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21. 发明授权

US07842759B2 Nitroxide compounds for minimizing scorch in crosslinkable compositions 失效
标题翻译：用于最小化可交联组合物中焦化的硝酸氧化物
公开(公告)号：US07842759B2
公开(公告)日：2010-11-30
申请号：US12267909
申请日：2008-11-10
申请人： Mohamed Esseghir , Bharat I. Chaudhary , Jeffrey M. Cogen , John Klier , Jinder Jow , Robert F. Eaton , Suzanne M. Guerra
发明人： Mohamed Esseghir , Bharat I. Chaudhary , Jeffrey M. Cogen , John Klier , Jinder Jow , Robert F. Eaton , Suzanne M. Guerra
IPC分类号： C08F8/30
CPC分类号： C08F2/38 , C08F4/00 , C08K5/0025 , C08K5/3435
摘要： Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.
摘要翻译：在可交联聚合物（例如EPDM）的自由基交联期间，通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物，优选醚，酯或氨基甲酸酯衍生物的交联之前引入聚合物中，焦烧被抑制，例如4-羟基 - 四氢环丁基哌啶-1-基。在类似的聚合物组合物和类似的条件下，本发明的焦烧抑制剂（如果不是更好）也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样，在焦烧抑制和最终交联度方面也表现出较低的挥发性，聚合物组合物内迁移少。

22. 发明申请

US20070243481A1 Aqueous dispersions for use as toners 有权
标题翻译：用作调色剂的水性分散体
公开(公告)号：US20070243481A1
公开(公告)日：2007-10-18
申请号：US11712206
申请日：2007-02-28
申请人： John Klier , Richard Varjian , Alastair Hill
发明人： John Klier , Richard Varjian , Alastair Hill
IPC分类号： G03G9/08 , C08J5/00 , C08K11/00 , C08L31/00
CPC分类号： G03G9/08 , C08K5/005 , C08K11/00 , C08L25/14 , C08L33/06 , C08L67/02 , G03G9/0806 , G03G9/081 , G03G9/0815 , G03G9/0831 , G03G9/0832 , G03G9/0833 , G03G9/08708 , G03G9/08711 , G03G9/08726 , G03G9/08733 , G03G9/08755 , G03G9/08795 , G03G9/08797 , G03G9/09 , G03G9/0926 , G03G9/09708 , G03G9/09716 , G03G9/09725 , C08L2666/02
摘要： A compound that includes an aqueous dispersion, wherein the dispersion includes a thermoplastic resin and at least one stabilizing agent, and at least one selected from the group consisting of a colorant and a magnetic pigment, wherein the dispersion has an average volume diameter particle size from about 0.05 to about 10 microns is described.
摘要翻译：一种包含水分散体的化合物，其中所述分散体包含热塑性树脂和至少一种稳定剂，以及选自着色剂和磁性颜料中的至少一种，其中所述分散体的平均体积直径粒径为约0.05至约10微米。

23. 发明申请

US20070020453A1 Elastic, heat and moisture resistant bicomponent and biconstituent fibers 有权
标题翻译：弹性，耐热和防潮双组分和双组分纤维
公开(公告)号：US20070020453A1
公开(公告)日：2007-01-25
申请号：US11526498
申请日：2006-09-25
申请人： Ashish Sen , John Klier , Rajen Patel , Hongyu Chen , Thoi Ho
发明人： Ashish Sen , John Klier , Rajen Patel , Hongyu Chen , Thoi Ho
IPC分类号： D02G3/00
CPC分类号： D01F8/06 , D01F6/46 , Y10T428/29 , Y10T428/2929 , Y10T428/2964 , Y10T428/2967 , Y10T428/2969
摘要： Fibers having improved resistance to moisture at elevated temperatures comprise at least two elastic polymers, one polymer heat-settable and the other polymer heat-resistant, the heat-resistant polymer comprising at least a portion of the exterior surface of the fiber. The fibers typically have a bicomponent and/or a biconstituent core/sheath morphology. Typically, the core comprises an elastic thermoplastic urethane, and the sheath comprises a homogeneously branched polyolefin, preferably a homogeneously branched substantially linear ethylene polymer.
摘要翻译：具有改善的耐高温性的纤维包括至少两种弹性聚合物，一种聚合物可热固化的，另一种聚合物耐热的，所述耐热聚合物包含纤维外表面的至少一部分。纤维通常具有双组分和/或双成核芯/鞘形态。通常，芯包括弹性热塑性聚氨酯，并且护套包含均匀支化的聚烯烃，优选均匀支化的基本线性的乙烯聚合物。

24. 发明授权

US07135228B2 Elastic, heat and moisture resistant bicomponent and biconstituent fibers 有权
公开(公告)号：US07135228B2
公开(公告)日：2006-11-14
申请号：US10195232
申请日：2002-07-15
申请人： Ashish Sen , John Klier , Rajen M. Patel , Hongyu Chen , Thoi H. Ho
发明人： Ashish Sen , John Klier , Rajen M. Patel , Hongyu Chen , Thoi H. Ho
IPC分类号： D01F6/04 , D01F6/46
CPC分类号： D01F8/06 , D01F6/46 , Y10T428/29 , Y10T428/2929 , Y10T428/2964 , Y10T428/2967 , Y10T428/2969
摘要： Fibers having improved resistance to moisture at elevated temperatures comprise at least two elastic polymers, one polymer heat-settable and the other polymer heat-resistant, the heat-resistant polymer comprising at least a portion of the exterior surface of the fiber. The fibers typically have a bicomponent and/or a biconstituent core/sheath morphology. Typically, the core comprises an elastic thermoplastic urethane, and the sheath comprises a homogeneously branched polyolefin, preferably a homogeneously branched substantially linear ethylene polymer.

25. 发明申请

US20050197457A1 Stable organic free radical polymer systems: grafting functional monomers 审中-公开
标题翻译：稳定的有机自由基聚合物体系：接枝官能单体
公开(公告)号：US20050197457A1
公开(公告)日：2005-09-08
申请号：US11021955
申请日：2004-12-24
申请人： Bharat Chaudhary , Yunwa Cheung , Mohamed Esseghir , John Klier , John Weaver
发明人： Bharat Chaudhary , Yunwa Cheung , Mohamed Esseghir , John Klier , John Weaver
IPC分类号： C08F8/00 , C08G18/00 , C08K5/14 , C08K5/34 , C08K5/3435 , C08L23/06 , C08L23/10 , C08L23/22 , C08L101/00
CPC分类号： C08L101/00 , C08F8/30 , C08K5/14 , C08K5/3435 , C08L23/10 , C08L23/22 , C08L2666/04
摘要： The present invention is a stable organic free radical polymer system. The system is useful as a composition, provides processing advantages over existing grafting technologies, and imparts unique properties to articles of manufacture made therefrom.
摘要翻译：本发明是稳定的有机自由基聚合物体系。该系统作为组合物是有用的，提供了超过现有接枝技术的加工优点，并赋予由其制成的制品的独特性质。

26. 发明授权

US06773810B2 Elastic bicomponent and biconstituent fibers, and methods of making cellulosic structures from the same 有权
公开(公告)号：US06773810B2
公开(公告)日：2004-08-10
申请号：US10195279
申请日：2002-07-15
申请人： Ashish Sen , John Klier , Rexford A. Maugans , Kenneth Stewart, Jr.
发明人： Ashish Sen , John Klier , Rexford A. Maugans , Kenneth Stewart, Jr.
IPC分类号： D01F800
CPC分类号： D04H1/54 , D01F6/46 , D01F8/06 , D04H1/4209 , D04H1/425 , D04H1/4258 , D04H1/4266 , D04H1/4291 , D04H1/4382 , D21H13/14 , D21H13/20 , D21H15/10 , Y10T428/29 , Y10T428/2909 , Y10T428/2924 , Y10T428/2929 , Y10T428/2931 , Y10T428/2967
摘要： The elasticity of elastic, absorbent structures, e.g., diapers, is improved without a significant compromise of the absorbency of the structure by the use of bicomponent and/or biconstituent elastic fibers. The absorbent structures typically comprise a staple fiber, e.g., cellulose fibers, and a bicomponent and/or a biconstituent elastic. The bicomponent fiber typically has a core/sheath construction. The core comprises an elastic thermoplastic elastomer, preferably a TPU, and the sheath comprises a homogeneously branched polyolefin, preferably a homogeneously branched substantially linear ethylene polymer. In various embodiments of the invention, the elasticity is improved by preparation techniques that enhance the ratio of elastic fiber:cellulose fiber bonding versus cellulose fiber:cellulose fiber bonding. These techniques include wet and dry high intensity agitation of the elastic fibers prior to mixing with the cellulose fibers, deactivation of the hydrogen bonding between cellulose fibers, and grafting the elastic fiber with a polar group containing compound, e.g. maleic anhydride.

27. 发明授权

US5844039A Polymers comprising reversible hydrophobic functionalities 失效
公开(公告)号：US5844039A
公开(公告)日：1998-12-01
申请号：US910082
申请日：1997-08-12
申请人： Alec B. Scranton , Arvind M. Mathur , John Klier
发明人： Alec B. Scranton , Arvind M. Mathur , John Klier
IPC分类号： A61K9/28 , A61K9/50 , A61K47/34 , A61L15/60 , C08F2/24 , C08F283/06 , C08F290/06 , C08F8/14
CPC分类号： C08F290/062 , A61K47/34 , A61L15/60 , C08F2/24 , C08F283/06 , A61K9/2853 , A61K9/5031
摘要： Polymers comprising reversible hydrophobic functionalities are disclosed. The preferred embodiment polymers comprise Lewis acid segments and Lewis base segments. The polymer segments are, by themselves, hydrophilic and will either swell or dissolve in water. When the segments are incorporated into a polymer according to the present invention, the segments form water-insoluble or hydrophobic complexes. Upon changes in pH, temperature or solvent type, these complexes may dissociate, giving large transitions in polymer viscosity, emulsification ability, mechanical strength or transport properties. These polymers are useful as reversible emulsifiers which form stable emulsions at acidic pH and unstable emulsions at basic pH, as water-borne thickeners having low viscosity at low pH and high viscosity at high pH, as superabsorbing resins, or as coatings for pharmaceutical or agricultural agents.

28. 发明申请

US20100016515A1 CROSSLINKABLE POLYETHYLENE COMPOSITION, METHOD OF MAKING THE SAME, AND ARTICLES MADE THEREFROM 有权
标题翻译：可交联聚乙烯组合物，其制备方法及其制备方法
公开(公告)号：US20100016515A1
公开(公告)日：2010-01-21
申请号：US12525688
申请日：2008-01-25
申请人： Bharat I. Chaudhary , John Klier
发明人： Bharat I. Chaudhary , John Klier
IPC分类号： C08L23/06
CPC分类号： C08K5/14 , C08K5/0025 , C08K5/01 , C08L51/06 , C08L23/04 , C08L2666/02
摘要： The instant invention is a crosslinkable polyethylene composition, a method of making the same, and articles made therefrom. The crosslinkable polyethylene composition according to instant invention includes a polyethylene component, a crosslinking agent, and a crosslinking coagent. The crosslinking agent is an organic peroxide, and the crosslinking coagent is an alkadiene, alkatriene, or alkatetraene compound comprising at least two terminal carbon-carbon double bonds. The crosslinkable polyethylene composition may, optionally, further include a scorch inhibitor, a cure booster, a stable free radical, one or more conventional additives, blends thereof, and/or combinations thereof. The method for producing a crosslinkable polyethylene composition according to instant invention includes the steps of: (1) providing a polyethylene component; (2) providing a crosslinking agent, wherein the crosslinking agent is an organic peroxide; (3) providing a crosslinking coagent, wherein the crosslinking coagent is an alkadiene, alkatriene, or alkatetraene compound comprising at least two terminal carbon-carbon double bonds; (4) melt blending the a polyethylene component, the crosslinking agent, and the crosslinking coagent at a temperature in the range of less than the decomposition temperature of the crosslinking agent; and (5) thereby forming the crosslinkable polyethylene composition. The article according to instant invention includes the crosslinked product of a polyethylene component; a crosslinking agent, wherein the crosslinking agent is an organic peroxide; and a crosslinking coagent, wherein the crosslinking coagent is an alkadiene, alkatriene, or alkatetraene compound comprising at least two terminal carbon-carbon double bonds.
摘要翻译：本发明是可交联聚乙烯组合物，其制备方法和由其制成的制品。根据本发明的可交联聚乙烯组合物包括聚乙烯组分，交联剂和交联助剂。交联剂是有机过氧化物，交联助剂是包含至少两个末端碳 - 碳双键的链二烯，亚烷基或烷基四烯化合物。可交联聚乙烯组合物可以任选地进一步包括焦烧抑制剂，固化促进剂，稳定的自由基，一种或多种常规添加剂，其共混物和/或其组合。根据本发明的可交联聚乙烯组合物的制造方法包括以下步骤：（1）提供聚乙烯组分; （2）提供交联剂，其中所述交联剂是有机过氧化物; （3）提供交联助剂，其中所述交联助剂是包含至少两个末端碳 - 碳双键的链二烯，亚烷基或烷基四烯化合物; （4）在小于交联剂的分解温度的范围内的温度下熔融共混聚乙烯组分，交联剂和交联助剂; 和（5），从而形成可交联聚乙烯组合物。根据本发明的制品包括聚乙烯组分的交联产物; 交联剂，其中所述交联剂是有机过氧化物; 和交联助剂，其中所述交联助剂是包含至少两个末端碳 - 碳双键的链二烯，亚烷基或烷基四烯化合物。

29. 发明申请

US20080227887A1 Polypropylene-Based Wire and Cable Insulation or Jacket 审中-公开
标题翻译：聚丙烯基电线电缆绝缘或护套
公开(公告)号：US20080227887A1
公开(公告)日：2008-09-18
申请号：US11997787
申请日：2006-07-27
申请人： John Klier , David Paul Wright , Bharat Indu Chaudhary
发明人： John Klier , David Paul Wright , Bharat Indu Chaudhary
IPC分类号： H01B3/44
CPC分类号： H01B3/441 , H01B3/28
摘要： The invention is an electrically conductive device, e.g., a wire or cable, having a crush resistance of at least about 18 pounds per square inch (psi), the device comprising: A. An electrically conductive member comprising at least one electrically conductive substrate, e.g., a wire strand or a pair of twisted wire strands; and B. At least one electric-insulating member substantially surrounding the electrically conductive member, e.g., a polymer coating or layer, the electric-insulating member comprising a polymer blend, the polymer blend comprising: 1. At least about 50 weight percent of a polypropylene, and 2. At least about 10 weight percent of an elastomer. In one embodiment, the blend is characterized as having (i) a hot creep of less than 200% at 150 C, (ii) a dielectric constant at 60 Hz and 90 C of less than about 2.5, (iii) a dissipation factor at 60 Hz and 90 C of less than about 0.005, and (iv) an AC breakdown strength of greater than about 600 v/mil.
摘要翻译：本发明是具有至少约18磅/平方英寸（psi）的抗压强度的导电装置，例如电线或电缆，该装置包括：A.导电构件，其包括至少一个导电基底，例如，绞线或一对扭绞线股; B.至少一个电绝缘构件，其基本上围绕导电构件，例如聚合物涂层或层，所述电绝缘构件包含聚合物共混物，所述聚合物共混物包含：1.至少约50重量％的聚丙烯和2.至少约10重量％的弹性体。在一个实施方案中，共混物的特征在于具有（i）在150℃下小于200％的热蠕变，（ii）在60Hz和90℃下的介电常数小于约2.5，（iii） 60Hz和90℃小于约0.005，以及（iv）大于约600v / mil的AC击穿强度。

30. 发明申请

US20070173613A1 Free-radical-initiated crosslinking of polymers 审中-公开
标题翻译：自由基引发的聚合物交联
公开(公告)号：US20070173613A1
公开(公告)日：2007-07-26
申请号：US10583299
申请日：2004-12-24
申请人： Bharat Chaudhary , Yunwa Cheung , Randall Cuntala , Mohamed Esseghir , John Klier
发明人： Bharat Chaudhary , Yunwa Cheung , Randall Cuntala , Mohamed Esseghir , John Klier
IPC分类号： C08F8/30
CPC分类号： C08L101/00 , C08F8/30 , C08K5/14 , C08K5/3435 , C08L23/10 , C08L23/22 , C08L2666/04
摘要： The present invention is a free-radical carbon-FRTS-carbon crosslinkable polymeric composition. The resulting carbon-FRTS-carbon crosslinked polymer is prepared from at least one polymer which upon forming free radicals preferentially degrades or carbon-carbon crosslinks. The present invention permits suppression of the preferential reaction while permitting the polymer to be carbon-FRTS-carbon crosslinked through a free-radical trapping species. Suppressing the undesirable degradation or carbon-carbon crosslinking reaction and permitting the desirable carbon-FRTS-carbon crosslinking reaction yield a uniquely crosslinked polymer.
摘要翻译：本发明是一种自由基碳-FRTS-碳可交联聚合物组合物。所得到的碳-FRTS-碳交联聚合物由至少一种形成自由基优先降解或碳 - 碳交联的聚合物制备。本发明允许抑制优选反应，同时允许聚合物是通过自由基捕获物质交联的碳-FRTS-碳。抑制不期望的降解或碳 - 碳交联反应并允许所需的碳-FFR-碳交联反应产生独特的交联聚合物。

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