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21. 发明授权

US4119687A Process for the production of powder-form hydrolyzed ethylene/vinyl acetate copolymers 失效
标题翻译：制备粉末状水解乙烯/乙酸乙烯酯共聚物的方法
公开(公告)号：US4119687A
公开(公告)日：1978-10-10
申请号：US777331
申请日：1977-03-14
申请人： Raoul Resz , Herbert Bartl , Karl Nothen , Joachim Priemer , Aziz El-Sayed
发明人： Raoul Resz , Herbert Bartl , Karl Nothen , Joachim Priemer , Aziz El-Sayed
IPC分类号： C08J3/12 , B29B9/06 , B29K29/00 , C08F2/06 , C08F8/12 , C08J3/14 , B01J2/06
CPC分类号： C08J3/14 , B29C47/00 , C08F8/12 , C08F2800/20 , C08F2810/50 , Y10S524/904
摘要： A process for the production of partially or completely hydrolyzed ethylene/vinyl acetate copolymer which is suitable for the various powder coating techniques, wherein the polymer solution is extruded in a non-gelled state into water with a temperature no more than 20.degree. C below the gellation temperature and the gelling solution is converted into particles from 0.02 to 5 mm in diameter by means of high shear forces.
摘要翻译：一种用于生产部分或完全水解的乙烯/乙酸乙烯酯共聚物的方法，其适用于各种粉末涂料技术，其中将聚合物溶液以非胶凝状态挤出至不超过20℃的温度的水中胶凝温度和胶凝溶液通过高剪切力转化成直径为0.02至5mm的颗粒。

22. 发明授权

US4071580A Graft polymers 失效
标题翻译：接枝聚合物
公开(公告)号：US4071580A
公开(公告)日：1978-01-31
申请号：US662263
申请日：1976-02-27
申请人： Heinrich Alberts , Herbert Bartl
发明人： Heinrich Alberts , Herbert Bartl
IPC分类号： C08F255/00 , C08F255/02 , C08F291/06 , C08F263/02 , C08F263/04
CPC分类号： C08F255/02 , C08F291/06
摘要： A process for the preparation of graft polymers from ethylene homopolymers or copolymers and olefinically unsaturated monomers, especially from ethylene/vinyl ester copolymers, in the presence of a radical forming agent in homogenous or heterogeneous phase, in which a mixture of (meth)acrylonitrile, at least one aromatic vinyl compound and vinylchloride are polymerized in the presence of an ethylene homopolymer or copolymer. The products obtained contain no ungrafted styrene/acrylonitrile copolymer and more than 80% by weight of the graft polymer is chemically almost uniform in structure. The products obtained according to the invention are eminently suitable for use as coating materials and as materials which can be thermoplastically processed.
摘要翻译：一种在乙烯均聚物或共聚物和烯属不饱和单体，特别是乙烯/乙烯基酯共聚物的自由基形成剂存在下在均相或非均相中制备接枝聚合物的方法，其中（甲基）丙烯腈，在乙烯均聚物或共聚物存在下聚合至少一种芳族乙烯基化合物和氯乙烯。获得的产品不含未接枝的苯乙烯/丙烯腈共聚物，并且大于80重量％的接枝聚合物在结构上化学上几乎均匀。根据本发明获得的产品非常适合用作涂料和作为可热塑化处理的材料。

23. 发明授权

US3968184A Impact-resistant polyvinyl chloride grafted ethylene-vinyl esters 失效
标题翻译：耐冲击聚氯乙烯接枝乙烯 - 乙烯基酯
公开(公告)号：US3968184A
公开(公告)日：1976-07-06
申请号：US457259
申请日：1974-04-02
申请人： Dietrich Hardt , Heinrich Alberts , Herbert Bartl
发明人： Dietrich Hardt , Heinrich Alberts , Herbert Bartl
IPC分类号： C08L27/00 , C08L1/00 , C08L23/00 , C08L27/06 , C08L51/00 , C08L51/02 , C08L51/06 , C08L101/00 , C08J9/16 , C08L33/18
CPC分类号： C08L27/06 , C08L51/003 , C08L51/06
摘要： Moulding compounds with improved impact strength and weather resistance comprising mixtures of polyvinylchloride and graft polymers prepared from ethylene/vinyl ester copolymers on which have been grafted units of monomer mixtures of aromatic vinyl compounds, (meth)acrylonitrile and aliphatic monoolefins.
摘要翻译：具有改进的冲击强度和耐候性的成型化合物包括由乙烯/乙烯基酯共聚物制备的聚氯乙烯和接枝聚合物的混合物，其上已经接枝了芳族乙烯基化合物，（甲基）丙烯腈和脂族单烯烃的单体混合物。

24. 发明授权

US4873289A Graft polymers and blends thereof with polyamides 失效
标题翻译：接枝聚合物及其与聚酰胺的共混物
公开(公告)号：US4873289A
公开(公告)日：1989-10-10
申请号：US246887
申请日：1988-09-15
申请人： Christian Lindner , Dieter Wittmann , Ludwig Trabert , Carlhans Suling , Herbert Bartl , Karl-Heinz Ott
发明人： Christian Lindner , Dieter Wittmann , Ludwig Trabert , Carlhans Suling , Herbert Bartl , Karl-Heinz Ott
IPC分类号： C08F291/00 , C08F291/02 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L77/00 , C08L101/00
CPC分类号： C08F291/02 , C08L77/00
摘要： The invention relates to new graft polymers based on elastomers as the graft base and grafted-on vinyl monomers, their preparation and blend thereof with polyamides.
摘要翻译：本发明涉及基于弹性体作为接枝基质和接枝的乙烯基单体的新型接枝聚合物，其与聚酰胺的制备和共混。

25. 发明授权

US4691036A Organic nickel compounds, the production thereof and the use thereof as polymerization catalysts 失效
标题翻译：有机镍化合物，其生产方法及其作为聚合催化剂的用途
公开(公告)号：US4691036A
公开(公告)日：1987-09-01
申请号：US830330
申请日：1986-02-18
申请人： Karl-Heinz A. O. Starzewski , Josef Witte , Herbert Bartl
发明人： Karl-Heinz A. O. Starzewski , Josef Witte , Herbert Bartl
IPC分类号： C08F4/00 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C07F15/04
CPC分类号： C08F4/80 , C08F10/00
摘要： Nickel compounds which can be produced by reacting a nickel(O) compound or a nickel compound, which can be converted in situ into a nickel(O) compound, with an adduct or a mixture of maleic acid anhydride and a tertiary phosphine, optionally with a compound of the formula (I) ##STR1## wherein X represents O, NR.sup.4 or ##STR2## and n represents zero or one,and optionally with an organoaluminium compound, are suitable for the homo-and copolymerization of 1-olefins and for the polymerization of acetylene.
摘要翻译：可以通过使镍（O）化合物或镍化合物原位转化成镍（O）化合物的镍化合物与马来酸酐和叔膦的加合物或混合物任选地与式（I）的化合物其中X代表O，NR4或者“IMA”，n代表0或1，并且任选地与有机铝化合物一起适用于1-烯烃的均相和共聚并用于乙炔的聚合。

26. 发明授权

US4297455A Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups and their use for the preparation of polyester-diol bis-diphenol carbonates and polyester/polycarbonates 失效
标题翻译：通过碳酸酯基延长的聚酯二醇的碳酸芳酯的制备方法及其用于制备聚酯 - 二醇双二酚碳酸酯和聚酯/聚碳酸酯的用途
公开(公告)号：US4297455A
公开(公告)日：1981-10-27
申请号：US910986
申请日：1978-05-30
申请人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
发明人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
IPC分类号： C08G63/64 , C08G63/00 , C08G63/76
CPC分类号： C08G63/64
摘要： The present invention relates to a process for the preparation of bis-carbonic acid aryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups obtained according to the instant invention and their use for the preparation of polyester diol bis-diphenol carbonates, lengthened via carbonate groups, characterized in that polyester-diol bis-aryl carbonates are reacted with a diphenol at a temperature of from about 100.degree. to about 200.degree. C. in vacuo below about 35 mm Hg in the presence of a catalyst, wherein more than 1 mol of diphenol is employed per mol of carbonic acid aryl ester groups of the polyester-diol bis-aryl carbonate, lengthened via carbonate groups, and the resulting hydroxyaryl compound is distilled off.The invention finally relates to the polyester-diol bis-diphenol carbonates, lengthened via carbonate groups obtained according to the instant invention and their use for the preparation of polyester/polycarbonates and the polycarbonate/polyesters so prepared.
摘要翻译：本发明涉及通过-OCOO-基团延长的聚酯二醇的双碳酸芳基酯的制备方法，其特征在于分子量Mn（数均分子）超过250的聚酯二醇优选超过 600，在约100℃至200℃之间，优选约110℃至180℃之间的温度下，用碳酸双芳基酯加热，真空度低于约35mmHg，优选约25mm 和1mm Hg，在催化剂的存在下，每聚酯二醇的OH基和所形成的羟基芳基化合物使用少于1摩尔的碳酸双芳基酯。本发明还涉及通过根据本发明获得的-OCOO-基团延长的聚酯二醇的双碳酸芳基酯及其用于制备通过碳酸酯基团延长的聚酯二醇双 - 二酚酚酸酯的用途，其特征在于在催化剂存在下，聚酯 - 二醇双芳基碳酸酯与二酚在约100至约200℃的温度下在真空下在约35mm Hg下真空反应，其中每次使用多于1mol的二酚将通过碳酸酯基延长的聚酯 - 二醇双芳基碳酸酯的碳酸芳基酯基和所得羟基芳基化合物蒸馏出。本发明最终涉及通过根据本发明获得的碳酸酯基团延长的聚酯 - 二醇双 - 二酚碳酸酯及其制备聚酯/聚碳酸酯和如此制备的聚碳酸酯/聚酯的用途。

27. 发明授权

US4217437A Process for the preparation of carbonic acid bis-diphenol esters of polyalkylene oxide-diols lengthened via carbonate groups and their use for the preparation of high-molecular, segmented polyether/polycarbonates which can be processed as thermoplastics 失效
标题翻译：通过碳酸酯基加成的聚环氧烷 - 二醇的碳酸双 - 二酚酯的制备方法及其用于制备高分子，分段聚醚/聚碳酸酯的方法，可以加工成热塑性塑料
公开(公告)号：US4217437A
公开(公告)日：1980-08-12
申请号：US913773
申请日：1978-06-08
申请人： Manfred Schreckenberg , Dieter Freitag , Christian Lindner , Carlhans Suling , Herbert Bartl , Klaus Konig
发明人： Manfred Schreckenberg , Dieter Freitag , Christian Lindner , Carlhans Suling , Herbert Bartl , Klaus Konig
IPC分类号： C08G63/00 , B01J31/00 , C07B61/00 , C07C67/00 , C07C69/96 , C07C313/00 , C07C315/04 , C07C317/22 , C07C319/20 , C07C323/20 , C08G64/00 , C08G64/16 , C08G64/18 , C08G64/20 , C08G64/22 , C08G64/24 , C08G64/30 , C08G63/62
CPC分类号： C08G64/183
摘要： The present invention relates to the transesterification of the carbonic acid aryl esters obtainable according to German Published Patent Specification No. 2,650,533 with an excess of diphenol for the preparation of polyalkylene oxide-diol bis-diphenol carbonates lengthened via carbonate groups. The present invention also relates to the polyalkylene oxide-diol bis-diphenol carbonates, lengthened via carbonate groups, obtained according to the invention and their use for the preparation of polyether/polycarbonates. Finally, the present invention relates to the polyether/polycarbonates, obtained according to the invention, with an improved phase separation between the elastomeric segment and hard segment, which leads to better technological properties of the corresponding polycarbonate elastomers.
摘要翻译：本发明涉及根据德国公开专利说明书2,650,533可得到的碳酸芳基酯与过量的二酚的酯交换反应，用于制备通过碳酸酯基团延长的聚亚烷基氧化物 - 二醇双酚酚碳酸酯。本发明还涉及根据本发明获得的通过碳酸酯基延长的聚环氧烷 - 二醇双 - 二酚碳酸酯及其在制备聚醚/聚碳酸酯中的用途。最后，本发明涉及根据本发明获得的聚醚/聚碳酸酯，其在弹性链段和硬链段之间具有改进的相分离，这导致相应的聚碳酸酯弹性体的更好的技术性能。

28. 发明授权

US4217297A Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups 失效
标题翻译：通过碳酸酯基团延长的聚酯二醇的碳酸芳酯的制备方法
公开(公告)号：US4217297A
公开(公告)日：1980-08-12
申请号：US886212
申请日：1978-03-13
申请人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
发明人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
IPC分类号： C08G63/00 , C08G63/64 , C08G63/66 , C07C68/06 , C08G63/62
CPC分类号： C08G63/64
摘要： The present invention relates to a process for the preparation of bis-carbonic acid monoaryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per mol of OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups.
摘要翻译：本发明涉及通过-OCOO-基团来制备聚酯二醇的双碳酸单芳基酯的方法，其特征在于分子量Mn（数均分子）超过250的聚酯二醇优选超过 600，在约100℃至200℃之间，优选约110℃至180℃之间的温度下，用碳酸双芳基酯加热，真空度低于约35mmHg，优选约25mm 和1mm Hg，在催化剂的存在下，每摩尔聚酯二醇的OH基和所形成的羟基芳基化合物使用少于1摩尔的碳酸双芳基酯。本发明还涉及通过-OCOO-基团延长的聚酯二醇的双碳酸芳基酯。

29. 发明授权

US4005037A Polycarbonate-polyvinyl chloride moulding compounds 失效
标题翻译：聚碳酸酯 - 聚氯乙烯模塑料
公开(公告)号：US4005037A
公开(公告)日：1977-01-25
申请号：US540981
申请日：1975-01-14
申请人： Fritz Mietzsch , Dietrich Hardt , Volker Serini , Herbert Bartl , Hugo Vernaleken
发明人： Fritz Mietzsch , Dietrich Hardt , Volker Serini , Herbert Bartl , Hugo Vernaleken
IPC分类号： C08F14/00 , C08F283/00 , C08F283/02 , C08F291/00 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L51/08 , C08L77/00 , C08L87/00 , C08L101/00 , C08L67/06
CPC分类号： C08F283/00 , C08F283/02 , C08L51/08
摘要： Process for the production of vinyl chloride polymers modified with aromatic polycarbonate, characterized in that mixtures of olefinically unsaturated monomers containing at least 70 % by weight of vinyl chloride are polymerized by radical polymerization in the presence of aromatic polycarbonates, 0 - 100 % by weight of rubber or rubber-modified thermoplastic resin, based on the polycarbonate-modified vinyl chloride polymer, being added before or after polymerization.
摘要翻译：用于制备用芳族聚碳酸酯改性的氯乙烯聚合物的方法，其特征在于含有至少70重量％氯乙烯的烯属不饱和单体的混合物在芳族聚碳酸酯存在下通过自由基聚合而聚合，0-100重量％在聚合之前或之后加入基于聚碳酸酯改性的氯乙烯聚合物的橡胶或橡胶改性的热塑性树脂。

30. 发明授权

US3993710A Polymerizable organic dispersions 失效
标题翻译：可聚合的有机分散体
公开(公告)号：US3993710A
公开(公告)日：1976-11-23
申请号：US589949
申请日：1975-06-24
申请人： Heinrich Alberts , Klaus Schuster , Herbert Bartl , Hansjochen Schulz-Walz
发明人： Heinrich Alberts , Klaus Schuster , Herbert Bartl , Hansjochen Schulz-Walz
IPC分类号： C08L23/00 , C08F210/00 , C08J5/24 , C08L33/00 , C08L33/02 , C08L67/00 , C08L67/06 , C08L101/00 , C08L23/08
CPC分类号： C08L67/06
摘要： Dispersions suitable for the manufacture of moulding compositions which can be cured with low shrinkage to give mouldings with excellent surfaces can be obtained by the addition of finely divided ethylene copolymers manufactured in aqueous emulsion to unsaturated polyester resins.
摘要翻译：可以通过向不饱和聚酯树脂中加入以水性乳液制造的精细分散的乙烯共聚物来获得适于制造可以以低收缩率固化以得到具有优异表面的模制品的模塑组合物的分散体。

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