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    • 29. 发明授权
    • Method for semiconductor device manufacturing to include multistage chemical vapor deposition of material oxide film
    • 半导体器件制造方法包括材料氧化膜的多级化学气相沉积
    • US06939760B2
    • 2005-09-06
    • US10609476
    • 2003-07-01
    • Hirofumi FujiokaKenichi KoyanagiHiroyuki Kitamura
    • Hirofumi FujiokaKenichi KoyanagiHiroyuki Kitamura
    • C23C16/44C23C16/40C23C16/455G11C7/00H01L21/02H01L21/205H01L21/316H01L21/8242H01L27/108
    • H01L21/0228C23C16/405C23C16/45553H01L21/02181H01L21/02183H01L21/02189H01L21/31637H01L27/10852H01L28/40
    • There is provided a method for manufacturing a semiconductor device including a capacitor having a lower electrode, an upper electrode and a capacitive insulating film between the lower electrode and the upper electrode on a semiconductor substrate, wherein the capacitive insulating film is formed on the lower electrode over the semiconductor substrate using a chemical vapor deposition method, the method including: a lower electrode forming step of forming the lower electrode on the semiconductor, a dual-stage deposition step including a first stage for introducing a material gas containing a specified metal into a reactor in which the semiconductor substrate is placed and a second stage for subsequently introducing an oxidizing gas into the reactor, and wherein a metal oxide film as an oxide of the specified metal is formed on the lower electrode over the semiconductor substrate, by repeating the dual-stage deposition step two or more times, thereby forming the capacitive insulating film; and an upper electrode forming step of forming the upper electrode on the capacitive insulating film. Thus, it is possible to obtain the capacitive insulating film having good step coverage and a good film quality, without reducing throughput.
    • 提供一种制造半导体器件的方法,该半导体器件包括在半导体衬底上的下电极和上电极之间具有下电极,上电极和电容绝缘膜的电容器,其中电容绝缘膜形成在下电极 在半导体基板上使用化学气相沉积法,该方法包括:在半导体上形成下电极的下电极形成步骤,包括用于将含有特定金属的材料气体引入到第一级的第一级的双级沉积步骤 其中放置半导体衬底的反应器和用于随后将氧化气体引入反应器的第二阶段,并且其中在半导体衬底上的下电极上形成作为特定金属的氧化物的金属氧化物膜, 阶段沉积步骤两次或更多次,从而形成电容绝缘f ; 以及在电容绝缘膜上形成上电极的上电极形成步骤。 因此,可以获得具有良好的台阶覆盖率和良好的膜质量的电容绝缘膜,而不降低生产量。
    • 30. 发明授权
    • Heat treatment of a tantalum oxide film
    • 氧化钽膜的热处理
    • US06187693B1
    • 2001-02-13
    • US09439346
    • 1999-11-15
    • Kenichi Koyanagi
    • Kenichi Koyanagi
    • H01L2131
    • H01L21/02183C23C16/405C23C16/56H01L21/02271H01L21/02337H01L21/02356H01L21/31604H01L28/40
    • A method of manufacturing a tantalum oxide film having a high dielectric constant suitable for use in a high density DRAM, and a small leakage current. After forming a tantalum oxide film in amorphous state which includes moisture and impurities such as organic substances, and before crystallizing the film, the tantalum oxide film in amorphous state is subjected to a first heat treatment at a temperature which is higher than the formation temperature of the tantalum oxide film in amorphous state and which is lower than the temperature of crystallization of the tantalum oxide film in amorphous state. As a result of the first heat treatment, the moisture and the impurities such as organic substances existing in the film are surely removed from the film. Accordingly, in a subsequent heat treatment for crystallization at a high temperature, there arises no phenomenon in which crystallization of the film proceeds while impurities in the film are being removed. In other words, the crystallized tantalum oxide film obtained is free from stresses and defects.
    • 一种适用于高密度DRAM的具有高介电常数的钽氧化物膜的制造方法和小的漏电流。 在形成包含水分和诸如有机物质的杂质的非晶状态的氧化钽膜之后,并且在使膜结晶之前,将非晶态的氧化钽膜在高于形成温度的温度下进行第一次热处理 该非晶态钽氧化物膜比非晶态的氧化钽膜的结晶温度低。 作为第一次热处理的结果,膜中存在的水分和有机物质等杂质被确实地除去。 因此,在随后的高温结晶热处理中,不会发生膜的结晶化,同时除去膜中的杂质的现象。 换句话说,所得结晶的氧化钽膜没有应力和缺陷。