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21. 发明授权

US06692616B2 Method for purifying trimethylolpropane, which is produced by hydrogenation, by means of continuous distillation 失效
标题翻译：通过连续蒸馏通过氢化制备三羟甲基丙烷的方法
公开(公告)号：US06692616B2
公开(公告)日：2004-02-17
申请号：US10168980
申请日：2002-06-26
申请人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Harald Rust , Gerhard Schulz
发明人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Harald Rust , Gerhard Schulz
IPC分类号： B01D314
CPC分类号： C07C29/80 , C07C31/225 , C07C31/12 , C07C31/245 , C07C31/04
摘要： A process is disclosed for the purification, by distillation, of trimethylolpropane originating from the hydrogenation of 2,2-dimethylolbutanal, said process including the following steps: (a) reaction of n-butyraldehyde with formaldehyde in the presence of catalytic amounts of a tertiary amine, and hydrogenation of the resulting mixture to give a mixture containing trimethylolpropane; (b) separation of water, methanol, trialkylamine and/or trialkylammonium formate by distillation; (c) heating of the residue obtained in (b) under reduced pressure to a temperature at which TMP is volatile and compounds boiling above TMP are cleaved, in order to separate off, by distillation, TMP and compounds more volatile than TMP; (d) distillation of the distillate obtained in (c) in order to separate off the more volatile compounds and recover pure TMP; and (e) optional distillation of the TMP obtained in (d) in order to recover TMP with a low APHA color index. A process is also disclosed in which trialkylammonium formate is distilled under mild conditions from crude mixtures of polyhydric alcohols, predominantly trimethylolpropane.
摘要翻译：公开了一种通过蒸馏纯化来自2,2-二羟甲基丁烷的氢化的三羟甲基丙烷的方法，所述方法包括以下步骤：（a）在催化量的叔碳酸存在下，正丁醛与甲醛的反应胺，并氢化得到的混合物，得到含有三羟甲基丙烷的混合物;（b）通过蒸馏分离水，甲醇，三烷基胺和/或三烷基铵甲酸盐;（c）将（b）中得到的残余物在减压下加热至 TMP挥发的温度和TMP沸点高的化合物被切割，以便通过蒸馏分离TMP和比TMP更易挥发的化合物;（d）蒸馏（c）中获得的馏出物，以分离出更多的挥发性化合物，回收纯TMP; 为了回收具有低APHA颜色指数的TMP，还可以任选地蒸馏（d）中获得的TMP。还公开了一种方法，其中在温和条件下从多元醇，主要是三羟甲基丙烷的粗混合物中蒸馏出三烷基铵甲酸盐。

22. 发明授权

US06447870B1 Optical storage disk blank and method for manufacturing the disk blank 失效
标题翻译：光存储磁盘空白和制造磁盘空白的方法
公开(公告)号：US06447870B1
公开(公告)日：2002-09-10
申请号：US09509130
申请日：2000-03-23
申请人： Herbert Beck , Gerhard Schulz
发明人： Herbert Beck , Gerhard Schulz
IPC分类号： B32B302
CPC分类号： G11B7/26 , G11B7/24 , Y10T428/21
摘要： Method for manufacturing an optically readable digital storage disk having an arbitrary edge contour from a CD-R disk blank, as well as a CD-R disk blank suitable for the manufacture of a storage disk, starts with a blank having a plastic disk that is provided with a reflective layer on the side opposite a scanning side. The reflective layer, which is connected with the plastic disk along a first line, is welded with the plastic disk along an arbitrarily shaped second line that is closed on itself. Afterwards, the storage disk is cut from the CD-R disk blank along a third line that corresponds to the edge contour.
摘要翻译：用于制造具有来自CD-R盘坯料的任意边缘轮廓的光学可读数字存储盘以及适合于制造存储盘的CD-R盘坯的方法从具有塑料盘的坯料开始在与扫描侧相对的一侧设置有反射层。沿着第一线与塑料盘连接的反射层与塑料盘一起沿着自身闭合的任意形状的第二线焊接。之后，沿着对应于边缘轮廓的第三条线从CD-R盘坯件切割存储盘。

23. 发明授权

US06353141B1 Functionalized cyclopentene-derived oligomer mixtures, their preparation and their use 失效
标题翻译：官能化的环戊烯衍生的低聚物混合物，其制备及其用途
公开(公告)号：US06353141B1
公开(公告)日：2002-03-05
申请号：US09331419
申请日：1999-06-21
申请人： Edgar Zeller , Gerhard Schulz , Bernhard Geissler , Michael Röper , Guido Voit
发明人： Edgar Zeller , Gerhard Schulz , Bernhard Geissler , Michael Röper , Guido Voit
IPC分类号： C07C4500
CPC分类号： C07C209/26 , C07C29/16 , C07C45/50 , C07C51/145 , C07C47/02
摘要： Functionalized cyclopentene-derived oligomer mixtures are prepared by reacting oligomer mixtures which contain ethyleneic double bonds in one or more reaction steps starting from cyclopentene-derived oligomer mixtures of the formula I R1R2C═[═CH—(CH2)3—CH═]n═CR3R4 (I) where n is an integer from 1 to 15, and R1, R2, R3 and R4 are, independently of one another, hydrogen or alkyl, and are used as described.
摘要翻译：官能化的环戊烯衍生的低聚物混合物通过在一个或多个反应步骤中含有乙烯双键的低聚物混合物反应来制备，所述混合物起始于式Iwheren为1至15的整数的环戊烯衍生的低聚物混合物，R1，R2，R3和R4为，彼此独立地是氢或烷基，并按照所述使用。

24. 发明授权

US06292720B1 Trimming process for adapting a simulation system to an automatically controlled reference system 失效
标题翻译：用于将模拟系统适配到自动控制的参考系统的修整过程
公开(公告)号：US06292720B1
公开(公告)日：2001-09-18
申请号：US09433313
申请日：1999-11-03
申请人： Gerhard Schulz , Thomas Meyer
发明人： Gerhard Schulz , Thomas Meyer
IPC分类号： G05D100
CPC分类号： G05D1/0808 , B64C13/00 , B64C13/20
摘要： Trimming process for adapting a first control loop of a controllable, automatically controlled reference system, which is or represents an aircraft, to a second control loop which simulates the reference system, Flying condition values including controlled variables, which are returned in each control loop for the purpose of the control, are detected, and both control loops are acted upon by the same desired input data. In the first process loop, a conversion of the unreturned flying condition values of the airplane model takes place to the values of the corresponding flying condition values of the reference system. The second process loop is provided for the adaptation of the returned condition values of the airplane simulation system to the corresponding condition values of the reference system.
摘要翻译：调整过程，用于将可控自动控制的参考系统的第一控制回路（其是或代表飞行器）适配到模拟参考系统的第二控制回路，包括受控变量的飞行条件值，其在每个控制回路中返回，检测到控制的目的，并且通过相同的期望输入数据对两个控制回路进行操作。在第一个过程循环中，将飞机模型的未返回飞行状态值的转换发生到参考系统的相应飞行状态值的值。提供第二处理循环用于将飞机模拟系统的返回条件值适配到参考系统的相应条件值。

25. 发明授权

US06207865B1 Method for the hydrogenation of carbonyl compounds 有权
标题翻译：羰基化合物氢化方法
公开(公告)号：US06207865B1
公开(公告)日：2001-03-27
申请号：US09462628
申请日：2000-01-11
申请人： Boris Breitscheidel , Marc Walter , Detlef Kratz , Gerhard Schulz , Manfred Sauerwald
发明人： Boris Breitscheidel , Marc Walter , Detlef Kratz , Gerhard Schulz , Manfred Sauerwald
IPC分类号： C07C29136
CPC分类号： C07B31/00 , B01J25/00 , C07C29/141 , C07C31/20 , C07C31/22
摘要： A carbonyl compound or a mixture of two or more carbonyl compounds is catalytically hydrogenated in the presence of a Raney copper catalyst in the form of nuggets.
摘要翻译：羰基化合物或两种或多种羰基化合物的混合物在掘金形式的阮内铜催化剂存在下进行催化氢化。

26. 发明授权

US06187971B1 Method for producing polyalcohols 失效
标题翻译：生产多元醇的方法
公开(公告)号：US06187971B1
公开(公告)日：2001-02-13
申请号：US09331370
申请日：1999-06-21
申请人： Detlef Kratz , Achim Stammer , Gerhard Schulz , Guido Voit
发明人： Detlef Kratz , Achim Stammer , Gerhard Schulz , Guido Voit
IPC分类号： C07C3118
CPC分类号： C07C45/75 , C07C29/141 , Y02P20/582 , C07C31/04 , C07C31/12 , C07C31/125 , C07C31/20 , C07C31/22
摘要： Methylolalkanal of the formula II (R=CH2OH, C1-C22-alkyl, aryl or C6-C22-aralkyl) is prepared spe-wise by a) reacting a C2-C24-aldehyde with formaldehyde in the presence of a tertiary amine, b) separating the reaction mixture i) into a bottom fraction comprising the compound of formula II and an incompletely methylolated compound of the formula III and a distillate stream comprising unconverted or partially converted starting materials, or ii) into an aqueous phase and an organic phase, and recycling the distillate stream or the organic phase to a), and c) subjecting the bottom fraction or the aqueous phase i) to a catalytic or thermal reaction to convert the compound of formula III to the compound of formula II and to a corresponding methylene compound of formula IV (R′=H or R) and ii) separating the reaction product into an overhead stream comprising the compound of formula IV and unconverted formaldehyde which is recycled to a), and a bottom fraction comprising the compound of formula II.
摘要翻译：在叔胺存在下，通过使C2-C24-醛与甲醛反应制备式II的（C 1 -C 22 - 烷基，芳基或C 6 -C 22 - 芳烷基）的羟甲基烷醛，b）将反应混合物分离）至包含式II化合物的底部馏分和式III的不完全羟甲基化的化合物和包含未转化的或部分转化的起始物质的馏出物流，或ii）进入水相和有机相，并将馏出物流或有机相至a），和c）使底部馏分或水相）进行催化或热反应以将式III化合物转化为式II化合物和相应的式IV的亚甲基化合物（R '= H或R）和ii）将反应产物分离成包含式IV化合物和未转化甲醛的塔顶物流，将其再循环至a），以及包含式II化合物的塔底馏分。

27. 发明授权

US06187957B1 Preparation of amines 失效
标题翻译：胺的制备
公开(公告)号：US06187957B1
公开(公告)日：2001-02-13
申请号：US09459856
申请日：1999-12-14
申请人： Gerald Meyer , Frank Funke , Gerhard Schulz , Detlef Kratz , Marc Walter , Michael Hesse
发明人： Gerald Meyer , Frank Funke , Gerhard Schulz , Detlef Kratz , Marc Walter , Michael Hesse
IPC分类号： C07C20900
CPC分类号： C07C213/02 , B01J23/72 , B01J35/10 , B01J37/0009 , C07C209/16 , C07C209/60 , C07C211/03 , C07C217/08
摘要： Amines are prepared by reacting primary or secondary alcohols, aldehydes or ketones with nitrogen compounds selected from the group consisting of ammonia and primary and secondary amines at elevated temperatures and superatmospheric pressures in the presence of hydrogen and of a catalyst containing copper and oxygen-containing compounds of titanium by a process in which the catalyst is used in the form of moldings which have been prepared with the addition of metallic copper powder.
摘要翻译：通过在氢气和含铜和含氧化合物的催化剂的高温和超大气压下，使伯醇或仲醇，醛或酮与选自氨和伯胺和仲胺的氮化合物反应制备胺的钛，其中催化剂以通过添加金属铜粉制备的模制品的形式使用。

28. 发明授权

US5916838A Catalysts for the amination of alkylene oxides, alcohols, aldehydes and ketones 失效
公开(公告)号：US5916838A
公开(公告)日：1999-06-29
申请号：US955264
申请日：1997-10-21
申请人： Joachim Wulff-Doring , Johann-Peter Melder , Gerhard Schulz , Guido Voit , Gutshoven Frank , Wolfgang Harder
发明人： Joachim Wulff-Doring , Johann-Peter Melder , Gerhard Schulz , Guido Voit , Gutshoven Frank , Wolfgang Harder
IPC分类号： B01J23/89 , C07B61/00 , C07C209/02 , C07C209/14 , C07C209/16 , C07C209/26 , C07C211/10 , C07C211/13 , C07C213/02 , C07C215/14 , B01J23/40 , B01J23/46
CPC分类号： C07C209/16 , B01J23/8926 , B01J23/8933
摘要： A catalyst comprises, based on the total weight of the catalyst,0.1-6% by weight of cobalt, nickel or a mixture thereof,0.001-25% by weight of ruthenium,0-10% by weight of copper and0-5% by weight of promoterson a porous metal oxide carrier.It preferably comprises 0.1-3% by weight of cobalt and 0.1-3% by weight of nickel. It can be used in hydrogenation reactions, dehydrogenation reactions or hydrogenation/dehydrogenation reactions, in particular in the amination of alkylene oxides, alcohols, aldehydes or ketones with ammonia or primary or secondary amines.

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