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21. 发明授权

US5182024A Separation of hydrocarbon dewaxing and deasphalting solvents from dewaxed and/or deasphalted oil using interfacially polymerized membrane 失效
标题翻译：使用界面聚合膜从脱蜡和/或去除油中分离烃类脱蜡和去除溶剂
公开(公告)号：US5182024A
公开(公告)日：1993-01-26
申请号：US622449
申请日：1990-12-05
申请人： Tan-Jen Chen
发明人： Tan-Jen Chen
IPC分类号： C10G31/09 , B01D61/02 , B01D69/12 , C10G31/11 , C10G73/10
CPC分类号： B01D61/025 , B01D69/125 , C10G31/11
摘要： Hydrocarbon solvents used or the dewaxing and/or deasphalting of oils can be recovered by the selective permeation of said solvents through an interfacially polymerized membrane under reverse osmosis conditions.

22. 发明授权

US5120900A Integrated solvent extraction/membrane extraction with retentate recycle for improved raffinate yield 失效
标题翻译：一体化溶剂萃取/膜提取具有改善回收率的回收再生
公开(公告)号：US5120900A
公开(公告)日：1992-06-09
申请号：US624807
申请日：1990-12-05
申请人： Tan-Jen Chen , James R. Sweet
发明人： Tan-Jen Chen , James R. Sweet
IPC分类号： C07B63/00 , C07C7/00 , C07C7/10 , C07C7/144 , C07C15/02 , C07C15/20 , C10G21/00 , C10G21/28 , C10G53/04
CPC分类号： C10G53/04 , C07C7/005 , C07C7/10 , C07C7/144 , C10G21/28
摘要： Raffinate yield from solvent extraction is improved when the extract phase recovered from the solvent extraction process is subjected to a membrane separation step wherein a saturates/1-ring aromatics rich retentate is produced and a 2+ ring aromatics rich permeate are produced and the saturates/1-ring aromatic rich retentate phase is recycled to the solvent extraction process.
摘要翻译：当从溶剂萃取过程中回收的提取相进行膜分离步骤时，溶剂萃取提取残油的产率得到改善，其中产生饱和/ 1-芳烃富集滞留物，产生富含2-环芳烃的渗透物，饱和物/ 将1-环芳香富集滞留相再循环至溶剂萃取过程。

23. 发明授权

US5107059A Iso/normal paraffin separation by membrane extraction 失效
标题翻译： Iso /正常石蜡分离膜提取
公开(公告)号：US5107059A
公开(公告)日：1992-04-21
申请号：US622689
申请日：1990-12-05
申请人： Tan-Jen Chen , James R. Sweet
发明人： Tan-Jen Chen , James R. Sweet
IPC分类号： C07C7/144
CPC分类号： C07C7/144
摘要： Non-normal, branched paraffins (isoparaffins) are separated from hydrocarbon feeds comprising mixtures of isoparaffins and normal paraffins by the procedure involving the steps of contacting the hydrocarbon feed with one face of a non-selective, microporous partition barrier membrane while simultaneously contacting the opposite face of said membrane, preferably in countercurrent flow, with a polar solvent. The isoparaffins in the feed selectively permeate across the porous partition barrier membrane in response to the polar solvent to the solvent side of the membrane whereby a permeate enriched in isoparaffins and a retentate of decreased isoparaffin content as compared to the feed are obtained.
摘要翻译：通过包括使烃进料与非选择性微孔隔壁隔离膜的一面接触的步骤，将包含异链烷烃和正链烷烃的混合物的非正构支链烷烃（异链烷烃）与包含异链烷烃和正链烷烃的混合物分离，同时使相反的所述膜的表面，优选以逆流流动，与极性溶剂反应。进料中的异链烷烃选择性渗透多孔分隔阻隔膜，以响应于极性溶剂到膜的溶剂侧，从而获得富含异链烷烃的渗透物和与进料相比降低的异链烷烃含量的渗余物。

24. 发明授权

US5107056A Selective separation of naphthenes from paraffins by membrane extraction 失效
标题翻译：通过膜萃取从石蜡中选择性分离环烷烃
公开(公告)号：US5107056A
公开(公告)日：1992-04-21
申请号：US622442
申请日：1990-12-05
申请人： Tan-Jen Chen , James R. Sweet
发明人： Tan-Jen Chen , James R. Sweet
IPC分类号： C07C7/144 , C10G31/11
CPC分类号： C10G31/11 , C07C7/144
摘要： Naphthenic hydrocarbons are separated from aliphatic rich hydrocarbon feeds comprising mixtures of naphthenes with paraffinic hydrocarbons by a membrane extraction process whereby the hydrocarbon feed is contacted with one face of a porous, non-selective partition barrier membrane while simultaneously contacting the other side of said membrane with a polar solvent such as ethylenediamine. The naphthenic hydrocarbon preferentially migrates through the porous membrane partition barrier in response to the polar solvent present on the permeate side of the barrier.
摘要翻译：环烷烃通过膜提取方法从包含环烷烃与链烷烃的混合物的富含脂肪烃的进料中分离，由此烃进料与多孔非选择性分隔壁隔膜的一面接触，同时使所述膜的另一侧与极性溶剂如乙二胺。响应于存在于屏障的渗透侧的极性溶剂，环烷烃优先通过多孔膜隔离屏障迁移。

25. 发明申请

US20130202522A1 "HYDROALKYLATION PROCESSES" 有权
标题翻译： “氢化方法”
公开(公告)号：US20130202522A1
公开(公告)日：2013-08-08
申请号：US13640503
申请日：2011-04-04
申请人： Tan-Jen Chen , Teng Xu , Terry Helton , Francisco M. Benitez , Charles M. Smith
发明人： Tan-Jen Chen , Teng Xu , Terry Helton , Francisco M. Benitez , Charles M. Smith
IPC分类号： C07C2/74
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/02 , C07C2523/44 , C07C2529/70 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
摘要： The invention relates to hydroalkylation processes. In the processes, a hydrogen stream comprising hydrogen and an impurity is treated to reduce the amount of the impurity in the hydrogen stream. The hydrogen is then hydroalkylated with benzene to form at least some cyclohexylbenzene. The processes also relate to treating a benzene stream comprising benzene and an impurity with an adsorbent to reduce the amount of the impurity in the benzene stream. The hydroalkylation processes described herein may be used as part of a process to make phenol.
摘要翻译：本发明涉及加氢烷基化方法。在该方法中，处理包含氢和杂质的氢气流以减少氢气流中杂质的量。然后将氢气与苯加氢烷基化以形成至少一些环己基苯。该方法还涉及用吸附剂处理包含苯和杂质的苯料流以减少苯流中杂质的量。本文所述的加氢烷基化方法可用作制备苯酚的方法的一部分。

26. 发明授权

US08178728B2 Process for producing cyclohexylbenzene 有权
标题翻译：生产环己基苯的方法
公开(公告)号：US08178728B2
公开(公告)日：2012-05-15
申请号：US12920383
申请日：2009-02-24
申请人： Jane C. Cheng , Tan-Jen Chen , Prasenjeet Ghosh
发明人： Jane C. Cheng , Tan-Jen Chen , Prasenjeet Ghosh
IPC分类号： C07C45/27 , C07C27/08 , C07C2/64 , C07C2/66
CPC分类号： B01J29/7088 , B01J21/04 , B01J23/44 , B01J29/7476 , B01J29/7676 , B01J35/0006 , B01J37/0009 , B01J2229/42 , C07C2/74 , C07C6/126 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2521/04 , C07C2521/06 , C07C2523/44 , C07C2529/74 , C07C2529/76 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted under hydroalkylation conditions with a catalyst system comprising a MCM-22 family molecular sieve and at least one hydrogenation metal. The conditions comprise a temperature of about 140° C. to about 175° C., a pressure of about 135 psig to about 175 psig (931 kPag to 1207 kPag), a hydrogen to benzene molar ratio of about 0.30 to about 0.65 and a weight hourly space velocity of benzene of about 0.26 to about 1.05 hr−1.
摘要翻译：在制备环己基苯的方法中，苯和氢在加氢烷基化条件下与包含MCM-22族分子筛和至少一种氢化金属的催化剂体系接触。条件包括约140℃至约175℃的温度，约135psig至约175psig（931kPag至1207kPag）的压力，约0.30至约0.65的氢至苯摩尔比和苯的重时空速为约0.26至约1.05小时-1。

27. 发明授权

US07910779B2 Process for producing cyclohexylbenzene 有权
标题翻译：生产环己基苯的方法
公开(公告)号：US07910779B2
公开(公告)日：2011-03-22
申请号：US12904215
申请日：2010-10-14
申请人： Tan-Jen Chen , Jane C. Cheng , Terry E. Helton , John Scott Buchanan
发明人： Tan-Jen Chen , Jane C. Cheng , Terry E. Helton , John Scott Buchanan
IPC分类号： C07C45/27 , C07C27/08 , C07C2/68 , C07C15/067
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.
摘要翻译：在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。催化剂体系具有约75-约750的酸 - 金属摩尔比。

28. 发明申请

US20110015457A1 Process for Producing Cyclohexylbenzene 有权
标题翻译：生产环己基苯的方法
公开(公告)号：US20110015457A1
公开(公告)日：2011-01-20
申请号：US12920383
申请日：2009-02-24
申请人： Jane C. Cheng , Tan-Jen Chen , Prasenjeet Ghosh
发明人： Jane C. Cheng , Tan-Jen Chen , Prasenjeet Ghosh
IPC分类号： C07C5/10
CPC分类号： B01J29/7088 , B01J21/04 , B01J23/44 , B01J29/7476 , B01J29/7676 , B01J35/0006 , B01J37/0009 , B01J2229/42 , C07C2/74 , C07C6/126 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2521/04 , C07C2521/06 , C07C2523/44 , C07C2529/74 , C07C2529/76 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted under hydroalkylation conditions with a catalyst system comprising a MCM-22 family molecular sieve and at least one hydrogenation metal. The conditions comprise a temperature of about 140° C. to about 175° C., a pressure of about 135 psig to about 175 psig (931 kPag to 1207 kPag), a hydrogen to benzene molar ratio of about 0.30 to about 0.65 and a weight hourly space velocity of benzene of about 0.26 to about 1.05 hr−1.
摘要翻译：在制备环己基苯的方法中，苯和氢在加氢烷基化条件下与包含MCM-22族分子筛和至少一种氢化金属的催化剂体系接触。条件包括约140℃至约175℃的温度，约135psig至约175psig（931kPag至1207kPag）的压力，约0.30至约0.65的氢至苯摩尔比和苯的重时空速为约0.26至约1.05小时-1。

29. 发明授权

US6080303A Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus 失效
标题翻译：沸石催化剂活性提高磷酸铝和磷
公开(公告)号：US6080303A
公开(公告)日：2000-06-27
申请号：US38649
申请日：1998-03-11
申请人： Guang Cao , Luc R. M. Martens , Jeffrey L. White , Tan-Jen Chen , Matu J. Shah
发明人： Guang Cao , Luc R. M. Martens , Jeffrey L. White , Tan-Jen Chen , Matu J. Shah
IPC分类号： B01J29/84 , B01J27/16 , B01J29/06 , C10G11/05 , C10G11/18
CPC分类号： C10G11/05 , B01J27/16 , B01J29/06
摘要： The present invention provides a process for improving the catalytic activity of small and medium pore acidic zeolite catalyst which comprises the steps of treating a zeolite with a phosphorus compound to form a phosphorus treated zeolite and combining the phosphorus treated zeolite with AlPO.sub.4. Optionally the phosphorus treated zeolite is calcined. The step of combining the zeolite with AlPO.sub.4 may optionally be followed by steaming the combined catalyst. Examples of useful phosphorus containing compounds useful in treating the zeolite include phosphoric acid, ammonium mono or dihydrogen phosphate, organic phosphites, and organophosphines. Preferably the phosphorus containing compound is an ammonium acid phosphate. An additional alternate embodiment provides a process for increasing the hydrothermal stability of a zeolite catalyst which comprises first treating a zeolite with a phosphorus containing compound then blending with AlPO.sub.4. The catalyst of the invention may be combined with other catalysts or used alone. The invention may be used in a process for cracking hydrocarbons which comprises contacting a hydrocarbon feedstock with a catalyst prepared as described above.
摘要翻译：本发明提供了改善中孔酸性沸石催化剂的催化活性的方法，其包括用磷化合物处理沸石以形成磷处理的沸石并将磷处理的沸石与AlPO 4组合的步骤。任选地，将经磷处理的沸石煅烧。将沸石与AlPO 4组合的步骤可以任选地随后蒸合组合的催化剂。可用于处理沸石的含磷化合物的实例包括磷酸，磷酸一铵或二磷酸酯，有机亚磷酸酯和有机膦。含磷化合物优选为磷酸铵。另外的替代实施方案提供了一种提高沸石催化剂的水热稳定性的方法，其包括首先用含磷化合物处理沸石，然后与AlPO 4共混。本发明的催化剂可与其它催化剂组合使用或单独使用。本发明可用于裂解烃的方法，其包括使烃原料与如上所述制备的催化剂接触。

30. 发明授权

US5284574A Improved integrated coking-gasification process with mitigation of slagging 失效
标题翻译：改进了整体焦化气化过程，减少了结渣
公开(公告)号：US5284574A
公开(公告)日：1994-02-08
申请号：US851037
申请日：1992-03-12
申请人： Tan-Jen Chen , Paul E. Eberly, Jr. , Francis X. Mayer
发明人： Tan-Jen Chen , Paul E. Eberly, Jr. , Francis X. Mayer
IPC分类号： C10G9/32 , C10G9/28
CPC分类号： C10G9/32
摘要： A fluid coking-gasification process for converting heavy hydrocarbonaceous chargestocks to lower boiling products in which an inorganic metal composition is used to mitigate slagging in the gasifier, wherein the metal is selected from the alkaline-earths, the rare earths, and zirconium. The inorganic metal composition is added either directly into the gasifier or it is mixed with the coke passing from the heating zone to the gasification zone.
摘要翻译：一种用于将重质含烃物料转化为较低沸点产物的流化焦化气化方法，其中使用无机金属组合物来减轻气化器中的结渣，其中金属选自碱土金属，稀土和锆。将无机金属组合物直接加入到气化器中，或者将其与通过加热区的焦炭混合到气化区。

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