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21. 发明授权

US5451642A Thermoplastic resin composition and article comprising the same 失效
标题翻译：热塑性树脂组合物及其制品
公开(公告)号：US5451642A
公开(公告)日：1995-09-19
申请号：US363587
申请日：1994-12-23
申请人： Hiroomi Abe , Takeshi Fujii , Kiyoshi Mitsui , Hideo Shinonaga , Satoru Sogabe , Satoru Hosoda , Keitaro Kojima
发明人： Hiroomi Abe , Takeshi Fujii , Kiyoshi Mitsui , Hideo Shinonaga , Satoru Sogabe , Satoru Hosoda , Keitaro Kojima
IPC分类号： C08L23/02 , C08L23/16 , C08L67/02 , C08L77/00 , C08L77/02
CPC分类号： C08L77/00 , C08L23/02 , C08L67/02 , C08G2261/312 , C08L23/16
摘要： A thermoplastic resin composition containing a polyamide resin composition (C) consisting of a polyamide resin (A) and another thermoplastic resin (B) and at least one modifier (D) is excellent in coatability, mechanical properties, linear expansion coefficient and appearance, can be molded into an article which comprises the polyamide resin (C), wherein the ratio of the percent occupied area of the polyamide resin on the surface of the article to the weight percentage of the polyamide in the polyamide resin composition (C) is not less than 1.2, and/or the ratio of the percent concentration of the polyamide resin on the surface of the article determined on the basis of the nitrogen concentration on the surface of the article to the weight percentage of the polyamide in the polyamide resin composition (C) is not less than 1,2, which article is suited for electric and electronic parts and automobile parts such as a bumper, fender and wheel cover.
摘要翻译：包含由聚酰胺树脂（A）和另一种热塑性树脂（B）组成的聚酰胺树脂组合物（C）和至少一种改性剂（D）的热塑性树脂组合物的涂布性，机械性能，线膨胀系数和外观都是优异的模塑成包含聚酰胺树脂（C）的制品，其中在聚酰胺树脂组合物（C）中，制品表面上的聚酰胺树脂的占占据面积与聚酰胺的重量百分比的比率不小于和/或基于制品表面上的氮浓度确定的制品表面上的聚酰胺树脂的浓度百分比与聚酰胺树脂组合物中的聚酰胺的重量百分比（C ）不小于1.2，该产品适用于电气和电子部件以及汽车部件，如保险杠，挡泥板和车轮罩。

22. 发明授权

US5420201A Thermoplastic resin composition comprising modified polypropylene, anhydride containing copolymer and epoxy containing copolymer 失效
标题翻译：包含改性聚丙烯，含酸酐的共聚物和含环氧的共聚物的热塑性树脂组合物
公开(公告)号：US5420201A
公开(公告)日：1995-05-30
申请号：US154533
申请日：1993-11-19
申请人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinji Date
发明人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinji Date
IPC分类号： C08L23/26 , C08F20/32 , C08F220/32 , C08G59/00 , C08K5/17 , C08L23/08 , C08L23/10 , C08L23/16 , C08L33/12 , C08L51/04 , C08L51/06 , C08L63/00 , C08L63/08
CPC分类号： C08L23/10 , C08L23/12 , C08L23/16 , C08L51/06 , C08L63/00 , C08L2205/03 , C08L2205/035 , C08L23/0815 , C08L33/12 , C08L53/02
摘要： A thermoplastic resin composition exhibiting excellent processability and producing remarkable advantages in that it gives far better physical properties than that expected from each polymer which constitutes the thermoplastic resin composition. The composition can be easily processed into molded articles, films and sheets and can give products which have well-balanced properties among stiffness, heat resistance, impact resistance, scratch resistance, coatability, oil-resistance, chemical resistance, water resistance, etc. and which are excellent in appearance, uniformity and smoothness.
摘要翻译：表现出优异的加工性和显着优点的热塑性树脂组合物，其具有比构成热塑性树脂组合物的每种聚合物所预期的更好的物理性能。该组合物可以容易地加工成模塑制品，薄膜和薄片，并且可以得到在刚度，耐热性，耐冲击性，耐刮擦性，涂布性，耐油性，耐化学性，耐水性等方面具有良好平衡性能的产品，其外观，均匀性和平滑性优异。

23. 发明授权

US5585437A Thermoplastic resin compositions comprising polyphenylene ether resins and thermoplastic resins which exhibit improved flow properties 失效
标题翻译：包含聚苯醚树脂和热塑性树脂的热塑性树脂组合物具有改进的流动性能
公开(公告)号：US5585437A
公开(公告)日：1996-12-17
申请号：US445856
申请日：1995-05-22
申请人： Tadayuki Ohmae , Sumio Hara , Hiroomi Abe , Kenji Nagaoka
发明人： Tadayuki Ohmae , Sumio Hara , Hiroomi Abe , Kenji Nagaoka
IPC分类号： C08L71/12 , C08L59/00 , C08L67/00 , C08L77/00 , C08L81/00 , C08L81/02 , C08L101/00 , C08L31/00 , C08L81/04
CPC分类号： C08L71/123 , C08L101/00 , C08L59/00 , C08L67/00 , C08L81/00
摘要： The present invention relates to a thermoplastic resin composition which comprises (C) 0.1 through 30 parts by weight of an adduct of alkylene oxide with a saponified copolymer of ethylene and vinyl ester of saturated carboxylic acid based on 100 parts by weight of a mixture of a crystalline thermoplastic resin (A) and a polyphenylene ether resin (B).In the resin composition, the crystalline thermoplastic resin (A) forms a continuous phase and the polyphenylene ether resin (B) forms a dispersed phase.The present invention provides a novel thermoplastic resin composition containing a polyphenylene ether resin, which has excellent flow properties, impact resistance and heat resistance.
摘要翻译：本发明涉及一种热塑性树脂组合物，其包含（C）0.1至30重量份的环氧烷烃与乙烯和饱和羧酸乙烯基酯的皂化共聚物的加合物，基于100重量份的结晶性热塑性树脂（A）和聚苯醚树脂（B）。在树脂组合物中，结晶性热塑性树脂（A）形成连续相，聚苯醚树脂（B）形成分散相。本发明提供含有聚苯醚树脂的新型热塑性树脂组合物，其具有优异的流动性，耐冲击性和耐热性。

24. 发明授权

US5385976A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US5385976A
公开(公告)日：1995-01-31
申请号：US867191
申请日：1992-07-02
申请人： Motonobu Furuta , Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto
发明人： Motonobu Furuta , Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto
IPC分类号： C08G65/48 , C08L51/06 , C08L51/08 , C08L67/00 , C08L71/00 , C08L71/02 , C08L71/12 , C08L75/00 , C08L77/00 , C08L81/00 , C08F255/02
CPC分类号： C08L51/06 , C08G65/485 , C08L51/08 , C08L71/126 , C08L67/00 , C08L71/00 , C08L71/02 , C08L75/00 , C08L77/00 , C08L81/00 , Y10S525/905
摘要： A thermoplastic resin composition comprising a modified polyphenylene ether to which an amino group-containing monomer such as amino styrene is grafted and a propylene polymer which is modified with a compound having a functional group reactive with an amino group in a molecule. This composition is excellent in heat resistance, chemical resistance, impact resistance and appearance and used to produce a part which is required to have strength and heat resistance such as an automobile part.
摘要翻译：包含接枝有氨基单体如氨基苯乙烯的改性聚苯醚的热塑性树脂组合物和在分子内具有与氨基反应的官能团的化合物改性的丙烯聚合物。该组合物的耐热性，耐化学性，耐冲击性和外观优异，并且用于制造要求具有强度和耐热性的部件如汽车部件。

25. 发明授权

US5278233A Thermoplastic resin composition 失效
公开(公告)号：US5278233A
公开(公告)日：1994-01-11
申请号：US713868
申请日：1991-06-12
申请人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinji Date
发明人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinji Date
IPC分类号： C08L23/26 , C08F20/32 , C08F220/32 , C08G59/00 , C08K5/17 , C08L23/08 , C08L23/10 , C08L23/16 , C08L33/12 , C08L51/04 , C08L51/06 , C08L63/00 , C08L23/12
CPC分类号： C08L23/10 , C08L23/12 , C08L23/16 , C08L51/06 , C08L63/00 , C08L2205/03 , C08L2205/035 , C08L23/0815 , C08L33/12 , C08L53/02
摘要： The thermoplastic resin composition disclosed herein comprises:(1) a resin composition consisting of(i) at least one member selected from the group consisting of(a) a modified polypropylene to which has been graft copolymerized an unsaturated carboxylic acid or the derivative thereof,(b) a modified polypropylene to which have been graft comodified an unsaturated aromatic monomer and either an unsaturated carboxylic acid or the derivative thereof,(c) a mixture of the modified polypropylene (a) and a polypropylene,(d) a mixture of the modified polypropylene (b) and a polypropylene,(e) a modified mixture of a polypropylene and a rubbery substance to which mixture has been graft copolymerized an unsaturated carboxylic acid or the derivative thereof,(f) a modified mixture of a polypropylene and a rubbery substance to which mixture have been graft copolymerized an unsaturated aromatic monomer and either an unsaturated carboxylic acid or the derivative thereof,(g) a mixture of the modified mixture (e) and a polypropylene, and(h) a mixture of the modified mixture (f) and a polypropylene, and(ii) a thermoplastic copolymer (E) containing acid anhydride moiety of six-membered ring, and(2) an epoxy group-containing copolymer (G).The thermoplastic resin composition according to the present invention not only exhibits excellent processability but also produces remarkable advantages in that it gives far better physical properties than those expected from each polymer which constitutes the thermoplastic resin composition of the present invention.The novel resin composition provided by the present invention can be easily processed into molded articles, films and sheets by a molding method generally used for thermoplastic resins such as injection molding, extrusion molding, etc, and can give products which have well-balanced properties among stiffness, heat resistance, impact resistance, scratch resistance, coatability, oil resistance, chemical resistance, water resistance, etc., and which are excellent in appearance uniformity and smoothness. The thermoplastic resin composition of the present invention is particularly suitable for use where well-balanced properties among heat resistance and impact resistance, low-temperature impact resistance in particular, are required.

26. 发明授权

US5212256A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US5212256A
公开(公告)日：1993-05-18
申请号：US610205
申请日：1990-11-08
申请人： Yukio Mizuno , Takashi Maruyama , Hiroomi Abe , Yutaka Terada
发明人： Yukio Mizuno , Takashi Maruyama , Hiroomi Abe , Yutaka Terada
IPC分类号： C08L61/20 , C08L71/12 , C08L77/00
CPC分类号： C08L71/123 , C08L77/00 , C08L61/20 , Y10S525/905
摘要： The present invention provides a thermoplastic resin composition which is improved in compatibility between polyphenylene ether and polyamide and is excellent in processability and impact strength. This composition comprises:(A) 100 parts by weight of a composition comprising 95-5% by weight of a polyphenylene ether obtained by oxidation polymerization of one or more of phenol compounds represented by the following formula: ##STR1## (wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 which may be identical or different, each represents a hydrogen atom, a halogen atom, a hydrocarbon radical or a substituted hydrocarbon radical and at least one of them is a hydrogen atom) and 5-95% by weight of a polyamide,(B) 0-30 parts by weight of an impact strength modifier, and(C) 0.01-10 parts by weight of an amino resin obtained by modifying with an alcohol an addition reaction product of formaldehyde and at least one compound selected from the group consisting of melamine, guanamine and urea.
摘要翻译：本发明提供一种提高聚苯醚和聚酰胺之间的相容性并且加工性和冲击强度优异的热塑性树脂组合物。该组合物包含：（A）100重量份的组合物，其包含95-5重量％的通过氧化聚合一种或多种下式表示的酚化合物获得的聚苯醚：其中R1，R2 可以相同或不同的R 3，R 4和R 5各自表示氢原子，卤素原子，烃基或取代烃基，并且其中至少一个为氢原子）和5-95重量％聚酰胺，（B）0-30重量份的冲击强度改性剂，和（C）0.01-10重量份通过用醇改性得到的氨基树脂，所述加成反应产物与所选择的至少一种化合物由三聚氰胺，胍胺和尿素组成。

27. 发明授权

US5139817A Method for surface treating and coating thermoplastic resin shaped articles 失效
标题翻译：表面处理和涂层热塑性树脂形状方法
公开(公告)号：US5139817A
公开(公告)日：1992-08-18
申请号：US678564
申请日：1991-03-13
申请人： Hiroomi Abe , Hideo Shinonaga , Kaoru Kitadono , Yasuro Suzuki , Satoru Sogabe
发明人： Hiroomi Abe , Hideo Shinonaga , Kaoru Kitadono , Yasuro Suzuki , Satoru Sogabe
IPC分类号： B05D3/06 , B29C59/00 , B29C59/16 , C08J7/00 , C08L67/00 , C08L71/12 , C08L77/00
CPC分类号： B29C59/16 , B05D3/063 , B29C59/005 , C08L71/123 , B29K2071/00 , C08L67/00 , C08L77/00
摘要： A method for surface treating a thermoplastic resin shaped article is disclosed, which comprises irradiating a surface of the shaped article with an ultraviolet light having a wavelength of 300 nm or less, said shaped article being obtained from a resin composition comprising (I) 100 parts by weight of a resin comprising from 5 to 100% by weight of a polyphenylene ether resin, a mixture of a polyphenylene ether resin and a styrene resin; or a graft copolymer of a polyphenylene ether resin and styrene and from 95 to 0% by weight of at least one thermoplastic resin selected from the group consisting of a polyamide resin and a saturated polyester resin; (II) from ) 0 to 50 parts by weight of a rubbery substance; (III) from 0 to 50 parts by weight of an inorganic filler and/or glass fibers; and (IV) from 0 to 10 parts by weight of at least one compatibilizer for improving the compatibility between said polyphenylene ether resin and said polyamide resin and/or saturated polyester resin. A method for coating said shaped article is also disclosed.

28. 发明授权

US5300568A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US5300568A
公开(公告)日：1994-04-05
申请号：US667408
申请日：1991-04-08
申请人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinichi Yachigo , Hideo Nagasaki , Naoki Inui
发明人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinichi Yachigo , Hideo Nagasaki , Naoki Inui
IPC分类号： C08K5/32 , C08K5/34 , C08L21/00 , C08L23/00 , C08L23/04 , C08L25/00 , C08L51/06 , C08L71/12 , C08L53/00
CPC分类号： C08L23/04 , C08K5/32 , C08K5/34 , C08L71/12 , Y10S525/905
摘要： A thermoplastic resin composition which comprises 100 parts by weight of a composition comprising 95-5% by weight of at least one polyolefin-resin (A) selected from homopolymers of ethylene or .alpha.-olefin or copolymers thereof and these homopolymers or copolymers modified with a polyfunctional compound (E) and/or an unsaturated monomer (L) and 5-95% by weight of at least one polyphenylene-ether-resin (B) selected from polyphenylene ether, modified polyphenylene ether with the above (E) and/or (L) and a composition comprising the polyphenylene or modified polyphenylene ether and an aromatic vinyl polymer resin (M) and 0.001-10 parts by weight of a dinitrodiamine (D) of the following formula (I). ##STR1## (wherein X represents a divalent chain aliphatic group, a cyclic aliphatic group or an aromatic group which may contain a halogen or an oxygen atom, R.sup.1 represents a hydrogen atom, a chain aliphatic group, a cyclic aliphatic group or an aromatic group and when both of X and R.sup.1 are chain aliphatic groups, the nitrogen atoms may further bond each other to form a ring through X and R.sup.1 ; R.sup.2 and R.sup.3 are independently a hydrogen atom or an alkyl group of 1-12 carbon atoms and R.sup.2 and R.sup.3 may bond to form a ring).
摘要翻译： PCT No.PCT / JP90 / 00759 Sec。 371日期：1991年4月8日 102（e）日期1991年4月8日PCT Filed 1990年6月11日PCT公布。 WO91 / 19762 PCT出版物日本1991年12月26日。一种热塑性树脂组合物，其包含100重量份的组合物，其包含95-5重量％的至少一种选自乙烯或（α-）α-烯烃或共聚物的均聚物的聚烯烃树脂（A）和由多官能化合物（E）和/或不饱和单体（L）改性的这些均聚物或共聚物和5-95重量％的至少一种选自聚苯醚，改性聚苯醚的聚苯醚树脂（B）与上述（E）和/或（L）和包含聚亚苯基或改性聚苯醚和芳族乙烯基聚合物树脂（M）的组合物和0.001-10重量份下式（I）的二硝基二胺（D））。（*化学结构*）（I）（其中X表示可以含有卤素或氧原子的二价链脂肪族基团，环状脂肪族基团或芳香族基团，R 1表示氢原子，链状脂肪族基团，环状脂族基团或芳香族基团，当X和R 1均为链状脂族基团时，氮原子可以进一步通过X和R 1彼此键合形成环; R2和R3独立地为氢原子或1- 12个碳原子，R2和R3可以键合形成环）。

29. 发明授权

US5280060A Thermoplastic resin composition containing a fluidity modifier 失效
标题翻译：含有流动性改性剂的热塑性树脂组合物
公开(公告)号：US5280060A
公开(公告)日：1994-01-18
申请号：US983252
申请日：1992-11-30
申请人： Hiroomi Abe , Takeshi Fujii , Kiyoshi Mitsui
发明人： Hiroomi Abe , Takeshi Fujii , Kiyoshi Mitsui
IPC分类号： C08K5/09 , C08K5/17 , C08K5/21 , C08K5/16
CPC分类号： C08K5/17 , C08K5/09 , C08K5/21
摘要： A thermoplastic resin composition comprises:100 parts by weight of at least one polyamide resin, and0.01 to 20 parts by weight of at least one fluidity modifier selected from the group consisting of:Succinic anhydride,hexamethylenetetramine and1,12-diaminododecane.
摘要翻译：热塑性树脂组合物包括：100重量份的至少一种聚酰胺树脂和0.01至20重量份的选自琥珀酸酐，六亚甲基四胺和1,12-二氨基十二烷的至少一种流动性改性剂。

30. 发明授权

US5185188A Method for surface treating and coating resin composition molded articles 失效
标题翻译：表面处理和涂料树脂组合物成型制品的方法
公开(公告)号：US5185188A
公开(公告)日：1993-02-09
申请号：US616969
申请日：1990-11-21
申请人： Hiroomi Abe , Hideo Shinonaga , Kiyoshi Mitsui , Satoru Sogabe
发明人： Hiroomi Abe , Hideo Shinonaga , Kiyoshi Mitsui , Satoru Sogabe
IPC分类号： B29C35/08 , B29C59/00 , B29C59/16 , C08K5/00 , C08K5/17 , C08L23/12 , C08L51/06
CPC分类号： C08L23/12 , B29C59/005 , B29C59/16 , C08K5/0008 , C08K5/17 , C08L51/06 , B29C2035/0827 , B29K2023/12 , Y10T428/31562 , Y10T428/31565 , Y10T428/31587
摘要： A method for surface treating a resin composition molded article and a method for coating a resin composition molded article are disclosed, which comprise irradiating a molded article with ultraviolet light having an irradiation wavelength in the region of 300 nm or less and, if desired, coating the thus UV-irradiated surface with a coating, the molded article being obtained from a resin composition comprising (I) 100 parts by weight of a resin composition comprising (A) from 5 to 99.5% by weight of a polypropylene resin selected from the group consisting of polypropylene, modified polypropylene, and a modified polypropylene/polypropylene composition and (B) from 0.5 to 95% by weight of at least one thermoplastic resin selected from the group consisting of a polyamide resin, a polyphenylene ether resin, a mixture of a polyphenylene ether resin and a styrene resin, a graft copolymer of a polyphenylene ether resin and styrene, and a saturated polyester resin; and (II) up to 30 parts by weight of at least one compatibilizer for improving compatibility between the polypropylene resin (A) and the thermoplastic resin (B), the compatabilizer being selected from the group consisting of an unsaturated carboxylic acid compound having at least one carboxyl group in the molecule thereof or a derivative thereof, a diamine compound having at least two nitrogen atoms in the molecule thereof or a derivative thereof, and an epoxy-containing copolymer.

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