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21. 发明申请

US20090010860A1 Merocyanine Derivatives 有权
公开(公告)号：US20090010860A1
公开(公告)日：2009-01-08
申请号：US11630489
申请日：2005-06-20
申请人： Barbara Wagner , Frank Bienewald , Heinz Wolleb , Olof Wallquist , Bernd Herzog , Thomas Ehlis , Jurg Haase
发明人： Barbara Wagner , Frank Bienewald , Heinz Wolleb , Olof Wallquist , Bernd Herzog , Thomas Ehlis , Jurg Haase
IPC分类号： A61K8/49 , C07D309/38 , A61K31/366 , A61K31/505 , C07D239/26 , C07D207/08 , A61K31/40 , A61Q17/04
CPC分类号： A61K8/498 , A61K8/4913 , A61K8/494 , A61Q17/04
摘要： Disclosed is the use of the compounds of formula wherein Q is —OH; —OR7; —NH2; —NHR7; —NR7R8; or —N═R9; T is —COR5; —CN; or —SO2—(C6-C12)aryl; R1 is hydrogen; —OR7, —SR7; —NHR7; —NR7R8; C1-C22alkyl; C2-C12Alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl, C2-C11heteroaralkyl; C6-C10aryl; or C1-C9heteroaryl; R2 and R3 independently from each other are C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl, C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl; C3-C12cycloheteroalkyl; C2-C11heteroaralkyl, C6-C10aryl; or C1-C9heteroaryl; R4 is cyano; COR7, COOR7; CONH2; CONHR7; CONR7R8; SO2(C6-C12)aryl, C2-C12alk-1-enyl; C3-C12cycloalk-1-enyl; C2-C12alk-1-inyl; C2-C12heteroalkyl, C3-C5heterocycloalkyl, C6-C10aryl; or C1-C9heteroaryl; R5 is —COR7; —COOR7; —OR7; —SR7, —NHR7, —NR7R8; C2-C12alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12alkylphenyl; C1-C12alkoxy-C8-C10aryl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C3-C12cycloheteroalkyl; C6-C10aryl; C1-C12alkoxy-C8-C10aryl or C1-C9heteroaryl; R6, R7 and R8 independently from each other are hydrogen; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C6-C10aryl; o-C6-C10aryl; or C1-C9heteroaryl; R9 is a (C1-C6)alkylidene radical; or R1 and R2, R1 and Q, R1 and R4, R1 and R8, R2 and R3, R3 and Q, R6 and Q, T and Q, each independently, are linked together, so that 1, 2, 3 or 4 carbocyclic or N, O and/or S-heterocyclic rings are formed, wherein each of them, independently from each other, may be condensed with an aromatic or heteroaromatic ring, and/or more N-, O- and/or S-heterocycic rings, and each N atom in a N-heterocyclic ring may be substituted by C1-C22alkyl; and n is a number from 1 to 4; for protecting of human hair and skin against the damaging effect of UV radiation.

22. 发明申请

US20050033086A1 Process for the preparation of 7-amino syn 3,5-dihydroxy heptanoic acid derivatives via 6-cyano syn 3,5-dihydroxy hexanoic acid derivatives 失效
标题翻译：通过6-氰基顺式3,5-二羟基己酸衍生物制备7-氨基顺式3,5-二羟基庚酸衍生物的方法
公开(公告)号：US20050033086A1
公开(公告)日：2005-02-10
申请号：US10481704
申请日：2002-07-02
申请人： Reinhold Ohrlein , Gabriele Baisch , Hans Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
发明人： Reinhold Ohrlein , Gabriele Baisch , Hans Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
IPC分类号： C07C67/307 , C07B53/00 , C07B61/00 , C07C67/30 , C07C67/31 , C07C69/67 , C07C69/675 , C07C69/708 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/06 , C07C227/16 , C07C227/32 , C07C229/22 , C07C231/02 , C07C235/06 , C07C235/74 , C07C247/12 , C07C253/30 , C07D207/34 , C12P7/62
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and Rb is a carboxy-protecting group, which methods are carried out by conversion of the intermediate of formula XIX wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group, and Rb is a carboxy-protective group.
摘要翻译：本发明涉及适用于制备他汀类衍生物的中间体的新型合成方法，特别是式VI中间体的新合成方法，其中R a和R c各自独立地为氢或羟基 - 保护基或一起是桥接羟基保护基，Rb是羧基保护基，该方法通过式XIX的中间体转化而进行，其中R a和R c各自独立地为氢或羟基保护基基团，Rb是羧基保护基。

23. 发明授权

US06207853B1 Homogeneous asymmetric hydrogenation using phosphine ligands of transition metals 有权
标题翻译：使用过渡金属膦配体的均相不对称氢化
公开(公告)号：US06207853B1
公开(公告)日：2001-03-27
申请号：US09213745
申请日：1998-12-17
申请人： Mark Joseph Burk , Frank Bienewald , Martin Edward Fox , Antonio Zanotti-Gerosa
发明人： Mark Joseph Burk , Frank Bienewald , Martin Edward Fox , Antonio Zanotti-Gerosa
IPC分类号： C07C6976
CPC分类号： C07C67/303 , C07C69/34
摘要： A process for the preparation of an enantiomerically enriched 2-substituted succinic acid derivative of formula 2, which comprises asymmetric hydrogenation of the dehydro precursor of formula 7 or 8, or a mixture thereof wherein R1 and R2 are independently H, a salt-forming cation, or an organic group of up to 30 C atoms, and R3 and R4 are independently H or an organic group of up to 30 C atoms, provided that R3 and R4 are not both H, in the presence of a transition metal complex of a chiral phosphine ligand having the partial formula 10 wherein n is 0 to 6 and R represents at least one non-hydrogen organic group of up to 30 C atoms.
摘要翻译：制备式2的对映体富集的2-取代琥珀酸衍生物的方法，其包括式7或8的脱氢前体或其混合物的不对称氢化，其中R1和R2独立地为H，成盐阳离子，或至多30个C原子的有机基团，并且R3和R4独立地为H或至多30个C原子的有机基团，条件是在手性的过渡金属络合物存在下，R 3和R 4不同时为H 具有部分式10的膦配体，其中n为0至6，R表示至多一个至多30个C原子的非氢有机基团。

24. 发明授权

US08101776B2 Organic semiconductors and their manufacture 有权
标题翻译：有机半导体及其制造
公开(公告)号：US08101776B2
公开(公告)日：2012-01-24
申请号：US12086157
申请日：2006-12-04
申请人： Ulrich Berens , Frank Bienewald , Hans Jürg Kirner
发明人： Ulrich Berens , Frank Bienewald , Hans Jürg Kirner
IPC分类号： C07D277/60
CPC分类号： H01L51/0071 , C07D471/04 , C07D487/04 , C07D493/04 , C07D495/04 , C07D495/22 , C07D513/04 , C09B5/026 , C09B5/14 , C09B5/60 , C09B57/00 , C09B69/008 , H01L51/0058 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0074 , H01L51/0083 , H01L51/0094 , H01L51/0525 , H01L51/0545
摘要： The invention relates to a semiconductor device comprising a compound of the formula I and of the formula XXI, wherein the symbols have the meanings defined in the specification, to the novel compounds of the formula I and XXI and to the use of such a compound as an organic semiconductor for the preparation of an electronic device, and further compounds and devices, as well as other embodiments given in the specification.
摘要翻译：本发明涉及一种半导体器件，其包含式I和式XXI的化合物，其中符号具有本说明书中定义的含义与式I和XXI的新型化合物以及使用这样的化合物用于制备电子器件的有机半导体，以及本说明书中给出的其它化合物和器件以及其它实施方案。

25. 发明申请

US20110004004A1 PYRROLOPYRROLE DERIVATIVES, THEIR MANUFACTURE AND USE 有权
标题翻译：吡咯烷酮衍生物及其制备和使用
公开(公告)号：US20110004004A1
公开(公告)日：2011-01-06
申请号：US12680904
申请日：2008-09-22
申请人： Zhimin Hao , Beat Schmidhalter , Jean-Luc Budry , Margherita Fontana , Matheiu G.R. Turbiez , Frank Bienewald , Mathias Duggeli , Oliver Frederic Aebischer , Pascal Hayoz , Marta Fondrodona Turon
发明人： Zhimin Hao , Beat Schmidhalter , Jean-Luc Budry , Margherita Fontana , Matheiu G.R. Turbiez , Frank Bienewald , Mathias Duggeli , Oliver Frederic Aebischer , Pascal Hayoz , Marta Fondrodona Turon
IPC分类号： C07D487/04
CPC分类号： H01L51/0071 , C07D487/04 , C09B57/004 , H01L51/0053 , H01L51/0058 , H01L51/0068 , H01L51/0095 , Y02E10/549
摘要： The present invention relates to compounds of the formula (I) wherein the substituents are as defined in claim 1, and their use as organic semiconductor in organic devices, like diodes, organic field effect transistors and/or a solar cells. The compounds of the formula I have excellent solubility in organic solvents. High efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when said compounds are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).
摘要翻译：本发明涉及式（I）化合物，其中取代基如权利要求1中所定义，及其作为有机半导体在有机器件中的用途，如二极管，有机场效应晶体管和/或太阳能电池。式I的化合物在有机溶剂中具有优异的溶解性。当所述化合物用于半导体器件或有机光伏（PV）器件（太阳能电池））时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的导通/截止电流比和/或优异的稳定性。

26. 发明授权

US07692034B2 Process for the preparation of 7-amino syn 3,5-dihydroxy heptanoic acid derivatives via 6-cyano syn 3,5-dihydroxy hexanoic acid derivatives 失效
标题翻译：通过6-氰基顺式3,5-二羟基己酸衍生物制备7-氨基顺式3,5-二羟基庚酸衍生物的方法
公开(公告)号：US07692034B2
公开(公告)日：2010-04-06
申请号：US11657808
申请日：2007-01-24
申请人： Reinhold Öhrlein , Gabriele Baisch , Hans Jürg Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
发明人： Reinhold Öhrlein , Gabriele Baisch , Hans Jürg Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
IPC分类号： C07C229/00
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and Rb is a carboxy-protecting group, which methods are carried out by conversion of the intermediate of formula XIX wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group, and Rb is a carboxy-protective group.
摘要翻译：本发明涉及适用于制备他汀类衍生物的中间体的新型合成方法，特别是式VI中间体的新合成方法，其中R a和R c各自独立地为氢或羟基 - 保护基或一起是桥接羟基保护基，Rb是羧基保护基，该方法通过式XIX的中间体转化而进行，其中R a和R c各自独立地为氢或羟基保护基基团，Rb是羧基保护基。

27. 发明申请

US20080193700A1 Metal Chelates and Their Use in Optical Recording Media Having High Storage Capacity 审中-公开
标题翻译：金属螯合物及其在具有高存储容量的光记录介质中的应用
公开(公告)号：US20080193700A1
公开(公告)日：2008-08-14
申请号：US11579261
申请日：2005-04-25
申请人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry
发明人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry
IPC分类号： B32B3/00 , C07D277/64 , C07D401/06 , C07F9/6541
CPC分类号： G11B7/246 , C07D277/64 , C07D277/84 , C07D417/06 , C07D513/04 , C07F17/02 , G11B7/2467 , G11B7/249 , G11B7/2492 , G11B7/2495 , G11B7/2534 , G11B7/259 , G11B2007/24612 , G11B2007/25706 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715
摘要： The invention relates to novel optical recording media, which comprise particular novel metal chelates and have an excellent recording and playback quality, especially at a wavelength of from 300 to 500 nm.
摘要翻译：本发明涉及新颖的光学记录介质，其包含特别新颖的金属螯合物，并且具有优异的记录和回放质量，特别是在300-500nm的波长下。

28. 发明申请

US20080125601A1 PROCESS FOR THE PREPARATION OF 7-AMINO SYN 3,5-DIHYDROXY HEPTANOIC ACID DERIVATIVES, INTERMEDIATES THEREOF AND METHODS FOR THEIR PREPARATION 失效
标题翻译：制备7-氨基-3,5-二羟基丙酸衍生物的方法，其中间体及其制备方法
公开(公告)号：US20080125601A1
公开(公告)日：2008-05-29
申请号：US11941347
申请日：2007-11-16
申请人： Reinhold Ohrlein , Gabriele Baisch , Hans Jorg Kirner , Stephan Burkhardt , Martin Studer , Frank Bienewald
发明人： Reinhold Ohrlein , Gabriele Baisch , Hans Jorg Kirner , Stephan Burkhardt , Martin Studer , Frank Bienewald
IPC分类号： C07C233/08
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： Synthesis methods for the preparation of intermediates which are suitable for the preparation of statin derivatives, and especially to synthesis methods for the intermediate of formula (VI) wherein Ra′ and Rc′ are each independently of the other hydrogen or hydroxy-protecting group, or together are a bridging hydroxy-protecting group; and Rb is a carboxy-protecting group.
摘要翻译：制备适于制备他汀类衍生物的中间体的合成方法，特别是其中R a和R c的中间体的合成方法各自独立地为氢或羟基保护基，或者一起是桥羟基保护基; R b是羧基保护基。

29. 发明授权

US07317123B2 Process for preparation of 7-amino syn 3,5-dihydroxy heptanoic acid derivatives, intermediates thereof and methods for their preparation 失效
标题翻译： 7-氨基顺式3,5-二羟基庚酸衍生物的制备方法，其中间体及其制备方法
公开(公告)号：US07317123B2
公开(公告)日：2008-01-08
申请号：US10482946
申请日：2002-07-02
申请人： Reinhold Öhrlein , Gabriele Baisch , Hans Jörg Kirner , Stephan Burkhardt , Martin Studer , Frank Bienewald
发明人： Reinhold Öhrlein , Gabriele Baisch , Hans Jörg Kirner , Stephan Burkhardt , Martin Studer , Frank Bienewald
IPC分类号： C07C229/00 , C07C233/00
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein Ra′ and Rc′ are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and Rb is a carboxy-protecting group, which methods are carried out by conversion of the intermediate of formula XVI wherein Ra′ and Rc′ are each independently of the other hydrogen or a hydroxy-protecting group, R* and R** are each independently of the other hydrogen or an amide-protecting group, and Rb is a carboxy-protecting group; which methods proceed to further new intermediates and methods for their preparation
摘要翻译：本发明涉及用于制备适于制备他汀类衍生物的中间体的新型合成方法，特别涉及式VI中间体的新型合成方法，其中R a'和R“ > C独立地是氢或羟基保护基，或者一起是桥接羟基保护基，R b是羧基保护基，这些方法是通过式XVI的中间体的转化而进行，其中R a a和R c'各自独立地是氢或羟基保护基，R *和R **各自独立地为另一个氢或酰胺保护基团，并且R b为羧基保护基团; 哪些方法进行进一步的新中间体及其制备方法

30. 发明授权

US07199261B2 Process for the preparation of 7-amino syn 3,5-dihydroxy heptanoic acid derivatives via 6-cyano syn 3,5-dihydroxy hexanoic acid derivatives 失效
标题翻译：通过6-氰基顺式3,5-二羟基己酸衍生物制备7-氨基顺式3,5-二羟基庚酸衍生物的方法
公开(公告)号：US07199261B2
公开(公告)日：2007-04-03
申请号：US10481704
申请日：2002-07-02
申请人： Reinhold Öhrlein , Gabriele Baisch , Hans Jürg Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
发明人： Reinhold Öhrlein , Gabriele Baisch , Hans Jürg Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
IPC分类号： C07C229/00
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and Rb is a carboxy-protecting group, which methods are carried out by conversion of the intermediate of formula XIX wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group, and Rb is a carboxy-protective group
摘要翻译：本发明涉及用于制备适于制备他汀类衍生物的中间体的新型合成方法，特别涉及式VI中间体的新型合成方法，其中R a a， C 1各自独立地为另一个氢或羟基保护基团，或者一起是桥接羟基保护基团，并且R b是羧基保护基团，该方法进行通过其中R a a和R c C分别独立于另一个氢或羟基保护基的式XIX的中间体的转化，并且R b' SUB>是羧基保护基

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