利

CA1185226A PROCESS FOR POLYMERIZATION OF ETHYLENE 未知
公开(公告)号：CA1185226A
公开(公告)日：1985-04-09
申请号：CA410168
申请日：1982-08-26
申请人： UBE INDUSTRIES
发明人： UENO HARUO , YANO TAKEFUMI , INOUE TOKUJI , IKAI SHIGERU , KAI YOSHIYUKI , SHIMIZU MICHIMASA , TAMURA MASANORI
IPC分类号： C08F4/00 , C08F4/60 , C08F10/02 , B01J31/14 , C08F110/02
摘要： Ethylene is polymerized in the presence of a catalyst formed from a solid catalyst component and an organic aluminum compound of the formula: AlR43 wherein R4 is C1-6 alkyl. The solid catalyst component is prepared by reacting a reaction product of an aluminum halide and an organic silicon compound of the formula: R1nSi(OR2)4-n wherein R1 and R2 are independently phenyl or C1-8 alkyl and n is 0, 1, 2, or 3, with a Grignard compound of the formula: R3MgX wherein R3 is C1-8 alkyl and X is halogen; and subjecting the resulting carrier to a contact treatment with a titanium tetrahalide at least two times.

23. 发明专利

DE3119713A1 未知
公开(公告)号：DE3119713A1
公开(公告)日：1982-03-04
申请号：DE3119713
申请日：1981-05-18
申请人： UBE INDUSTRIES
发明人： UENO HARUO , YANO TAKEFUMI , INOUE TOKUJI , IKAI SHIGERU , KAI YOSHIYUKI , SHIMIZU MICHIMASA
IPC分类号： C08F4/00 , C08F4/02 , C08F4/50 , C08F4/58 , C08F4/60 , C08F4/64 , C08F10/00 , C08F4/52
摘要： Poly alpha -olefin, for example, polypropylene, is produced with an excellent yield by bringing, in the presence of an organic acid ester, a feed, containing at least one alpha -olefin having 3 or more carbon atoms, for example, propylene, into contact with a catalyst which comprises (A) a solid catalytic ingredient prepared (a) by reacting a Grignard compound of the formula, R3MgX wherein R3=C1-8 alkyl and X=halogen, with a reaction product of an aluminium halide with an organic silicon compound of the formula, Rn1Si(OR2)4-n, wherein R1=C1-8 alkyl or phenyl, R2=C1-8 alkyl, n=1, 2 or 3, (b) bringing the resultant reaction product into a first contact with titanium tetrahalide, (c) treating the resultant titanium-containing solid product with an organic acid ester, and, finally, (d) bringing the treated solid product into a second contact with titanium tetrahalide, and; (B) another catalytic ingredient consisting of a trialkyl aluminium of the formula, AlR34 wherein R4=C2-6 alkyl.

24. 发明专利

DE3044635A1 未知
公开(公告)号：DE3044635A1
公开(公告)日：1981-10-08
申请号：DE3044635
申请日：1980-11-27
申请人： UBE INDUSTRIES
发明人： UENO HARUO , YANO TAKEFUMI , INOUE TOKUJI , IKAI SHIGERU , TAMURA MASANORI , YUASA SAKAE
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00
摘要： An alpha -olefin polymer having an excellent H.I. is produced with a high yield by bringing, in the presence of an organic acid ester, a feed containing at least one alpha -olefin, having 3 or more carbon atoms, into contact with a catalyst composed of: a solid catalytic ingredient which has been prepared in such a manner that an aluminosiloxy compound of the formula, [1] wherein X1 represents a chlorine atom, a bromine atom or an iodine atom, is reacted with a Grignard compound of the formula R1MgX2[II] wherein R1 represents an alkyl radical having 1 to 8 carbon atoms and X2 represents a halogen atom, the resultant solid reaction product is brought into contact with a titanium tetrahalide, the resultant titanium-containing solid product is treated with an organic acid ester, and the treated solid product is brought into contact with a titanium tetrahalide; and a trialkyl aluminum.

25. 发明专利

IT8026312D0 未知
公开(公告)号：IT8026312D0
公开(公告)日：1980-11-28
申请号：IT2631280
申请日：1980-11-28
申请人： UBE INDUSTRIES
发明人： UENO HARUO , YANO TAKEFUMI , INOUE TOKYJI , IKAI SHIGERU , TAMURA MASANORI , YUASA SAKAE
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F
摘要： An alpha -olefin polymer having an excellent H.I. is produced with a high yield by bringing, in the presence of an organic acid ester, a feed containing at least one alpha -olefin, having 3 or more carbon atoms, into contact with a catalyst composed of: a solid catalytic ingredient which has been prepared in such a manner that an aluminosiloxy compound of the formula, [1] wherein X1 represents a chlorine atom, a bromine atom or an iodine atom, is reacted with a Grignard compound of the formula R1MgX2[II] wherein R1 represents an alkyl radical having 1 to 8 carbon atoms and X2 represents a halogen atom, the resultant solid reaction product is brought into contact with a titanium tetrahalide, the resultant titanium-containing solid product is treated with an organic acid ester, and the treated solid product is brought into contact with a titanium tetrahalide; and a trialkyl aluminum.

26. 发明专利

CA948348A PROCESS FOR THE PREPARATION OF 1,2-POLYBUTADIENE 未知
公开(公告)号：CA948348A
公开(公告)日：1974-05-28
申请号：CA99685
申请日：1970-12-02
申请人： UBE INDUSTRIES
发明人： SUGIURA SHOTARO , UENO HARUO , KONO MINORU , HAMADA HISAWAKI
IPC分类号： C08F4/70 , C08F136/06
摘要： 1310621 Syndiotactic 1,2-polybutadiene UBE INDUSTRIES Ltd 1 Dec 1970 [2 Dec 1969 (2)] 57056/70 Heading C3P Butadiene is polymerized to 1,2-polybutadiene in the liquid monomer or in an inert liquid diluent by using a catalyst comprising (a) a cobalt compound, (b) an organoaluminium compound, AlR 3 , where R is a C 1 -C 6 hydrocarbon group, (c) carbon disulphide and optionally (d) a nitrile R 1 (CN) n where n is 1 or 2 and R 1 is a mono- or di-valent aliphatic, araliphatic or aromatic hydrocarbon group. When only components (a), (b) and (c) are used a novel polymer is obtained having a linear, highly syndiotactic structure, a melting point of at least 200‹ C. and good solvent resistance. Addition of component (d) in varying amounts enables polymers to be produced with a selected melting point in the range 100-210‹ C. The catalyst components are preferably mixed in the presence of the butadiene. The cobalt compound should preferably be soluble in the reaction medium, e.g. with benzene as the diluent, cobalt octoate, naphthenate or acetylacetonate or CoCl 2 complexes, such as the pyridine complex. As component (b), Et 3 Al is exemplified and as component (d), acetonitrile, benzonitrile, adiponitrile, sebaconitrile or benzyl cyanide.

27. 发明专利

DE2059378A1 未知
公开(公告)号：DE2059378A1
公开(公告)日：1971-06-09
申请号：DE2059378
申请日：1970-12-02
申请人： UBE INDUSTRIES
发明人： SUGIURA SHOTARO , UENO HARUO , KONO MINORU , HAMADA HISAWAKI
IPC分类号： C08F4/70 , C08F136/06 , C08D3/08
摘要： 1310621 Syndiotactic 1,2-polybutadiene UBE INDUSTRIES Ltd 1 Dec 1970 [2 Dec 1969 (2)] 57056/70 Heading C3P Butadiene is polymerized to 1,2-polybutadiene in the liquid monomer or in an inert liquid diluent by using a catalyst comprising (a) a cobalt compound, (b) an organoaluminium compound, AlR 3 , where R is a C 1 -C 6 hydrocarbon group, (c) carbon disulphide and optionally (d) a nitrile R 1 (CN) n where n is 1 or 2 and R 1 is a mono- or di-valent aliphatic, araliphatic or aromatic hydrocarbon group. When only components (a), (b) and (c) are used a novel polymer is obtained having a linear, highly syndiotactic structure, a melting point of at least 200‹ C. and good solvent resistance. Addition of component (d) in varying amounts enables polymers to be produced with a selected melting point in the range 100-210‹ C. The catalyst components are preferably mixed in the presence of the butadiene. The cobalt compound should preferably be soluble in the reaction medium, e.g. with benzene as the diluent, cobalt octoate, naphthenate or acetylacetonate or CoCl 2 complexes, such as the pyridine complex. As component (b), Et 3 Al is exemplified and as component (d), acetonitrile, benzonitrile, adiponitrile, sebaconitrile or benzyl cyanide.

28. 发明专利

GB1206230A PROCESS FOR THE PRODUCTION OF HIGHLY CRYSTALLINE OLEFIN POLYMERS 未知
公开(公告)号：GB1206230A
公开(公告)日：1970-09-23
申请号：GB5902168
申请日：1968-12-11
申请人： UBE INDUSTRIES
发明人： SUGIURA SHOTARO , UENO HARUO , ISHIKAWA HIDEO , YANO TAKEFUMI , SHIMAMURA TUNEO
IPC分类号： C08F10/00
摘要： 1,206,230. Three - component olefin polymerization catalyst. UBE INDUSTRIES Ltd. 11 Dec., 1968, No. 59021/68. Heading C3P Solid crystalline olefin polymers are obtained by homopolymerizing a C 3-6 alpha monoolefin or copolymerizing such an olefin with another such olefin or up to 10% of ethylene in the presence of (a) a titanium trihalide, (b) an organoaluminium compound of formula where R is C 1-8 alkyl, X is halogen and n is 2 or 3, and (c) a hydrocarbyl metal mercaptide of the formula M(SR 1 ) where R 1 is a C 1-20 hydrocarbyl group, M is a metal of groups IA, IB, IIB, IV B , VII A or VIII, and m is the valence of said metal. Conventional Ziegler polymerization conditions are employed. In examples, propylene or butene - 1 are homopolymerized in the presence of (a) TiCl 3 or 3TiCl 3 .AlCl 3 , (b) Al(C 2 H 5 ) 3 or Al(C 2 H 5 ) 2 Cl and (c) various alkyl, aralkyl aryl mercaptides of Cu, Na, Li, Hg, Cd, Sn, Pb, Fe, Co, Ni and Mn, and the catalyst deactivated with methanolic HCl and a methanol - i - propanol mixture. The products are fractionated in heptane or ether.

29. 发明专利

DE3270415D1 PROCESS FOR POLYMERIZING 1,3-BUTADIENE 未知
公开(公告)号：DE3270415D1
公开(公告)日：1986-05-15
申请号：DE3270415
申请日：1982-08-18
申请人： UBE INDUSTRIES
发明人： UENO HARUO , ASHITAKA HIDETOMO , JINDA KAZUYA , NAKAJIMA KOUICHI
IPC分类号： C08F4/00 , C08F4/60 , C08F36/00 , C08F136/06 , C08F4/70
摘要： A process for polymerizing 1,3-butadiene, comprising bring into contact a 1,2-polymerization catalyst consisting essentially of a soluble cobalt compound, an organic aluminum halide, an organic lithium compound, and carbon disulfide or phenyl isothiocyanate with 1,3-butadiene in a polymerization medium. The process can be applied particularly advantageously in the preparation of 1,2-polybutadiene, and the resultant 1,2-polybutadiene has a content of syndiotactic 1,2-structural units of not less than 90%, a melting point of 200 DEG C. to 220 DEG C., and an intrinsic viscosity [ eta ] of 1.2 to 7.

30. 发明专利

FR2500458B1 未知
公开(公告)号：FR2500458B1
公开(公告)日：1986-04-11
申请号：FR8203042
申请日：1982-02-24
申请人： UBE INDUSTRIES
发明人： UENO HARUO , YANO TAKEFUMI , SHIMIZU MICHIMASA , TAMURA MASANORI , YUASA SAKAE
IPC分类号： C08F4/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/02

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