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    • 22. 发明专利
    • NITROGEN FIXING METHOD IN CLOSED SYSTEM AND DEVICE FOR THE SAME
    • JPH1129320A
    • 1999-02-02
    • JP18396897
    • 1997-07-09
    • TOYO ENGINEERING CORPNITTA KEIJI
    • SAKAMOTO TAKAYUKISAKAEDA HIROSHINITTA KEIJI
    • C01C1/18
    • PROBLEM TO BE SOLVED: To provide a method safely fixing nitrogen as ammonium nitrate under a low pressure in a closed system. SOLUTION: Hydrogen obtained by electrolysis of water and nitrogen 1 are processed in a low pressure ammonium synthesis at less than 10 barr, the reaction mixture containing unreacted gas is separated into a gas mixture rich in ammonium and the other gas rich in nitrogen and hydrogen by PSA 6. The gas rich in nitrogen and hydrogen is circulated to ammonium synthesis 5, and a part of the gas rich in ammonium is collected as ammonia water, the catalytic oxidation of the rest and the oxygen generated by electrolysis of water to NO and NO2 us carried out at the ammonium oxidizing tower 8, the reaction mixture is quenched in a quenching tower 9 having a choke up inhibiting system for start.up and shut.down of the ammonium oxidizing tower. The NO2 is absorbed by water in the absorbing tower 10 affording nitric acid, a part of the gas containing No discharged from the NO2 absorbing tower 10 is circulated to ammonium oxidizing tower 8, and the rest is discharged to outside of the system, the ammonium nitrate is produced from ammonia water and nitric acid.
    • 27. 发明专利
    • IMPROVED PRESSURE SWING ADSORPTION METHOD
    • JPH09267016A
    • 1997-10-14
    • JP1139197
    • 1997-01-24
    • TOYO ENGINEERING CORPSAKATA YUSAKU
    • SAKATA YUSAKUSAKAMOTO TAKAYUKI
    • B01D53/04C01B7/01C01B32/40C01C1/12C01B31/18
    • PROBLEM TO BE SOLVED: To improve the purity and the yield of a product in at least one stage by using an adsorptive component described under negative presser from an adsorbed in the regeneration process during the same step under the same pressure as that of mixed gas to be treated as a reflux to the other adsorber. SOLUTION: In a pressure swing adsorption method by which an adsorptive component is separated from mixed gas containing the adsorptive component having atmospheric pressure or more in at least one stage, the adsorptive component described under negative pressure from an adsorber in the regeneration process during the same step under the same pressure as that of mixed gas to be treated is used as a reflux to the other adsorber. For example, ammonia is taken as an adsorptive component. In a adsorptive product reflux process, gas of high ammonia concentration obtained in the previous process is made to have almost the same pressure as that of a line 1 and is introduced into an adsorber A and an adsorber B just before adsorption equilibrium is attained. In a between-columns pressure equalizing process, gas of high ammonia concentration is introduced into one adsorber to make one adsorber to have the same pressure as operating pressure of the other adsorber, that is, almost the same pressure as pressure of the line 1.