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    • 30. 发明授权
    • Isoprene-butadiene diblock rubber
    • 异戊二烯二嵌段橡胶
    • US5612436A
    • 1997-03-18
    • US524666
    • 1995-09-08
    • Adel F. HalasaWen-Liang HsuDavid J. ZanzigPaul H. SandstromLaurie E. Austin
    • Adel F. HalasaWen-Liang HsuDavid J. ZanzigPaul H. SandstromLaurie E. Austin
    • B60C1/00B23P6/00C08F297/02C08F236/00
    • C08F297/02B23P6/00
    • The subject invention discloses an isoprene-butadiene diblock rubber which is particularly valuable for use in making treads for tires which have improved wear characteristics without compromising traction characteristics or rolling resistance. Said isoprene-butadiene diblock rubber is comprised of (1) a first block which is comprised of repeat units which are derived from 1,3-butadiene and (2) a second block which is comprised of repeat units which are derived from both 1,3-butadiene and isoprene, wherein the repeat units derived from isoprene and 1,3-butadiene in the second block are in an essentially random order, wherein the diblock rubber has a glass transition temperature which is within the range of about -100.degree. C. to about -70.degree. C., and wherein the diblock rubber has a Mooney viscosity which is within the range of about 50 to about 140. In cases where the isoprene-butadiene diblock rubber of this invention is employed in automobile tires it will preferably have a second glass transition temperature which is within the range of about -50.degree. C. to about 0.degree. C. The Mooney viscosity will preferably be within the range of about 80 to about 135 and in the case of oil extended polymers will more preferably be within the range of about 100 to about 130 before oil extension.
    • 本发明公开了一种异戊二烯 - 丁二烯二嵌段橡胶,其特别有价值,用于制造具有改进的磨损特性而不损害牵引特性或滚动阻力的轮胎胎面。 所述异戊二烯 - 丁二烯二嵌段橡胶包括(1)由1,3-丁二烯衍生的重复单元组成的第一嵌段和(2)由重复单元组成的第二嵌段, 3-丁二烯和异戊二烯,其中在第二嵌段中衍生自异戊二烯和1,3-丁二烯的重复单元基本上是无规顺序,其中二嵌段橡胶的玻璃化转变温度在约-100℃的范围内 至约-70℃,并且其中二嵌段橡胶的门尼粘度在约50至约140的范围内。在本发明的异戊二烯 - 丁二烯二嵌段橡胶用于汽车轮胎的情况下,其优选 具有在约-50℃至约0℃的范围内的第二玻璃化转变温度。门尼粘度优选在约80至约135的范围内,并且在油延伸聚合物的情况下更优选 在t内 在油延伸之前,其范围约为100至约130。