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    • 23. 发明申请
    • Addition cure silicone rubber adhesive composition and making method
    • 添加固化硅橡胶胶的组成及制作方法
    • US20080153956A1
    • 2008-06-26
    • US12003366
    • 2007-12-21
    • Hiroyasu Hara
    • Hiroyasu Hara
    • C08K5/541
    • C09J183/04C08L83/00
    • An addition cure silicone rubber adhesive composition comprising (A) an organopolysiloxane, (B) an inorganic filler, (C) an alkoxysilane, (D) a hydrolytic catalyst selected from titanium, zirconium and aluminum compounds, (E) an organohydrogenpolysiloxane, (F) a cure regulator, and (G) a platinum compound is prepared by mixing components (A), (B), (C) and (D), in the absence of component (G), at 0-200° C. and a reduced pressure to form a premix, and thereafter, adding component (G) and the remaining components to the premix and mixing at 0-60° C. and a reduced pressure.
    • 一种加成固化硅橡胶粘合剂组合物,其包含(A)有机聚硅氧烷,(B)无机填料,(C)烷氧基硅烷,(D)选自钛,锆和铝化合物的水解催化剂,(E)有机氢聚硅氧烷,(F )固化调节剂,和(G)在0-200℃下将组分(A),(B),(C)和(D))在不存在组分(G)的情况下混合制备铂化合物, 减压以形成预混物,然后将组分(G)和其余组分加入到预混物中,并在0-60℃和减压下混合。
    • 24. 发明申请
    • Addition reaction curable silicone rubber composition
    • 加成反应固化硅橡胶组合物
    • US20060009577A1
    • 2006-01-12
    • US11176319
    • 2005-07-08
    • Hiroyasu Hara
    • Hiroyasu Hara
    • C08L83/04B32B27/00
    • C08L83/04B32B7/12B32B25/20C08G77/12C08G77/20C08K5/05C08K5/34922C08L83/00C08L2666/28C08L2666/54C09J183/04Y10T428/31663
    • Provided is a self-adhesive addition reaction curable silicone rubber composition including (A) 100 parts by mass of an organopolysiloxane containing at least two alkenyl groups bonded to silicon atoms, (B) an organohydrogenpolysiloxane, in sufficient quantity to provide from 0.4 to 10.0 mols of hydrogen atoms bonded to silicon atoms within this component (B) for every 1 mol of alkenyl groups within the entire composition, (C) an effective quantity of a platinum-based catalyst, (D) a curing retarder, and (E) an adhesion imparting agent, in which the blend quantity of the curing retarder of the component (D) is sufficient to ensure that, if a torque value of the composition after standing for 180 minutes at 80° C. following preparation is deemed 100%, the time required for the torque value to reach 90% is no more than 120 minutes. Also provided is a method of bonding a plastic substrate and a silicone rubber, in which the above-stated addition reaction curable silicone rubber composition is cured on the plastic substrate at a temperature of no more than 120° C. The addition reaction curable silicone rubber composition is able to be cured even in the presence of curing inhibiting substances, and is very useful as a silicone adhesive.
    • 本发明提供一种自粘合加成反应性固化性硅橡胶组合物,其包含(A)100质量份含有至少两个与硅原子键合的烯基的有机聚硅氧烷,(B)有机氢聚硅氧烷,足量提供0.4〜10.0摩尔 (B)中与硅原子键合的氢原子对于整个组合物中的每1摩尔烯基,(C)有效量的铂系催化剂,(D)固化延迟剂,和(E) 粘合赋予剂,其中组分(D)的固化缓凝剂的共混量足以确保如果在制备后80℃下静置180分钟后的组合物的扭矩值被认为是100%,则 扭矩值达到90%所需的时间不超过120分钟。 还提供了一种粘合塑料基材和硅橡胶的方法,其中上述加成反应可固化的硅橡胶组合物在不超过120℃的温度下在塑料基材上固化。加成反应可固化的硅橡胶 组合物即使在固化抑制物质的存在下也能够固化,并且作为有机硅粘合剂是非常有用的。
    • 25. 发明授权
    • Adhesive silicone compositions
    • 粘合硅胶组合物
    • US5536803A
    • 1996-07-16
    • US461012
    • 1995-06-05
    • Hironao FujikiShigeki ShudoToshiaki TakahashiHiroyasu HaraTakeshi Miyao
    • Hironao FujikiShigeki ShudoToshiaki TakahashiHiroyasu HaraTakeshi Miyao
    • C08L83/07C09J183/04C09J183/07C08G77/08
    • C09J183/04
    • An adhesive silicone composition comprising a diorganopolysiloxane, an organohydrogenpolysiloxane, and a platinum catalyst is blended with an organohydrogenpolysiloxane having at least two hydrogen atoms each bonded to a silicon atom in a molecule and containing an aromatic ring-bearing hydrocarbon radical in an amount of at least 12 mol % of the entire monovalent organic radicals bonded to silicon atoms, or a compound containing at least one hydrogen atom bonded to a silicon atom in a molecule and having a radical of two benzene rings separated by --R.sup.13 R.sup.14 Si--, --R.sup.13 R.sup.14 SiO--, --OR.sup.13 R.sup.14 SiO-- or --R.sup.13 R.sup.14 SiOR.sup.13 R.sup.14 Si-- wherein R.sup.13 and R.sup.14 are a monovalent hydrocarbon radical. The composition firmly adheres to organic resins, but is readily releasable from metal molds.
    • 将包含二有机聚硅氧烷,有机氢聚硅氧烷和铂催化剂的粘合性有机硅组合物与具有至少两个氢原子的有机氢聚硅氧烷共混,每个氢原子分子键合至硅原子并且含有至少含有芳环的烃基 与硅原子键合的全部一价有机基团的12摩尔%,或分子中含有与硅原子键合的至少一个氢原子的化合物,其具有由-R 13 R 14 -Si,-R 13 R 14 SiO, - OR13R14SiO-或-R13R14SiOR13R14Si-,其中R13和R14是一价烃基。 组合物牢固地粘附到有机树脂上,但是容易从金属模具中剥离。
    • 27. 发明授权
    • Addition cure silicone rubber adhesive composition and making method
    • 添加固化硅橡胶胶的组成及制作方法
    • US07825177B2
    • 2010-11-02
    • US12003366
    • 2007-12-21
    • Hiroyasu Hara
    • Hiroyasu Hara
    • C08K5/541C08K3/10
    • C09J183/04C08L83/00
    • An addition cure silicone rubber adhesive composition comprising (A) an organopolysiloxane, (B) an inorganic filler, (C) an alkoxysilane, (D) a hydrolytic catalyst selected from titanium, zirconium and aluminum compounds, (E) an organohydrogenpolysiloxane, (F) a cure regulator, and (G) a platinum compound is prepared by mixing components (A), (B), (C) and (D), in the absence of component (G), at 0-200° C. and a reduced pressure to form a premix, and thereafter, adding component (G) and the remaining components to the premix and mixing at 0-60° C. and a reduced pressure.
    • 一种加成固化硅橡胶粘合剂组合物,其包含(A)有机聚硅氧烷,(B)无机填料,(C)烷氧基硅烷,(D)选自钛,锆和铝化合物的水解催化剂,(E)有机氢聚硅氧烷,(F )固化调节剂,和(G)在0-200℃下将组分(A),(B),(C)和(D))在不存在组分(G)的情况下混合制备铂化合物, 减压以形成预混物,然后将组分(G)和其余组分加入到预混物中,并在0-60℃和减压下混合。
    • 28. 发明授权
    • Compounds for solvent resistant silicone gels
    • 耐溶剂硅胶的化合物
    • US5519096A
    • 1996-05-21
    • US268926
    • 1994-06-30
    • Hiroyasu Hara
    • Hiroyasu Hara
    • C08G77/24C08L83/08C08G77/08
    • C08G77/24C08L83/08
    • A composition for a solvent resistant silicone gel which comprises (A) 100 weight parts of branched organopolysiloxane having vinyl groups which contains:______________________________________ (CF.sub.3 --CH.sub.2 --CH.sub.2)(CH.sub.3)SiO units 70.0-98.5 mol % RSiO.sub.1.5 units 0.5-10.0 mol %, and (CH.sub.2 .dbd.CH)(CH.sub.3).sub.2 SiO.sub.0.5 units 1.0-10.0 mol %, ______________________________________ where R is a group selected from a 3,3,3-trifluoropropyl group, a phenyl group, a methyl group and a vinyl group, (B) 0.1 to 30 weight parts of organohydrogen polysiloxane having at least one hydrogen atom bound to a silicon atom within the molecule, and (C) an addition reaction catalyst. The composition can form a cured silicone gel product which possesses a superior solvent resistance towards, for example, gasoline, while maintaining flexibility at low temperature.
    • 一种耐溶剂硅凝胶组合物,其包含(A)100重量份具有乙烯基的支链有机聚硅氧烷,其含有: - (CF 3 -CH 2 -CH 2)(CH 3)SiO单元70.0-98.5摩尔%-RSiO1.5单元0.5- 10.0摩尔%,和 - (CH 2 = CH)(CH 3)2 SiO 0.5单位1.0-10.0摩尔%, - 其中R是选自3,3,3-三氟丙基,苯基,甲基和 乙烯基,(B)0.1〜30重量份具有与分子内的硅原子键合的至少一个氢原子的有机氢聚硅氧烷,(C)加成反应催化剂。 组合物可以形成固化的硅氧烷凝胶产品,其在例如汽油中具有优异的耐溶剂性,同时保持低温下的柔韧性。
    • 29. 发明授权
    • Process for producing branched organopolysiloxane
    • 生产支链有机聚硅氧烷的方法
    • US5391674A
    • 1995-02-21
    • US197872
    • 1994-02-17
    • Hiroyasu HaraMasayuki IkenoAkihito Tsukuno
    • Hiroyasu HaraMasayuki IkenoAkihito Tsukuno
    • C08G77/06C08G77/10C08G77/38
    • C08G77/10C08G77/06
    • A process for producing a branched organopolysiloxane, comprising the steps of subjecting mixture of (A) a trialkoxysilane having the general formula (1):R.sup.1 Si(OR.sup.2).sub.3 (1)wherein R.sup.1 is a hydrocarbon group, and R.sup.2 are each a hydrocarbon group, and (B) an organosiloxane oligomer obtained by hydrolysis-condensation of a silane compound having the general formula (2):R.sup.3.sub.a SiCl.sub.4-a (2)wherein R.sup.3 are each a hydrocarbon group and a is 2 or 3, to equilibration reaction in the presence of an alkali catalyst, and adding water, subsequently to or concurrently with the equilibration reaction, to the reaction mixture, thereby hydrolyzing the Si--OR.sup.2 groups contained in the organopolysiloxane resulting from the hydrolysis-condensation. A branched organopolysiloxane stable in molecular composition and properties such as viscosity, can be produced.
    • 一种制备支链有机聚硅氧烷的方法,包括以下步骤:(A)具有通式(1)的三烷氧基硅烷:其中R 1为烃基的R 1 Si(OR 2)3(1)和R 2各自为烃基 ,(B)通过具有通式(2)的硅烷化合物的水解缩合得到的有机硅氧烷低聚物:R3aSiCl4-a(2)其中R3各自为烃基,a为2或3,以平衡反应 存在碱催化剂,然后在平衡反应中或同时向反应混合物中加入水,由此水解由水解缩合产生的有机聚硅氧烷中所含的Si-OR 2基团。 可以制备分子组成稳定的分支有机聚硅氧烷和粘度等性质。
    • 30. 发明授权
    • Silicone gel composition excellent in damping property
    • 硅胶组合物阻尼性能优异
    • US5332795A
    • 1994-07-26
    • US944275
    • 1992-09-14
    • Hironao FujikiHiroyasu Hara
    • Hironao FujikiHiroyasu Hara
    • B01J13/00C08L83/04C08L83/05C08L83/07C08L83/08C08G77/08
    • C08L83/04C08L83/08C08G77/12C08G77/20C08G77/24C08G77/70
    • A silicone gel composition, comprising as essential components(A) an organopolysiloxane comprising substantially 90 to 97 mol % of R(CH.sub.3)SiO units, 0.1 to 2.5 mol % of RSiO.sub.1.5 units, and 0.1 to 4.0 mol % of CH.sub.3 R(CH.sub.2 .dbd.CH)Si.sub.0.5 units, wherein R represents a group selected from the group consisting of a methyl group, a phenyl group, and a CF.sub.3 CH.sub.2 CH.sub.2 -- group, provided that the total of the phenyl groups and the CF.sub.3 CH.sub.2 CH.sub.2 -- groups out of the R groups amounts to 0.5 to 10 mol % in all the R groups,(B) a hydrogenpolysiloxane containing at least one silicon-bonded hydrogen atom per molecule in such an amount that the number of the silicon-bonded hydrogen atoms is 0.5 to 1.5 per vinyl group bonded to silicon atoms in the component (A), and(C) a platinum catalyst. From this composition, a silicone gel excellent damping properties, rapid curability, and low-temperature properties can be obtained.
    • 一种硅凝胶组合物,其包含基本组分(A)包含基本上90至97mol%的R(CH 3)SiO单元,0.1至2.5mol%的RSiO 1.5单元和0.1至4.0mol%的CH 3 R(CH 2) = CH)Si0.5单元,其中R表示选自甲基,苯基和CF 3 CH 2 CH 2 - 基团的基团,条件是R中的苯基和CF 3 CH 2 CH 2 - 基团的总数 的基团在所有R基团中为0.5至10摩尔%,(B)每分子含有至少一个与硅键合的氢原子的氢聚硅氧烷,其量使得硅键合的氢原子的数量为每个乙烯基为0.5至1.5 组分(A)中与硅原子键合的基团,和(C)铂催化剂。 通过该组合物,可以获得硅酮凝胶,阻尼性能优异,固化性快,温度低的特性。