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    • 30. 发明授权
    • Metal complex photosensitizer and photovoltaic cell
    • 金属复合光敏剂和光伏电池
    • US06245988B1
    • 2001-06-12
    • US09423162
    • 1999-11-02
    • Michael GrätzelMohammad Khaja NazeeruddinPéter Péchy
    • Michael GrätzelMohammad Khaja NazeeruddinPéter Péchy
    • C07F1500
    • H01G9/2031C07F9/58C07F15/0026C07F15/0053C09B57/10H01G9/2059H01L51/0086Y02E10/542Y02E10/549
    • A photosensitizer complex of formulae (Ia) MX3Lt or (Ib) MXYLt in which M is a transition metal selected from ruthenium, osmium, iron, rhenium and technetium, preferably ruthenium or osmium; each X is a co-ligand independently selected from NCS—, Cl—, Br—, I—, CN—, NCO—, H2O, NCN2−; pyridine unsubstituted or substituted by at least one group selected from vinyl, primary, secondary or tertiary amine, OH and C1-30 alkyl, preferably NCS—; and Lt is a tridentate ligand comprising heterocycles such as pyridine, thiophene, imidazole, pyrazole, triazole, carrying at least one carboxylic, phosphoric, hydoxamic acid or a chelating group. A photovoltaic cell comprising an electrically conductive layer deposited on a support to which at least one titanium dioxide layer has been applied and, as a photosensitizer applied to the titanium dioxide layer, a photosensitizer complex of formula (Ia) or Ib) as specified above.
    • 式(Ia)MX3Lt或(Ib)MXYLt的光敏剂配合物,其中M是选自钌,锇,铁,铼和锝的过渡金属,优选钌或锇; 每个X是独立地选自NCS,Cl,Br,I,CN,NCO,H 2 O,NCN 2 - 的共配体; 未取代或被至少一个选自乙烯基,伯,仲或叔胺的基团取代的吡啶,OH和C 1-3烷基,优选NCS-; Lt是含有至少一种羧酸,磷酸,羟肟酸或螯合基团的吡啶,噻吩,咪唑,吡唑,三唑等杂环的三齿配位体。 一种光伏电池,包括沉积在已经施加了至少一个二氧化钛层的载体上的导电层,作为施加到二氧化钛层的光敏剂,如上所述,式(1a)或(1b)的光敏剂配合物 。