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21. 发明授权

US4720301A Reversible heat sensitive recording composition 失效
标题翻译：可逆热敏记录组合物
公开(公告)号：US4720301A
公开(公告)日：1988-01-19
申请号：US807908
申请日：1985-12-11
申请人： Tsutomu Kito , Norikazu Nakasuji , Takashi Kataoka , Hiroshi Inagaki , Yutaka Shibahashi
发明人： Tsutomu Kito , Norikazu Nakasuji , Takashi Kataoka , Hiroshi Inagaki , Yutaka Shibahashi
IPC分类号： B41M5/323 , B41M5/30 , B41M5/333 , B41M5/337 , C09D11/00
CPC分类号： B41M5/305 , B41M5/3333 , B41M5/3335 , B41M5/3375
摘要： A new reversible heat sensitive recording composition for erasable recording is disclosed which is used as a recording or marking material that is capable of erasure at a specific temperature so that coloring or decoloring can be controlled to occur at desired temperature ranges. This range or the hysteresis value of the composition is determined by the .DELTA.T value of the contained ester compound. In addition, the composition can provide a wide variety of hues and can readily be prepared. The marking or recording drawn in this composition can be maintained at room temperature or less.
摘要翻译：公开了一种用于可擦除记录的新的可逆热敏记录组合物，其用作能够在特定温度下擦除的记录或标记材料，从而可以控制在所需温度范围内发生着色或脱色。组合物的该范围或滞后值由所含酯化合物的DELTA T值确定。此外，组合物可以提供多种色调并且可以容易地制备。在该组合物中绘制的标记或记录可以保持在室温或更低。

22. 发明授权

US4681791A Thermochromic textile material 失效
标题翻译：热变色纺织材料
公开(公告)号：US4681791A
公开(公告)日：1987-07-21
申请号：US824039
申请日：1986-01-30
申请人： Yutaka Shibahashi , Norikazu Nakasuji , Takashi Kataoka , Hiroshi Inagaki , Tutomu Kito , Masaharu Ozaki , Nobuaki Matunami , Naoya Ishimura , Katuyuki Fujita
发明人： Yutaka Shibahashi , Norikazu Nakasuji , Takashi Kataoka , Hiroshi Inagaki , Tutomu Kito , Masaharu Ozaki , Nobuaki Matunami , Naoya Ishimura , Katuyuki Fujita
IPC分类号： B41M5/28 , D05C17/00 , D06N7/04 , D06N7/06 , D06P1/00 , D06P1/44 , G01K11/16 , C09D11/06 , C09D11/12
CPC分类号： G01K11/16 , B41M5/287 , D05C17/00 , D06P1/004 , D06P1/44 , Y10S428/913 , Y10T428/23986 , Y10T428/2481 , Y10T428/24901 , Y10T428/2927 , Y10T442/3049 , Y10T442/425 , Y10T442/603
摘要： A textile material in the form of fiber, raw stock, yarn or fabric, which comprises fibers each of which is coated with a thermochromic layer containing a thermochromic pigment having a particle size satisfying the formula: ##EQU1## wherein r represents a particle size of a pigment; D represents fineness (denier) of a fiber; and d represents a density (g/cm.sup.3) of a fiber. The textile material can undergo reversible color change in a wide variety of colors and can be applied to any kind of textile products.
摘要翻译：纤维，原料，纱线或织物形式的纺织材料，其包含纤维，每个纤维均涂有含有具有满足下列通式的粒度的热变色颜料的热致变色层：其中r表示颜料; D表示纤维的细度（旦数）; d表示纤维的密度（g / cm 3）。纺织材料可以以各种颜色经历可逆的颜色变化，并且可以应用于任何种类的纺织品。

23. 发明授权

US06713431B2 Metallic luster tone thermochromic laminate member 有权
标题翻译：金属色泽热变色层压件
公开(公告)号：US06713431B2
公开(公告)日：2004-03-30
申请号：US10179393
申请日：2002-06-26
申请人： Michiyuki Yasuda , Yutaka Shibahashi
发明人： Michiyuki Yasuda , Yutaka Shibahashi
IPC分类号： B41M540
CPC分类号： B41M5/305 , B41M5/41
摘要： A metallic luster tone thermochromic laminate member 1, which comprises a laminate of a metallic luster layer 2 containing a metallic luster pigment prepared by coating the surface of a synthetic mica or thin section aluminum oxide with a metal oxide and a reversible thermochromic layer 3 containing a thermochromic composition comprising an electron-donating color-forming organic compound, an electron-accepting compound and an organic compound medium in which color reactions of both compounds take place reversibly. The metallic luster tone thermochromic laminate member can visualize metallic luster colors having glittering high brightness and distinct changes in color by its reversible thermochromic layer so that it can be used in versatile applications and developments.
摘要翻译：一种金属光泽热致变色层压件1，其包括金属光泽层2的层压材料，该金属光泽层2含有通过将金属氧化物涂覆合成云母或薄壁氧化铝的表面制备的金属光泽颜料和可逆热致变色层3，包含给电子成色有机化合物，电子接受性化合物和两种化合物的显色反应可逆地发生的有机化合物介质的热变色组合物。金属色泽热变色层压件可以通过其可逆热变色层来显现具有闪烁的高亮度和明显的颜色变化的金属光泽颜色，从而可以用于通用的应用和开发。

24. 发明授权

US5558699A Thermochromic color-memory composition 失效
标题翻译：热变色色记忆组合物
公开(公告)号：US5558699A
公开(公告)日：1996-09-24
申请号：US362984
申请日：1994-12-23
申请人： Akio Nakashima , Yutaka Shibahashi
发明人： Akio Nakashima , Yutaka Shibahashi
IPC分类号： B41M5/30 , C09D5/26 , C09D11/00
CPC分类号： C09D11/50 , B41M5/305 , C09D5/26 , Y10S428/913 , Y10T428/2984
摘要： A thermochromic color-memory compositions exhibiting high color contrast between high color density in a colored state and sufficiently low color density in a decolored state with high freedom of selection of the reaction medium, and highly useful as a thermochromic material. The thermochromic color-memory composition comprises a homogeneous solubilized mixture of essential three components of (a) an electron-donating color-developing organic compound, (b) an electron-accepting compound, and (c) a reaction medium for controlling a color reaction of the component (a) with the component (b); the component (c) being selected from aliphatic ketones of 10 to 22 total carbons and aryl alkyl ketones of 12 to 24 total carbons; and the composition changing the color thereof with a large hysteresis width (.DELTA.H) of from 8.degree. C. to 80.degree. C.
摘要翻译：一种热色变色记忆组合物，在着色状态下具有高色密度和脱色状态下具有足够低色密度的高颜色对比度，具有高自由度的选择反应介质，并且作为热变色材料非常有用。热变色色记忆组合物包含（a）给电子显色有机化合物，（b）电子接受性化合物，（c）用于控制着色反应的反应介质的必要三组分的均匀溶解混合物的组分（a）与组分（b）反应; 组分（c）选自10至22个总碳的脂族酮和12至24个总碳的芳基烷基酮; 并且组合物以大的滞后宽度（DELTA H）为8℃至80℃改变其颜色。

25. 发明授权

US5352649A Thermochromic laminate member, and composition and sheet for producing the same 失效
标题翻译：热变色层压构件，及其制造用组合物和片材
公开(公告)号：US5352649A
公开(公告)日：1994-10-04
申请号：US907577
申请日：1992-07-02
申请人： Yutaka Shibahashi , Michiyuki Yasuda
发明人： Yutaka Shibahashi , Michiyuki Yasuda
IPC分类号： A61K8/02 , A61Q3/00 , B41M3/14 , B41M5/26 , B41M5/28 , B41M5/40 , B41M5/42 , B44F1/08 , D06M23/00 , D06P1/00 , D06Q1/00 , D06Q1/10
CPC分类号： A61Q3/00 , A61K8/02 , B41M3/142 , B41M5/282 , B41M5/426 , B44F1/08 , D06M23/00 , D06P1/0096 , D06Q1/00 , D06Q1/10 , A61K2800/438 , A63F2250/1031 , H01H2209/0021 , Y10S428/913 , Y10T428/251 , Y10T428/2991
摘要： A thermochromic laminate member capable of reversible change from a metallic luster color to a colorless state, comprises a first layer for regulating the wavelength of reflected light, composed of a metal luster pigment, which consists of natural mica surfacially covered with titanium oxide and has a grain size of 5 to 100 .mu.m, and a film forming material; anda second layer composed of a thermochromic material, which consists of an electron donating compound, an electron accepting compound, and an organic medium enabling a reversible color-forming reaction between said compounds and has a luminocity value of 6 or lower in the colored state and a luminocity value of 8 or higher in the colorless state, and a film forming material.
摘要翻译：能够从金属光泽颜色变为无色状态的热致变色层压构件包括由金属光泽颜料构成的用于调节反射光的波长的第一层，该金属光泽颜料由表面覆盖有氧化钛的天然云母组成，并具有晶粒尺寸为5〜100μm，成膜材料为以及由电致发光化合物，电子接受性化合物和能够在所述化合物之间进行可逆成色反应的有机介质构成的热致变色材料构成的第二层，并且在着色状态下具有6以下的发光度值无色状态下的亮度值为8以上，成膜材料。

26. 发明授权

US5011445A Color memory toy set 失效
标题翻译：彩色记忆玩具套装
公开(公告)号：US5011445A
公开(公告)日：1991-04-30
申请号：US476941
申请日：1990-02-08
申请人： Norikazu Nakasuji , Tsutomu Kito , Yutaka Shibahashi
发明人： Norikazu Nakasuji , Tsutomu Kito , Yutaka Shibahashi
IPC分类号： B43K8/00 , A63H33/22 , B41M5/28 , B43K19/08 , B43K29/00
CPC分类号： B41M5/284 , A63H33/22 , A63F2250/1031 , Y10S428/913 , Y10S430/114
摘要： A color memory toy set has a color memory toy with surface, at least one portion of the surface being provided with a color memory temperature-sensitive color changing layer colored with a coloring material including a color memory temperature-sensitive dye exhibiting hysteresis characteristics in response to temperature change between a colored state and a colorless state or between a color (I) state and a color (II) state. The toy set also includes a writing pen for either causing an image to appear or disappear on the color memory temperature-sensitive layer by drawing the image on the layer to change the color state of the drawn portion into a first state, or for causing an image to appear or disappear on the color memory temperature-sensitive layer by drawing the image on the layer to change the color state of the drawn portion to a second state.

27. 发明授权

US4865648A Reversible heat sensitive recording composition 失效
标题翻译：可逆热敏记录组合物
公开(公告)号：US4865648A
公开(公告)日：1989-09-12
申请号：US101098
申请日：1987-09-25
申请人： Tsutomu Kito , Norikazu Nakasuji , Takashi Kataoka , Hiroshi Inagaki , Yutaka Shibahashi
发明人： Tsutomu Kito , Norikazu Nakasuji , Takashi Kataoka , Hiroshi Inagaki , Yutaka Shibahashi
IPC分类号： B41M5/30 , B41M5/333 , B41M5/337
CPC分类号： B41M5/305 , B41M5/3333 , B41M5/3335 , B41M5/3375 , Y10T428/2984 , Y10T428/2989
摘要： A new reversible heat sensitive recording composition for erasable recording is disclosed which is used as a recording or marking material that is capable of erasure at a specific temperature so that coloring or decoloring can be controlled to occur at desired temperature ranges. This range or the hysteresis value of the composition is determined by the .DELTA.T value of the contained ester compound. In addition, the compostion can provide a wide variety of hues and can readily be prepared. The marking or recording drawn in this composition can be maintained at room temperature or less.
摘要翻译：公开了一种用于可擦除记录的新的可逆热敏记录组合物，其用作能够在特定温度下擦除的记录或标记材料，从而可以控制在所需温度范围内发生着色或脱色。组合物的该范围或滞后值由所含酯化合物的DELTA T值确定。此外，组合物可以提供各种色调并且可以容易地准备。在该组合物中绘制的标记或记录可以保持在室温或更低。

28. 发明授权

US4732810A Reversible temperature-indicating composition 失效
标题翻译：可逆温度指示组成
公开(公告)号：US4732810A
公开(公告)日：1988-03-22
申请号：US812572
申请日：1985-12-23
申请人： Tsutomu Kito , Norikazu Nakasuji , Takashi Kataoka , Hiroshi Inagaki , Yutaka Shibahashi , Nobuaki Matsunami
发明人： Tsutomu Kito , Norikazu Nakasuji , Takashi Kataoka , Hiroshi Inagaki , Yutaka Shibahashi , Nobuaki Matsunami
IPC分类号： C09K9/02 , B41M5/124 , G01K11/12 , G01K11/16 , B01J13/02
CPC分类号： G01K11/16 , B41M5/305 , Y10S252/962 , Y10T428/2984
摘要： A new reversible temperature indicating composition for use in temperature indicating instruments is diclosed which is capable of accurate temperature indication in a variety of colors and characterized by a minimum range of hysteresis so that the marking drawn in this composition can decolor at or close the temperature at which its coloring takes place. In addition, the composition can provide a wide variety of hues and can be readily prepared. These and other advantages are provided by the inclusion as a main ingredient of an ester compound having .DELTA.T value, defined .DELTA.T=melting point--clouding point, in the range under 3.degree. C., the value that determines a desirably small range of hysteresis.
摘要翻译：一种用于温度指示仪器的新型可逆温度指示组合物被封闭，其能够以各种颜色精确地进行温度指示，其特征在于最小滞后范围，使得在该组合物中绘制的标记可以在或接近温度它的着色发生。此外，组合物可以提供多种色调并且可以容易地制备。这些和其它优点通过包含作为主要成分的具有在3℃范围内具有DELTA T值，定义为ΔTA=熔点 - 浊点的酯化合物的主要成分，该值确定期望的小范围迟滞

29. 发明授权

US4425161A Thermochromic materials 失效
标题翻译：热变色材料
公开(公告)号：US4425161A
公开(公告)日：1984-01-10
申请号：US324701
申请日：1981-11-24
申请人： Yutaka Shibahashi , Norikazu Nakasuji , Takashi Kataoka , Hiroshi Inagaki , Tsutomu Kito
发明人： Yutaka Shibahashi , Norikazu Nakasuji , Takashi Kataoka , Hiroshi Inagaki , Tsutomu Kito
IPC分类号： C09K9/02 , B41M5/28 , B41M5/323 , B44F1/12 , C09D5/26 , C09D11/00
CPC分类号： C09D11/50 , B41M5/282 , C09D5/26 , B41M5/305
摘要： A thermochromic material is described which comprises (a) an electron-donating, chromatic organic compound, (b) a compound capable of reversibly accepting an electron or electrons from the electron-donating, chromatic organic compound, (c) a compound controlling the temperature and sensitivity of coloration/decoloration of the thermochromic material and (d) a N-radical, P-radical, O-radical or S-radical cationic compound having an aromatic ring or rings which improves by light-fastness.
摘要翻译：描述了一种热致变色材料，其包括（a）给电子，有色有机化合物，（b）能够从给电子的有机化合物中可逆地接受电子或电子的化合物，（c）控制温度的化合物和热变色材料的着色/脱色的敏感性和（d）具有通过耐光性改善的芳香环或环的N-自由基，P-自由基，O-自由基或S-自由基阳离子化合物。

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