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21. 发明授权

US07087691B2 Photo-imageable compositions of norbornene and acrylate copolymers and use thereof 失效
标题翻译：降冰片烯和丙烯酸酯共聚物的可光成像组合物及其用途
公开(公告)号：US07087691B2
公开(公告)日：2006-08-08
申请号：US10614502
申请日：2003-07-07
申请人： Larry F. Rhodes , Larry Seger , Ayusman Sen , April Hennis Marchetti
发明人： Larry F. Rhodes , Larry Seger , Ayusman Sen , April Hennis Marchetti
IPC分类号： G03C1/492
CPC分类号： C08F32/08 , C08F4/80 , C08F20/12 , C08F232/08 , C08G61/08 , C08F2220/1825 , C08F220/14
摘要： Embodiments in accordance with the present invention encompass photo-imageable compositions that include polymers of acrylate-type monomers and norbornene-type monomers. In some embodiments a catalyst system comprising a cationic or a neutral Pd(II) dimer component having the formula (Allyl)Pd(P(R21)3) or (L′)[(L)Pd(R)(X)]2, respectively is employed to effect polymerization. In other embodiments a free radical or living free radical catalyst is employed to effect polymerization. At least one of the acrylate-type monomers and norbornene-type monomers of the polymer embodiments of the present invention encompass an acid labile moiety. Some polymer embodiments of the present invention include more than one type of acrylate-type monomer and norbornene-type monomer. Embodiments of the present invention include forming a patterned layer on a substrate and some embodiments include transferring the patterned structure to a material layer first formed on the substrate.
摘要翻译：根据本发明的实施方案包括可包含丙烯酸酯类单体和降冰片烯型单体的聚合物的光可成像组合物。在一些实施方案中，包含具有式（烯丙基）Pd（P（R 21）3））的阳离子或中性Pd（II）二聚体组分的催化剂体系或（L '）[（L）Pd（R）（X）] 2 N 2分别用于进行聚合。在其它实施方案中，使用自由基或活性自由基催化剂来进行聚合。本发明的聚合物实施方案中的至少一种丙烯酸酯类单体和降冰片烯型单体包括酸不稳定部分。本发明的一些聚合物实施方案包括多于一种类型的丙烯酸酯型单体和降冰片烯型单体。本发明的实施例包括在衬底上形成图案化层，并且一些实施例包括将图案化结构转移到首先形成在衬底上的材料层。

22. 发明授权

US06649707B1 Blends and alloys of polycyclic polymers 失效
标题翻译：多环聚合物的共混物和合金
公开(公告)号：US06649707B1
公开(公告)日：2003-11-18
申请号：US09679001
申请日：2000-10-04
申请人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
发明人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
IPC分类号： C08G7704
CPC分类号： C08G77/442 , C08F232/08 , C08F277/00 , C08L53/025 , C08L2666/04
摘要： Polycyclic addition polymers derived from norbornene-type monomers are mixed with a variety of other polymers to generate families of new blends, alloys, and block copolymers.
摘要翻译：衍生自降冰片烯型单体的多环加成聚合物与各种其它聚合物混合以产生新的共混物，合金和嵌段共聚物的族。

23. 发明授权

US4923936A Heteropolymetallate metathesis catalysts for cycloolefin polymerization 失效
标题翻译：用于环烯烃聚合的杂多金属复分解催化剂
公开(公告)号：US4923936A
公开(公告)日：1990-05-08
申请号：US312150
申请日：1989-02-21
申请人： Brian L. Goodall , Larry F. Rhodes
发明人： Brian L. Goodall , Larry F. Rhodes
IPC分类号： B01J31/02 , B01J31/14 , B01J31/18 , C08F4/78 , C08G61/06 , C08G61/08
CPC分类号： C08G61/08 , B01J31/0239 , B01J31/0268 , B01J31/143
摘要： This invention pertains to the use of organoammonium, organophosphonium, organoarsonium heteropolymolybdates and heteropolytungstates, and mixtures thereof, as catalysts in a metathesis catalyst system in polymerization of cycloolefin monomers by ring opening polymerization. Polymerization can be by reaction injection molding in absence of a solvent whereby a thermoset polymer is produced or by solution polymerization in presence of a suitable solvent whereby a thermosetting or a thermoplastic polymer is produced. The cycloolefin monomers are selected from monocycloolefins except cyclohexane, polycycloolefins containing at least one norbornene group, and mixtures thereof.
摘要翻译：本发明涉及有机铵，有机鏻，有机砷杂多钼酸盐和杂多钨酸盐及其混合物作为复分解催化剂体系中的环烯烃单体通过开环聚合反应的催化剂。可以通过在不存在溶剂的情况下通过反应注射成型聚合，由此制备热固性聚合物，或者通过在合适的溶剂存在下通过溶液聚合制备热固性或热塑性聚合物。环烯烃单体选自除环己烷以外的单环烯烃，含有至少一个降冰片烯基团的聚环烯烃及其混合物。

24. 发明授权

US06294616B1 Blends and alloys of polycyclic polymers 失效
标题翻译：多环聚合物的共混物和合金
公开(公告)号：US06294616B1
公开(公告)日：2001-09-25
申请号：US08450648
申请日：1995-05-25
申请人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
发明人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
IPC分类号： C08F1014
CPC分类号： C08G77/442 , C08F232/08 , C08F277/00 , C08L53/025 , C08L2666/04
摘要： Polycyclic addition polymers derived from norbornene-type monomers are mixed with a variety of other polymers to generate families of new blends, alloys, and block copolymers.
摘要翻译：衍生自降冰片烯型单体的多环加成聚合物与各种其它聚合物混合以产生新的共混物，合金和嵌段共聚物的族。

25. 发明授权

US5571881A Addition polymers derived from norbornene-functional monomers and process therefor 失效
公开(公告)号：US5571881A
公开(公告)日：1996-11-05
申请号：US476810
申请日：1995-06-07
申请人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
发明人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
IPC分类号： C08F4/70 , C08F4/30 , C08F4/42 , C08F4/80 , C08F32/00 , C08F32/08 , C08F36/04 , C08F36/20 , C08F210/14 , C08F232/08 , C08F236/20 , C08F4/76 , C08F4/78
CPC分类号： C08F232/08 , C08F32/08
摘要： Addition polymers derived from norbornene-functional monomers are terminated with an olefinic moiety derived from a chain transfer agent selected from a compound having a terminal olefinic double bond between adjacent carbon atoms, excluding styrenes, vinyl ethers, and conjugated dienes and at least one of said carbon atoms has two hydrogen atoms attached thereto. The addition polymers of this invention are prepared from a single or multicomponent catalyst system including a Group VIII metal ion source. The catalyst systems are unique in that they catalyze the insertion of the chain transfer agent exclusively at a terminal end of the polymer chain.

26. 发明授权

US5569730A Addition polymers derived from norbornene-functional monomers and process therefor 失效
标题翻译：衍生自降冰片烯官能单体的加成聚合物及其工艺
公开(公告)号：US5569730A
公开(公告)日：1996-10-29
申请号：US339863
申请日：1994-11-15
申请人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
发明人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
IPC分类号： C08F4/70 , C08F4/30 , C08F4/42 , C08F4/80 , C08F32/00 , C08F32/08 , C08F36/04 , C08F36/20 , C08F210/14 , C08F232/08 , C08F236/20 , C08F10/00 , C08F32/02 , C08F34/00
CPC分类号： C08F232/08 , C08F32/08
摘要： Addition polymers derived from norbornene-functional monomers are terminated with an olefinic moiety derived from a chain transfer agent selected from a compound having a terminal olefinic double bond between adjacent carbon atoms, excluding styrenes, vinyl ethers, and conjugated dienes and at least one of said carbon atoms has two hydrogen atoms attached thereto. The addition polymers of this invention are prepared from a single or multicomponent catalyst system including a Group VIII metal ion source. The catalyst systems are unique in that they catalyze the insertion of the chain transfer agent exclusively at a terminal end of the polymer chain.
摘要翻译：衍生自降冰片烯官能单体的加成聚合物由衍生自链转移剂的烯烃部分封端，所述链转移剂选自相邻碳原子之间具有末端烯属双键的化合物，不包括苯乙烯，乙烯基醚和共轭二烯，并且所述碳原子上连有两个氢原子。本发明的加成聚合物由包含VIII族金属离子源的单组分或多组分催化剂体系制备。催化剂体系是独特的，因为它们催化仅在聚合物链的末端插入链转移剂。

27. 发明授权

US07422836B2 Dissolution rate modifiers for photoresist compositions 有权
标题翻译：光刻胶组合物的溶解速率改性剂
公开(公告)号：US07422836B2
公开(公告)日：2008-09-09
申请号：US10783386
申请日：2004-02-20
申请人： Larry F. Rhodes , Lawrence Seger , Brian L. Goodall , Lester H. McIntosh, III , Robert J. Duff
发明人： Larry F. Rhodes , Lawrence Seger , Brian L. Goodall , Lester H. McIntosh, III , Robert J. Duff
IPC分类号： G03F7/00 , G03F7/004 , C08F136/00
CPC分类号： C08F232/08 , G03F7/0045 , G03F7/0046 , G03F7/038 , G03F7/0382 , G03F7/0392 , G03F7/0395 , G03F7/0397
摘要： Oligomers of polycyclic olefin monomers, and optionally allylic or olefinic monomers, and a method of making such oligomers that includes reacting polycyclic olefin monomers in the presence of a Ni or Pd containing catalyst, or in the case of allylic monomers in the presence of a free radical initiator. The oligomers can be included in photoresist compositions as dissolution rate modifiers. The photoresist compositions can further include a polymeric binder resin, a photoacid generator, and solvents.
摘要翻译：多环烯烃单体和任选的烯丙基或烯属单体的低聚物，以及制备这样的低聚物的方法，其包括在含有Ni或Pd的催化剂存在下使多环烯烃单体反应，或者在烯丙基单体的情况下，自由基引发剂。低聚物可以包含在光致抗蚀剂组合物中作为溶解速率改性剂。光致抗蚀剂组合物还可以包括聚合物粘合剂树脂，光致酸产生剂和溶剂。

28. 发明授权

US09175123B2 Gate insulator layer for organic electronic devices 有权
标题翻译：有机电子器件的栅极绝缘层
公开(公告)号：US09175123B2
公开(公告)日：2015-11-03
申请号：US13223884
申请日：2011-09-01
申请人： David Christoph Mueller , Toby Cull , Pawel Miskiewicz , Miguel Carrasco-Orozco , Andrew Bell , Edmund Elce , Larry F. Rhodes , Kazuyoshi Fujita , Hendra Ng , Pramod Kandanarachchi , Steven Smith
发明人： David Christoph Mueller , Toby Cull , Pawel Miskiewicz , Miguel Carrasco-Orozco , Andrew Bell , Edmund Elce , Larry F. Rhodes , Kazuyoshi Fujita , Hendra Ng , Pramod Kandanarachchi , Steven Smith
IPC分类号： B32B27/32 , C08F132/08 , C08F232/00 , H01L51/05
CPC分类号： H01L51/052 , C08F32/04 , C08F232/00 , C08L45/00 , H01L51/0035 , H01L51/004 , H01L51/0043 , H01L51/0537 , H01L51/0541 , H01L51/0545 , H01L51/107
摘要： Embodiments in accordance with the present invention provide for the use of polycycloolefins in electronic devices and more specifically to the use of such polycycloolefins as gate insulator layers used in the fabrication of electronic devices, the electronic devices that encompass such polycycloolefin gate insulator and processes for preparing such polycycloolefin gate insulator layers and electronic devices encompassing such layers.
摘要翻译：根据本发明的实施方案提供了聚环烯烃在电子器件中的用途，更具体地说，涉及使用这种聚环烯烃作为用于制造电子器件的栅极绝缘体层，包括这种聚环烯烃栅极绝缘体的电子器件以及用于制备这种多环烯烃栅极绝缘体层和包含这些层的电子器件。

29. 发明申请

US20120056249A1 INTERLAYER FOR ELECTRONIC DEVICES 有权
标题翻译：电子设备中间层
公开(公告)号：US20120056249A1
公开(公告)日：2012-03-08
申请号：US13223784
申请日：2011-09-01
申请人： David Christoph Mueller , Pawel Miskiewicz , Toby Cull , Piotr Wierzchowiec , Andrew Bell , Edmund Elce , Larry F. Rhodes , Kazuyoshi Fujita , Hendra Ng , Pramod Kandanarachchi , Steven Smith
发明人： David Christoph Mueller , Pawel Miskiewicz , Toby Cull , Piotr Wierzchowiec , Andrew Bell , Edmund Elce , Larry F. Rhodes , Kazuyoshi Fujita , Hendra Ng , Pramod Kandanarachchi , Steven Smith
IPC分类号： B32B27/32 , C08F136/20 , H01L21/336 , C08F232/08 , H01L29/78 , C08F236/20 , C08F132/08
CPC分类号： H01L51/0043 , C08F232/00 , C08L65/00 , C08L2203/20 , H01L51/0035 , H01L51/0529 , H01L51/0541 , H01L51/0545 , Y10T428/31938
摘要： Embodiments in accordance with the present invention provide for the use of polycycloolefins in electronic devices and more specifically to the use of such polycycloolefins as interlayers applied to fluoropolymer layers used in the fabrication of electronic devices, the electronic devices that encompass such polycycloolefin interlayers and processes for preparing such polycycloolefin interlayers and electronic devices.
摘要翻译：根据本发明的实施方案提供了聚环烯烃在电子器件中的用途，更具体地说，涉及使用这种聚环烯烃作为中间层，其用于制备电子器件的氟聚合物层，包含这种聚环烯夹层的电子器件和制备这种聚环烯夹层和电子器件。

30. 发明授权

US06538087B2 Polymeric compositions for forming optical waveguides; optical waveguides formed therefrom; and methods for making same 有权
公开(公告)号：US06538087B2
公开(公告)日：2003-03-25
申请号：US09916449
申请日：2001-07-27
申请人： Xiao-Mei Zhao , Ramakrishna Ravikiran , Phillip S. Neal , Robert A. Shick , Larry F. Rhodes , Andrew Bell
发明人： Xiao-Mei Zhao , Ramakrishna Ravikiran , Phillip S. Neal , Robert A. Shick , Larry F. Rhodes , Andrew Bell
IPC分类号： C08F1000
CPC分类号： G02B6/1221 , C08F32/08 , C08F34/00 , C08F230/08 , C08F232/02 , C08F232/08 , C08F234/02 , C08F234/04 , G02B6/132 , G02B6/138 , G02B2006/12069 , G02B2006/12097
摘要： The present invention relates to polymer compositions and methods of polymerizing such compositions. Furthermore, the present invention relates to polymer compositions that are useful in forming waveguides and to methods for making waveguides using such polymer compositions.

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