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    • 23. 发明授权
    • Structure suitable for solid electrochemical elements
    • 结构适用于固体电化学元素
    • US4810599A
    • 1989-03-07
    • US172166
    • 1988-03-23
    • Shigeo KondoNaoshi YasudaMasaki NagataTadashi Sotomura
    • Shigeo KondoNaoshi YasudaMasaki NagataTadashi Sotomura
    • G02F1/15H01G9/02H01G11/56H01M4/62H01M6/18
    • H01G9/038G02F1/1525H01G11/56H01M4/621H01M6/18H01M6/181Y02E60/13
    • A structure comprising a pair of electrode sheets and an electrolyte sheet, the latter being sandwiched in between the former, wherein each of the pair of electrode sheets comprises a mixture comprising an insulating elastomer and an electrode active substance powder and/or an inorganic solid electrolyte powder, in which mixture the electrode active substance powder and/or the inorganic solid electrolyte powder are dispersed in a volume fraction of 75-95% in the insulating elastomer, and said electrolyte sheet comprises a mixture of an inorganic solid electrolyte powder and an insulating elastomer and optionally an electrode active substance powder, in which mixture the inorganic solid electrolyte powder and optionally the electrode active substance powder are dispersed in a volume fraction of 55-95% in the insulating elastomer. Each of said electrode sheet and said electrolyte sheet may further comprise a reticulate material sheet, the openions of which are filled with the mixture. The structure is excellent in ion-conductivity, processability, productivity, storage stability and flexibility and enables one to make solid electrolyte cells, solid electric double layer capacitors and solid electrochromic display thinner and larger in area.
    • 一种结构,包括一对电极片和电解质片,后者被夹在前者之间,其中每对电极片包括包含绝缘弹性体和电极活性物质粉末和/或无机固体电解质的混合物 粉末,其中电极活性物质粉末和/或无机固体电解质粉末在绝缘弹性体中以75-95%的体积分数分散,并且所述电解质片材包含无机固体电解质粉末和绝缘体的混合物 弹性体和任选的电极活性物质粉末,其中无机固体电解质粉末和任选的电极活性物质粉末在绝缘弹性体中以55-95%的体积分数分散。 所述电极片和所述电解质片中的每一个可以进一步包括网状材料片,其开口填充有混合物。 该结构具有优异的离子传导性,加工性,生产率,储存稳定性和柔韧性,使得固体电解质电池,固体双电层电容器和固体电致变色显示器的面积更薄更大。
    • 28. 发明授权
    • Solid electrochemical element and production process therefor
    • 固体电化学元件及其生产工艺
    • US4977007A
    • 1990-12-11
    • US097367
    • 1987-09-08
    • Shigeo KondoTadashi Sotomura
    • Shigeo KondoTadashi Sotomura
    • H01M12/00G02F1/15H01G9/00H01G9/155H01M4/02H01M6/18
    • H01G9/155G02F1/1525H01M4/02H01M6/18H01M6/188Y02E60/13Y10T428/239Y10T428/24917Y10T428/25Y10T428/2933Y10T428/30Y10T428/31786Y10T428/31913Y10T428/31935
    • A solid electrochemical element which is flexible and has improved resistance to environmental exposure includes at least one solid electrolyte sheet which is flexible, has a pair of opposing surfaces, and is comprised of solid electrolyte particles and a plastic resin, which plastic resin was coated on each particle of the solid electrolyte particles prior to formation of the at least one solid electrolyte; and at least two electrode sheets comprised of an electrode material, one of the at least two electrode sheets being provided on each of the pair of opposing surfaces of the at least one solid electrolyte sheet, wherein an ion conductive path is formed between the pair of opposing surfaces of the at least one solid electrolyte sheet by virtual contact of the solid electrolyte particles and the electrode material. A process for producing the solid electrochemical element uses, as starting materials, (a) solid electrolyte particles coated with a thin layer of a plastic resin and (b) electrode material particles coated with a thin layer of a plastic resin, and preferably includes a step of crushing the solid electrolyte particles by pressing.
    • 柔性并且具有改善的耐环境暴露性的固体电化学元件包括至少一种柔性的固体电解质片,具有一对相对表面,并且由固体电解质颗粒和塑料树脂构成,该塑料树脂被涂覆在 所述固体电解质颗粒的每个颗粒在形成所述至少一种固体电解质之前; 以及至少两个由电极材料组成的电极片,所述至少两个电极片中的至少一个电极片中的一个设置在所述至少一个固体电解质片的所述一对相对表面中的每一个上,其中在所述一对电极片之间形成离子传导路径 通过固体电解质颗粒和电极材料的虚拟接触,至少一个固体电解质片的相对表面。 固体电化学元件的制造方法使用(a)涂覆有塑料树脂薄层的固体电解质颗粒和(b)涂覆有塑料树脂薄层的电极材料颗粒,优选包括 通过压制粉碎固体电解质颗粒的步骤。
    • 29. 发明授权
    • Solid electrolyte sheet and process for producing the same
    • 固体电解质片及其制造方法
    • US4828945A
    • 1989-05-09
    • US172165
    • 1988-03-23
    • Masaki NagataNaoshi YasudaShigeo KondoTadashi Sotomura
    • Masaki NagataNaoshi YasudaShigeo KondoTadashi Sotomura
    • C08K3/16H01G9/02H01G11/56H01M6/18H01M6/22
    • H01G9/038C08K3/16H01G11/56H01M6/18H01M6/181H01M6/22Y02E60/13
    • A solid electrolyte sheet comprising an ion-conductive inorganic solid electrolyte and an insulating elastomer, wherein the inorganic solid electrolyte powder is uniformly dispersed in the insulating elastomer in a volume fraction of 55-95% and which sheet has a hardness (ASTM A) of 65-96 and a thickness of 10-250 .mu.m, or a solid electrolyte sheet comprising a non-conductive reticulate material and a mixture of an ion-conductive inorganic solid electrolyte powder and an insulating elastomer, in which mixture the solid electrolyte powder is uniformly dispersed in the insulating elastomer in a volume fraction of 55-95%, at least the openings of the reticulate material being filled with said mixture. Said solid electrolyte sheets are superior in ion-conductivity, processability, productivity, storage stability and flexibility and are suitable for use in thin and large electrochemical elements.
    • 一种固体电解质片,包括离子传导性无机固体电解质和绝缘弹性体,其中所述无机固体电解质粉末以55-95%的体积分数均匀地分散在所述绝缘弹性体中,并且所述片的硬度(ASTM A)为 65-96和10-250μm的厚度,或包含非导电网状材料和离子传导无机固体电解质粉末和绝缘弹性体的混合物的固体电解质片,其中固体电解质粉末是 均匀地分散在绝缘弹性体中,体积分数为55-95%,网状材料的至少开口填充有所述混合物。 所述固体电解质片材的离子传导性,加工性,生产率,储存稳定性和柔软性都优异,适用于薄型和大型电化学元件。