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    • 21. 发明授权
    • Heat-sensitive recording material
    • 热敏记录材料
    • US07098168B2
    • 2006-08-29
    • US10499057
    • 2002-12-20
    • Masayuki IwasakiTsutomu WatanabeHirofumi Mitsuo
    • Masayuki IwasakiTsutomu WatanabeHirofumi Mitsuo
    • B41M5/30
    • B41M5/323B41M5/3275B41M5/3336B41M5/3372B41M5/3375B41M5/3377B41M5/41C08K5/0008C08K5/0016C08K5/11C09J7/35C09J11/06C09J2205/102C09J2429/00Y02P20/582
    • (B) A thermosensitive recording material comprises a thermosensitive recording layer containing an electron-donating colorless dye, an electron-accepting compound which develops color upon a reaction with the electron-donating colorless dye and a sensitizer, wherein the thermosensitive recording material satisfies at least one of the following conditions (1) to (3). (1) An image density when thermal printing is performed with a printing energy is 1.20 or more, and the thermosensitive recording material is used for a recording device having a printing speed of 10 cm/sec or more. (2) An image density after the thermosensitive recording material is brought into contact with a heat source of 70° C. for 5 seconds is 0.15 or less, and the sensitizer is 2-benzyloxynaphthalene or the like. (3) the electron-accepting compound is a compound represented by R1-Ph-SO2R2 wherein R1 represents a hydroxyl group or an alkyl group, R2 represents -Ph, —NH-Ph, -Ph-OR3 or —NH—CO—NH-Ph, R3 represents an alkyl group, Ph represents a phenyl group and may be substituted with a substituent containing SO2R2, and a volume-averaged grain size is in a range of 0.5 to 1.0 μm.
    • (B)热敏记录材料包括含有给电子性无色染料的热敏记录层,与给电子性无色染料反应形成颜色的电子接受性化合物和敏化剂,其中热敏记录材料至少满足 以下条件(1)至(3)之一。 (1)以打印能量进行热敏打印时的图像浓度为1.20以上,热敏记录材料用于印刷速度为10cm /秒以上的记录装置。 (2)热敏记录材料与70℃的热源接触5秒后的图像浓度为0.15以下,敏化剂为2-苄氧基萘等。 (3)电子接受性化合物是由R 1 -O-P 2 -SO 2 R 2 R 2表示的化合物,其中R 1, / SUP>表示羟基或烷基,R 2表示-Ph,-NH-Ph,-Ph-OR 3或-NH-CO-NH- Ph,R 3表示烷基,Ph表示苯基,可以被含有SO 2 R 2 O 2的取代基取代,并且 体积平均粒径在0.5〜1.0μm的范围内。
    • 22. 发明申请
    • Heat-sensitive recording material
    • 热敏记录材料
    • US20060046933A1
    • 2006-03-02
    • US10499514
    • 2002-12-20
    • Masayuki IwasakiTsutomu WatanabeHirofumi Mitsuo
    • Masayuki IwasakiTsutomu WatanabeHirofumi Mitsuo
    • B41M5/30
    • B41M5/3336B41M5/3275B41M5/3375
    • The present invention provides a heat-sensitive recording material having a support, and a heat-sensitive recording layer containing an electron-donating colorless dye and an electron-accepting compound for coloring by reacting with the electron-donating colorless dye on the support. The above-mentioned electron-accepting compound is preferably a compound represented by R1-Ph-SO2R2. The maximum value of the curl height of the material is preferably 5.0 mm or less. The image density formed by thermal printing by energy application at 15.2 mJ/mm2 from the heat-sensitive recording layer side of the support is preferably 1.20 or more. The static friction coefficient and the dynamic friction coefficient of the material are preferably in the range of 0.2 to 0.5 in the case where the outermost surface of the front side having at least one heat-sensitive recording layer and the outermost surface of the rear side are rubbed against each other. The pigment preferably has the boiled linseed oil absorption amount of 30 to 200 ml/100 g and an volume average particle diameter of 0.5 to 3 μm, and the heat-sensitive recording material is preferably used for a recording apparatus capable of thermal printing at speed of 10 cm/sec or more.
    • 本发明提供一种具有载体的热敏记录材料和含有给电子性无色染料和受电子性化合物的热敏记录层,用于通过与载体上的给电子性无色染料反应进行着色。 上述电子接受性化合物优选为由R 1〜P 2 -SO 2 R 2 O 2表示的化合物。 材料的卷曲高度的最大值优选为5.0mm以下。 通过在载体的热敏记录层侧以15.2mJ / mm 2的能量施加的热印打印形成的图像密度优选为1.20以上。 在具有至少一个热敏记录层的前侧的最外表面和后侧的最外表面的情况下,材料的静摩擦系数和动摩擦系数优选在0.2至0.5的范围内 相互摩擦 颜料优选具有30至200ml / 100g的煮沸亚麻子油吸收量和0.5至3μm的体积平均粒径,并且热敏记录材料优选用于能够以速度进行热打印的记录装置 为10厘米/秒以上。
    • 28. 发明授权
    • Photopolymerizable composition, color filter, and production of color
filter
    • US5650263A
    • 1997-07-22
    • US599354
    • 1996-02-09
    • Yuichi WakataMasayuki IwasakiKoji Inoue
    • Yuichi WakataMasayuki IwasakiKoji Inoue
    • C08F257/02G02B1/04G02B5/22G02F1/1335G03F7/037
    • G02B5/223C08F257/02G02B1/04G02F2001/133519Y10S430/107Y10S430/162
    • An alkali-developable photopolymerizable composition is disclosed, comprising (1) a photopolymerization initiator or a photopolymerization initiator system, (2) an addition polymerizable monomer having an ethylenically unsaturated double bond, and (3) a resin obtained by reacting a copolymer comprising at least a repeating unit represented by formula (I): ##STR1## wherein Ar.sup.1 represents a phenyl group or a phenyl group substituted with an alkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an aryl group having from 6 to 10 carbon atoms, an aralkyl group having from 8 to 12 carbon atoms, a halogen atom, or a combination of two or more of these substituents; and x represents a molar content of the repeating unit in the copolymer, ranging from 0.85 to 0.55,and a repeating unit represented by formula (II): ##STR2## wherein y represents a molar content of the repeating unit in the copolymer, ranging from 0.15 to 0.45, and wherein the copolymer has a number average molecular weight of from 500 to 30,000,with a primary amine represented by formula (III):Ar.sup.2 --R--NH.sub.2 (III)wherein R represents a straight-chain or branched alkylene group having from 1 to 6 carbon atoms; and Ar.sup.2 represents an aryl group or an aryl group substituted with an alkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an aryl group having from 6 to 10 carbon atoms, an aralkyl group having from 8 to 12 carbon atoms, a halogen atom, or a combination of two or more of these substituents,at a ratio of from 0.1 to 1.0 molar equivalent of the primary amine to the acid anhydride group of the copolymer. A cured film of the composition is excellent in flatness, hardness, chemical resistance, transparency, adhesion to a substrate, and suitability for forming a transparent conductive film, e.g., an ITO film, thereon, and is useful as a protective layer for a color filter of liquid crystal display panels.
    • 30. 发明授权
    • Image formation method using a photosensitive transfer material
    • 使用光敏转印材料的图像形成方法
    • US5397678A
    • 1995-03-14
    • US216327
    • 1994-03-23
    • Morimasa SatoMasayuki IwasakiFumiaki ShinozakiKoji Inoue
    • Morimasa SatoMasayuki IwasakiFumiaki ShinozakiKoji Inoue
    • G03F3/10G03F7/16G03F7/34H05K3/00G03C11/12
    • G03F7/161G03F3/10G03F7/346H05K3/0079
    • A photosensitive transfer material comprises a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the interlaminar adhesion in the transfer material being the smallest at the interface between the thermoplastic resin layer and the temporary substrate. The photosensitive resin layer can be transferred to a permanent substrate without involving failure due to fine dust, air bubbles or unevenness of the permanent substrate. An image can be formed with the transfer material by adhering the transfer material to a permanent substrate at least under heat and, after stripping the temporary substrate, imagewise exposing the photosensitive resin layer to light, and processing the transferred layers to develop the photosensitive resin layer. If the thermoplastic resin layer and the intermediate layer are first removed with a processing method with which the photosensitive resin layer is not substantially developed and then the photosensitive resin layer is developed using a processing solution other than used for revmoving the thermoplastic resin layer and the intermediate layer, excessive fatigue of the developing solution for the photosensitive resin layer and unevenness of development can be prevented.
    • 光敏转印材料包括依次设置有碱溶性热塑性树脂树脂层,中间层和感光性树脂层的临时基材,在热塑性树脂层之间的界面处,转印材料中的层间粘合力最小 和临时衬底。 可以将感光性树脂层转印到永久性基板上,而不会由于细小的灰尘,气泡或永久基板的不均匀性而导致故障。 可以通过至少在加热下将转印材料粘附到永久性基板上,并且在剥离临时基板之后,使感光性树脂层成像曝光,并且处理转印层以显影感光性树脂层 。 如果首先用感光性树脂层未显影的处理方法去除热塑性树脂层和中间层,然后使用除了用于将热塑性树脂层和中间体的旋转以外的处理溶液使感光性树脂层显影 可以防止感光性树脂层的显影液的过度疲劳和显影不均匀。