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    • 22. 发明申请
    • LIGHT-EMITTING MATERIAL
    • 发光材料
    • US20090115327A1
    • 2009-05-07
    • US12295933
    • 2007-04-03
    • Mohammad Khaja NazeeruddinCedric KleinMichael Graetzel
    • Mohammad Khaja NazeeruddinCedric KleinMichael Graetzel
    • H01L51/50C07F15/00
    • C07F15/0046Y10S428/917Y10T428/265Y10T428/31504
    • This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [ĈN]2M(T)(L), comprising chelate dialkylamino-substituted ĈN ligands, monodentate neutral ligand (L) having sp2 hybridized N atom and a monodentate anionic ligand (T) chosen among CN−, CNO−, CNS−. It has been surprisingly found that when the metal has bound thereto in addition to substituted orthometalated ligands, both an anion chosen among cyanide, thiocyanate, cyanate, possessing strong C donor and π acceptor properties, and a monodentate neutral ligand L, as above defined, said ligands advantageously participate in the emission process, significantly shifting emission towards higher energies (blue-shift) and enabling appreciable improvement of the emission efficiency of complexes [ĈN]2M(T)(L).Still objects of the invention are the use of said light emitting materials and organic light emitting device comprising said light emitting material.
    • 本发明涉及包含新型邻位金属化过渡金属络合物[ĈN] 2M(T)(L))的发光材料,其包含螯合二烷基氨基取代的ĈN配体,具有sp2杂化的N原子的单齿中性配体(L)和单齿阴离子配体 (T)选自CN-,CNO-,CNS-。 已经令人惊奇地发现,除了取代的正交金属化配体之外,当金属与其结合时,选自具有强C供体和π受体性质的氰化物,硫氰酸盐,氰酸盐中的阴离子和如上所定义的单齿中性配体L, 所述配体有利地参与发射过程,将发射显着地转移到更高的能量(蓝移),并且使复合物[ĈN] 2M(T)(L)的发射效率明显改善。 本发明的另一个目的是使用所述发光材料和包括所述发光材料的有机发光器件。
    • 24. 发明授权
    • Light-emitting material
    • 发光材料
    • US08980440B2
    • 2015-03-17
    • US12295933
    • 2007-04-03
    • Mohammad Khaja NazeeruddinCedric KleinMichael Graetzel
    • Mohammad Khaja NazeeruddinCedric KleinMichael Graetzel
    • H01L51/50C07F15/00
    • C07F15/0046Y10S428/917Y10T428/265Y10T428/31504
    • This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [C^N]2M(T)(L), comprising chelate dialkylamino-substituted C^N ligands, monodentate neutral ligand (L) having sp2 hybridized N atom and a monodentate anionic ligand (T) chosen among CN−, CNO−, CNS−. It has been surprisingly found that when the metal has bound thereto in addition to substituted orthometalated ligands, both an anion chosen among cyanide, thiocyanate, cyanate, possessing strong C donor and π acceptor properties, and a monodentate neutral ligand L, as above defined, said ligands advantageously participate in the emission process, significantly shifting emission towards higher energies (blue-shift) and enabling appreciable improvement of the emission efficiency of complexes [C^N]2M(T)(L).Still objects of the invention are the use of said light emitting materials and organic light emitting device comprising said light emitting material.
    • 本发明涉及包含新型邻位金属过渡金属络合物[C 1 N] 2M(T)(L))的发光材料,其包含螯合二烷基氨基取代的C 1 N配体,具有sp2杂化的N原子的单齿中性配体(L)和 选自CN-,CNO-,CNS-的单齿阴离子配位体(T)。 已经令人惊奇地发现,当金属除了取代的正极金属化配体之外还结合有金属时,选自氰化物,硫氰酸盐,氰酸盐,具有强C供体和阴离子的阴离子; 受体特性和如上所定义的单齿中性配体L,所述配体有利地参与发射过程,将发射显着地偏移到更高的能量(蓝移)并且使复合物的发射效率明显提高[C ^ N] 2M (T)(L)。 本发明的另一个目的是使用所述发光材料和包括所述发光材料的有机发光器件。
    • 30. 发明授权
    • Metal complex photosensitizer and photovoltaic cell
    • 金属复合光敏剂和光伏电池
    • US06245988B1
    • 2001-06-12
    • US09423162
    • 1999-11-02
    • Michael GrätzelMohammad Khaja NazeeruddinPéter Péchy
    • Michael GrätzelMohammad Khaja NazeeruddinPéter Péchy
    • C07F1500
    • H01G9/2031C07F9/58C07F15/0026C07F15/0053C09B57/10H01G9/2059H01L51/0086Y02E10/542Y02E10/549
    • A photosensitizer complex of formulae (Ia) MX3Lt or (Ib) MXYLt in which M is a transition metal selected from ruthenium, osmium, iron, rhenium and technetium, preferably ruthenium or osmium; each X is a co-ligand independently selected from NCS—, Cl—, Br—, I—, CN—, NCO—, H2O, NCN2−; pyridine unsubstituted or substituted by at least one group selected from vinyl, primary, secondary or tertiary amine, OH and C1-30 alkyl, preferably NCS—; and Lt is a tridentate ligand comprising heterocycles such as pyridine, thiophene, imidazole, pyrazole, triazole, carrying at least one carboxylic, phosphoric, hydoxamic acid or a chelating group. A photovoltaic cell comprising an electrically conductive layer deposited on a support to which at least one titanium dioxide layer has been applied and, as a photosensitizer applied to the titanium dioxide layer, a photosensitizer complex of formula (Ia) or Ib) as specified above.
    • 式(Ia)MX3Lt或(Ib)MXYLt的光敏剂配合物,其中M是选自钌,锇,铁,铼和锝的过渡金属,优选钌或锇; 每个X是独立地选自NCS,Cl,Br,I,CN,NCO,H 2 O,NCN 2 - 的共配体; 未取代或被至少一个选自乙烯基,伯,仲或叔胺的基团取代的吡啶,OH和C 1-3烷基,优选NCS-; Lt是含有至少一种羧酸,磷酸,羟肟酸或螯合基团的吡啶,噻吩,咪唑,吡唑,三唑等杂环的三齿配位体。 一种光伏电池,包括沉积在已经施加了至少一个二氧化钛层的载体上的导电层,作为施加到二氧化钛层的光敏剂,如上所述,式(1a)或(1b)的光敏剂配合物 。