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21. 发明授权

US5885757A Aminopolycarboxylic acid chelating agent, heavy metal chelate compound thereof, photographic additive and processing method 失效
标题翻译：氨基多羧酸螯合剂，其重金属螯合物，照相添加剂和加工方法
公开(公告)号：US5885757A
公开(公告)日：1999-03-23
申请号：US960559
申请日：1997-10-29
申请人： Tadashi Inaba , Kiyoshi Morimoto , Shigeo Hirano
发明人： Tadashi Inaba , Kiyoshi Morimoto , Shigeo Hirano
IPC分类号： C07C229/24 , C07C323/25 , G03C5/26 , G03C5/305 , G03C5/38 , G03C7/30 , G03C7/413 , G03C7/42
CPC分类号： C07C323/25 , C07C229/24 , G03C5/3053 , G03C7/3046 , G03C7/42 , G03C5/268 , G03C5/38 , G03C7/413
摘要： An aminopolycarboxylic acid compound represented by the following formula or analogous thereof: ##STR1## The aminopolycarboxylic acid compound of the present invention can be used as a chelating agent for various metals, which is excellent in the biodegradability and masking effect on metals.
摘要翻译：由下式表示的氨基多羧酸化合物或其类似物：本发明的氨基多羧酸化合物可用作各种金属的螯合剂，其对金属的生物降解性和掩蔽效果优异。

22. 发明授权

US5541044A Silver halide color photographic material 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US5541044A
公开(公告)日：1996-07-30
申请号：US152871
申请日：1993-11-16
申请人： Mitsuru Yamamoto , Shigeo Hirano , Akira Ogawa , Kouichi Hanaki
发明人： Mitsuru Yamamoto , Shigeo Hirano , Akira Ogawa , Kouichi Hanaki
IPC分类号： G03C7/305 , G03C7/32 , G03C7/36 , G03C1/46
CPC分类号： G03C7/30511 , G03C7/3225 , Y10S430/158
摘要： The present invention relates to a silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein at least one layer of said photographic material contains at least one yellow coupler represented by the following general formulas (3) or (2): ##STR1## as defined in the specification.
摘要翻译：本发明涉及一种卤化银彩色照相材料，其包括其上具有至少一个卤化银乳剂层的载体，其中至少一层所述照相材料含有至少一种由以下通式（3）或（ 2）：（3）（2）如说明书中所定义。

23. 发明授权

US5110719A Process for preparing a direct positive photographic material 失效
标题翻译：制备直接摄影材料的方法
公开(公告)号：US5110719A
公开(公告)日：1992-05-05
申请号：US611373
申请日：1990-11-13
申请人： Sadanobu Shuto , Hatsumi Tanemura , Shigeo Hirano
发明人： Sadanobu Shuto , Hatsumi Tanemura , Shigeo Hirano
IPC分类号： G03C1/485
CPC分类号： G03C1/48538 , Y10S430/141
摘要： A process for preparing a direct positive photosensitive material comprising providing on a support at least one silver halide light-sensitive emulsion layer containing the combination of (a) non-prefogged internal latent image silver halide grains; (b) a binder; (c) at least one compound represented by formulae (I), (II), or (III); and at least one compound represented by formula (IV):R--SO.sub.2 S--M (I)R--SO.sub.2 S--R.sup.1 (II)R--SO.sub.2 S--L.sub.m --S.O.sub.2 S--R.sup.2 (III)wherein R, R.sup.1 and R.sup.2 each represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group or a substituted or unsubstituted heterocyclic group; M represents a cation; L represents a divalent linking group; and m is 0 or 1; andR.sup.3 --SO.sub.2 --M.sup.1 (IV)wherein R.sup.3 represents an aliphatic group, an aromatic group or a heterocyclic group; and M.sup.1 represents a cation. The material provides a direct positive image with high Dmax, low Dmin and high contrast.

24. 发明授权

US4948712A Direct positive photographic materials and a method of forming direct positive images 失效
标题翻译：直接的正性照相材料和形成直接正像的方法
公开(公告)号：US4948712A
公开(公告)日：1990-08-14
申请号：US184552
申请日：1988-06-07
申请人： Noriyuki Inoue , Tatsuo Heki , Hidetoshi Kobayashi , Naoyasu Deguchi , Shigeo Hirano
发明人： Noriyuki Inoue , Tatsuo Heki , Hidetoshi Kobayashi , Naoyasu Deguchi , Shigeo Hirano
IPC分类号： G03C7/30
CPC分类号： G03C7/3022 , G03C2200/20 , G03C7/3029 , Y10S430/156
摘要： The invention provides (1) direct positive photographic photosensitive materials in which at least one type of FR compound which releases fogging agent or development accelerator or a precursor thereof in accordance with the amount of silver developed when the silver halide is being developed is included in a direct positive photographic material comprising at least one layer of non-pre-fogged internal latent image type silver halide emulsion on a support, and (2) a method of forming direct positive images of which the distinguishing features are that in a method for the formation of direct positive images in which a direct positive photographic photosensitive material comprising at least one layer of non-pre-fogged internal latent image forming silver halide emulsion on a support is processed, after image exposure, in a surface developer, at least one type of FR compound which releases fogging agent or development accelerator or precursors thereof is included in the said photographic mateiral, and that the said photosensitive material is subjected to a fogging process and to a development process during and/or after the said fogging process.It is possible by means of this invention to obtain direct positive photographic materials which have excellent stability with respect to the passage of time and especially good stability with respect to the passage of time under conditions of high temperature and high humidity.Moreover, it is possible to obtain direct positive photographic materials and a method of forming direct positive images which have a high maximum image density and a high resolving power.Moreover, it is possible to obtain direct positive photographic materials and a method of forming direct positive images with which direct positive images which have a satisfactorily high color density can be obtained, even on processing in highly stable developers of low pH.

25. 发明授权

US4791049A Silver halide photographic material containing a compound having an oxidation-reduction moiety and timing group 失效
标题翻译：卤化银照相材料含有具有氧化还原部分和时间基团的化合物
公开(公告)号：US4791049A
公开(公告)日：1988-12-13
申请号：US41570
申请日：1987-04-23
申请人： Tetsuro Kojima , Shigeo Hirano , Hideo Usui
发明人： Tetsuro Kojima , Shigeo Hirano , Hideo Usui
IPC分类号： G03C7/26 , G03C7/305 , G03C7/392 , G03C1/08 , G03C1/46 , G03C7/32
CPC分类号： G03C7/30552 , Y10S430/156 , Y10S430/158 , Y10S430/16 , Y10S430/161
摘要： A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide photographic material contains at least one compound represented by the following general formula (I):A--Time).sub.t X (I)wherein A represents an oxidation reduction moiety comprising an atomic group which does not enable --Time).sub.t X to be released until the oxidation reduction moiety is oxidized during photographic development processing; Time represents a timing group which is connected to A through a sulfur atom, a nitrogen atom or an oxygen atom; t represents an integer of 0 or 1; and X represents a group represented by the following general formula (II): ##STR1## wherein R represents a straight chain or branched chain alkylene group, a straight chain or branched chain alkenylene group, a straight chain or branched chain aralkylene group or an arylene group; Z represents a polar substituent; Y represents ##STR2## R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aralkyl group; and n represents an integer of 0 or 1. The silver halide photographic material exhibits a large interimage effect without deterioration of other photographic properties and thus provides photographic images excellent in sharpness and graininess.
摘要翻译：一种卤化银照相材料，包括其上具有至少一个卤化银乳剂层的载体，其中所述卤化银照相材料含有至少一种由以下通式（I）表示的化合物：A-Time）tX（I）其中A表示包含原子团的氧化还原部分，其不能使-Time）tX释放直到氧化还原部分在照相显影处理过程中被氧化; 时间表示通过硫原子，氮原子或氧原子与A连接的时基; t表示0或1的整数; X表示由下列通式（II）表示的基团：其中R表示直链或支链亚烷基，直链或支链亚烯基，直链或支链亚芳基或亚芳基; Z表示极性取代基; Y表示R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8各自表示氢原子，取代或未取代的烷基，取代或未取代的芳基，取代或未取代的烯基基团或取代或未取代的芳烷基; 并且n表示0或1的整数。卤化银照相材料表现出大的图像效果，而不会降低其它照相性能，因此提供了清晰度和颗粒度优异的照相图像。

26. 发明授权

US4789624A Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US4789624A
公开(公告)日：1988-12-06
申请号：US42612
申请日：1987-04-21
申请人： Kei Sakanoue , Shigeo Hirano , Takehiko Ueda , Keiichi Adachi
发明人： Kei Sakanoue , Shigeo Hirano , Takehiko Ueda , Keiichi Adachi
IPC分类号： G03C7/26 , G03C7/32 , G03C7/392 , G03C7/34 , G03C7/36 , G03C7/38
CPC分类号： G03C7/39216
摘要： A silver halide color photographic light-sensitive material which contains a high speed reactive type coupler having a relative coupling speed of 0.35 to 1.0 and a compound represented by the following general formula (I): ##STR1## wherein R represents a hydrogen atom, a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group, or a substituted or unsubstituted heterocyclic group.The silver halide color photographic light-sensitive material provides color images having greatly improved graininess in both high density areas and low density areas, without adversely affecting sensitivity.
摘要翻译：一种卤化银彩色照相感光材料，其含有相对耦合速度为0.35至1.0的高速反应型偶合剂和由以下通式（I）表示的化合物：其中R表示氢取代或未取代的脂族基团，取代或未取代的芳基，或取代或未取代的杂环基。卤化银彩色摄影感光材料提供了在高密度区域和低密度区域中具有极大改善的颗粒度的彩色图像，而不会不利地影响灵敏度。

27. 发明授权

US4769316A Method for restraining the formation of re-reversal negative image in direct positive silver halide photographic materials 失效
标题翻译：用于抑制在直接正性卤化银照相材料中形成再反转负像的方法
公开(公告)号：US4769316A
公开(公告)日：1988-09-06
申请号：US876300
申请日：1986-06-18
申请人： Tsutomu Miyasaki , Shigeo Hirano , Kiyoshi Morimoto
发明人： Tsutomu Miyasaki , Shigeo Hirano , Kiyoshi Morimoto
IPC分类号： G03C1/36 , G03C1/485 , G03C1/12 , G03C1/06
CPC分类号： G03C1/48584 , Y10S430/141
摘要： A restraining method for restraining the formation of a re-reversal negative image is described, comprising incorporating a cyanine dye or a merocyanine dye which is electron donative and is adsorbable on silver halide in at least one hydrophilic colloid layer of an internal latent image type direct positive silver halide photographic material as a re-reversal restrainer.
摘要翻译：描述了限制形成反转负像的抑制方法，其包括：花青染料或部分花菁染料，该染料是电子给体，并且可吸附在卤化银上至少一个内部潜像型直接的亲水胶体层正卤化银照相材料作为反转抑制剂。

28. 发明授权

US4740453A Silver halide photosensitive material containing a compound capable of releasing a photographically useful group 失效
标题翻译：含有能释放摄影有用基团的化合物的卤化银感光材料
公开(公告)号：US4740453A
公开(公告)日：1988-04-26
申请号：US813308
申请日：1985-12-24
申请人： Koki Nakamura , Shigeo Hirano , Tadashi Ikeda , Keiji Mihayashi , Mitsunori Ono , Toshiro Takahashi , Ken-ichi Kuwabara , Morio Yagihara , Isamu Itoh
发明人： Koki Nakamura , Shigeo Hirano , Tadashi Ikeda , Keiji Mihayashi , Mitsunori Ono , Toshiro Takahashi , Ken-ichi Kuwabara , Morio Yagihara , Isamu Itoh
IPC分类号： G03C1/43 , G03C7/305 , G03C1/40 , G03C5/54
CPC分类号： G03C1/43 , G03C7/305 , G03C2005/168 , Y10S430/156 , Y10S430/158 , Y10S430/16
摘要： A silver halide photosensitive material is described, comprising a support and at least one silver halide emulsion layer, wherein said emulsion layer or another layer contains a compound represented by formula (I) ##STR1## wherein X represents an atomic group forming a redox center of benzene type having substituents by linking with C.sub.A and C.sub.B, and which does not enable Time-PUG to be released until the redox center is oxidized during development processing; EWG represents an electron withdrawing group having a Hammet's .sigma. para value exceeding 0.3; C.sub.A and C.sub.B each represents a carbon atom; R.sub.1 and R.sub.2 each represents a hydrogen atom or a suitable substituent; Time represents a timing group connecting to C.sub.B through a sulfur, nitrogen, or selenium atom thereof, t is an integer of 0 or 1, and when t=0, Time is a chemical bond; PUG represents a photographically useful group and connects to C.sub.B through a sulfur, nitrogen, or selenium atom thereof when t=0; and n is an integer of 0 or 1.
摘要翻译：描述了卤化银感光材料，其包括载体和至少一种卤化银乳剂层，其中所述乳剂层或另一层含有由式（I）表示的化合物（I），其中X表示形成通过与CA和CB连接而具有取代基的苯类氧化还原中心，并且不能使Time-PUG释放直到氧化还原中心在显影处理期间被氧化; EWG代表Hammet sigma值超过0.3的吸电子基团; CA和CB各自表示碳原子; R1和R2各自表示氢原子或适当的取代基; 时间表示通过其硫，氮或硒原子与CB连接的定时基团，t为0或1的整数，当t = 0时，为化学键; PUG表示当t = 0时，通过其硫，氮或硒原子连接CB; n为0或1的整数。

29. 发明授权

US4738918A Process for processing silver halide photographic material 失效
标题翻译：卤化银照相材料的处理方法
公开(公告)号：US4738918A
公开(公告)日：1988-04-19
申请号：US907335
申请日：1986-09-15
申请人： Shoji Ishiguro , Hiroyuki Mifune , Shigeo Hirano , Nobuyuki Iwasaki
发明人： Shoji Ishiguro , Hiroyuki Mifune , Shigeo Hirano , Nobuyuki Iwasaki
IPC分类号： G03C7/30 , G03C1/10 , G03C5/29 , G03C5/305 , G03C7/392 , G03C5/24
CPC分类号： G03C5/305 , G03C1/10 , G03C7/3924
摘要： A process for processing silver halide photographic material is disclosed, which comprises development-processing a silver halide photographic material in the presence of a compound represented by formula (I) or a salt thereof with an inorganic or organic acid: ##STR1## wherein Z represents an atomic group of carbon atoms, nitrogen atoms, or a combination thereof forming a 5-, 6-, or 7-membered unsaturated heterocyclic ring, said unsaturated heterocyclic ring being optionally fused with a monocyclic or bicyclic aryl group;R.sup.0 represents ##STR2## R.sup.1 represents an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group;R.sup.2 and R.sup.3 each represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an alkoxy group, a substituted alkoxy group, an amino group, or a substituted amino group;R.sup.4 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group or a substituted aryl group; andR.sup.5 represents an acyl group, a sulfinyl group, a sulfonyl group, or a carbamoyl group, or represents a group selected from the groups represented by R.sup.1, R.sup.2, R.sup.3 and R.sup.4.
摘要翻译：公开了一种用于处理卤化银照相材料的方法，其包括在由式（I）表示的化合物或其盐与无机或有机酸存在下显影处理卤化银照相材料：（I）其中Z表示碳原子的原子团，氮原子或其组合形成5-，6-或7-元不饱和杂环，所述不饱和杂环任选地与单环或双环芳基稠合; R 0表示R 1表示烷基，取代的烷基，芳基或取代的芳基; R2和R3各自表示氢原子，烷基，取代的烷基，芳基，取代的芳基，烷氧基，取代的烷氧基，氨基或取代的氨基; R4表示氢原子，烷基，取代的烷基，芳基或取代的芳基; 并且R 5表示酰基，亚磺酰基，磺酰基或氨基甲酰基，或表示选自由R 1，R 2，R 3和R 4表示的基团的基团。

30. 发明授权

US4699873A Negative silver halide photographic light-sensitive material 失效
标题翻译：负卤化银照相感光材料
公开(公告)号：US4699873A
公开(公告)日：1987-10-13
申请号：US823720
申请日：1986-01-29
申请人： Toshiro Takahashi , Shigeo Hirano
发明人： Toshiro Takahashi , Shigeo Hirano
IPC分类号： G03C1/06 , G03C1/09 , G03C1/295
CPC分类号： G03C1/09 , G03C1/061 , G03C2001/094 , Y10S430/15
摘要： A negative silver halide photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer is disclosed. At least one of the silver halide emulsion layers or another hydrophilic colloidal layer of the material contains a hydrazine derivative and a compound represented by the formula:R.sub.1 --S--S--R.sub.2wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an aliphatic group, an aromatic group or a heterocyclic group, or when R.sub.1 and R.sub.2 are both aliphatic groups they may together form a ring. The material can rapidly form a superhigh contrast image using a stable processing solution.
摘要翻译：公开了一种负极卤化银照相感光材料，其包括其上提供有至少一个卤化银乳剂层的载体。卤化银乳剂层或材料的另一亲水性胶体层中的至少一种含有肼衍生物和由下式表示的化合物：R1-SS-R2，其中R1和R2可以相同或不同，各自表示脂族基，芳基或杂环基，或者当R 1和R 2都是脂族基团时，它们可以一起形成环。该材料可以使用稳定的处理溶液快速形成超高对比度图像。

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