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    • 24. 发明授权
    • Photothermographic recording material
    • 光热记录材料
    • US06607872B1
    • 2003-08-19
    • US09202256
    • 1999-06-14
    • Herman UytterhoevenYvan GilliamsJohan LoccufierSabine EmmersRonny De Clercq
    • Herman UytterhoevenYvan GilliamsJohan LoccufierSabine EmmersRonny De Clercq
    • G03C1498
    • G03C1/49818G03C2001/03594G03C2200/38
    • A photothermographic recording material comprising a photo-addressable thermally developable element coatable from aqueous media comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt and a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, characterized in that the binder comprises a water-soluble polymer, a water-dispersible polymer or a mixture of a water-soluble polymer and a water-dispersible polymer and particles of the photosensitive silver halide are non-aggregating in the photo-addressable thermally developable element and are uniformly distributed over and between particles of the substantially light-insensitive organic silver salt, at least 80% by number of the particles having a diameter, determined by transmission electron microscopy, of ≦40 nm; and a recording process therefor.
    • 一种光热记录材料,其包含可光寻址的可热显影元件,其由含有基本上不光敏的有机银盐的水性介质涂覆,光敏卤化银与基本上不受光敏感的有机银盐催化缔合,和与热处理关系的还原剂 基本上不光敏的有机银盐和粘合剂,其特征在于粘合剂包括水溶性聚合物,水分散性聚合物或水溶性聚合物和水分散性聚合物的混合物以及感光性银颗粒 卤化物在光寻址热可显影元件中是非聚集的,并且均匀地分布在基本上不受光的有机银盐的颗粒之间和之间,至少80%的具有通过透射电子显微镜测定的直径的颗粒, 的<= 40nm; 及其记录过程。
    • 25. 发明授权
    • Photothermographic recording material
    • 光热记录材料
    • US06280923B1
    • 2001-08-28
    • US09009717
    • 1998-01-20
    • Herman UytterhoevenYvan GilliamsJohan LoccufierSabine Emmers
    • Herman UytterhoevenYvan GilliamsJohan LoccufierSabine Emmers
    • G03C1498
    • G03C1/49809G03C1/035G03C1/498G03C1/49863G03C1/4989G03C2001/0156G03C2001/03594G03C2200/36G03C2200/43
    • A photothermographic recording material comprising a support and a photo-addressable thermally developable element comprising photosensitive silver halide in catalytic association with a substantially light-insensitive silver salt of an organic carboxylic acid, an organic reducing agent for the substantially light-insensitive silver salt of an organic carboxylic acid in thermal working relationship therewith and a binder, characterized in that the binder is water soluble or water dispersible and the reducing agent is a non-sulfo-substituted 6-membered aromatic or heteroaromatic ring compound with at least three substituents one of which is a hydroxy group at a first carbon atom and a second of which is a hydroxy or amino-group substituted on a second carbon atom one, three or five ring atoms removed in a system of conjugated double bonds from the first carbon atom in the compound, in which (i) the third substituent may be part of an annelated carbocyclic or heterocyclic ring system; (ii) the third substituent or a further substituent is not an aryl- or oxo-aryl-group whose aryl group is substituted with hydroxy-, thiol- or amino-groups; and (iii) the third substituent or a further substituent is a non-sulfo-electron withdrawing group if the second substiuent is an amino-group and the photo-addressable thermally developable element is coated from an aqueous medium and is capable of producing stable images without a wet-processing step. A process for producing the photothermographic recording material and a photothermographic recording process therefor is also provided.
    • 一种光热记录材料,其包含载体和可光寻址热可显影元件,其包含与有机羧酸的基本上不敏感的银盐催化缔合的感光卤化银,用于基本上不敏感的银盐的有机还原剂 与其结合的有机羧酸和粘合剂,其特征在于所述粘合剂是水溶性或水分散性的,并且所述还原剂是具有至少三个取代基的非磺基取代的6元芳族或杂芳族环化合物 是在第一个碳原子上的羟基,其中第二个是在第二个碳原子上被取代的羟基或氨基,在化合物中的第一个碳原子的共轭双键系统中除去三个或五个环原子 ,其中(i)第三取代基可以是环状碳环或杂环系的一部分; (ii)第三取代基或另外的取代基不是芳基或氧代 - 芳基,其芳基被羟基,硫醇或氨基取代; 和(iii)第三取代基或另外的取代基是非磺基电子取代基,如果第二个取代基是氨基,并且可光寻址的热显影元素由水性介质包被并且能够产生稳定的图像 没有湿处理步骤。 还提供了一种制备光热敏记录材料的方法及其光热敏记录方法。
    • 30. 发明授权
    • Photothermographic material comprising an infra-red sensitizer
    • 光热成像材料包括红外线敏化剂
    • US6074814A
    • 2000-06-13
    • US889411
    • 1997-07-08
    • Geert DerooverHerman UytterhoevenPaul CallantJohan Loccufier
    • Geert DerooverHerman UytterhoevenPaul CallantJohan Loccufier
    • G03C1/28G03C1/498G03C1/490
    • C09B23/0066C09B23/0075C09B23/086C09B23/148G03C1/49854G03C1/49863G03C1/28
    • A photothermographic recording material comprising a photo-addressable thermally developable element including a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt, in a quantity of 0.1 to 35 mol % relative to the organic silver salt and spectrally sensitized to infra-red light with a dye, a supersensitizer for the dye, a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, wherein the binder comprises a water soluble polymer, a water-dispersible polymer or a water soluble polymer and a water-dispersible polymer and the dye is represented by formula (I): ##STR1## wherein Z.sup.1 and Z.sup.2 independently represent S, O or Se; R.sup.1 and R.sup.17 are independently each an alkyl or sulfo-alkyl group which may be substituted with at least one fluorine, chlorine, bromine, iodine or an alkoxy-, aryloxy- or ester-group; and X represents an anion.
    • 一种光热记录材料,其包含可光寻址的热显影元件,其包含基本上不光敏的有机银盐,相对于基本上不光敏的有机银盐催化缔合的感光卤化银,其量相对于 有机银盐,用染料对红外线进行光谱敏化,染料用超增敏剂,与基本上不透光的有机银盐和粘合剂的热加工关系的还原剂,其中粘合剂包含水溶性聚合物, 水分散性聚合物或水溶性聚合物和水分散性聚合物,染料由式(I)表示:其中Z1和Z2独立地表示S,O或Se; R 1和R 17各自独立地为可以被至少一个氟,氯,溴,碘或烷氧基 - ,芳氧基或酯基取代的烷基或磺基 - 烷基; X表示阴离子。