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21. 发明授权

US4433138A Process for the preparation of polyarylene sulphides 失效
标题翻译：聚亚芳基硫醚的制备方法
公开(公告)号：US4433138A
公开(公告)日：1984-02-21
申请号：US379036
申请日：1982-05-17
申请人： Karsten Idel , Dieter Freitag , Ludwig Bottenbruch , Otto Neuner
发明人： Karsten Idel , Dieter Freitag , Ludwig Bottenbruch , Otto Neuner
IPC分类号： C08G75/02 , C08G75/06 , C08G75/14
CPC分类号： C08G75/0254 , C08G75/0231
摘要： High molecular weight p-polyarylensulfides having a high melt viscosity, capable of being processed thermoplastically, and have good mechanical properties are produced by reacting components (a), (b), and (c) in a polar solvent with a molar ratio of (a):(c) in the range of 0.85:1 to 1.15:1 and a molar ratio of (c): solvent in the range of 1:2 to 1:15, for a time of up to 10 hours at a temperature of from 160.degree. C. to 300.degree. C., and in the presence of from 2 to 100 mole percent, relative to (c), of an N,N-dialkylcarboxamide;wherein component (a) is dihalogenobenzene with 50 to 100 mole percent of the formula ##STR1## and 0 to 50 mole percent of the formula ##STR2## wherein X is fluoro, chloro, bromo or iodo, and R is the same or different and each is selected from the group consisting of hydrogen, alkyl having 1 to 20 carbon atoms, cycloalkyl having 5 to 20 carbon atoms, aryl having 6 to 24 carbon atoms, alkaryl having 7 to 24 carbon atoms, aralkyl having 7 to 24 carbon atoms, and two R moieties linked together forming aryl having 6 to 24 carbon atoms or a heterocyclic moiety having an oxygen, nitrogen or sulphur hetero-atom and having 6 to 24 carbon atoms; with the proviso that at least one R is not hydrogen;component (b) is 0.1 to 2.4 mole percent, relative to the dihalogenobenzene, of a polyhalogenoaromatic of the formulaArX.sub.nwherein Ar is aryl or a heterocyclic moiety having an oxygen, nitrogen or sulphur heteroatom with said aryl and said heterocyclic each having from 6 to 24 carbon atoms;X is fluoro, chloro, bromo or iodo; andn is 3 or 4;and component (c) is alkali metal sulphide.
摘要翻译：通过使组分（a），（b）和（c）在极性溶剂中以摩尔比为（（a），（b）和（c））反应，可以通过热塑性地热处理和具有良好的机械性能而具有高熔体粘度的高分子量对聚芳基硫化物 a）：（c）在0.85:1至1.15:1的范围内，（c）：溶剂的摩尔比在1:2至1:15的范围内，在温度下达10小时相对于（c）为2〜100摩尔％的N，N-二烷基甲酰胺; 其中组分（a）是二卤代苯，其具有50-100摩尔％的式“IMAGE”和0至50摩尔％的式“IMAGE”，其中X是氟，氯，溴或碘，R是相同或不同的，各自选自氢，具有1至20个碳原子的烷基，具有5至20个碳原子的环烷基，具有6至24个碳原子的芳基，具有7至24个碳原子的烷芳基，具有7至24个碳原子的芳烷基，和两个连接在一起的R部分形成具有6至24个碳原子的芳基或具有氧，氮或硫杂原子并具有6至24个碳原子的杂环部分; 条件是至少一个R不是氢; 组分（b）相对于二卤代苯，为式ArXn的多卤代芳族化合物的0.1至2.4摩尔％，其中Ar为芳基或具有氧，氮或硫杂原子的杂环部分，所述芳基和所述杂环各自具有6至 24个碳原子; X是氟，氯，溴或碘; n为3或4; 组分（c）是碱金属硫化物。

22. 发明授权

US4424339A Process for the preparation of polyarylene sulphides 失效
标题翻译：聚亚芳基硫醚的制备方法
公开(公告)号：US4424339A
公开(公告)日：1984-01-03
申请号：US417048
申请日：1982-09-13
申请人： Karsten Idel , Edgar Ostlinning , Dieter Freitag , Ludwig Bottenbruch
发明人： Karsten Idel , Edgar Ostlinning , Dieter Freitag , Ludwig Bottenbruch
IPC分类号： C08G75/02 , C08G75/14
CPC分类号： C08G75/0254 , C08G75/0231
摘要： Process for preparing polyarylensulfides by reacting dihalogenobenzenes, optionally substituted with polyhalogenoaromatic compounds with 3 or 4 halogeno substituents, and alkali metal sulfide in polar solvents using alkali metal sulfites and/or alkaline earth metal sulfites as catalysts.
摘要翻译：通过使用碱金属亚硫酸盐和/或碱土金属亚硫酸盐作为催化剂，将极性溶剂中任选被多卤代芳族化合物与3或4个卤代取代基取代的二卤代苯和碱金属硫化物反应来制备聚芳基硫化物的方法。

23. 发明授权

US5288848A Process for preparation of high molecular weight, optionally branched polyarylene sulphides 失效
标题翻译：制备高分子量，任意支化聚亚芳基硫化物的方法
公开(公告)号：US5288848A
公开(公告)日：1994-02-22
申请号：US978174
申请日：1992-11-17
申请人： Karsten Idel , Wolfgang Ebert , Ludwig Bottenbruch , Dieter Freitag , Rolf-Volker Meyer
发明人： Karsten Idel , Wolfgang Ebert , Ludwig Bottenbruch , Dieter Freitag , Rolf-Volker Meyer
IPC分类号： C08G75/02 , C08G75/14
CPC分类号： C08G75/0231 , C08G75/0254
摘要： The invention relates to a process for the preparation of optionally branched, high molecular weight polyarylene sulphides with melt viscosities which can be established at defined values and low corrosion.These polyarylene sulphides are obtained by reacting alkali metal sulphides, if appropriate mixed with alkali metal bisulphides and reaction accelerators, with dihalogenoaromatics and, if appropriate, polyhalogenoaromatics, with the addition of particular monohalogenoaromatics as chain stoppers.
摘要翻译：本发明涉及一种制备任选支化的高分子量聚亚芳基硫醚的方法，其熔融粘度可以在确定的值和低腐蚀下确定。这些聚亚芳基硫化物是通过使碱金属硫化物（如果适用的话）与碱金属二硫化物和反应促进剂混合，与二卤代芳族化合物反应，如果合适的话，通过加入特定的一卤代芳族化合物作为连锁停止剂。

24. 发明授权

US4600764A Thermotropic aromatic polyesters with good rigidity and toughness, process for the production thereof and the use thereof for the production of mouldings, filaments fibres and films 失效
标题翻译：具有良好刚性和韧性的热致变性芳族聚酯，其生产方法及其用于生产模制品，长丝纤维和薄膜的用途
公开(公告)号：US4600764A
公开(公告)日：1986-07-15
申请号：US723268
申请日：1985-04-15
申请人： Hans-Rudolf Dicke , Ludwig Bottenbruch , Dieter Freitag , Aziz E. Sayed
发明人： Hans-Rudolf Dicke , Ludwig Bottenbruch , Dieter Freitag , Aziz E. Sayed
IPC分类号： C08G63/00 , C08G63/60
CPC分类号： C08G63/605
摘要： Thermotropic fully-aromatic polyesters which contain radicals of 3,4'- and/or 4,4'-dihydroxybenzophenone in addition to radicals of p-hydroxybenzoic acid, iso- and optionally terephthalic acid, hydroquinone and/or 4,4'-dihydroxydiphenyl, have good rigidity and toughness and yet are easily processible.
摘要翻译：除了对羟基苯甲酸，异 - 和任选的对苯二甲酸，氢醌和/或4,4'-二羟基二苯基的基团之外，还含有3,4'-和/或4,4'-二羟基二苯甲酮基团的热致全芳族聚酯具有良好的刚性和韧性，并且易于加工。

25. 发明授权

US4600753A Two stage process for the production of aromatic polyester-carbonate 失效
标题翻译：二阶段生产芳香族聚碳酸酯工艺
公开(公告)号：US4600753A
公开(公告)日：1986-07-15
申请号：US680156
申请日：1984-12-10
申请人： Dieter Freitag , Claus H. Wulff , Gerhard Henes , Ludwig Bottenbruch , Peter Tacke
发明人： Dieter Freitag , Claus H. Wulff , Gerhard Henes , Ludwig Bottenbruch , Peter Tacke
IPC分类号： C08G63/00 , C08G63/64
CPC分类号： C08G63/64
摘要： The invention relates to a process for the preparation of aromatic polyester-carbonates wherein, in a first stage, aromatic oligo-esters or oligo-ester-carbonates having hydroxyl end groups are prepared from diaryl esters of aromatic dicarboxylic acids (or their starting materials) and diphenols and, optionally, a diaryl carbonate, by trans-esterification in the melt, and in a second stage these oligo-esters or oligo-ester-carbonates are condensed with phosgene by the phase boundary process to give the polyester-carbonate.
摘要翻译：本发明涉及一种制备芳族聚酯 - 碳酸酯的方法，其中在第一阶段中，由芳族二羧酸（或它们的起始原料）的二芳基酯制备具有羟基端基的芳族低聚酯或低聚酯 - 碳酸酯，和二醇和任选的碳酸二芳基酯，并且在第二阶段中，这些低聚酯或低聚酯 - 碳酸酯通过相界过程与光气缩合，得到聚酯 - 碳酸酯。

26. 发明授权

US4393009A Process for the preparation of aromatic dicarboxylic acid dichlorides 失效
标题翻译：芳族二羧酸二氯化物的制备方法
公开(公告)号：US4393009A
公开(公告)日：1983-07-12
申请号：US280898
申请日：1981-07-06
申请人： Dieter Freitag , Ludwig Bottenbruch , Claus Wulff
发明人： Dieter Freitag , Ludwig Bottenbruch , Claus Wulff
IPC分类号： C07C63/15 , B01J31/00 , B01J31/02 , C07B61/00 , C07C51/00 , C07C51/60 , C07C63/33 , C07C65/21 , C07C67/00 , C07C313/00 , C07C323/62
CPC分类号： B01J31/0237 , B01J31/0247 , C07C51/60
摘要： Process for the preparation of pure aromatic dicarboxylic acid dichlorides which comprises reacting an aromatic dicarboxylic acid or an aromatic dicarboxylic acid mixture with phosgen in one stage and in the presence of an N--C.sub.1 --C.sub.6 -alkyl-pyrrolidine, -piperidine or -morpholine as a catalyst and optionally in a solvent or diluent.
摘要翻译：制备纯芳族二羧酸二氯化物的方法，其包括将芳族二羧酸或芳族二羧酸混合物与光气在一个阶段和在N-C 1 -C 6烷基 - 吡咯烷， - 哌啶或 - 吗啉存在下反应，催化剂和任选地在溶剂或稀释剂中。

27. 发明授权

US4801677A Thermotropic aromatic polyester with high thermal stability 失效
标题翻译：具有高热稳定性的热致变芳香族聚酯
公开(公告)号：US4801677A
公开(公告)日：1989-01-31
申请号：US3586
申请日：1987-01-15
申请人： Volker Eckhardt , Hans-Rudolf Dicke , Ludwig Bottenbruch , Dieter Freitag , Ulrich Biskup
发明人： Volker Eckhardt , Hans-Rudolf Dicke , Ludwig Bottenbruch , Dieter Freitag , Ulrich Biskup
IPC分类号： C08G63/00 , C08G63/18 , C08G63/193 , C08G63/199
CPC分类号： C08G63/193
摘要： Thermotropic aromatic polyesters which contain condensed radicals of bis-.alpha., .omega.-(4-hydroxyphenyl)-n-alkanes, have high dimensional stability under heat and at the same time high thermal stability. They can be processed thermoplastically at temperatures below 370.degree. C.
摘要翻译：含有双-α，ω-（4-羟基苯基） - 正烷烃的缩合基团的热致芳香族聚酯在加热下具有高尺寸稳定性，同时具有高的热稳定性。它们可以在低于370℃的温度下热塑性地加工

28. 发明授权

US4334053A Process for the preparation of aromatic polyesters and the use thereof for the production of injection molded articles, films and coatings 失效
标题翻译：制备芳族聚酯的方法及其用于生产注塑制品，薄膜和涂料的用途
公开(公告)号：US4334053A
公开(公告)日：1982-06-08
申请号：US191670
申请日：1980-09-29
申请人： Dieter Freitag , Klaus Reinking , Karsten Idel , Harald Medem , Ludwig Bottenbruch
发明人： Dieter Freitag , Klaus Reinking , Karsten Idel , Harald Medem , Ludwig Bottenbruch
IPC分类号： C08G63/00 , C08G63/12 , C08G63/19 , C08G63/20 , C09D167/00 , C08F4/46
CPC分类号： C08G63/20
摘要： Aromatic polyesters based on diphenols, terephthalic and isophthalic acid and particular chain terminators exhibit an improved color number, an improved flowability and increased dimensional heat stability with otherwise comparable mechanical characteristics.
摘要翻译：基于二酚，对苯二甲酸和间苯二甲酸和特定的链终止剂的芳族聚酯表现出改进的颜色数量，改进的流动性和增加的尺寸热稳定性以及可比较的机械特性。

29. 发明授权

US5032661A Thermoplastic polyester-carbonate/polysiloxane block copolymers 失效
标题翻译：热塑性聚酯 - 碳酸酯/聚硅氧烷嵌段共聚物
公开(公告)号：US5032661A
公开(公告)日：1991-07-16
申请号：US428837
申请日：1989-10-30
申请人： Volker Serini , Werner Nouvertne , Ulrich Grigo , Winfried Paul , Dieter Freitag
发明人： Volker Serini , Werner Nouvertne , Ulrich Grigo , Winfried Paul , Dieter Freitag
IPC分类号： C08G77/445 , C08G63/64 , C08G63/68 , C08G64/18 , C08G77/42 , C08G77/448
CPC分类号： C08G77/448 , C08G63/64 , C08G64/186
摘要： Polyester-carbonate/polysiloxane block copolymers containing the following recurring structural units: ##STR1## wherein the structural units (1) comprise at least 75 wt.% of the sum of the structural units (1) and (2), exhibit better low temperature tough fracture properties than the known polyester-carbonate/polysiloxane block copolymers containing comparable recurring structural units on comparison of polyester-carbonate/polysiloxane block copolymers of the same heat resistance.
摘要翻译：包含以下重复结构单元的聚酯 - 碳酸酯/聚硅氧烷嵌段共聚物：其中结构单元（1）包含至少75 与聚酯 - 碳酸酯/聚硅氧烷嵌段共聚物比较，含有比较重复结构单元的已知聚酯 - 碳酸酯/聚硅氧烷嵌段共聚物，结构单元（1）和（2）之和的重量％显示出更好的低温韧性断裂性能具有相同的耐热性。

30. 发明授权

US4269964A Polycarbonates with alkylphenyl end groups, their preparation and their use 失效
标题翻译：具有烷基苯基端基的聚碳酸酯，其制备及其用途
公开(公告)号：US4269964A
公开(公告)日：1981-05-26
申请号：US75439
申请日：1979-09-14
申请人： Dieter Freitag , Werner Nouvertne , Claus Burkhardt , Frank Kleiner
发明人： Dieter Freitag , Werner Nouvertne , Claus Burkhardt , Frank Kleiner
IPC分类号： C08G63/00 , C08G64/00 , C08G64/04 , C08G64/14 , C08G64/20 , C08G8/28
CPC分类号： C08G64/14
摘要： This development is concerned with aromatic thermoplastic polycarbonates with special chain terminators which give the polymers enhanced hydrolysis resistance and impact toughness. These chain terminators are alkyl substituted monohydroxy phenyls in which each phenyl is substituted by one alkyl group having 8 or 9 carbon atoms and about 47 to 89% of its hydrogen atoms trisubstituted on carbon atoms with up to about 20% of the substituents in the ortho position and the balance at the para position. This development is also concerned with a process for synthesizing such polymers by using such chain terminators as reactants in generically known synthesis methods for polycarbonates.
摘要翻译：这种发展涉及具有特殊链终止剂的芳族热塑性聚碳酸酯，其赋予聚合物增强的耐水解性和冲击韧性。这些链终止剂是烷基取代的单羟基苯基，其中每个苯基被一个具有8或9个碳原子的烷基取代，并且其在碳原子上三取代的氢原子的约47-89％，在邻位上具有高达约20％的取代基。位置和对位的余额。这种发展也涉及通过使用这种链终止剂作为一般已知的聚碳酸酯合成方法中的反应物合成这种聚合物的方法。

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