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21. 发明授权

US5939466A Poly-unsaturated carbohydrate derivatives, polymers thereof and their use 失效
标题翻译：多不饱和碳水化合物衍生物及其用途及其用途
公开(公告)号：US5939466A
公开(公告)日：1999-08-17
申请号：US817044
申请日：1997-04-04
申请人： Frank Bachmann , Dieter Lohmann , Peter Chabrecek
发明人： Frank Bachmann , Dieter Lohmann , Peter Chabrecek
IPC分类号： G02C7/04 , A61K9/00 , A61K47/36 , C07D493/04 , C07H13/12 , C07H15/04 , C08B37/00 , C08B37/16 , C08F12/00 , C08F18/00 , C08F20/36 , C08F220/36 , G02B1/04 , G02B1/10 , C07H15/02 , C07H265/04
CPC分类号： C07D493/04 , C07H13/12 , C07H15/04 , C08B37/0012 , C08F220/36 , G02B1/043
摘要： The present invention relates to polymerizable derivatives of carbohydrates comprising a carbohydrate radical and more than one radically polymerizable hydrocarbon group which is linked optionally via a spacer to the carbohydrate radical, to homopolymers, copolymers, block copolymers, graft copolymers and polymeric networks thereof, to capsules, fibers, films and coatings having water-binding and biocompatible properties, and to molded articles, for example contact lenses or biomedicinal articles, comprising the mentioned polymers, as well as to processes for the preparation of the mentioned polymers and articles.
摘要翻译： PCT No.PCT / EP95 / 04052 Sec。 371日期1997年04月4日 102（e）日期1997年4月4日PCT提交1995年10月16日PCT公布。第WO96 / 13511号公报日期1996年5月9日本发明涉及碳水化合物的可聚合衍生物，其包含碳水化合物基团和多于一个可自由基聚合的烃基，其任选经由间隔基连接至碳水化合物基团，至均聚物，共聚物，嵌段共聚物，接枝共聚物和聚合物网络具有水结合和生物相容性质的胶囊，纤维，膜和涂层，以及包含所述聚合物的模制品，例如隐形眼镜或生物医学制品，以及制备所述聚合物和制品的方法。

22. 发明授权

US5612391A Functionalized photoinitiators, macromers thereof, and the use thereof for contact lens 失效
标题翻译：官能化光引发剂，其大分子单体及其用于隐形眼镜的用途
公开(公告)号：US5612391A
公开(公告)日：1997-03-18
申请号：US469399
申请日：1995-06-06
申请人： Peter Chabrecek , Dieter Lohmann
发明人： Peter Chabrecek , Dieter Lohmann
IPC分类号： G02C7/04 , C07C49/76 , C07C49/82 , C07C271/20 , C07C271/24 , C07C271/28 , C07C271/32 , C07C271/38 , C07D317/26 , C07F7/10 , C08B31/00 , C08B33/00 , C08B37/00 , C08B37/08 , C08B37/16 , C08F2/48 , C08F2/50 , C08F8/30 , C08F16/36 , C08G18/00 , C08G18/08 , C08G18/71 , C08G77/04 , C08G77/38 , C08J3/28 , C08J7/12 , C08J7/18 , C08L101/02 , G02B1/04 , G03F7/031 , G03F7/075 , C08J5/00 , C08J5/18 , C08J7/04
CPC分类号： G03F7/075 , C07C271/20 , C07C271/24 , C07C271/28 , C07C271/38 , C08B37/0012 , C08B37/0072 , C08F2/50 , C08F8/30 , C08G77/38 , C08J7/12 , C08J7/18 , G02B1/043 , G03F7/031 , C07C2101/14 , Y10S522/904 , Y10S522/905 , Y10T428/31645 , Y10T428/31663 , Y10T428/31667 , Y10T428/31855 , Y10T428/31971
摘要： Contact lenses formed from compounds of formula I: ##STR1## are disclosed. The compounds are photoinitiators which can be functionalized by means of ethylenic groups or can be bonded to H-active substances, in order, for example, to modify surfaces by means of photopolymerizable substances. The compounds are especially useful in the manufacture of contact lenses.
摘要翻译：公开了由式I化合物形成的隐形眼镜：。这些化合物是可以通过烯属基官能化或可以与H-活性物质结合的光引发剂，以便例如通过可光聚合物质来修饰表面。这些化合物在隐形眼镜的制造中特别有用。

23. 发明申请

US20050228065A1 Extended wear ophthalmic lens 失效
公开(公告)号：US20050228065A1
公开(公告)日：2005-10-13
申请号：US11146586
申请日：2005-06-07
申请人： Paul Nicolson , Richard Baron , Peter Chabrecek , John Court , Angelika Domschke , Hans Griesser , Arthur Ho , Jens Hopken , Bronwyn Laycock , Qin Liu , Dieter Lohmann , Gordon Meijs , Eric Papaspiliotopoulos , Judy Smith Riffle , Klaus Schindhelm , Deborah Sweeney , Wilson Terry , Jurgen Vogt , Lynn Winterton
发明人： Paul Nicolson , Richard Baron , Peter Chabrecek , John Court , Angelika Domschke , Hans Griesser , Arthur Ho , Jens Hopken , Bronwyn Laycock , Qin Liu , Dieter Lohmann , Gordon Meijs , Eric Papaspiliotopoulos , Judy Smith Riffle , Klaus Schindhelm , Deborah Sweeney , Wilson Terry , Jurgen Vogt , Lynn Winterton
IPC分类号： A61L27/26 , B29C39/42 , B29C71/00 , C08G18/10 , C08G18/48 , C08G18/50 , C08G18/61 , C08G18/67 , C08G18/81 , C08K3/00 , C08L43/04 , C08L75/04 , G02B1/04
CPC分类号： G02B1/043 , A61L27/26 , B29C39/42 , B29C71/00 , B29L2011/0041 , C08G18/10 , C08G18/4833 , C08G18/5015 , C08G18/61 , C08G18/672 , C08G18/8116 , C08G18/8175 , C08L43/04 , C08L75/04 , C08L51/085 , C08L2666/20 , C08L51/08 , C08L83/04 , C08L33/00 , C08G18/63 , C08G18/48
摘要： An ophthalmic lens suited for extended-wear periods of at least one day on the eye without a clinically significant amount of corneal swelling and without substantial wearer discomfort. The lens has a balance of oxygen permeability and ion or water permeability, with the ion or water permeability being sufficient to provide good on-eye movement, such that a good tear exchange occurs between the lens and the eye. A preferred lens is a copolymerization product of a oxyperm macromer and an ionoperm monomer. The invention encompasses extended wear contact lenses, which include a core having oxygen transmission and ion transmission pathways extending from the inner surface to the outer surface.

24. 发明授权

US6099122A Process for the functionalization of surfaces 失效
标题翻译：表面功能化的工艺
公开(公告)号：US6099122A
公开(公告)日：2000-08-08
申请号：US860130
申请日：1997-08-18
申请人： Peter Chabrecek , Dieter Lohmann
发明人： Peter Chabrecek , Dieter Lohmann
IPC分类号： G02C7/04 , B05D3/06 , C07C271/20 , C07C271/24 , C07C271/28 , C08F2/50 , C08F283/12 , C08F290/02 , C08F290/04 , C08G18/50 , C08G18/61 , C08G18/64 , C08G18/70 , C08G18/80 , C08G18/81 , C08G77/442 , C09D175/04 , G02B1/04 , G02B1/10 , G03F7/027 , G03F7/031 , G03F7/075
CPC分类号： G03F7/0757 , C07C271/20 , C07C271/24 , C07C271/28 , C08F2/50 , C08F283/124 , C08F290/02 , C08F290/042 , C08G18/5015 , C08G18/5024 , C08G18/61 , C08G18/6446 , C08G18/70 , C08G18/80 , C08G18/807 , C08G18/8166 , C08G18/8175 , C08G77/442 , G02B1/043 , G03F7/027 , G03F7/031 , C07C2101/14
摘要： The present invention describes a novel coating process that comprises the use of a functional photoinitiator, or a macroinitiator derived therefrom, in a cascade of process steps, wherein, on the one hand, a functional photoinitiator or a macroinitiator derived therefrom is covalently bonded to a carrier and, on the other hand, an oligomer or polymer forming a new surface layer is covalently bonded to the functional photoinitiator, or to the carrier modified by a functional photoinitiator, via functional groups that are co-reactive with isocyanate groups. The invention relates also to novel intermediates that are carriers to which functional photoinitiators that contain free isocyanate groups are bonded.
摘要翻译： PCT No.PCT / EP95 / 05013 Sec。 371日期：1997年8月18日 102（e）日期1997年8月18日PCT 1995年12月18日PCT PCT。 WO96 / 20796 PCT公开号日期1996年7月11日本发明描述了一种新颖的涂覆方法，其包括在级联的工艺步骤中使用功能性光引发剂或衍生自其的大分子引发剂，其中一方面由功能性光引发剂或衍生自其的大分子引发剂共价结合到载体上，另一方面，形成新表面层的低聚物或聚合物通过与异氰酸酯共反应的官能团共价键合到功能性光引发剂或由功能性光引发剂改性的载体上团体本发明还涉及作为包含游离异氰酸酯基团的功能性光引发剂键合的载体的新型中间体。

25. 发明授权

US5856416A Unsaturated carbohydrate derivatives polymers thereof and their use 失效
标题翻译：不饱和碳水化合物衍生物的聚合物及其用途
公开(公告)号：US5856416A
公开(公告)日：1999-01-05
申请号：US867747
申请日：1997-06-03
申请人： Frank Bachmann , Dieter Lohmann , Peter Chabrecek
发明人： Frank Bachmann , Dieter Lohmann , Peter Chabrecek
IPC分类号： G02C7/04 , A61L27/34 , C07H13/12 , C07H15/04 , C08B37/16 , C08F20/36 , C08F290/00 , C08F290/06 , G02B1/04 , C08F220/04
CPC分类号： C07H13/12 , A61L27/34 , C07H15/04 , C08B37/0012 , C08F20/36 , G02B1/043
摘要： The present invention relates to polymerizable derivatives of carbohydrates comprising a compound of formula (I)R.sup.1 --(COO--Alk).sub.m --(OCONH--R).sub.n --(NHCO).sub.p --Y--Z (I)whereinR.sup.1 is a radically polymerizable hydrocarbon group;m, n and p are 0 or 1;Alk is alkylene having up to 10 carbon atoms;R is a diradical, having up to 20 carbon atoms, of an organic diisocyanate;Z is a monovalent radical, minus a single hydroxy group, of a mono-, di- or tri-saccharide, of an oligosaccharide, of a cyclodextrin (CD) or of an anhydrosaccharide; andY is --O-- or --NH--;with the proviso that when p is zero, m and n are also zero and Y is --NH--; to homopolymers, copolymers, block copolymers, graft copolymers and polymeric networks thereof, to molded articles, for example contact lenses or biomedicinal articles, comprising the mentioned polymers, as well as to processes for the preparation of the mentioned polymers and articles.
摘要翻译：本发明涉及碳水化合物的可聚合衍生物，其包含式（I）化合物R1-（COO-Alk）m-（OCONH-R）n-（NHCO）p-Y-Z（I）的化合物，其中R1是可自由基聚合的烃基; m，n和p为0或1; Alk是具有至多10个碳原子的亚烷基; R是具有至多20个碳原子的双键，有机二异氰酸酯; Z是低聚糖，环糊精（CD）或非水解糖的单糖，二糖或三糖的单一基团，减去单个羟基; Y为-O-或-NH-; 条件是当p为0时，m和n也为零，Y为-NH-; 至均聚物，共聚物，嵌段共聚物，接枝共聚物和聚合物网络，包括所述聚合物的模塑制品，例如隐形眼镜或生物医学制品，以及制备所述聚合物和制品的方法。

26. 发明授权

US06169127A Plasma-induced polymer coatings 失效
标题翻译：等离子体诱导的聚合物涂层
公开(公告)号：US06169127A
公开(公告)日：2001-01-02
申请号：US09077505
申请日：1998-06-02
申请人： Dieter Lohmann , Peter Chabrecek , Jens Höpken
发明人： Dieter Lohmann , Peter Chabrecek , Jens Höpken
IPC分类号： G02C704
CPC分类号： B05D1/62 , A61L27/34 , C08L33/00 , C08L39/06
摘要： The present invention relates to coated particles wherein the polymer chains of the coating are obtainable by after-glow plasma induced polymerization of a monomer under special plasma conditions. The invention further relates to a method for the production of articles coated with a polymer having these features.
摘要翻译：本发明涉及涂覆的颗粒，其中涂层的聚合物链可通过在特殊等离子体条件下单体的后辉度等离子体诱导聚合而获得。本发明还涉及一种制备涂覆有具有这些特征的聚合物的制品的方法。

27. 发明授权

US6087412A Polymers based on block copolymers 失效
标题翻译：基于嵌段共聚物的聚合物
公开(公告)号：US6087412A
公开(公告)日：2000-07-11
申请号：US860132
申请日：1997-09-12
申请人： Peter Chabrecek , Dieter Lohmann , Kurt Dietliker
发明人： Peter Chabrecek , Dieter Lohmann , Kurt Dietliker
IPC分类号： G02C7/04 , A61L27/00 , B05D3/06 , B05D7/24 , B29D11/00 , C07C225/16 , C07C271/20 , C07C271/24 , C07C271/28 , C07D295/10 , C08F2/50 , C08F283/00 , C08F283/12 , C08F290/02 , C08F290/04 , C08F293/00 , C08F299/00 , C08G18/28 , C08G18/32 , C08G18/50 , C08G18/61 , C08G18/62 , C08G18/64 , C08G18/67 , C08G18/70 , C08G18/72 , C08G18/80 , C08G18/81 , C08G77/442 , C08G81/00 , C08G81/02 , G02B1/04 , G02B1/10 , G03F7/027 , G03F7/031 , G03F7/033 , G03F7/075 , G02C7/02 , C08F287/00
CPC分类号： C08G18/3215 , C07C271/20 , C07C271/24 , C07C271/28 , C08F2/50 , C08F283/124 , C08F290/02 , C08F290/042 , C08G18/2875 , C08G18/5015 , C08G18/5024 , C08G18/61 , C08G18/6446 , C08G18/678 , C08G18/70 , C08G18/728 , C08G18/80 , C08G18/807 , C08G18/8166 , C08G18/8175 , C08G77/442 , G02B1/043 , G03F7/027 , G03F7/031 , G03F7/033 , G03F7/0757 , C07C2101/14 , Y10S522/904
摘要： The invention relates to crosslinked polymers, which are polymerisation products of a polymerisable mixture that comprises the following components:a) a macromer of formula C ##STR1## wherein Macro is an m-valent radical of a macromer from which the number m of groups Rx.sub.x --H has been removed,each R.sub.x, independently of the others, is a bond, --O--, --NR.sub.N -- or --S-- wherein R.sub.N is hydrogen or lower alkyl,PI* is a bivalent radical of a photoinitiator,R.sub.aa is the moiety of a photoinitiator that forms the less reactive free radical on cleavage of the photoinitiator, andm is an integer from 1 to 100,b) a copolymerisable vinyl monomer andc) a copolymerisable crosslinker.The polymers are suitable especially for the production of mouldings, such as for contact lenses.
摘要翻译： PCT No.PCT / CH95 / 00309 Sec。 371日期：1997年9月12日 102（e）日期1997年9月12日PCT 1995年12月27日PCT PCT。出版物WO96 / 21167 日期：1996年7月11日本发明涉及交联聚合物，其是可聚合混合物的聚合产物，其包含以下组分：a）式C的大分子单体，其中Macro是大分子单体的m价基团，其中m 基团Rxx-H已经被除去，每个Rx独立于其它，是键，-O-，-NRN-或-S-，其中RN是氢或低级烷基，PI *是光引发剂的二价基团，Raa 是光引发剂的部分，其在光引发剂裂解时形成较少反应性的自由基，m为1至100的整数，b）可共聚的乙烯基单体和c）可共聚的交联剂。聚合物特别适用于制造模制品，如隐形眼镜。

28. 发明授权

US5693768A Unsaturated carbohydrate derivatives polymers thereof and their use 失效
标题翻译：不饱和碳水化合物衍生物的聚合物及其用途
公开(公告)号：US5693768A
公开(公告)日：1997-12-02
申请号：US388006
申请日：1995-02-13
申请人： Frank Bachmann , Dieter Lohmann , Peter Chabrecek
发明人： Frank Bachmann , Dieter Lohmann , Peter Chabrecek
IPC分类号： G02C7/04 , A61L27/34 , C07H13/12 , C07H15/04 , C08B37/16 , C08F20/36 , C08F290/00 , C08F290/06 , G02B1/04 , C07H15/10 , C07H15/12
CPC分类号： C07H13/12 , A61L27/34 , C07H15/04 , C08B37/0012 , C08F20/36 , G02B1/043
摘要： The present invention relates to polymerisable derivatives of carbohydrates comprising a compound of formula (I) R.sup.1 --(COO--Alk).sub.m -(OCONH--R).sub.n -(NHCO).sub.p Y--Z (I) wherein R.sup.1 is a radically polymerisable hydrocarbon group; m, n and p are 0 or 1; Alk is alkylene having up to 10 carbon atoms; R is a diradical, having up to 20 carbon atoms, of an organic diisocyanate; Z is a monovalent radical, minus a single hydroxy group, of a mono-, di- or tri-saccharide, of an oligosaccharide, of a cyclodextrin (CD) or of an anhydrosaccharide; and Y is --O-- or --NH--; with the proviso that when p is zero, m and n are also zero and Y is --NH--; to homopolymers, copolymers, block copolymers, graft copolymers and polymeric networks thereof, to moulded articles, for example contact lenses or biomedicinal articles, comprising the mentioned polymers, as well as to processes for the preparation of the mentioned polymers and articles.
摘要翻译：本发明涉及碳水化合物的可聚合衍生物，其包含式（I）化合物R1-（COO-Alk）m-（OCONH-R）n-（NHCO）pY-Z（I）的化合物，其中R1是可自由基聚合的烃基 ; m，n和p为0或1; Alk是具有至多10个碳原子的亚烷基; R是具有至多20个碳原子的双键，有机二异氰酸酯; Z是低聚糖，环糊精（CD）或非水解糖的单糖，二糖或三糖的单一基团，减去单个羟基; Y为-O-或-NH-; 条件是当p为0时，m和n也为零，Y为-NH-; 至均聚物，共聚物，嵌段共聚物，接枝共聚物和聚合物网络，包括所述聚合物的模塑制品，例如隐形眼镜或生物医学制品，以及制备所述聚合物和制品的方法。

29. 发明授权

US5527925A Functionalized photoinitiators, macromers thereof, and the use thereof 失效
标题翻译：官能化光引发剂，其大分子单体及其用途
公开(公告)号：US5527925A
公开(公告)日：1996-06-18
申请号：US265597
申请日：1994-06-24
申请人： Peter Chabrecek , Dieter Lohmann
发明人： Peter Chabrecek , Dieter Lohmann
IPC分类号： G02C7/04 , C07C49/76 , C07C49/82 , C07C271/20 , C07C271/24 , C07C271/28 , C07C271/32 , C07C271/38 , C07D317/26 , C07F7/10 , C08B31/00 , C08B33/00 , C08B37/00 , C08B37/08 , C08B37/16 , C08F2/48 , C08F2/50 , C08F8/30 , C08F16/36 , C08G18/00 , C08G18/08 , C08G18/71 , C08G77/04 , C08G77/38 , C08J3/28 , C08J7/12 , C08J7/18 , C08L101/02 , G02B1/04 , G03F7/031 , G03F7/075 , C07C249/00 , C07C251/00 , C07D317/32
CPC分类号： G03F7/075 , C07C271/20 , C07C271/24 , C07C271/28 , C07C271/38 , C08B37/0012 , C08B37/0072 , C08F2/50 , C08F8/30 , C08G77/38 , C08J7/12 , C08J7/18 , G02B1/043 , G03F7/031 , C07C2101/14 , Y10S522/904 , Y10S522/905 , Y10T428/31645 , Y10T428/31663 , Y10T428/31667 , Y10T428/31855 , Y10T428/31971
摘要： Compounds of formula I: ##STR1## are disclosed. The compounds are photoinitiators which can be functionalized by means of ethylenic groups or can be bonded to H-active substances, in order, for example, to modify surfaces by means of photopolymerizable substances. The compounds are especially useful in the manufacture of contact lenses.
摘要翻译：公开了式I化合物：。这些化合物是可以通过烯属基官能化或可以与H-活性物质结合的光引发剂，以便例如通过可光聚合物质来修饰表面。这些化合物在隐形眼镜的制造中特别有用。

30. 发明授权

US06586038B1 Process for the modification of a material surface 失效
标题翻译：用于修饰材料表面的工艺
公开(公告)号：US06586038B1
公开(公告)日：2003-07-01
申请号：US09697859
申请日：2000-10-27
申请人： Peter Chabrecek , Dieter Lohmann
发明人： Peter Chabrecek , Dieter Lohmann
IPC分类号： G02B110
CPC分类号： G02B1/043 , C08J7/12 , C08J7/16
摘要： The invention relates to a process for coating a material surface. The process comprises the steps of: (a) covalently binding polymerization initiator radicals to the surface; (b) graft polymerizing a vinyl monomer carrying a reactive group onto the initiator-modified material surface and thereby providing a primary polymer coating comprising reactive groups; and (c) reacting the reactive groups of the primary polymer coating with a hydrophilic telomer having a functional group that is coreactive with the reactive groups of the primary polymer coating. The coated articles that are obtainable by the process of the invention have desirable characteristics regarding adherence to the substrate, durability, hydrophilicity, wettability, biocompatibility and permeability and are thus useful for the manufacture of biomedical articles such as ophthalmic devices.
摘要翻译：本发明涉及一种涂覆材料表面的方法。该方法包括以下步骤：（a）将聚合引发剂基团与表面共价结合; （b）将携带反应性基团的乙烯基单体接枝聚合到引发剂改性的材料表面上，从而提供包含反应性基团的初级聚合物涂层; 和（c）使主聚合物涂层的反应性基团与具有与主聚合物涂层的反应性基团相互作用的官能团的亲水性调聚物反应。通过本发明的方法可获得的涂覆制品具有关于对基材的粘附性，耐久性，亲水性，润湿性，生物相容性和渗透性的所需特性，因此可用于制造生物医学制品如眼科装置。

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