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    • 21. 发明授权
    • Two-component aqueous polyurethane dispersions
    • 双组分水性聚氨酯分散体
    • US5389718A
    • 1995-02-14
    • US249486
    • 1994-05-26
    • Terry A. PotterPatricia B. JacobsPeter H. MarkuschJames W. Rosthauser
    • Terry A. PotterPatricia B. JacobsPeter H. MarkuschJames W. Rosthauser
    • C08G18/08C08G18/10C08G18/28C08G18/50C08G18/79C08L75/04
    • C08G18/792C08G18/0819C08G18/10C08G18/283C08G18/5042Y10S524/906
    • The present invention relates to a two-component, aqueous polyurethane coating composition which may be cured at ambient temperature and which containsI) a first component based on an aqueously dispersed polyurethane wherein the polyurethane hasa) an average hydroxy functionality of at least 1.8b) a total content of urethane and urea groups, calculated as --NH--C--O--, of 9 to 20% by weight, based on the weight of the polyurethane, andc) sufficient chemically incorporated anionic groups andd) ethylene oxide units incorporated within terminal and/or lateral polyether chainsto maintain the polyurethane stably dispersed in water, andII) a second component based on a water dispersible polyisocyanate wherein the polyisocyanate hasa) an isocyanate content of 2 to 30% by weight, based on the weight of the polyisocyanate,b) an average functionality of at least 1.8 andc) sufficient chemically incorporated anionic groups andd) ethylene oxide units incorporated within terminal and/or lateral polyether chainsto maintain the polyisocyanate stably dispersed in water, and components I and II are present in an amount sufficient to provide an equivalent ratio of isocyanate groups to hydroxyl groups of 0.8:1 to 6:1.The present invention is also directed to the coatings prepared from these coating compositions.
    • 本发明涉及双组分水性聚氨酯涂料组合物,其可以在环境温度下固化,并且其包含I)基于高分散聚氨酯的第一组分,其中所述聚氨酯具有a)至少1.8b的平均羟基官能度 )基于聚氨酯的重量计,氨基甲酸酯和尿素基团的总含量(以-NH-CO-计算)为9至20重量%,以及c)足够的化学引入的阴离子基团和d)掺入到其中的环氧乙烷单元 末端和/或侧面聚醚链以保持聚氨酯稳定地分散在水中,和II)基于水分散性多异氰酸酯的第二组分,其中多异氰酸酯的a)异氰酸酯含量为2-30重量%,基于 多异氰酸酯,b)至少1.8的平均官能度,和c)足够化学引入的阴离子基团,和d)结合在末端和/或之后的环氧乙烷单元 以保持多异氰酸酯稳定地分散在水中,并且组分I和II以足以提供异氰酸酯基与羟基的当量比为0.8:1至6:1的量存在。 本发明还涉及由这些涂料组合物制备的涂料。